Man8 PDF
Man8 PDF
Man8 PDF
SABITA MANUAL 8
2nd Edition
December 2003
Published by
Sabita
Postnet Suite 56
Private Bag X21
Howard Place 7450
Training Guides
TRIP
HMA
HSE
CEP
Technical Guideslines
TG1
TG2
Bitumen Emulsion
AV-4
AV-5
AV-6
AV-7
Hot-mix Asphalt
AV-8
AV-9
AV-I0
AV-11
AV-12
Bitumen Rubber
AV-13
AV-14
AV-15
Manufacture
Paving
Compaction
3
ACKNOWLEDGMENTS
Sabita gratefully acknowledges the valuable contribution of the
members of the Road Pavements Forum (RPF) Binder Distributor
Task Team in compiling this guideline document for the industry.
The Task Team consists of:
Trevor Distin (Chairman)
Colas SA
Wally Bennett
Douglas Judd
KZN DoT
WSP SA Civil and Structural
Engineers
Vela VKE Consulting Engineers
Power Construction Roads
Gautrans
Colas SA
Black Top Surfaces
SANRAL
Tosas
Spray Pave
Simon Kotze
Philip Khn
Theuns Lewis
Kobus Louw
Gerry Reitsma
Dennis Rossmann
Denzil Sadler
Steven Single
Preface
The scope of this manual on health, safety and environmental
aspects, which replaces Sabitas Manual 8: Bitumen Safety
Handbook, has been updated in accordance with current legislation
and extended to incorporate international best practice in respect of
worker safety and health, as well as environmental conservation.
As it is now globally accepted that the use of coal tar products as
binders for road construction may introduce undue health and
environmental hazards, their use is no longer considered best
practice. Sabita therefore does not endorse their application, and
reference to this material is excluded from this document.
Note that, in accordance with global nomenclature, the term
bituminous refers exclusively to binders and mixtures of binders
and aggregate containing bitumen. The term does not include tar
products produced by the pyrolysis of coal.
This new edition has been further expanded to include all aspects
involving the Safety, Health, Environmental, Risk and Quality
(SHERQ) requirements related to the manufacture and application of
bituminous binders.
In general, the structure of the document is based on the concept of
listing hazards associated with various operations in the handling of
bituminous products, and offers precautionary procedures to
minimise the risk of exposure to such hazards.
The document is intended as a reference and training manual for all
persons involved in the handling, storage and transportation of
bituminous binders used in road construction. It should be read in
conjunction with instructions issued by site supervisors, and with
those of plant operating manuals, all of which should be observed
by users of bituminous binders. The standards of worker health,
safety and environmental conservation are constantly under review
in the bituminous products industry as the state of knowledge
increases. This guideline reflects the state of knowledge and
SHERQ procedures applicable at the time of publishing.
Contents
1.
INTRODUCTION
11
2.
HAZARDS
2.1 Material Safety Data Sheets (MSDS)
2.2 Hazards from high temperatures
2.3 Hazards from the flammable nature of the product
2.4 Hazards from noxious vapours
12
12
12
13
15
3.
PERSONAL PROTECTION
3.1 Prevention of contact
3.2 Personal Protection Equipment (PPE)
3.3 Personal hazards
3.4 Personal hygiene
17
17
17
19
19
4.
FIRST AID
4.1 Treatment of burns
4.2 Eye burns
4.3 Circumferential burns
4.4 Mouth-to-mouth resuscitation
4.5 Basic steps for mouth-to-mouth resuscitation
4.6 First Aid Kit
4.7 Cardio-pulmonary resuscitation
21
21
22
22
22
23
24
25
5.
HEALTH ASPECTS
5.1 Bitumen
5.2 Cutback bitumen
5.3 Modified bitumen
5.4 Aromatic oils
5.5 Bitumen additives
26
26
26
27
27
27
6.
PRECAUTIONS
6.1 Fire prevention
6.2 Fire protection preparation
6.3 Types of fires
6.4 Fire-fighting
6.5 Fire-fighting equipment
28
28
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28
30
32
7.
ENVIRONMENTAL ASPECTS
7.1 Transporting and storage of bituminous binders
7.2 Application of bituminous products on site
7.3 Spillages
7.4 Flushing procedures
7.5 Disposal procedures
33
33
36
37
38
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8.
LEGAL RESPONSIBILITIES
8.1 Duties and responsibilities
8.2 Vehicles and transportation
8.3 Accidents/Incidents
8.4 Product handling
8.5 Environment
8.6 Risk Management
39
39
39
40
40
40
41
9.
PROCEDURES
9.1 Care of equipment
9.2 Equipment checks
9.3 Product handling and sampling
9.4 Heating
9.5 Loading and offloading
9.6 Transportation
9.7 Blending
9.8 Loading of different products
9.9 Storage and storage temperatures
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45
47
50
50
51
52
10.
TRAINING
54
11.
GLOSSARY
55
APPENDICES
1.
2.
3.
4.
5.
10
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60
62
63
65
66
67
1. INTRODUCTION
Worker health and safety, from both physical and chemical hazards,
should be assured at all times. This manual considers the hazards to
which workers handling bituminous binders may be exposed, and
the risks associated with these hazards including various aspects
of personal safety, precautions to be taken when working with
bituminous binders, health aspects and environmental
considerations.
The European Inventory of Existing Commercial Chemical
Substances (EINECS) makes specific reference to the concepts of
hazard and risk:
Hazard
Risk
11
2. HAZARDS
2.1 Material Safety Data Sheets (MSDS)
The suppliers remain responsible for drawing up material safety
data sheets (MSDS) for each product according to the
regulations for hazardous chemical substances.
However, the following environmental compatibility
guidelines should be observed:
The suppliers MSDS is the primary source of safe handling
advice for the specific product;
The MSDS should address the safety of both personnel and
the physical environment;
The MSDS should provide an indication of each class of fumes
that may be generated at application temperatures;
The supplier will be liable for the consequences of negligently
incorrect information or deliberate omission of known facts;
The user is liable for the consequences of the incorrect use of
application techniques;
The user has an overriding responsibility to ensure that work
practices minimise exposure to fumes and contact with
product.
Note
Always wear the required Personal Protection Equipment
(PPE), including overalls, heat resistant gloves, face shield
and safety boots when working with bitumen.
12
Note
The temperature of bitumen in storage is normally above the
boiling point of water. Water should not be allowed to
contact hot bitumen as this will cause boil-over and
possible fire or explosion.
13
Figure 1: Keep any source of ignition away from potential fire sources.
Note also that in the region where escaping vapour starts to mix with
air, extreme care should be exercised, since this is where the
mixture may become explosive. Further away from an exit, the
vapour will be too dilute to ignite.
It is important that the precautions and instructions contained in this
manual be strictly observed to prevent vapours igniting.
It is necessary to isolate any source of ignition in areas where there
is likely to be a concentration of flammable vapours, e.g. in the
proximity of loose or open manhole covers, and at the ends of
hoses.
Smoking, naked lights or the use of cell phones is not permitted
within 15 m of any vehicle when filling or circulating bitumen or
changing LPG bottles. Gas burners must be fitted with safety
nozzles.
Cutback bitumen will readily ignite or explode in the presence of a
flame, spark or hot object. Fire or explosion can occur if LPG
burners are used to heat pipelines or pumps when handling cutback
bitumen.
The application of excess heat (e.g. welding torch) to bitumen can
cause thermal cracking and the evolution of flammable vapour.
Open flame heating may only be used to free plugged bitumen
valves as a last resort, and the vehicle must be in a clear area.
14
Note
Safety precautions must be followed to prevent fumes from
flammable products coming into contact with sources of
ignition!
Avoid use of open flames or sparks near flammable
product;
Do not smoke or use cell phones within 15m of
flammable product;
Do not heat products above the recommended
temperatures;
Fumes must blow downwind from gas burners.
15
Note
Fumes may be toxic:
Locate equipment and plant operations so that odours
and other irritations to workers and the public are
minimised;
Wear appropriate respiratory protection equipment when
working in poorly ventilated spaces;
Provide first aid to workers affected by fumes;
Follow procedures given in Material Safety Data Sheets
(MSDS);
Dont breathe fumes from open hatches, vents, etc.
16
3. PERSONAL PROTECTION
3.1 Prevention of contact
Operations for the movement or transfer of bitumen should be in
closed and controlled systems.
Repairs to cold bitumen equipment may involve skin contact with
cold bitumen, emulsions or cutbacks. In these instances, oil
insoluble barrier creams may be applied to exposed parts of the skin
prior to working with the bitumen. The skin should be thoroughly
washed after being exposed to contact with bitumen or after
completion of the work. Petrol or solvents must not be used to clean
exposed parts of the skin as this can cause dermatitis.
Note
It is stressed that barrier creams are not a substitute for
protective clothing and gloves.
17
When spraying, a
sprayer operator
must also wear
protective gloves,
overalls and
appropriate safety
vests for visibility. A
respirator is also
required when
spraying cutbacks
or modified binders.
Figure 4: Wear full protective clothing
Note
Polyester and other combustible materials, which can melt
and stick to the skin, must not be used for protective
18
19
20
4 First Aid
First Aid can be defined as the initial preservation of life and the
preliminary management of pain and injury until formal medical
attention or treatment can be obtained. First Aid is not a substitute
for prompt and appropriate medical attention or treatment. Adequate
numbers of people trained in First Aid must be on site during
hazardous operations. It is recommended that each driver/operator
be trained to at least Level 1.
Suitable contents of a first aid kit are listen in Appendix 1.
Appendix 2 covers guidance notes for first aid and medical
personnel. The content of this guideline is also contained in a
Bitumen Burns tag, five copies of which are packed in the sleeve
inside the back cover of this manual. The tag should be tied or
pinned onto the clothing of the patient before transport to a medical
facility.
21
22
23
Detailed procedure
Place the patient on his back. Open the mouth and check for any
obstructions.
If obstructed, turn the patient onto his side and clear the airway
using your fingers (wearing disposable gloves), then place the
patient on his back.
Tilt the patients head backwards by placing the hand high on the
forehead. At the same time, support the chin with the thumb and
index finger of the other hand. Lift the jaw forward and support whilst
opening the patients mouth slightly. Keep the tongue clear of the
airway, and check for breathing. If the patient is not breathing
proceed as follows:
1. Pinch the patients nostrils closed between your thumb and
forefinger, keeping the head tilted back. Open your mouth and
take a deep breath;
2. Cover the patients mouth with your mouth (if possible, insert a
device to prevent direct skin contact) making an airtight seal.
Blow into the mouth to inflate the lungs;
3. Look to see whether the patients chest rises. The rise of the
chest should be similar to that of normal breathing. Listen for the
air to be expelled;
4. Place your mouth back over the patients mouth and give four
full breaths quickly, checking the chest between inflations;
5. Check whether the carotid pulse is present. If it is, this means
the heart is beating and circulation is functioning. Continue with
mouth-to-mouth resuscitation one breath every three
seconds. Check the carotid pulse and breathing after one
minute and every two minutes thereafter.
24
ASSESS CASUALTY
FOR CIRCULATION
Interlock fingers
25
5.
HEALTH ASPECTS
5.1 Bitumen
The question of the potential adverse effects of the use of bitumen
on health and the environment is the subject of ongoing research in
Europe and the United States.
Generally, it may be stated that the health risk from working with
bitumen increases with the temperature of the product, the principal
hazards being burns or inhalation of fumes. The greatest risk, by far,
is burning of the skin.
Some agencies, particularly in the US, have raised the issue of the
potentially harmful effects of very low concentrations of Polycyclic
Aromatic Hydrocarbons (PAHs) in fumes. PAHs occur in crude oils
but are present in lesser quantities in bitumens. These PAHs are
considered carcinogenic. The concentration of PAHs in bitumen
fumes at normal road application temperatures is extremely low and
no studies to date have demonstrated any significant health risk to
workers exposed to these fumes.
At very high temperatures (2300C) not normally associated with road
building, or with the addition of solvents, cutters or aromatic oils, the
exposure to volatiles is increased. The specific exposure conditions
would relate to the type of additive being used, its composition and
the conditions of the working area itself. Information on the handling
conditions for these additive products must be obtained from the
suppliers.
The principal routes of worker exposure are through inhalation and
skin contact. Worker exposure depends on: PAH emission rate,
operator behaviour, protective measures taken, working conditions
and influences from outside, such as weather.
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27
6 PRECAUTIONS
6.1 Fire prevention
A disorderly or dirty workplace can introduce its own hazards in
addition to those associated with bituminous products and their
handling. Good housekeeping is the first principle of fire prevention:
Keep all areas clear of non-essential equipment and materials;
Store and handle flammable liquids carefully, in accordance
with regulations;
Install an adequate number of the right type of fire
extinguishers;
Keep fire extinguishers in good working order;
Keep all equipment clean;
Ensure that all equipment is in its assigned place and that no
loose or unnecessary tools are left lying about in the
workplace.
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29
6.4 Fire-fighting
What to do when a fire starts:
If the fire gets too large or fierce, and the extinguishers become
ineffective, leave the area.
Once the methods used to extinguish the fire have succeeded,
immediately cover the burnt area with sand and if practical, hose
down with water. This will help to keep out the oxygen and cool it
down, preventing re-ignition.
6.4.1 Fire Extinguishers
There are four main classes of fire extinguishers in general use.
1. Water extinguisher;
2. Carbon dioxide extinguisher;
3. Dry chemical powder extinguisher;
4. Vaporising liquid extinguisher.
Three basic ways of extinguishing a fire:
6.4.2 Quenching
Water is used to cool the surface of the fuels to a temperature
below the flash point of the particular fuel. Fuels with a low
flashpoint (petrol) cannot be cooled sufficiently with water to stop
the formation of vapours.
Precautions
Water must not be used when fighting a fire in a bitumen
tank. However, a water spray may be used to cool adjacent,
intact tanks.
30
6.4.3 Smothering
The fire is deprived of the oxygen needed to burn. CO2 or foam
cuts off the air supply.
6.4.4 Starving
This is achieved by shutting off the supply of fuel to the fire.
Bitumen fires
Foam for extinguishing a bitumen tank fire should be gradually
spread as a blanket over the surface of the burning liquid. This may
be done by directing it against part of the tank or other obstruction.
Indiscriminate application of foam will not extinguish the fire.
The fire may re-ignite when dry powder or CO2 extinguishers have
been used. It is recommended that this treatment be followed by a
foam application.
Tyre Fires
With moving vehicles, there is always a danger of tyre fires. These
fires often re-ignite and need application of foam or water to cool the
rubber as dry powder and CO2 extinguishers will not be effective.
Note
When high-pressure water is available, such as in a refinery,
water may be used, provided it is applied in the form of a
fine spray through fog or diffuser nozzles.
Remember
Once the fire is out, re-ignition can be prevented if the
following procedures are carried out.
Class A fires Use water to cool burn areas or smother
with sand.
Class B fires Smother burn area with sand or gravel to
exclude oxygen and then cool down the
equipment with water, if necessary.
Class C fires Cut off power.
31
Wind direction
32
7. ENVIRONMENTAL ASPECTS
Legislation has become stricter regarding the protection and
preservation of the environment. Preventative measures must be in
place where bituminous binders and vehicles carrying such
products can cause damage to the environment.
The viscous nature of most penetration grade binders ensures that
direct contact with the environment results in minimal contamination.
Volatile materials are released in very small amounts on heating
and, under normal use and storage, pose negligible threat to the
environment. Cutback bitumens and bitumen emulsions have the
potential to cause significant pollution to the environment.
There is at present no evidence to suggest that long-term emissions
into the atmosphere have any significant detrimental effect.
Precautions
Prevent spillage of bituminous materials and oils;
Prevent seepage of washing and flushing materials into
water sources; and
Remove all surplus and/or contaminated materials from
site and dispose of them in an environmentally
acceptable manner. This includes products used for
flushing purposes.
33
Transport and application vehicles often operate far from base, thus
pre-departure vehicle inspections are essential to minimise incidents
on site, and to ensure that the driver is adequately equipped and
trained to deal with any incident.
Over and above the checklist, specific focus can also be directed to
the following:
1. In the cab
In terms of current legislation all relevant documents related to
the delivery must be stored in an orange coloured box, affixed
in a conspicuous position. The contents must include MSDS,
route plan, tremcards, licenses and permits, dangerous goods
transportation documents, suppliers commercial documentation, PDPDG license and any relevant medical documentation;
No loose items of any nature may be left lying around. All
items must be secured, e.g. bedding, items of clothing,
refreshments, etc.;
All windscreens and windows to be clean with no unnecessary
stickers obscuring the drivers view;
First aid kit to be readily accessible.
2. Spray vehicle
All equipment must be stored in designated secured places;
Fire extinguishers, emergency water (25 litre) and toolboxes
must be secured in such a way that easy access is possible;
Spray bars must be covered when lifted, and the covers must
have designated storage positions when the bars are down
and the vehicle is spraying;
All flexible discharge hoses must be affixed in designated
positions. Ensure the hoses have been emptied before
uncoupling;
All working platforms must be kept clean and clear of
toolboxes, solvents, cleaning material, tins and rags;
Hand rails and steps of all ladders must be clean and dry;
All gauges must be clean and readable;
All flanges, nozzles and pumps must be maintained to prevent
spillage. However, where circumstances prevent this, drip
trays must be used;
34
Spillage procedure
Should spillage occur during transit, the driver must stop
and call for help. The driver must then put on his PPE,
assess the situation, and if safe, use a shovel to contain and
divert the product from any nearby sensitive environmental
areas until support arrives.
Note
Any form of malfunction of valves is to be reported to
maintenance for immediate repair or replacement;
During long trips the driver should stop periodically to
do necessary in-transit vehicle inspections (every two
hours).
35
Arrival on site
On arrival, the driver must request permission to stop in a
designated area where he may carry out his pre-spray checks. This
area is to be left in the same condition of cleanliness as it was prior
to his arrival.
Temporary storage of bituminous products on construction sites
To prevent pollution, the establishment of static tanks on sites must
be planned properly.
Consideration must be given to:
36
7.3 Spillages
Spillages must be avoided wherever possible. However, should they
occur, they must be cleaned up immediately and the waste product
stored for safe transport to the depot, after which it may be disposed
of at a classified waste dump for hazardous chemical substances.
Where spillage occurs, appropriate containment measures must be
taken depending upon the quantity involved. Small spillages will
cool rapidly, and should not spread to any significant distance.
Spills can be impounded with sand, earth, sawdust or specifically
designed impounding and absorbing agents. Sources of ignition
should be eliminated. Spilled binder may be reclaimed for
reprocessing or removed for disposal at an approved landfill site
(refer local government authority).
Bund walls must be erected around permanent storage installations.
On-site arrangements must be in place to limit the risk of spillages,
and to limit the extent of such spillages where they do occur.
If bituminous binders or petroleum solvents enter stormwater
channels or sewers, the authorities must be notified immediately.
37
Note
Waste must be handled as detailed in 7.5 below.
Note
The National Environmental Management Act 107 of 1998
will hold the polluter accountable for any incident where
environmental degradation has occurred.
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8. LEGAL RESPONSIBILITIES
The following are some of the important requirements of current
legislation:
8.3 Accidents/Incidents
All accidents and incidents must be reported to the employer and
relevant authorities as soon as possible after the event. All accidents
must be properly investigated and findings documented.
8.5 Environment
Everybody has the right to a clean, healthy, harmless and safe
environment which requires that the environment be kept as
clean as is reasonably practical in terms of current best practice.
This requires that everybody concerned take care to prevent
pollution of any kind. Spills must be stopped at source as soon as
possible. In the case of major spills the authorities concerned must
be notified at once. Disposal of waste must take place only at
approved dumping sites.
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9. PROCEDURES
9.1 Care of equipment
All bitumen equipment must be kept in good condition at all times.
Hoses, fittings and threads in particular should be thoroughly
cleaned after each delivery or transfer. Product lines, hand sprays,
pumps, valves and hoses should be flushed after use to avoid
bitumen slugs. Bitumen slugs blocking partially closed valves or
leaking hoses may remain undetected until the bitumen is too hot to
approach with safety.
Flexible hoses should be used under suction rather than under
pressure.
Hose assemblies should be inspected regularly for defects or holes.
Defective hoses and fittings must be withdrawn and destroyed.
Hose assemblies should be stored flat in such a way as to ensure
that no residual binder is left in the line.
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43
44
9.4 Heating
Bituminous material must be at least 200mm above heating flues.
Parking of vehicles on sloping ground may cause heating flues to
become uncovered and therefore dangerous during heating. When
discharging a tank, burners must be turned off.
Important notice
Heating flues should be designed such that:
The flues do not pass through the vapour space above
the product;
The surface temperature will not exceed 350 C on any
part of the heating flue;
The flame tube insert can be easily removed for service
or replacement;
The inlet or exhaust flues will not be closer than 1.5m
horizontally from any manhole or vent pipe;
The flues are not in direct contact with the tank.
45
Precautions
Do not leave the tanker unattended when burners are
on;
Position the tanker so that the wind will carry vapours
away from the burners;
Do not stand on top of the tank during heating;
Discharge product from the tanker only when the
burners have been turned off;
Only heat product if heating flues are covered by at
least 200mm;
Do not use burners if any heating equipment has fuel
leaks;
Do not stand directly behind burners when lighting or
adjusting;
Do not store open solvent or fuel containers near
heating operation. Do not smoke or use cell phones
during the heating operation.
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47
Note
Ensure that there is no water in the tank prior to loading as
this will cause a violent explosion, frothing and boiling over.
Before loading heated bitumen a check must be carried out to
ensure that the receiving tank is free of water or volatile liquid.
During loading no source of ignition should be allowed in the vicinity
of the receiving tank.
Earthing the vehicle to eliminate the accumulation of electrostatic
charge is necessary during the loading or offloading of cutback
bitumen e.g. MC30. This is done by making sure that the metal of
the loading pipe is in electrical contact with the metal at the manhole
by means of an earth cable. The simple act of a material flowing
through a pipe or hose may generate sufficient static electricity to
cause a spark when connecting/disconnecting hoses unless there is
a continuous connection.
Ullage of at least 10% should be left after loading to allow for
expansion resulting from any subsequent heating.
After completing the transfer of materials check that the valves on
both the supply and receiving units are closed and the bitumen
pump is turned off.
48
Carefully undo the hose. The bottom must first be loosened slightly.
A small amount of material may run out of the hose coupling into a
drip tray, indicating that it is empty, that there is no pressure, and
that it is safe to remove. If there is a large amount of material, or
residual pressure in the hose, possibly due to a valve not having
closed properly, this procedure will ensure that the product squirts
onto the ground rather than into the operators face or over his
body.
Keep the free end of the hose clear of the ground to avoid dirt,
stones etc. lodging in the hose. There are special hose chairs
available to plug and hold the end clear off the ground. Common
practice is to turn the end of the hose up and over so that it will
remain in that position. This procedure will also prevent entry of
rainwater into the hose. Failure to do this could cause a dangerous
boil-over of hot material loaded next into the tank.
After loading, empty the pump lines by sucking back into the tank.
On completion of discharge, pump, pipelines and hoses must be
flushed out with paraffin or diesel and cleared of product. Hose
couplings must also be thoroughly cleaned. Flushings must be
collected for re-use or disposal in accordance with statutory
requirements and best practice procedures (refer to section 7.5).
The manhole cover must be securely fastened.
In the event of any spillage of bitumen during delivery or transfer
(such as by hose failure or tank overflows), all valves should be
closed, hoses disconnected, all caps screwed down and the
customer or his representative informed of the spillage. The area
should be cleaned and authorities must be informed so that they
can certify that the site has been restored to its former condition.
Note
After the unloading of cutback bitumen that has been heated
to spraying temperatures, the tank will contain a gas/air
mixture that may be in the explosive range. This is the time
when the product is most dangerous. All sources of ignition
and heat must be prevented from coming into contact with
this explosive mixture.
49
9.6 Transportation
In addition to compliance with legislation in terms of the
transportation of bituminous binders, road rules and the
roadworthiness of the vehicle, the following requirements must be
considered during the transportation phase:
Cleanliness of the vehicle and visibility of hazard identification
signs;
Equipment checks before and after loading and unloading;
Proper closing of valves and covers, including gas supply
valves and manhole covers;
Fire extinguishers fitted and a stocked first aid kit to be on
hand;
Condition of tyres in compliance with the legal requirements
and tyre pressures to meet the manufacturers specification;
Adequate supply of PPE, including high visibility clothing and
a flashing light on the vehicle.
9.7 Blending
Cutting back hot binders
On-site cutting back of hot binders with volatile solvents is
undesirable and is not recommended, either from quality or safety
perspectives. Best practice dictates that all blending operations
using cutters be carried out at fixed facilities under controlled
conditions with the recommended safety and quality measures in
place.
Blending of modified binders
Blending of polymer modified binders and bitumen rubber must only
be conducted in tanks and blending units designed for this purpose
and must be carried out in accordance with suppliers method
statements. Due to the limited shelf life of some modified binders
such as bitumen rubber, the blending of these materials must be
done on site. The digestion of rubber in hot bitumen could cause an
increase of 1025% in volume. Sufficient ullage must be allowed for
this increase to avoid boil over.
The addition of rubber crumb to a blending tank should be done by
mechanical means that is earthed to prevent the build-up of static
electricity.
50
Polymers and rubber crumb must be stored in a dry place and away from
any source of heat.
Adhesion agents should only be added to binders shortly before spraying
unless they are temperature storage stable. The contents must be
circulated for 15 minutes before spraying. Gloves and eye protection must
be worn and care should be taken to avoid inhalation of fumes.
When mixing water with emulsions, always add water to the emulsion and
not emulsion to water. Compatibility with water should be established
before dilution.
51
52
Short Term
Handling
Storage
Max.
Spraying
Temp
(0C)
Max.
Temp
(0C)
Max.
Holding
time
(hrs)
Max.
Temp
(0C)
Max.
Holding
Time (hrs)
80/100
180
24
130
240
190
150/200
170
24
120
240
180
MC30
65
24
30
240
65
MC70
80
24
50
240
80
MC800
110
24
60
240
130
MC3000
130
24
90
240
155
Emulsions
(not mod)
80
24
50
240+
80
S-E1; S-E2
180
24
150
24-
200
C-E1
160
23
140
240
SC-E1;
SC-E2
70
24
Ambient
240+
80
CC-E1
Ambient
240+
Ambient
240+
S-R1
165
24
140
72
210
53
10. TRAINING
All personnel involved in the handling, storage, blending or spraying
of bituminous binders must receive training in the safe handling of
these products and the relevant legal requirements.
Drivers and operators involved with the handling, storage or
transportation of hot binders must be fully trained in the treatment of
bitumen burns caused by contact with hot bitumen.
Personnel shall receive training in the correct procedures for:
54
11. GLOSSARY
Additive:
Adhesion agent:
Anti-foaming liquid:
Barrier cream:
Bitumen:
Bitumen emulsion:
Bituminous binder:
Boil over:
Bund wall:
Carcinogenic:
Combustible:
Cutback bitumen:
Cutter:
Extender oil:
Flammable:
Flammable limits/
range:
Flash Off:
Flash Point:
Foam:
56
Gas Free:
Hazard:
Heating flues:
Hot Work:
IBP:
Ignition temperature:
Naked flame:
Risk:
Self ignition:
Self ignition temp.:
Source of ignition:
Tremcard:
Ullage:
57
Viscosity:
Volatile solvents:
58
APPENDIX 1
CONTENTS OF FIRST AID KIT
The items below can be ordered from most pharmacists or
suppliers.
Antiseptic solution
Antiseptic ointment
Assorted packs of sterile burn dressing
Cotton buds
CPR mouthpiece
Elastic bandages
Eye pads
Eye shields
Gauze swabs
Instant cold pack
Latex gloves
Micropore tape
Non-adhesive burn dressing for open burns
Rescue sheet
Safety pins
Scissors
Sterile eye irrigation solution
Triangular bandages
Tweezers
No. 3 wound dressing
No. 5 wound dressing
Burnshield & burnshield liquid
A 25 litre container of water (minimum) should be kept with the
safety box for cooling down the patients burnt section.
59
APPENDIX 2
TREATMENT OF BITUMEN BURNS
Notes for the guidance of first aid and medical personnel
All persons working with hot bitumen should be familiar with these
recommendations in order to administer first aid to burn victims. A
burns tag (in the pocket at the back of this manual) should
accompany the patient and be placed in a prominent position before
the patient is transported to a doctor or hospital.
NO ATTEMPT SHOULD BE MADE TO REMOVE THE BITUMEN
FROM THE BURNED AREA AT THE WORKSITE!
FIRST AID
If hot bitumen contacts the skin, the affected area should be
cooled immediately by drenching in cold preferably running
water for at least five minutes;
The cooling treatment should be continued until the bitumen
has cooled and hardened;
No attempt should be made to remove the bitumen from
the burned area.
Further treatment - first aid and medical care
The bitumen layer will be firmly attached to the skin, and
removal should NOT be attempted except at a medical facility
under the supervision of a doctor. The cold bitumen will form a
waterproof, sterile layer over the burn which will prevent the
burn from drying out. If the bitumen is removed from the
wound there is a possibility of complications.
The bitumen should be left in place and covered with tulle
dressing containing, or soaked in, liquid paraffin.
Petrolatum-based antibiotic ointments or petroleum jelly may
be used. The dressing should be changed daily, at which time
any emulsified bitumen can be gently removed.
The degree and extent of burns, and the general condition of
the patient, will dictate when transfer to a specialised burns
unit is indicated.
60
Circumferential burns
When hot bitumen completely encircles a limb or other body
part, the cooled and hardened bitumen may have a tourniquet
effect. The bitumen should be softened as described above
and the patient referred urgently for specialised medical
attention.
Eye burns
If hot bitumen enters an eye, it should be flushed with water
until the bitumen has cooled. No attempt should be made by
unqualified personnel to remove the bitumen. The patient
should be referred urgently for specialised medical
assessment and treatment.
61
APPENDIX 3
EMERGENCY TELEPHONE NUMBERS
Doctor
Ambulance
Fire Brigade
Police
Bitumen Supplier
Burns Unit/
Medical Centre
Others
Doctor
Ambulance
Fire Brigade
Police
Bitumen Supplier
Burns Unit/
Medical Centre
Others
Doctor
Ambulance
Fire Brigade
Police
Bitumen Supplier
Burns Unit/
Medical Centre
Others
62
Potential
hazards
(b)
List all the
potential
hazards.
(What are
the most
likely
injuries
that could
result from
the
activity?)
Activity
(a)
The task
or activity
being
perfor
med
List those
persons
who could
be at risk
from this
activity.
(c)
Persons at
risk
What
control
measures
are already
in place to
reduce the
risk?
(d)
Current
controls
63
The risk
rating from
the Risk
Assessment
Matrix (i.e.
H, M or L).
(e)
Risk rating
If the risk
rating in
the
previous
column (e)
is H or M,
then list
additional
controls
required to
further
reduce the
risk.
(f)
Further
controls to
minimise
risk
(if reqd.)
Only L is
acceptable.
This is the
risk
remaining
after the
further
controls
listed in
column (f).
(g)
Residual
risk
If further
controls
are
required
then a
review date
must be
agreed.
(h)
Review
date
APPENDIX 4
L
M
M
Minor injury
Serious injury
Fatality
Not likely to
occur
Possibility of
occurring at
some time
PROBABILITY
Possibility of
isolated
incidents
Possibility of
repeated
incidents
64
Extremely
unlikely
Slight injury or
less
Consequence
or Severity
APPENDIX 5
Item
Quantity
Equipment
Emergency triangle
Fire extinguisher
Water
25 litre
Documentation
Public Driving Permit for Dangerous Goods
Tremcard
Material Safety Data Sheet
Roadworthy certificate
Medical certificate
Drivers Workmans Compensation Act number
65
APPENDIX 6
TRANSPORT EMERGENCY CARD (TREMCARD)
CARGO:
MC 30 CUTBACK BITUMEN
BLACK BITUMINOUS PRODUCT
UN NO: 1999
NATURE OF HAZARD:
Highly flammable;
Product may adhere to the skin and cause burns;
Fumes may cause eye and skin irritation, respiratory irritation,
dizziness and nausea.
Keep upwind;
Notify emergency services.
SPILLAGE:
FIRE:
Extinguish with dry foam, powder or fine water spray;
Sand or earth may be used for small fires.
FIRST AID:
Remove to fresh air;
In case of contact with hot material immediately flush skin (or eyes)
with large amounts of cold water. Do not remove material from skin.
66
APPENDIX 7
FLAMMABILITY OF CUTBACKS
To understand why the hazards arising from the flammable nature of
bitumen cutbacks and their components are variable, parameters
used to define some of the properties relating to combustion are
provided below.
< 40
Illumination paraffin
38 40
Diesel
63 90
Bitumen*
290 310
67
300
100
85
10
65
20
50
30
40
500
Petrol
400
Diesel
335
Illumination paraffin
255
68
1.5 6
Illuminating paraffin
16
69
70
NOTES
71
NOTES
72