TECHNICAL SPECIFICATION

STAINLESS STEEL PLATE

(AMENDMENTS/SUPPLEMENTS TO ASTM A 240)

MESC SPE 76/222

December 2012
(Including Technical Errata To September 2012 Revision)

MESC SPECIFICATION DOCUMENT

This document is restricted. Neither the whole nor any part of this document may be disclosed to any third party without the prior written consent of Shell Global
Solutions International B.V., The Netherlands. The copyright of this document is vested in this company. All rights reserved. Neither the whole nor any part of this
document may be reproduced, stored in any retrieval system or transmitted in any form or by any means (electronic, mechanical, reprographic, recording or otherwise)
without the prior written consent of the copyright owner.

MESC SPE 76/222

December 2012
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PREFACE
MESC (Materials and Equipment Standards and Code) SPE documents reflect the views, at the time of publication, of:
Shell Global Solutions International B.V. (Shell GSI)
and/or
Shell International Exploration and Production B.V. (SIEP)
and/or
other Shell Service Companies.
They are based on the experience acquired during their involvement with the design, construction, operation and
maintenance of processing units and facilities, and they are supplemented with the experience of Shell Operating Units.
Where appropriate they are based on, or reference is made to, international, regional, national and industry standards.
The objective is to set the recommended standard for good design and engineering practice applied by Shell companies
operating an oil refinery, gas handling installation, chemical plant, oil and gas production facility, or any other such
facility, and thereby to achieve maximum technical and economic benefit from standardization.
The information set forth in these publications is provided to Shell companies for their consideration and decision to
implement. This is of particular importance where MESC SPEs may not cover every requirement or diversity of condition
at each locality. The system of MESC SPEs is expected to be sufficiently flexible to allow individual Operating Units to
adapt the information set forth in MESC SPEs to their own environment and requirements.
When Contractors or Manufacturers/Suppliers use MESC SPEs they shall be solely responsible for the quality of work
and the attainment of the required design and engineering standards. In particular, for those requirements not
specifically covered, the Principal will expect them to follow those practices, which will achieve the same level of
integrity as reflected in the MESC SPEs. If in doubt, the Contractor or Manufacturer/Supplier shall, without detracting
from his own responsibility, consult the Principal or its technical advisor.
The right to use MESC SPEs is granted by Shell GSI, in most cases under Service Agreements primarily with Shell
companies and other companies receiving technical advice and services from Shell GSI or another Shell Service
Company. Consequently, three categories of users of MESC SPEs can be distinguished:
1)

Operating Units having a Service Agreement with Shell GSI or other Shell Service Company. The use of MESC
SPEs by these Operating Units is subject in all respects to the terms and conditions of the relevant Service
Agreement.

2)

Other parties who are authorized to use MESC SPEs subject to appropriate contractual arrangements (whether
as part of a Service Agreement or otherwise).

3)

Contractors/subcontractors and Manufacturers/Suppliers under a contract with users referred to under 1) or 2)

which requires that tenders for projects, materials supplied or - generally - work performed on behalf of the said
users comply with the relevant standards.

Subject to any particular terms and conditions as may be set forth in specific agreements with users, Shell GSI
disclaims any liability of whatsoever nature for any damage (including injury or death) suffered by any company or
person whomsoever as a result of or in connection with the use, application or implementation of any MESC SPE,
combination of MESC SPEs or any part thereof, even if it is wholly or partly caused by negligence on the part of Shell
GSI or other Shell Service Company. The benefit of this disclaimer shall inure in all respects to Shell GSI and/or any
Shell Service Company, or companies affiliated to these companies, that may issue MESC SPEs or require the use of
MESC SPEs.
Without prejudice to any specific terms in respect of confidentiality under relevant contractual arrangements, MESC
SPEs shall not, without the prior written consent of Shell GSI, be disclosed by users to any company or person
whomsoever and the MESC SPEs shall be used exclusively for the purpose for which they have been provided to the
user. They shall be returned after use, including any copies, which shall only be made by users with the express prior
written consent of Shell GSI. The copyright of MESC SPEs vests in Shell GSI. Users shall arrange for MESC SPEs to
be held in safe custody and Shell GSI may at any time require information satisfactory to them in order to ascertain how
users implement this requirement.
All administrative queries should be directed to the MESC SPE Administrator in Shell GSI.

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TABLE OF CONTENTS
PART I
1.1
1.2
1.3
1.4
1.5

INTRODUCTION.................................................................................................... 4
SCOPE .................................................................................................................. 4
DISTRIBUTION, INTENDED USE AND REGULATORY CONSIDERATIONS......... 4
DEFINITIONS ........................................................................................................ 4
CHANGES SINCE PREVIOUS EDITION................................................................ 4
COMMENTS ON THIS MESC SPE ........................................................................ 5

PART II

AMENDMENTS/SUPPLEMENTS TO ASTM A 240:12............................................ 6

PART III

REFERENCES..................................................................................................... 10

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PART I INTRODUCTION
1.1

SCOPE
This MESC SPE specifies requirements for stainless steel plate.
This specification shall apply in addition to the applicable MESC Buying Description,
purchase order or requisition sheet.
This specification only applies to alloy steel plate for spectacle blinds, spades and spacers
and applies to ASTM A 240, Grades TP304, TP304L, TP304H, TP316, TP321, TP347,
UNS S31254, N08367, S31803, S32550, S32750 and S32760.
This specification is written as amendments and supplements to ASTM A 240:12, which are
covered in Part II of this MESC SPE. The clause numbering of ASTM A 240:12 has been
retained and any amendments are identified as Add, Modify to read or Delete. Any
clauses of ASTM A 240:12 that are not amended or supplemented by this MESC SPE,
shall apply as written.

1.2

DISTRIBUTION, INTENDED USE AND REGULATORY CONSIDERATIONS

Unless otherwise authorised by Shell GSI, the distribution of this MESC SPE is confined to
Shell companies and, where necessary, to Contractors and Manufacturers/Suppliers
nominated by them.
This MESC SPE is intended for use in oil refineries, chemical plants, gas plants, exploration
and production facilities and, where applicable, supply/distribution installations.
If national and/or local regulations exist in which some of the requirements may be more
stringent than in this MESC SPE the Contractor shall determine by careful scrutiny which of
the requirements are the more stringent and which combination of requirements will be
acceptable with regards to safety, environmental, economic and legal aspects. In all cases
the Contractor shall inform the Principal of any deviation from the requirements of this
MESC SPE which is considered to be necessary in order to comply with national and/or
local regulations. The Principal may then negotiate with the Authorities concerned, the
objective being to obtain agreement to follow this MESC SPE as closely as possible.

1.3

DEFINITIONS
The Contractor is the party that carries out all or part of the design, engineering,
procurement, construction, commissioning or management of a project, or operation or
maintenance of a facility. The Principal may undertake all or part of the duties of the
Contractor.
The Manufacturer/Supplier is the party that manufactures or supplies equipment and
services to perform the duties specified by the Contractor.
The Principal is the party that initiates the project and ultimately pays for its design and
construction. The Principal will generally specify the technical requirements. The Principal
may also include an agent or consultant authorised to act for, and on behalf of, the
Principal.
The word shall indicates a requirement.
The word should indicates a recommendation.

1.4

CHANGES SINCE PREVIOUS EDITION

The previous edition of this MESC SPE was dated May 2010. The change is to update
ASTM A240 version, incorporated duplex stainless steel additional requirements and
email address of MESC SPE administrator
Errata 1 (December 2012) : USC unit corrected
Errata 2 (December 2012) : Exposure time added

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1.5

COMMENTS ON THIS MESC SPE

Comments on this MESC SPE may be sent to the MESC SPE Administrator at
[email protected]. Shell staff may also post comments on this MESC SPE on the Surface
Global Network (SGN) under the Standards folder.

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PART II AMENDMENTS/SUPPLEMENTS TO ASTM A 240:12
4.1

Add:

For duplex and super duplex grades the following shall apply:
For 22Cr duplex (ferritic/austenitic) stainless steels, the Pitting
Resistance Equivalent (PREN) shall be 34 or higher, the Mo mass fraction
(wMo) 1.5% or higher and the N fraction (wN) 0.14% or higher.
For 25Cr super duplex (ferritic/austenitic) stainless steels, the Pitting
Resistance Equivalent (PREN) shall higher than 40 and the N fraction (wN)
0.20% or higher.
The PREN shall be calculated as given in Equation (1):
PREN = wCr + 3.3(wMo + 0.5wW) + 16wN (1)
where

wCr is the mass fraction of chromium in the alloy, expressed as a

percentage mass fraction of the total composition;

wMo is the mass fraction of molybdenum in the alloy, expressed as a

percentage mass fraction of the total composition;

wW is the mass fraction of tungsten in the alloy, expressed as a

percentage mass fraction of the total composition;

wN is the mass fraction of nitrogen in the alloy, expressed as a

percentage mass fraction of the total composition.

5.2

Add

For duplex and super duplex grades, mechanical testing shall be carried
out as defined in sections 5.2.1 5.2.3 at one plate per lot. One lot is
defined as a set of plates with the same wall thickness, produced from one
heat of material in the same production and hesat treatment batch. All
testing shall be carried out on the final product after heat treatment.

5.2.1

Add:

For duplex and super duplex grades impact testing shall be carried out:
-

Charpy impact tests shall be carried out in accordance with ASTM A

370 at a temperature of 50 C (58 F).

A set of three transverse Charpy test pieces shall be taken from one
plate representing each lot. Test pieces shall be located at the mid
thickness.

If the wall thickness exceeds 25 mm (0.98 in), additional sets of three

Charpy test pieces shall be taken 3 mm (0.12 in) from each surface of
the plate.

The notch of all Charpy pieces shall be perpendicular to the surface.

Sub-size samples can only be applied, if standard 10 mm x 10 mm (0.39

in x 0.39 in) samples are not possible. Longitudinal samples can only be
applied, if transverse samples are not possible.

The acceptance criteria shall be in accordance with Table 3.

If the thickness is below 6.5 mm (0.26 in), Charpy impact testing is not
practical. The Principal may require additional microstructural checks.

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Table 3

Add

Table 3 Acceptance criteria for Charpy impact testing

Sample size
mm (in)
10 x 10

Test
direction

Transverse

(0.39 x 0.39)
10 x 10

Longitudinal

(0.39 x 0.39)
10 x 7.5

Minimum
average
impact value

Minimum
single impact
value

60 J*

48 J

(44 ft.lbs)

(36 ft.lbs)

90 J

72 J

(66 ft.lbs)

(53 ft.lbs)

48 J

36 J

(36 ft.lbs)

(26 ft.lbs)

72 J

54 J

(53 ft.lbs)

(40 ft.lbs)

30 J

24 J

(22 ft.lbs)

(18 ft.lbs)

46 J

36 J

(34 ft.lbs)

(26 ft.lbs)

Transverse
(0.39 x 0.30
10 x 7.5
(0.39 x 0.30)
10 x 5

Longitudinal

Transverse

(0.39 x 0.20)
10 x 5

5.2.2

Add

50 %

50 %

50 %

Longitudinal
(0.39 x 0.20)

Minimum
single shear
area

50 %

50 %

50 %

Tensile testing
On duplex and super duplex grades tensile tests shall be performed in
accordance with ASTM A 370. Room temperature testing shall be carried
out in the rolling direction and perpendicular to the rolling direction on full
thickness plate type specimens.
Test frequency shall be one duplicate test for both test directions on one
plate representing each lot.

5.2.3

Add

Hardnes testing
In duplex and super duplex grades, series of Rockwell C hardness
measurements shall be performed in accordance with ASTM E 18 at two
locations. At each location, triplicate hardness readings shall be taken at 1
mm from both surfaces surface and at mid section. The requirements of the
applicable material standards shall be met.

Add

Heat treatment
Plates shall be in solution annealed condition.
Duplex and super duplex grades shall be solution annealed and rapidly
cooled by water quenching.
The finished items furnished to Grades UNS S31254 or UNS N08367 shall be
annealed and water-cooled.
Heat treatment procedures shall be subject to statistical process control to ensure
that the final material properties comply with the material standard and this
specification. The process control data and related periodic quality control checks
shall be documented.

Add

Repair welding
Weld repair of the plate is not allowed.

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10

Add

Finish
Finished items furnished to Grades UNS S31254 or UNS N08367 and duplex
and super duplex grades shall be pickled and cleaned in accordance with
ASTM A 380. The Principal shall approve the procedure.

11

Add

Corrosion testing

11.1

Add

Periodic quality control checks shall include a periodic intergranular corrosion test
in accordance with ASTM A 262, Practice E. If periodic test data is not available,
then an intergranular corrosion test shall be applied for each heat in the order.

11.2

Add

Errata 1 (December 2012)

Plate furnished to Grades UNS S31254 or UNS N08367 shall be subject to a
ferric chloride test in accordance with ASTM G 48, Method A. The test
temperature shall be 50 C (50 122 F) and the exposure time shall be 24
hours. Test specimens shall be in the as-delivered condition. The test shall
expose the external and internal surfaces. No pitting is acceptable at
internal or external surfaces at 20 times magnification. The weight loss
shall be < 4.0 g/m (0.013 oz/ft).

11.3

Add

For duplex and super duplex grades shall be capable of passing the ferric
chloride test in accordance with ASTM G 48, Method A, with the following
amendments. This corrosion test shall be performed for product
qualification only.
Errata 2 (December 2012)
-

The exposure time shall be 24 hours.

Testing shall be carried out on one specimen per lot including the plate
surface.

The test temperature for 22Cr (duplex) steel shall be 25 C (77 F) for
parent material and 22 C (72 F) for welds.
The test temperature for 25Cr (superduplex) steel shall be 40 C (104 F)
for parent material and 35 C (95 F) for welds.

A temperature variation of 0.5 C (0.9 F) is allowed.

The surface finish of the test face shall be as produced. Cut faces shall
be ground to 1200 grit.

The evaluation of results shall be via weight loss measurement and

macroscopic investigation of the surface. Macrographs obtained by low
magnification microscopy shall be provided.

The acceptance criteria shall be a weight loss < 4.0 g/m2 and no initiation of
localized corrosion > 0.025 mm at the test face. Note that only corrosion
2
(e.g. pitting) at the test face counts. If the weight loss is > 4.0 g/m and it
can be positively identified that this is only due to corrosion at the cut
faces, the test will be invalid. In this case re-testing shall be carried out on
replacement specimens.
12

Add

Microstructure evaluation of duplex and super duplex grades

12.1

Add

Ferrite content
For duplex and super duplex grades the microstructure and percentage of
ferrite phase of the base material shall be determined via point counting in
accordance with ASTM E 562 on one cross section from a plate
representing each lot. The ferrite content shall be in the range of 40 % - 60

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%.
12.2

Add

Detrimental phases
For duplex and super duplex grades the microstructure shall be examined
for detrimental phases in accordance with ASTM A 923 Method A on one
cross section from a plte representing each lot. The etching method shall
be suitable to reveal intermetallic phases (such as sigma phase) and
precipitates (such as nitrides).
The microscructure shall classify as unaffected structure as per section 6
of ASTM A 923. The microstructure shall display a uniform ferrite and
austenite phase distribution and shall have no continuous precipitates at
the grain boundaries. In addition, the sigma phase content shall not exceed
0.5 %, while the total of intermetallic phases shall not exceed 1.0 %. If these
criteria are not met, the plate shall be rejected and each plate of the lot
investigated.

13

Add

Certification
For duplex and super duplex grades inspection, heat treatment and test
certificates shall be provided to the Principal.

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PART III REFERENCES
In this MESC SPE, reference is made to the following publications:
NOTES:
1. Unless specifically designated by date, the latest edition of each publication shall be used, together with any
amendments/supplements/revisions thereto.
2. Most of the referenced external standards are available to Shell staff on the SWW (Shell Wide Web) at
http://sww05.europe.shell.com/standards.

SHELL STANDARDS
Spectacle blinds, spade blinds & spacers

MESC SPE 76/012:2006

AMERICAN STANDARDS
Line blanks

ASME B16.48

Issued by:
American Society of Mechnical Engineers
ASME International
Three Park Avenue, M/S 10E
New York, NY 10016, USA

Standard Specification for Chromium and ChromiumNickel Stainless Steel Plate, Sheet, and Strip for Pressure
Vessels and for General Applications

ASTM A 240:12

Standard Practices for Detecting Susceptibility to

Intergranular Attack in Austenitic Stainless Steels

ASTM A 262

Standard Practice for Cleaning, Descaling, and

Passivation of Stainless Steel Parts, Equipment, and
Systems

ASTM A 380

Standard Test Methods for Pitting and Crevice Corrosion

Resistance of Stainless Steels and Related Alloys by Use
of Ferric Chloride Solution

ASTM G 48

Issued by:
American Society for Testing and Materials
100 Barr Harbor Drive, West Conshohocken
PA 19428-2959
USA