EPRI Guidelines For Upgrading ESP Vol 1
EPRI Guidelines For Upgrading ESP Vol 1
EPRI Guidelines For Upgrading ESP Vol 1
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CITATIONS
This report was prepared by
Grady Nichols Enterprises, Inc.
400 Kiowa Street
Montevallo, Alabama 35115
Principal Investigator
G. Nichols
The following consultants provided major sections of the report
J. Gooch
A. Ferguson
G.H. Marchant
Bevilacqua Knight, Inc. were instrumental in organizing and writing the document.
This report describes research sponsored by EPRI.
The report is a corporate document that should be cited in the literature in the following manner:
Guidelines for Upgrading Electrostatic Precipitator Performance: Volume 1, Optimizing an
Existing Electrostatic Precipitator, EPRI, Palo Alto, CA,: 1999. TR-113582-V1.
iii
REPORT SUMMARY
The first of a two-volume set, this guide presents a systematic procedure to optimize a
chronically under-performing electrostatic precipitator (ESP) without conducting a major
upgrade. The guide focuses on ESPs that require only moderate improvements (less than $10
$20/kW) to achieve their emissions goals. The second volume of this report, which will appear at
the end of 1999, will cover more extensive upgrades, as well as flue gas conditioning.
Background
Various factors are spurring power producers to improve the performance of their electrostatic
precipitators. Equipment aging causes ESP performance to drop off from original levels, even as
emissions limits become more stringent. New PM25 standards under consideration could require
increased capture of fine particles, which are hardest for ESPs to collect. SO2 compliance
measures are another driver: low-sulfur coals generally produce fly ash particles with higher
electrical resistivity, which are more difficult for an ESP to collect and cause ESP performance
to drop as a result of the coal switch. Another compliance option, dry SO2 control systems,
dramatically increases the mass loading into the precipitator and can also alter the resistivity of
fly ash such that particle reentrainment becomes a serious problemagain reducing ESP
collection efficiency. Power plant engineers need tools for determining the most strategic
repair/replace/redesign option to meet their particulate emission targets.
Objective
To provide plant operators and engineers with a systematic method for (1) determining whether
emissions limits can be achieved with an existing ESP or whether an upgrade will be necessary;
(2) diagnosing the cause(s) of ESP under-performance; and (3) identifying the best corrective
actions.
Approach
The project team, comprised of experts on ESP design and operation, summarized published
EPRI research and drew on their own expertise to define systematic procedures to optimize
chronically under-performing ESPs without conducting a major upgrade. They produced a guide
that starts with a quick screening procedureusing computer-generated charts based on field
data from coal-fired unitsto determine whether emissions goals can be achieved by optimizing
the existing precipitator or whether an equipment upgrade will be needed. For units that can get
by with the current equipment, the remainder of the manual provides step-wise instructions for
determining the cause(s) of suboptimal performance and for taking corrective actions. The team
designed the manual to be used with or without an ESP modelsuch as ESPM or ESPert
although a model is recommended.
Results
The guide includes step-by-step procedures for diagnosing the cause(s) of suboptimal
performance, as well as a discussion of corrective measures. On-line diagnostics include
assessment of the rapping system and tests to identify problems such as back corona and
misalignment. Off-line diagnostics include air load tests under dirty and clean conditions,
physical inspections, and gas flow velocity measurements. The guide provides numerous
illustrations, including a data entry checklist for using an ESP model, a component checklist for
inspections, and sample opacity traces under normal and abnormal conditions. Special emphasis
is placed on interpreting electrical readings, with illustrations of power supply meter displays,
oscilloscope waveforms, and V-I curves under normal and abnormal conditions. Appendices
discuss the physics behind ESP operation, and can serve as a training guide or refresher.
EPRI Perspective
Power producers face the difficult task of meeting increasingly stringent pollution abatement
regulations while simultaneously reducing costs to compete in a deregulated market. Adding to
the challenge, various measures to meet acid rain regulations have had a negative impact on ESP
performance. This performance drop, combined with the new compliance assurance monitoring
(CAM) regulation for particulate emissions, requires many utilities to restore, or even improve,
precipitator performance to stay in compliance. EPRI has developed a vast body of information
to help its members meet this challenge cost-effectively. Much of that information has been
synthesized into this report, to help plant operators get the most out of their existing ESPs
(Volume 1). If further improvement is needed, power producers can consider the newest upgrade
options, analyzed and presented in Volume 2 to identify the least-expensive option for their
situation. Together, these two volumes help the user streamline the evaluation process and
identify the optimum solution to any ESP performance problem.
TR113582-V1
Keywords
Air Pollution Equipment Upgrades
Electrostatic Precipitator Optimization
ESP Upgrade
ESP Troubleshooting
ESP Performance Improvement
Particulate Control
vi
ACKNOWLEDGMENTS
Gerry Klemm and Wallis Harrison of the Southern Company made many valuable contributions
to this guidebook. They contributed to the original discussions on how the manual should be
organized, and reviewed drafts of the document, providing valuable guidance and additional
material for inclusion. Both provided valuable insight into the sections dedicated to internal
inspections and troubleshooting. Gerry Klemm provided the original figures with appropriate
discussion about the behavior of power supplies and controls as well as the opacity traces used to
illustrate the ESP rapper behavior. Special thanks to them.
Dr. John P. Gooch and Mr. G. H. (Wim) Marchant of Southern Research Institute provided the
information about determining the current performance of an ESP in relation to that theoretically
possible, as well as material pertinent to the discussion of gas velocity distribution
characteristics. Mr. Alan W Ferguson of Black and Veatch provided the material for the section
describing the internal inspection and some discussions of upgrade options and their
applicability.
Mr. Richard L. Roberts of Entergy and Dr. Leonard N. Lapatnick and Mr. Edward G. Waugh of
Public Service Electric and Gas provided valuable reviews and comments as well. Their
contributions are enthusiastically acknowledged.
Mr. Charles (Chuck) Altin is remembered as well. Chuck was part of the original team, but
passed away before the project had progressed very far.
vii
CONTENTS
1 INTRODUCTION.................................................................................................................. 1-1
1.1 Purpose of This Guide ................................................................................................. 1-1
1.2 Optimization Approach ................................................................................................ 1-1
1.3 Organization and Overview of Guide ........................................................................... 1-2
1.4 Tips for Using This Guide ............................................................................................ 1-4
ix
xi
xii
xiii
LIST OF FIGURES
Figure 1-1 Flow Chart of Analytical Procedure ........................................................................ 1-3
Figure 2-1 Coarse (Eastern Bituminous) and Fine (Western Subbituminous) Particle
Size Distribution Used in Figures 2-3 Through 2-8 .......................................................... 2-5
Figure 2-2 Average Values of Current Density vs. In-Situ Resistivity....................................... 2-8
Figure 2-3 Coarse Ash: Full-Load Collection Efficiency vs. Average Values of Useful
Current Density for ESP With Three Fields (plate spacing = 10 inches or 25 cm).......... 2-11
Figure 2-4 Coarse Ash: Full-Load Collection Efficiency vs. Average Values of Current
Density for ESP With Five Fields (plate spacing = 10 inches or 25 cm) ......................... 2-12
Figure 2-5 Coarse Ash: Full-Load Collection Efficiency vs. Average Values of Useful
Current Density for ESP With Seven Fields (plate spacing = 10 inches or 25 cm) ......... 2-13
Figure 2-6 Fine Ash: Full-Load Collection Efficiency vs. Average Values of Useful
Current Density for ESP With Three Fields (plate spacing = 10 inches or 25 cm).......... 2-14
Figure 2-7 Fine Ash: Full-Load Collection Efficiency vs. Average Values of Useful
Current Density for ESP with Five Fields (plate spacing = 10 inches or 25 cm) ............. 2-15
Figure 2-8 Fine Ash: Full-Load Collection Efficiency vs. Average Values of Useful
Current Density for ESP With Seven Fields (plate spacing = 10 inches or 25 cm) ......... 2-16
Figure 4-1 Opacity Trace Indicating Baseline Opacity Before and After Rappers Are
Turned Off ....................................................................................................................... 4-4
Figure 4-2 Opacity Trace Indicating Appropriate Levels of Rapping ........................................ 4-5
Figure 4-3 Opacity Trace Indicating Excessive Rapping Puffs ................................................ 4-6
Figure 4-4 Opacity Trace Suggesting Excessive Rapping Forces Causing Rapping
Reentrainment to Raise the Baseline Opacity.................................................................. 4-7
Figure 4-5 Opacity Trace Suggesting Localized Reentrainment From a Particular Region
of the ESP ....................................................................................................................... 4-8
Figure 4-6 Secondary Voltage Waveforms for Normal Resistivity With No Back Corona....... 4-12
Figure 4-7 Normal Gas Load V-j Curves for Healthy Four-Field ESP .................................... 4-14
Figure 4-8 Normal V-j Curves From a Microprocessor Control .............................................. 4-15
Figure 4-9 Example Secondary Meters for a Four-Field ESP ................................................ 4-17
Figure 4-10 Normal Readings on a Microprocessor Power Supply Control ........................... 4-20
Figure 4-11 Microprocessor Ramping After Control Start or Control Regulation.................... 4-21
Figure 4-12 Minor Sparking Under Normal Operation ........................................................... 4-22
Figure 4-13 Microprocessor Responding to Spark................................................................. 4-23
Figure 4-14 Sluggish Response to Multiple Sparks ............................................................... 4-24
Figure 4-15 Suppression and Restart After an Arc ................................................................ 4-25
xv
Figure 4-16 Sustained Arc Such as Caused by Broken Wire Shorting................................... 4-26
Figure 4-17 Secondary Voltage Waveform (Voltage vs. Time) at Corona Start ..................... 4-27
Figure 4-18 Secondary Voltage Waveform With No Back Corona......................................... 4-27
Figure 4-19 Secondary Voltage Waveform With Heavy Back Corona ................................... 4-28
Figure 4-20 Typical Gas Load V-j Curves for a Healthy Four-Field ESP................................ 4-29
Figure 4-21 Back Corona and Premature Sparking Due to High-Resistivity Ash (1012 :cm) ................................................................................................................................ 4-32
Figure 4-22 V-j Curve From Microprocessor Control With High Resistivity and Heavy
Back Corona ................................................................................................................. 4-33
Figure 4-23 Example Problem V-j Curves........................................................................... 4-34
Figure 5-1 Diagram of ESP for Inspection Use........................................................................ 5-3
Figure 5-2 Normal Air Load V-j Curves From Healthy ESP ..................................................... 5-8
Figure 5-3 Example of an Inspection Report With Photographs ............................................ 5-15
Figure 5-4 Relationship Between Collecting Efficiency and Gas Velocity Non-uniformity
for Different Resistivities (Gas Sneakage Factor = 10%) ............................................... 5-23
Figure 5-5 Relationship Between Collecting Efficiency and Gas Sneakage Factor (Gas
Velocity Vgas = 25%) ....................................................................................................... 5-24
Figure 6-1 Example Condition Assessment Curve: Plot of Metal Thickness vs. Time for
Collecting Plates (four casing arrangement) .................................................................... 6-2
Figure 6-2 Example Relationship Between Power, Rapping Intensity, and Opacity............... 6-11
Figure 6-3 Fly Ash Resistivity as a Function of Temperature................................................. 6-16
Figure 6-4 Electric Field as a Function of Position in the Inter-electrode Space .................... 6-21
Figure A-1 Current Density vs. Ash Resistivity for Inlet Section of an ESP............................. A-4
Figure A-2 Current Density vs. Ash Resistivity for Second Section of an ESP........................ A-5
Figure A-3 Current Density vs. Ash Resistivity for Third Section of an ESP ........................... A-6
Figure A-4 Voltage vs. Current Curve Composite From Seventeen ESP Tests Used for
Correlation (All Normalized to 10-inch Plate Spacing) ..................................................... A-7
Figure C-1 Depiction of Single-Stage and Two-Stage Electrostatic Precipitators ...................C-3
Figure C-2 Schematic Example of Wire-in-Pipe Electrostatic Precipitator ..............................C-4
Figure C-3 Example of Fly Ash Resistivity as a Function of Temperature ..............................C-5
Figure C-4 Idealized Secondary Voltage vs. Current Curve ...................................................C-8
Figure C-5 Idealized Electric Field vs. Radial Position, With and Without Current Flow
(Pipe Diameter = 8 inches, Wire Diameter = 0.109 inches)............................................C-10
Figure C-6 Particle Charging Sequence Depicted for Field Charging ...................................C-12
Figure C-7 Comparison of Field Charging Rates for Half-Wave and Pure DC Electrical
Energization ..................................................................................................................C-14
Figure C-8 Illustration of ESP Collection With Laminar Flow ................................................C-17
Figure C-9 Illustration of the Development of a Particle Concentration Gradient for ESP
Collecting a Wide Particle Size Range With Laminar Flow ............................................C-18
Figure C-10 Two Examples of Methods for Providing Wet Collecting Electrodes .................C-27
xvi
xvii
LIST OF TABLES
Table 1-1 Problem Identification Index .................................................................................... 1-5
Table 2-1 Process Variables and ESP Parameters Used to Generate PerformanceEstimating Curves ........................................................................................................... 2-3
Table 3-1 Information Required to Run an ESP Computer Simulation Model (Model
accepts only English, not metric, inputs. A conversion table is included in Appendix
E.) ................................................................................................................................... 3-3
Table 4-1 Example Power Supply Readings for Four-Field ESP (No Resistivity
Limitation)...................................................................................................................... 4-18
Table 5-1 ESP Inspection Area Checklist................................................................................ 5-4
Table 5-2 Suppliers of Gas Flow Measurement Equipment................................................... 5-20
Table A-1 Fly Ash Resistivity and Estimated Useful Current Densities (see Appendix E
for metric conversion factors) .......................................................................................... A-2
Table A-2 Operating Secondary Voltages for Each Electrical Field (kilovolts) (see
Appendix E for metric conversion factors) ....................................................................... A-3
Table C-1 Performance Comparison of an ESP Alone vs. an ESP With a Cyclone (see
Appendix E for SI conversion factors)............................................................................C-21
Table C-2 Example Showing Actual Migration Velocity With Changes in SCA (see
Appendix E for SI conversion factors)............................................................................C-24
Table C-3 Collecting Efficiencies for Selected Particle Sizes as a Function of SCA (see
Appendix E for SI conversion factors)............................................................................C-25
Table E-1 Unit Conversion Factors ....................................................................................... E-1
xix
1
INTRODUCTION
1-1
However, if the best performance your unit could hope to attain would still fall short of your
performance goalsfor example, if you expect more restrictive emissions limits or plan to burn
lower-sulfur coal, which produces higher-resistivity fly ashit will be necessary to conduct a
major overhaul or implement new control measures such as flue gas conditioning. In this case,
refer to Volume 2.
If your ESPs current collection efficiency matches or exceeds its best performance, the
optimization steps in this volume are unlikely to make any appreciable improvement. A
significant performance boost would require the technologies discussed in Volume 2.
1-2
Evaluation complete
Rapper testing
(4.3)
Gas flow
measurements
(5.7)
Poor rapping
(4.3, 5.3.5, 5.6.2, 6.3)
Inadequate controls
(6.6 and Vol. 2)
Leakage
(5.6.35.6.5, 6.2)
Poor sectionalization
(6.7 and Vol. 2)
Gas maldistribution
(5.7, 6.8.3; also Vol. 2)
Optimization complete
Figure 1-1
Flow Chart of Analytical Procedure
1-3
Chapter 6 presents guidelines for problem correction. Detailed cost estimates are not included,
as the costs for these types of upgrades are highly site specific. Typically, optimization should
cost no more than $10$20 per kilowatt of generating capacity, and in many cases, considerably
less. If needed repairs are so extensive they would cost more than $20/kW, a more complete
ESP upgrade should be considered.
Appendix A provides the data used to develop the performance-estimating graphs in Chapter 2.
Although provided for background purposes, these data can also assist in the selection of input
data for the ESP model if there are data gaps for the ESP under study.
Appendix B discusses the use of the ESP model in an optimization analysis program. The
appendix offers an example of a step-by-step procedure for diagnosing the cause of suboptimal
ESP performance.
Appendix C provides background theory of electrostatic precipitation to ensure that the
optimization program is based on a proper understanding of the physics of ESP operation.
Although a review for most readers, it is nonetheless useful as reference material for the
experienced technologist as well as a training document for those with primarily practical
experience.
Appendix D discusses the electrical conduction mechanisms in fly ash, providing the
background needed to understand the concept behind flue gas conditioning. The material
provided allows the user to evaluate the potential improvement in ash resistivity that the most
common commercial conditioning agent, SO3, could provide.
Appendix E provides a table to assist in converting from English to metric units.
1-4
Discussion
Air In-leakage
Ash Buildup
Insulators/Feedthrough
5.3.3, 5.6.3
6.8.2
Gas Sneakage
3.2.7, 5.7.2
5.3.3, 6.9.2
High Resistivity
6.9.2
4.5.1, 6.6
Rapping Problems
Reentrainment
1-5
2
CURRENT VS. EXPECTED PERFORMANCE
COMPARISON
This chapter describes how to determine if your ESP will achieve a sufficient performance gain
from the optimization program presented in this report, or whether it will have to undergo a more
thorough upgrade to reach performance goals. The method is simple: Compare your ESPs
actual performance to the best performance that could reasonably be expected for a wellfunctioning ESP of similar design operating under similar conditions. This comparison gives a
rough estimate of the potential efficiency gain that could be expected from an optimization
program.
This chapter features model-derived curves for estimating optimum performance, discusses the
data inputs required to use the curves, and provides an example of how to use them.
2-2
Gas Pressure
Gas Volume Flow
300 F (150 C)
Gas Temperature
1.0 atm
3
Plate Height
33.33 ft (10.16 m)
Plate Length
10.0 ft (3.08 m)
Plate Spacing
Parallel Lanes
30
2
20,000 ft (1860 m )
Wire Spacing
Wire Diameter
Coarse
15 m
Log-Normal particle
3.0
Fine
20 m
5.0
10
11
12
13
10 , 10 , 10 , 10
3, 5, 7
3, 5, 7
0.25
0.10
6 m
2.5
Although the data points used to create Figures 2-3 through 2-8 will probably not exactly match
those encountered in any particular ESP, they should be close enough in most cases to provide a
useful indication of what a units collection efficiency should be. Development of these
graphs is discussed in Appendix A, along with a summary of input data and plots that allow you
to check how well the data represent your particular precipitator.
2-3
Type of coal being fired (to estimate the inlet particle size distribution)
Current density
2-4
Figure 2-1
Coarse (Eastern Bituminous) and Fine (Western Subbituminous) Particle Size
Distribution Used in Figures 2-3 Through 2-8
Note that even though the mmd of the fine distribution is greater than that for the coarse one,
the larger geometric standard deviation is great enough to represent a greater amount of fine
particles. In general, a greater mass concentration of fine particles (that is, a smaller mmd and/or
a larger Vparticle) results in lower values of precipitator collection efficiency, because the smaller
particles are more difficult to collect.
If you have unit-specific data for fly ash particle size distribution, compare it to Figure 2-1 and
select the closest curve. Otherwise, simply choose a coarse or fine designation based on the rank
of coal being fired.
2-5
2-6
Consequently, for the sake of reading Figures 2-3 through 2-8, it is recommended that you
compare your measured current density (determined from directly averaging the meter readings)
to a useful current density value based on your ash resistivity, using Figure 2-2. If your
measured current density differs from the estimate in Figure 2-2, use both the actual and Figure
2-2based current densities (when applying Figures 2-3 through 2-8) to obtain the range of
predicted collection efficiencies. The two resulting efficiency values should bracket the
expected optimum performance for your ESP. Note that if you find a substantial difference
between your measured current density and what Figure 2-2 says it ought to be for your ashs
resistivity, it is a tip-off that your ESP may be suffering from excessive back corona.
To use Figure 2-2, you will obviously need to know the resistivity of your ash. Three methods
are available:
1. In situ measurement. This method yields the most accurate value of ash resistivity, and
thus is preferred.
2. Laboratory measurement. Laboratory analyses can be conducted on either isokinetic or
blended hopper samples. This is the next most accurate means of determining ash resistivity.
3. Estimate from ESP model. If direct data are not available, EPRIs ESPM or ESPert models
can be used to predict resistivity based on data from an ultimate analysis and elemental ash
analysis of your coal (see Chapter 3).
2-7
Figure 2-2
Average Values of Current Density vs. In-Situ Resistivity
Whatever the method for determining resistivity, note that if you have switched coals since
measuring the ESPs collection efficiency, you should use the resistivity that was current at the
time collection efficiency was determined. This will give the most accurate estimate of the
difference between your ESPs actual performance and its optimum performance. If you are
firing a blend, it is best to obtain an in situ measurement or a laboratory analysis of the blend, as
the blends resistivity is not simply the weighted average of the individual resistivities of the
fuels being fired.
2-8
First, find the appropriate chart based on the number of fields and the particle size distribution.
A five-field ESP firing bituminous coal (i.e., coarse particles) will use Figure 2-4.
Next, adjust the SCA to correspond to the 10-inch spacing used in the curves by multiplying by
the ratio of plate spacing (9/10). The equivalent SCA becomes 288 ft2/kacfm at 10-inch
spacingthus, the estimated best performance will be just below the curve for SCA = 300.
Finally, determine current density. Figure 2-2 indicates a current density of about 18 A/ft2.
Compare this to the actual current density measurements. The secondary readings are:
2-9
2-10
Figure 2-3
Coarse Ash: Full-Load Collection Efficiency vs. Average Values of Useful Current
Density for ESP With Three Fields (plate spacing = 10 inches or 25 cm)
2-11
Figure 2-4
Coarse Ash: Full-Load Collection Efficiency vs. Average Values of Current Density for
ESP With Five Fields (plate spacing = 10 inches or 25 cm)
2-12
Figure 2-5
Coarse Ash: Full-Load Collection Efficiency vs. Average Values of Useful Current
Density for ESP With Seven Fields (plate spacing = 10 inches or 25 cm)
2-13
Figure 2-6
Fine Ash: Full-Load Collection Efficiency vs. Average Values of Useful Current
Density for ESP With Three Fields (plate spacing = 10 inches or 25 cm)
2-14
Figure 2-7
Fine Ash: Full-Load Collection Efficiency vs. Average Values of Useful Current
Density for ESP with Five Fields (plate spacing = 10 inches or 25 cm)
2-15
Figure 2-8
Fine Ash: Full-Load Collection Efficiency vs. Average Values of Useful Current
Density for ESP With Seven Fields (plate spacing = 10 inches or 25 cm)
2-16
2-17
3
PERFORMANCE ESTIMATING WITH AN ESP MODEL
If the charts in Chapter 2 indicate that unit optimization (rather than a more extensive upgrade)
will successfully meet your ESP performance goal, it is possible to skip straight to Chapter 4.
However, it is recommended to use a computer model to refine your estimates of best-attainable
performance. Modeling is especially valuable if the estimated best performance from the
charts in Chapter 2 is near your ESP performance goal, or if your performance goal is
particularly demanding. The model provides a more precise prediction of the potential
improvement, so you can be sure that sufficient improvement is possible before undertaking
optimization procedures described in the remainder of this volume.
Moreover, once you have completed the diagnostic procedures in Chapters 4 and 5, the model is
a valuable tool to determine which repairs are worth making. And if you determine that the
existing ESP, as designed, will not achieve your target emission limits, then the model is
necessary to evaluate candidate upgrade options.
This chapter discusses the site-specific data inputs required to obtain the most accurate, useful
estimates from an ESP computer model. Even if you do not intend to run the model, scan this
chapter (especially Section 3.2), as it contains valuable information on data collection needed for
the optimization study.
parameters and ESP operation. In addition, ESPert serves as a useful tool for monitoring ESP
operation and alerting plant personnel to potential problems. However, for conducting the
optimization analysis in this guide, we recommend using ESPM due to its straightforward
simplicity, unless you have experience using one of the other versions of the model.
The core SRI-EPA-EPRI model is based on the Deutsch-Anderson equation (discussed in
Appendix C), which describes the behavior of a particle with a known value of electrical charge
in a given electric field being collected from a gas stream with fully developed turbulent flow,
assuming an idealized uniform flow field. Empirical correction factors have been added to the
model to account for the non-ideal conditions. These correction factors address non-uniform gas
flow, gas sneakage around electrified regions through hoppers and the space above the collecting
electrode assembly, and rapping reentrainment (rapping reentrainment correction factors were
developed independently for hot-side and cold-side units). The correction factors were
developed on the basis of particle size and loading measurements on several operating ESP units.
The model has been validated through many measurements from operating full-scale and pilotscale precipitators.
3-2
Table 3-1
Information Required to Run an ESP Computer Simulation Model
(Model accepts only English, not metric, inputs. A conversion table is included in Appendix E.)
Boiler and Plant Description
Plant Name
Unit Number
Gross Rating (MW)
Type of Furnace
Heat Rate (Btu/kWh)
Coal Usage (ton/hr)
Coal Heating Value (Btu/lb)
Coal Type and Mine Name
Overall ESP Parameters
Specific Collecting Area
2
(ft /kacfm)
2
Total Collecting Area (ft )
Design Gas Velocity (ft/s)
Number of Electrical Fields
Total Plate Length (ft)
Plate Height (ft)
ESP Width (ft)
Corona Electrode Diameter (in)
Stack Diameter at Top (ft)
Field Number
2
Plate Area (ft )
Field Length (ft)
Wire Diameter (in)
Wire-to-Plate Spacing (in)
Wire-to-Wire Spacing (in)
Secondary Voltage (kV)
Secondary Current (mA)
Corona Start Voltage (kV)
Rated Peak Voltage (kV)
Gas Temperature ( F)
Gas Volumetric Flow Rate (acfm/s)
% Nitrogen (N2)
% Oxygen (O2)
% Carbon Dioxide (CO2)
% Moisture Content (H2O)
ppm Sulfur Dioxide (SO2)
ppm Sulfur Trioxide (SO3)
3-3
3-4
3-5
measurement cell. If a measured value of resistivity cannot be obtained, estimation methods are
available, including the resistivity prediction method in EPRIs ESPM and ESPert computer
models.
3-7
In addition, the model incorporates a correction for rapping reentrainment. The total reentrained
mass loading is automatically calculated by the model as a function of the mass collected by the
outlet electrical section. This reentrained mass is divided into the particle size bands according
to a log-normal particle size distribution with mmd = 6.0 m and particle = 2.5, as determined by
a curve fit to the field test data. These typical values are based on data from six full-scale and
four pilot studies, and are programmed into the SRI model. If detailed particle size data are
available for your unit, the SRI model can accept specific particle size distributions for the
reentrained material (i.e., you can adjust the mmd and particle); however, it does not allow you to
input a different amount of reentrainment. The SRI model uses a different reentrained fraction
for hot-side and cold-side units determined in a rapping reentrainment study using some pilot and
full-scale installations. ESPM, on the other hand, allows you to input specific values for all of
the reentrainment characteristics.
relatively high sneakage values (large S values). Therefore, it is a general practice to increase or
decrease both gas and S values together. Changing the values of these factors by 0.05 will
usually lead to a match after a few iterations. If the model under-predicts performance, both gas
and S should be decreased; if the model over-predicts performance, these input values should be
increased. It should not be necessary to reduce either factor to 0 or increase either factor to a
value of more than 0.5 to achieve calibration. In fact, if a match is not achieved within these
limits, it is likely that one or more model input parameters is incorrect or that there exists an
unusual operating condition within the ESP.
Adjusting S and gas is appropriate if model projections are fairly close to measured values.
However, if the model-predicted performance is significantly greater than the measured
performance, you will need to investigate the cause(s) for the difference. Review the electrical
operating voltages and currents for out of normal values. If some electrical sections are low,
the model may need to be exercised for the different values to evaluate the influence on
collecting efficiency. To make this comparison, model different portions of the ESP
individually, and use a weighted average of the emissions (i.e., loading x flow rate)not of the
collecting efficiencywhen combining the different portions of the ESP.
Ash resistivity, temperature, gas flow distribution and mass loading may also be factors in
suboptimal performance, as may be the particle size distribution. Investigate such potential
limiting factors to identify the changes necessary to provide a match between the actual and
model-projected performance.
If the performance calibration requires input parameters well outside of the norm, it may be
necessary to conduct detailed diagnostic tests as described in this manual. Pay particular
attention to the on-line evaluations to determine that the electrical parameters are appropriate for
the resistivity, and to the off-line evaluations to assure the mechanical integrity of the ESP. By
using the model in combination with the data-gathering exercises presented in this manual, the
existing ESP should be completely characterized.
Note that modeling is most often done to simulate full-load operation because outlet emissions
are usually greatest at full load, and consequently, this condition is of the greatest concern. The
models can be used to simulate operation at lower loads, but sometimes recalibration will be
needed. The model parameter most likely to change at low load is reentrainment. When the
velocity in the precipitator is reduced, losses due to both continuous and rapping reentrainment
are reduced. ESP power levels at low load may also change due to temperature-induced fly ash
resistivity changes, and so power levels appropriate for low-load operation must be entered into
the model.
After the model has been calibrated to the ESP, the parameters descriptive of the existing ESP
can be modified to upgraded values to evaluate the potential for improving the performance of
the ESP. It is very important to have correct values for the ash resistivity, loading, and particle
size distribution for the ash into the ESP. The electrical voltages and currents should be
representative of those for the resistivity and size distribution as well. If these values are used,
the model will provide reliable data for evaluating the potential improvement in the existing
ESP.
3-10
Appendix B provides a step-by-step example of using the model to evaluate an existing ESP.
The data-gathering exercises do not exactly follow the sequence described in the body of the
manual, but all of the necessary steps are included. After some experience using the model
together with the data gathering, a user will become proficient in model calibration.
3-11
4
ON-LINE DIAGNOSTICS
To diagnose the cause(s) of poor ESP performance, begin by evaluating key metrics while the
unit is on-line. This chapter describes the diagnostic procedures that can be performed while the
ESP is in steady-state operation, typically at or near full load; Chapter 5 covers diagnostics that
require the ESP to be shut down. During steady-state operation, evaluate the following:
Basic operating data, e.g., opacity traces and voltage and current meter readings; significant
changes from previous measurements signal a likely problem area
Rapping performance
Detailed electrical datai.e., secondary voltage vs. current data graphs and oscilloscope
waveforms, obtained from a gas load test
Standard boiler, fuel, and fly ash dataload level (MW), heat rate, gas flow rate, gas
temperature, coal composition, fly ash resistivity, mills in service, excess O2, and other data
typically logged by the data acquisition system. Be sure to collect these data concurrent with
the mass loading and particle size tests. This auxiliary information provides guidance about
what may have caused test results to fall outside expected ranges. If there is a glitch in the
test program, these data are very useful to determine what went awry.
Coal proximate and ultimate analyses plus ash mineral analyses. These data can be used to
determine if changes in coal and ash properties are affecting ESP performance.
As the repository of the units electrical, opacity, and general operating data history, the ESP log
book serves as the starting point and baseline reference for the ESP optimization study.
Naturally, all tests and measurements undertaken as part of the optimization study should be
recorded in the log book as well.
Opacity traces
Secondary voltage
Secondary current
Spark rate
Auxiliary operational data such as boiler load, flue gas spatial temperature distribution at the
ESP inlet, and oxygen and sulfur dioxide levels in the flue gas
Check the key ESP data against historic norms; variations may indicate a problem area. As for
the auxiliary data, most of it will never be needed. However, detailed concurrent data are useful
for determining what happened in the plant when the ESP test data do not match expected
values. Seldom does a test program in an operating power station go off without a hitch. A
coal mill will fail, air heaters stop, clinkers fall into the furnace, unanticipated coal changes
occur, etc. When interpreting what happened in the ESP test, it is invaluable to know whether
the apparent problem with the ESP was actually due to another event elsewhere in the power
4-2
plant. Thus, be sure to collect these data during the rapping reentrainment test described in
Section 4.3.1 and during or just before beginning the gas load test described in Section 4.4.
4-3
A word of caution: If the rappers are off for a long time, a significant rapping puff could occur
when the rappers are placed back in service, which could create an opacity violation. In
general, try to avoid leaving the rappers off for more than a few hours.
Figure 4-1
Opacity Trace Indicating Baseline Opacity Before and After Rappers Are Turned Off
4-4
Figure 4-2
Opacity Trace Indicating Appropriate Levels of Rapping
4-5
Figure 4-3
Opacity Trace Indicating Excessive Rapping Puffs
4-6
Figure 4-4
Opacity Trace Suggesting Excessive Rapping Forces Causing Rapping Reentrainment to
Raise the Baseline Opacity
4-7
Figure 4-5
Opacity Trace Suggesting Localized Reentrainment From a Particular Region of the ESP
4-8
Figure 4-4 depicts the opposite problem, over-rapping. Here, rapping is so frequent and intense
that the rapping puffs are very small, but the overall base level of reentrainment has risen from
about 10% to about 15% (compare to Figure 4-2).
Figure 4-5 shows uneven rapping, with significant reentrainment occurring in a relatively
small portion of the ESP. Such a trace can indicate the need to vary rapping intensity across the
direction of gas flow.
If your trace appears similar to Figure 4-2, and rapping reentrainment is no more than 40% (coldside) or 50% (hot-side), then your rapping system is adequately adjusted. If reentrainment values
are higher than these bounds, you may need to fix the system, starting with visual inspection of
the rapping equipment. If you want an exact measure of the contribution of rapping
reentrainment to outlet emissions, conduct a mass emissions test using two independent sets of
measurement instruments; one set is operated with the rappers on and the other with the rappers
off. However, it is not necessary to measure the rapping reentrainment contribution this
precisely, as the rappers can be optimized without determining their specific contribution.
4.4 Obtain Electrical DataV-j Curves and Waveformsvia Gas Load Test
4.4.1 Diagnostic Value
Electrical datanamely, (1) secondary voltage vs. current curves and (2) secondary voltage and
current waveformsare key tools for diagnosing problems with ESP operation. The remainder
of this chapter focuses on collecting and interpreting these electrical data.
Note that this chapter will refer to voltage vs. current density (V-j) rather than straight voltage vs.
current (V-I) curves. V-j curves cover the case where different transformer-rectifier sets feed
different collecting plate areas, by normalizing all electrical sections for comparison purposes. If
4-9
all your T-R sets feed equal plate areas, you can simply plot straight V-I data without the extra
step of calculating current density.
Voltage vs. current data provide valuable insight into ESP operation. Variations in the shape of
the secondary V-j curves or the secondary waveforms can indicate a variety of problems,
including:
Electrical shorts (due, for example, to cracked insulators, carbon tracking on insulators,
broken wires, or overly full hoppers)
Abnormal sparking
Back corona (an undesirable condition that contributes to significantly degraded ESP
performance; caused by high-resistivity ash)
Meter readings for primary and secondary operating voltage and current. Note that if the
power supply controls are an older analog model, only average values of secondary
voltages and currents are available. Some of the newer control sets indicate the peak,
average, and trough (minimum) values of voltage for each value of current. If your
controls provide such information, record it for this preliminary measure and all
subsequent measurements throughout the gas load test.
4-11
4. Incrementally increase the secondary voltage through its range, and record the
corresponding current at each interval. In addition, record oscilloscope traces at key points
of the test: near corona start, midway through the voltage range, and at the voltage limit (end
of the test), or at whatever point sparking or back corona is detected.
Increasing the secondary voltage can be accomplished by either (1) increasing the conduction
angle of the silicon-controlled rectifier (SCR) in the power supply control, (2) increasing the
secondary current limits, or (3) using the control microcomputer to run the power supply
through its range.
Beginning at the corona start voltage, measure the corresponding secondary voltages and
currents at regular intervals of secondary current (i.e., adjust the applied voltage until you get
a secondary current reading at a pre-designated current interval, then measure the
corresponding secondary voltage). As is evident from the sample V-j curves later in this
4-12
chapter (e.g., Figure 4-7), the plot of secondary voltage vs. current density changes curvature
quite rapidly near corona start. Consequently, it is best to take frequent measurements at
lower values, to ensure enough data points to define the critical beginning part of the curve.
Thereafter, it is sufficient to use intervals corresponding to current densities of 25
microamperes per square foot of collecting surface, or 25 nanoamperes per square
centimeter of collecting surface.
Note that each time you proceed to a new test point, it takes a minute or so for the ESP to
stabilize. Wait for this steady state before recording the V-I data point. As stated earlier, if
your controls provide peak and trough electrical readings, record them as well; the trough
values provide the earliest indication of the onset of back corona.
As the secondary voltage is raised above corona start, its oscilloscope waveform changes in
appearance to that indicated as Curve 2 in Figure 4-6. The rising portion of the waveform
shows that the secondary voltage is increasing with the applied voltage until the ESP
secondary voltage reaches the peak value of the applied voltage waveform. During this time,
current is flowing from the power supply to charge the distributed capacitance of the ESP
system and to supply the corona current that is flowing. The letter A on Curve 2 indicates
this region.
As the input voltage from the power supply begins to fall below the voltage across the ESP
electrode system, the back-biased diode stack in the transformer secondary effectively
disconnects the power supply from the ESP electrodes until the next half cycle of
energization. This point is indicated as point B on Curve 2. During the remainder of this
half cycle of input from the power supply, the secondary voltage on the ESP decays as the
corona current flow discharges the energy stored in the distributed capacitance of the
electrode system. This decay in secondary voltage continues until the next half cycle of
energization arrives from the power supply. The decay in voltage from the stored energy is
indicated as segment C on Curve 2.
5. Continue increasing voltage until you reach a limitation. This limitation may be the
power supply voltage or current limit, electrical sparkover, or back corona. If there is no
problem with high-resistivity ash, the voltage is usually limited by sparking.
Sparkover can be detected by the secondary meters and the oscilloscope waveforms (see
Figure 4-14). Back corona can also be detected by meter readings (the current will continue
to increase while the voltage will fail to increase commensurately, or even decrease), as well
as oscilloscope waveforms (see Figure 4-19).
Some digital power supplies automatically plot V-I results. However, many of the new controls
jump the gun by logging the V-I values too soon (e.g., before the current has a chance to
stabilize in response to each incremental voltage increase). Some systems allow you to specify
the wait interval before taking a reading after a change in voltage or current. If you can set the
wait for 12 minutes, then your automatic V-I plot should be reliable. If not, log the stabilized
data points by hand and create your own graph.
The types of V-j curve that can be generated vary depending on the type and age of the power
supply controls. Figure 4-7 shows V-j curves for a precipitator with old analog controls, which
give only average values of secondary voltages and currents. Figure 4-8 shows a normal V-j
curve from a newer digital control set, which can record peak and trough values as well. (Both
Figures 4-7 and 4-8 correspond to a normally operating ESP without any limitation imposed by
high-resistivity ash.)
Figure 4-7
Normal Gas Load V-j Curves for Healthy Four-Field ESP
4-14
Figure 4-8
Normal V-j Curves From a Microprocessor Control
4-15
4-16
Figure 4-9
Example Secondary Meters for a Four-Field ESP
4-17
Table 4-1 provides an example set of electrical data from another ESP in good condition. This
unit is similar to the one whose readings are shown in Figure 4-9: four fields, 10-inch (25-cm)
plate spacing, pulverized bituminous coal, and no ash-resistivity limitation. Note that the values
are quite different from those in Figure 4-9, but the trend in electrical readings from field to field
is the same. This variation in voltage and current readings between these two normal ESPs
operating under similar conditions underscores the importance of keeping a historical log book
so you can compare your units meter readings to their own norm, rather than to some generic
ESP.
Table 4-1
Example Power Supply Readings for Four-Field ESP (No Resistivity Limitation)
Field No.
Primary
Voltage (V)
Primary
Current (A)
Primary
Power (W)
335
55
18,425
47
280
13,160
325
80
26,000
44
420
18,480
315
110
34,650
41
600
24,600
310
130
40,300
39
700
27,300
4-18
Figure 4-13 represents the response to a somewhat heavier spark. This condition causes a larger
increase in current and reduction in voltage. In this case, the control system responds by setting
the voltage back slightly to prevent the occurrence of a spark re-strike. The rate of sparking
should be measured with spark rate meters. Acceptable levels of sparking are in the range of 10
60 sparks per minute.
Figure 4-14 shows the occurrence of several sparks and the response of the control system. In
this case, the spark has repeated. This multiple spark condition is undesirable, as it tends to drive
the average secondary voltage down, reducing the electrical collecting force and encouraging
particle reentrainment. The reentrainment, in particular, comes from a disruption of the surface
of the collected fly ash layer by the sparks and by an overall reduction in the electrical holding
force over large regions of the layer because of decreased current to those regions.
Figure 4-15 suggests the formation of an arc. A single occurrence such as this usually cannot be
avoided. This undesirable condition may be either the result of unstable electrodes or a process
upset. The control system must reduce the voltage to the ESP to near zero to quench the arc.
Figure 4-16 illustrates a recurring full-conduction arc existing over many half cycles with a
significant reduction in secondary voltage. This depiction suggests a series of unregulated sparks
that are increasing in amplitude. This is a very damaging event that can lead to wire failure. The
broken wire can then cause a short, which is itself manifest by sustained arcing.
4-19
Figure 4-10
Normal Readings on a Microprocessor Power Supply Control
4-20
Figure 4-11
Microprocessor Ramping After Control Start or Control Regulation
4-21
Figure 4-12
Minor Sparking Under Normal Operation
4-22
Figure 4-13
Microprocessor Responding to Spark
4-23
Figure 4-14
Sluggish Response to Multiple Sparks
4-24
Figure 4-15
Suppression and Restart After an Arc
4-25
Figure 4-16
Sustained Arc Such as Caused by Broken Wire Shorting
4-26
Figure 4-17
Secondary Voltage Waveform (Voltage vs. Time) at Corona Start
Figure 4-18
Secondary Voltage Waveform With No Back Corona
4-27
Figure 4-19
Secondary Voltage Waveform With Heavy Back Corona
Caused by high-resistivity fly ash, the presence of back corona significantly degrades ESP
collection efficiency. Back corona generates ions that serve as charge carriers in addition to the
desirable charge carriers from the normal corona process. These additional positive ions
neutralize much of the negative space charge from the discharge electrode, causing a significant
increase in the total current flowing in the inter-electrode space. (The resulting increase in the
current in each field can be detected via a characteristic change in the shape of the V-j curves, as
discussed in Section 4.5.3.) Some of the positive ions formed in back corona flow to the fly ash
particles and neutralize a portion of the negative charge on them, thereby decreasing their
probability of being collected.
Figures 4-17, 4-18, and 4-19 give oscilloscope waveforms of secondary voltage as a function of
time for corona start, normal, and back corona conditions. Corona start voltage is indicated on
the operating waveforms for reference. Note that under conditions of heavy back corona, the
rectified voltage waveform dips below the corona-start voltage value.
Electrical space charge (responsible for curve variations between fields; see Figure 4-20)
Ash resistivity (high resistivity causes back corona, which has a characteristic back slant
curve shape; see Figures 4-21 and 4-22)
4-28
Figure 4-20 illustrates a V-j plot for a healthy ESP with 10-inch (25.4 cm) plate spacing,
operating at a temperature of 300OF (150OC), with no significant resistivity limitations. (Note
that Figure 4-20 is a repeat of Figure 4-7.)
Figure 4-20
Typical Gas Load V-j Curves for a Healthy Four-Field ESP
4-29
In Figure 4-20, observe that the curve for the inlet field is to the right of the second field (i.e.,
exhibits a lower current density for a given secondary voltage), and that this pattern continues
from field to field in the ESP. This variation in the V-j curves is caused by the change in
electrical space charge among the different fields. Approximately 60% of the total fly ash
particles are collected in the first field of the ESP. Thus, the particle loadingand
corresponding electrical space charge from the particlesin the second field is about 40% of that
in the inlet section, and so on down the line, until there are relatively few charged particles
remaining in the outlet field. It is this successive reduction in space charge that causes the shift
in the V-j curves from field to field. Removing the space charge allows more current to flow for
a given applied voltage, resulting in a systematic decrease in voltage coupled with a systematic
increase in current density from the inlet to the outlet field.
The amount of space charge influences the amount of shift to higher currents at a given voltage
as you progress from inlet to outlet. If the fly ash contains an unusually large amount of very
fine material, which is harder to collect, the space charge will be higher and the resultant V-j
curve will shift to a higher voltage (shift to the right) for a given current density. This sometimes
occurs with combined ammonia and sulfuric acid conditioning or ammonia injection into a highsulfur gas stream.
To analyze the V-j data, compare the V-j curves within a field and between fields. Ideally, the
curves for each section within a field should be almost identical (data points within a few
percent) unless different sections are equipped with different corona wire designs or are operated
with different energization methods. In actuality, however, most ESPs have variations in gas
flow or temperature distribution that will cause variations between the V-j curves for sections
within the same field.
Curves for different fields should share the same basic upward curve shape but have different
values of voltage and current due to the difference in electrical space charge in the different
fields.
When comparing curves, look for differences in:
Sparking voltage
Also compare the curves to historical gas load V-j curves, if available, to determine if there has
been a change in their appearance. If the curves for some sections deviate from the majority of
others, or differ significantly from previous V-j data, mechanical damage is likely. For example,
sparking at lower voltages than on previous occasions would suggest the possibility of electrode
misalignment or an insulator problem in that electrical section. Operating at higher current for a
given voltage would suggest an electrical fault or mechanical misalignment. An internal ESP
inspection is warranted to determine the cause(s).
4-30
Changes in the general shape of the V-j curves provide useful clues as to potential problems in
the unit. For example, if the ESP is exhibiting early sparkover and back corona, the appearance
of the V-j curves should resemble those in Figure 4-21 rather than those in Figure 4-20. The
back slant appearance to the curves as current rises indicates the presence of back corona. The
arrow drawn at the top of the inlet curve indicates the sparkover.
For a microprocessor power supply, the shape of a V-j curve indicating back corona will appear
as depicted in Figure 4-22. In this plot, note that as the SCR firing angle is increasedthereby
increasing the operating voltage above corona startthe peak, average, and trough (minimum)
values of secondary voltage increase until back corona is formed. After back corona is initiated,
further increases in the conduction angle for the SCR cause the peak value to continue to
increase, the average value to increase initially, then decrease, and the trough value to decrease.
When back corona becomes severe, the trough value falls below the corona start voltage,
indicating that the back corona is supplying positive ions as charge carriers even though the
corona from the discharge electrode has been interrupted between energization cycles.
Other deviations from a normal set of curves are illustrated by Figure 4-23. In this figure,
Curves 5 and 6 are normal, whereas curves for the other sections indicate problems, as noted
below:
Ash buildup on discharge electrodes. If the discharge electrode have a large buildup of ash
on their surfaces, they behave as an electrode with a much larger diameter as suggested by
Curve 1.
Back corona. Curves 3 and 4 indicate the presence of back corona as discussed above.
Curves 5 and 6 indicate no problems. Curve 5 represents a curve with either a near-clean
collecting electrode or one with an ash deposit with resistivity less than about 5 x 1010 -cm.
Curve 6 is expected to have a reasonable thickness of deposit with a resistivity on the order of 5
x 1011 -cm. Curve 6s shift to the right relative to Curve 5 represents the voltage drop across
the ash layer.
V-j Curves at Part Load
V-j curves taken at part load show the same characteristic shapes to indicate the same ESP
problems as curves taken at full boiler load. However, a gas load test at part load is not as
instructive as a test run at full load. Mechanical problems such as misalignment can generally be
detected just as well, but ash-related problems cannot. The lower flue gas temperature at part
4-31
load changes the ash resistivity, which can result in better-than-actual electrical readings for
cold-side units (e.g., back corona could be undetectable) and worse-than-actual readings for hotside units (because temperature reduction in a hot-side unit increases ash resistivity, back corona
is likely to develop in hot-side units at part load).
To detect back corona, evaluate secondary voltage waveforms obtained with an oscilloscope
while the plant is operating at full load. If the secondary voltage increases and the current
density decreases as you reduce load (and temperature), you likely had back corona in a coldside unit at full load. Misalignment can be detected in particular fields either at full or partial
load, if not obscured by back corona.
Figure 4-21
Back Corona and Premature Sparking Due to High-Resistivity Ash (1012 :-cm)
4-32
Figure 4-22
V-j Curve From Microprocessor Control With High Resistivity and Heavy Back Corona
4-33
Figure 4-23
Example Problem V-j Curves
4-34
5
OFF-LINE DIAGNOSTICS
If findings from the on-line tests covered in Chapter 4 indicate problems with the ESP internals,
the next step in performance optimization is to take the unit off-line for further testing and visual
inspection. Off-line diagnostics consist of the following:
Air load test under dirty conditions, yielding V-j curves to indicate mechanical and
electrical problems. When compared with V-j curves obtained through gas load and clean air
load tests, these dirty V-j curves can isolate problems due to ash deposits.
Dirty visual inspection, to diagnose problems with ash buildup, electrical tracking, poor
gas flow or leakage, and inadequate rapping.
Air load test under clean conditions, for V-j curves to evaluate mechanical alignment.
Clean visual inspection, to locate misalignment, corrosion, leaks, and other mechanical
damage.
Gas velocity distribution measurements, to determine whether better gas flow distribution
could significantly improve ESP collection efficiency.
5-1
5-2
Figure 5-1
Diagram of ESP for Inspection Use
5-3
5-4
Inspected
Notes
5-5
voltages significantly less than those on the other sections, this suggests a problem in those
sections warranting inspection and repair.
Although it would be unusual for all sections to spark before reaching the current limit, there
have been instances of this occurring in hot-side ESPs where the support structure has deformed
because of localized overheating or marginal design of the original structure. If the support
structure is permanently deformed, there is a chance that some or even all of the electrical
sections will have regions of misalignment where the air load V-j curves would exhibit sparking
before reaching the current limit. Early sparking on all sections could also indicate a
malfunction of the power supply controls.
5-7
Figure 5-2
Normal Air Load V-j Curves From Healthy ESP
constrained from expansion. Similarly, discrepancies between dirty air load V-j curves and clean
air load V-j curves can indicate the contribution of ash buildup to the problem (e.g., a problem
with electrical tracking on insulators). If you were not able to run a gas load test due to regulator
restrictions, the dirty air load test will be your only source of V-j data regarding ash-induced
problems.
5-8
5-9
5-10
5-11
5-12
5-13
5-14
Figure 5-3
Example of an Inspection Report With Photographs
5-15
5-16
The suspension systems for the discharge electrodes often use stand-off insulators to provide a
stable position in the ESP box between the collecting plates. Carefully check these insulators, as
they can accumulate significant ash buildup that can cause electrical tracking and subsequent
cracking. Damaged insulators can no longer maintain proper positioning of the discharge
electrodes relative to plates and other parts, resulting in poor ESP performance.
The restraining grid is often held in place by an insulator that attaches to the hopper. The
insulator maintains electrical isolation for the discharge electrodes and prevents the entire
discharge electrode assembly from swaying either due to gas flow or electrical forces. This
insulator should be inspected and replaced if damaged or broken.
casing near the collected ash can reentrain some of that ash, thereby increasing emissions as well
as causing ash caking from moisture condensation. Water (primarily rainwater) in-leakage can
plug hoppers, thus resulting in electrical shorts if the discharge electrodes contact overflowing
ash, plus accelerated corrosion even more severe than that caused by air in-leakage.
Conduct a detailed inspection of all areas prone to leakage. As needed, clean off any remaining
ash residue to get a clear view of component surfaces.
Be sure to include the following:
Access doors. When properly fitted and maintained, the gaskets sealing the access doors in
the ductwork and casing will not allow air leakage. If the doors are not properly sealed, air
in-leakage can cause cold spots, with consequent condensation and eventual corrosion. The
problem self-perpetuates as damage increases with time, causing the holes to get larger and
thereby allowing more leakage. Eventually leakage increases to the point that the gas
distribution in the ESP is affected. The capability of the ID fans to draw the flue gas through
the ESP may also become a problem, resulting in unit de-rating. (Obviously a derate would
occur only after a long time, but there have been door seal leaks which eventually formed
holes about a square foot, or 0.1 m2, in size!) Carefully examine the door seal as you close
up the ESP after inspections or maintenance. Extra care as the doors are closed can minimize
repair costs in the future.
Corners near the inlet mouthpiece and outlet nozzles. These are prone to cracking and
tears.
Support stanchions, walkway anchors, conduit struts, and other casing attachments.
These are heat sinks that produce a relatively cold spot on the interior of the casing wall. If
conditions favor acid condensation, these areas will become perforated in time, allowing flue
gas to escape or air and rainwater to leak in.
Slide plates on the stub columns. If the plates do not move as they should (e.g., because of
grit in the sliding area or retainer (guide) bars not functioning properly), the seal welds at the
hopper attachment areas can tear.
Intentional holes or pass-throughs, such as those for opacity meters or sampling ports.
Make sure that seals are in good condition and there is no corrosion of the surrounding
casing.
One source of intentional air in-leakage is through the high-voltage support insulators. Ideally,
each insulator should be equipped with a heated purge/ventilation system to minimize ash and
highly conductive carbon buildup on these insulators, thereby preventing electrical tracking and
subsequent cracking. Such a system features holes in the insulator cap which allow ambient air
to enter, become warmed, and purge the ash deposits. (Note that the heater-only systems
5-18
installed on some ESPs provide only minimum protection against condensation and are
ineffective against high concentrations of unburned carbon.)
Carefully check the insulator holes for corrosion or blockage. Cold air entering through the
purge system sometimes results in secondary corrosion of the insulator compartment floor
(where applicable) and the support shafts. Personnel entering the crawl space area (if equipped)
could be injured if the upper frame should collapse as a result of deteriorated support shafts. As a
rule, natural-draft purge systems should be replaced with forced-draft combination heat and
purge systems whenever possible.
5.6.5 Ductwork
The entire ductwork system should be inspected as well. Examine the corners, seams, and access
doors for tears and corrosion, especially if there was a significant ash buildup in the area. Loose
or damaged turning vanes, expansion joints at inlet and outlet flanges, and connections should be
noted so appropriate repairs can be made.
Also check for holes in the ductwork. In many instances, leaks in ducts and expansion joints can
be determined from an external inspection of the duct while the unit is in service. However,
some holes may be too small to be visible from the outside or may be blocked by insulation and
lagging on the ducts; these holes can usually be detected from the interior of the duct by turning
off all the lights inside and observing the entry of sunlight. It is also helpful to check the ducts
for water leakage if it happens to rain during the outage.
Company
Address
Tel. 847-677-3500
Fax 847-677-3539
Barnant Co.
Tel. 847-381-7050
800-637-3739
Fax 847-381-7053
Tel. 800-548-9409
Fax 410-358-0252
Tel. 800-899-9717
Fax 412-788-4890
Tel. 800-424-7356
Fax 408-646-8901
Tel. 800-826-6342
Fax 203-659-7700
Tel. 800-788-5666
Fax 609-844-0466
Solomat, a Division of
Zellweger Analytics
Tel 800-765-6628
Fax 770-967-1854
Testo, Inc.
35 Ironia Rd.
Flanders, NJ 07836
Tel. 800-227-0729
Fax 973-252-1729
5-20
Gas flow measurements are customarily made either just before or after the inlet field
(downstream is the common choice for large ESPs) and possibly just before or after the outlet
field. Also measure gas flow above the electrified fields (typically midway through the field
length) and through the hoppers (typically mid-hopper).
At each measurement location, divide the ESPs internal cross section into an array of sampling
points and take gas velocity measurements at each of these points. For a typical installation,
measurements should be made in the center of the space between about every fifth set of
collecting plates across the ESP at vertical intervals of about every three to four feet. Test
personnel should stay well away from the measurement instrument location to avoid interfering
with the actual gas flow.
precipitator performance by both kinds of non-ideal effects are illustrated below in Figure 5-5. It
should be noted that as precipitator performance is improved throughout the optimization
program, the relative impact of the various non-ideal effects escalates in importance. Indeed, for
applications where the ash resistivity is optimum (on the order of 1 x 1010 -cm) and all
electrical and mechanical equipment is in good condition, the non-ideal effects become the
limiting factor on ultimate ESP performance.
5-22
Figure 5-4
Relationship Between Collecting Efficiency and Gas Velocity Non-uniformity for Different
Resistivities (Gas Sneakage Factor = 10%)
5-23
Figure 5-5
Relationship Between Collecting Efficiency and Gas Sneakage Factor (Gas Velocity gas =
25%)
5-24
6
CORRECTIVE MEASURES FOR COMMON PROBLEMS
This chapter reviews the following frequently encountered suboptimal conditions, as well as
correction options that can restore ESP performance:
Non-optimum rapping
Undesirable fly ash properties (high or very low resistivity, excessive fines)
Some of these problems will have been observed during on-line data gathering; others may have
become obvious during internal inspection. Naturally, repair and replacement decisions should
be made in the context of the remaining time to the next replacement of an ESPs internals. The
ESP models discussed in Chapter 3 can be used to simulate precipitator performance as is to
determine the value of the proposed correction (i.e., the expected increase in collection
efficiency).
Note that some problemssuch as high-resistivity ash or poor gas flow distributioncall for
solutions that may entail a significant capital investment. Such measures are covered more
thoroughly in Volume 2 of this guide. Indeed, optimization should typically cost no more than
$10$20 per kilowatt of generating capacity. If needed repairs are so extensive that costs are
estimated to be much higher, a more significant upgrade should be considered.
coincident design changes that would improve environmental performance. Such improvements
include eliminating sigma-style plates, converting to rigid electrodes, rebuilding with wide-plate
spacing, re-sectionalizing, adding rappers or heated purge systems, etc. Rebuild options are
discussed in Volume 2 of this report.
Figure 6-1
Example Condition Assessment Curve: Plot of Metal Thickness vs. Time
for Collecting Plates (four casing arrangement)
The remaining time until collecting plates need to be replaced can be estimated by sampling the
plate thickness periodically, usually annually, and correlating the trend with the original
thickness and year installed. This will produce a curve that, in time, will approach zero
thickness, as depicted in Figure 6-1. Obviously, thinning plates will create problems before they
wear down to nothing; as a general rule, the minimum thickness for a sigma-type plate is about
17 mils (0.43 mm). Other plates, such as those with fabricated stiffeners, can function as thin as
15 mils (0.38 mm). These minimum levels allow the plate to be self-supporting. Original
performance cannot be expected at these thickness levels, as incidences of warpage, detachment,
and perforation are common. The thickness level at which these problems usually begin to occur
is about 25 mils (0.64 mm).
6-2
Note that plate wastage does not occur evenly throughout a precipitator. Wastage frequently
begins at the bottom elevation of the outlet. While this is true for both hot- and cold-side
precipitators, the plate replacement cycle for a hot-side precipitator is generally longer than for a
cold-side unit. Of course, there are exceptions. Units that are energized before the flue gas
stabilizes near operating temperature usually experience deterioration beginning at the inlet and
traveling to the outlet. Also, units with unheated natural or forced purge air for the insulators
generally experience deterioration beginning at the top elevations. (The pattern in these
examples is greater wastage in cooler areasi.e., those more prone to moisture and acid
condensation.) Further, certain duct configurations that produce cross-sectional flow
maldistribution may create localized wastage within the precipitator.
6.2 Leakage
Leakage of ambient air or water into the ESP or ductwork will decrease particulate collection
efficiency. Air in-leakage disturbs flue gas flow adjacent to the hole and adds to the gas load
that must be handled by the ESP and ID fans. Further, because the in-leaked air is at a lower
temperature than the flue gas, it may cause the water and acid vapor in the flue gas to condense,
which in turn can cause corrosion. Condensation increases the likelihood of ash buildup, with
corrosion occurring under the cover of the ashhidden until significant damage has occurred.
Damage from water leakage is similar only worse.
In a positive-pressure ESP, out-leakage will occur, causing different but similarly serious
problems. As noted in Chapter 5, out-leakage can promote deterioration of lagging, rappers, and
controls; moreover, the hot, SO2-laden flue gas can pose a safety hazard. Although out-leakage
will probably increase the collecting efficiency of ESP proper, the fly ash leaked out with the
flue gas will increase total plant emissions of particulate matter.
Before you determine the best way to plug a hole, verify that it was not created by design. Small
holes are required in various places, such as for pass-through of an energy transmission device or
electrical power feed, or for air intake to the support insulator purge system. Naturally, if these
intentional holes have been enlarged by corrosion, they should be repaired down to their proper
size. Note that the purge holes in the top of the high-voltage insulator caps may be larger than
inspectors sometimes think they should be, but unless there is evidence of unintentional
enlargement, they should be left alone.
Welding can repair most holes in the casing, rooftop, or metallic ducts. Be sure that the weld
material does not reduce electrical clearances or leave a sharp point for sparking from the high
voltage distribution or discharge electrode systems. Nonmetallic joints can also be repaired as
long as the patch can be made to adhere to the joint material. Avoid patching that diminishes the
ability of the joint to allow dimensional growth. If the expansion joint can no longer function
properly, the ESP or ductwork could incur even worse damage than that caused by the hole. The
caution in any joint repair is to keep the joint flexible and allow for thermal expansion in the
appropriate directions.
Be sure to replace any damaged sealing boots on access doors and ports.
6-3
buildup increases, corona start voltage increases and the V-I curve shifts toward a secondary
voltage noticeably higher than historical norms.
As with the collecting plates, adjust the rapping frequency field by field. The same time
intervals suggested for collecting plate rappingor perhaps more frequent intervalsare good
starting points.
6-6
spacing (1216 inches or 3041 cm) can tolerate a greater degree of misalignment; if
misalignment is truly a problem, it should show up on the V-j curves.
It is important to determine the root cause of plate misalignment, because if the underlying
problem is not addressed, the misalignment will probably recur. Misalignment can be classified
into two categories: dead and live.
properly during construction or are not level, a dead misalignment may develop over time
because of the improper installation. The installation errors should be corrected if possible. A
permanent correction may not be possible because other factors such as poor gas flow
distribution may also be responsible. Finally, there are instances where the root cause is difficult
to identify, such as when residual stress relief is responsible.
6-8
Rigid frames can warp for reasons similar to those that would bend the collecting plates.
Straightening them can also be accomplished by heating and bending or crimping as described
for the collecting plates (see Section 6.4.3). Replacement of badly damaged sections should be
considered. Often where collecting plates are severely damaged, the discharge electrode system
will also be damaged.
Entrance access for replacements can be obtained by cutting a slot in the roof or moving
replacement pieces in through the hopper. As with plates, be sure to consider longitudinal as
well as vertical misalignment, and investigate the root cause to ensure the long-term efficacy of
the repair or replacement procedure.
The frame restraining grid is often held in place by an insulator attached to the hopper wall. The
insulator maintains electrical isolation for the discharge electrodes and prevents the entire
discharge electrode assembly from shifting or swaying due to either gas flow or electrical forces.
This insulator should be replaced if damaged or broken.
6-10
Figure 6-2
Example Relationship Between Power, Rapping Intensity, and Opacity
T-R sets, however, can sometimes be undersized for present conditions. This situation could
arise if an ESP designed for a relatively high-resistivity ash is now collecting an intermediateresistivity ashdue to coal switching, the addition of flue gas conditioning, or operational
changes that altered flue gas temperature. In this case, the power density in the ESP fields (watts
per unit of collecting plate area) could easily double or triple, e.g., 1.8 W/ft2 (19 W/m2) vs. 0.5
W/ft2 (5.4 W/m2). Also, older controls that permit operation in back corona can have very high
power densities, e.g., 1.52.0 W/ft2 (1622 W/m2), although not all of this power is useful. TR sets with inadequate power typically require some combination of the replacement of the
transformer with one of a higher rating and the addition of new power supplies. Such a retrofit
will enable higher power densities in the collecting region, which in turn will yield a small boost
in collection efficiency.
Replacement of an antiquated control system will often improve ESP performance, increase
reliability, and save energy. Volume 2 of this guide discusses available options. In general, the
big improvement comes from upgrading analog controls to digital. Changing from one type of
digital control to another may not appreciably change performance.
Note that upgraded controls offer limited performance improvement potential for units with
moderate ash resistivity; benefits are usually greatest for high-resistivity ashes. Accordingly, it
is worthwhile to consider specific precipitator challenges (e.g., back corona), control system
6-11
response, and potential modifications or partial replacement before replacing power supply and
control systems en masse.
back corona forms, and the increase in conduction angle carries the power supply to current
limit. In contrast, a digital, PC-based system can detect operation tending toward back corona
and reduce the power input to maintain operation before back corona formation.
In other instances with higher ash resistivity, there is a general electrical breakdown in the entire
ash layer causing a great increase in current flow at lower voltages. Older power supply controls
will operate near current limit under these circumstances, while computer-based control systems
can be programmed to operate at a point just at the beginning of back corona formation. If back
corona is a persistent problem, upgrading to a digital control system is recommended.
6-13
setswork that is beyond the normal capability of plant maintenance personnel. In such cases,
this is an option for a serious ESP rebuild, and is described in Volume 2 of these guidelines.
difficult to collect with an ESP. Such a high resistivity would require flue gas conditioning with
SO3 to maintain near-expected ESP performance.
You may be able to correct the problem by adding or modifying baffles to promote more even
flue gas mixing. If this fails to achieve the desired improvement, you will need to lower the ash
resistivitytypically through flue gas conditioning, which is discussed in detail in Volume 2 of
this guide.
6-15
Figure 6-3
Fly Ash Resistivity as a Function of Temperature
However, in practice, many ESPs do not meet these standards and exhibit undesirable gas flow
characteristics that, when corrected, could significantly boost collection efficiency. Very poor
gas velocity distributions can arise because a careful gas flow model study was not performed
and implemented initially, or because events within the ESP or upstream of it are affecting the
gas flow.
6-16
Two examples illustrate this point. In one case, the power station was equipped with a
multiclone particle collecting system preceding an ESP. The unit burned a higher-sulfur coal
that produced a flue gas with sufficient sulfuric acid to corrode the multiclone system. As the
multiclones deteriorated, some of the flue gas would flow through the holes in the multiclones,
causing a very poor gas velocity distribution in the ESP and severely degrading overall
precipitator performance. The solution to this problem was to remove the old multiclone.
Thereafter, the ESP alone provided about the same collecting efficiency as the previous
combination when both collectors were operating in tandem. This result is not unexpected, as an
ESP provides very high collecting efficiencies for the larger particles that were previously
removed in the cyclonic pre-collectors.
The second example concerns an ESP that was not equipped with anti-sneak baffles in the ash
hoppers. This particular plant burned a coal with an ash content approaching 50%, and thus
required very large ash hoppers. An ESP model study indicated that the addition of anti-sneak
baffles in the hoppers would reduce the outlet emissions by more than half. Thus, careful gas
velocity distribution control was critical.
Use one of the ESP models discussed in Chapter 3 to evaluate your units gas velocity
distribution measurements (discussed in Section 5.7). If the measured data are such that gas =
0.25 or more and S = 0.12 to 0.15 or higher, there is ample opportunity to improve ESP
performance by modifying the gas velocity distribution and gas flow baffles.
Before embarking on such an improvement, it will be necessary to model the gas flow in detail.
This complex exercisewhich requires modeling a significant portion of the boiler, ductwork,
particulate collecting, and stack systemwill usually require hiring an expert with previous
experience in gas flow studies. Several contractors specialize in either physical or computer
model studies; both types of study are probably equally successful in establishing a good gas
flow distribution and the costs are generally comparable. Alternatively, some ESP
manufacturers can also provide this modeling service, and bring not only modeling experience
but also the expertise to provide workable corrections for the unit.
The model study will provide a description of the modifications needed to correct the gas flow in
the ESP. These corrections can usually be installed during a short plant outage. Another round
of flow measurements is appropriate after modification, to verify that the new distribution
achieves the modeled performance projections.
Note that consideration is currently being given to the use of a non-uniform gas velocity
distribution to compensate for some rapping reentrainment situations. Data available are
inconclusive, but the concept seems to have validity. Volume 2 of this guide discusses this
skewed flow redesign concept in greater detail.
6-17
considering; however, blending adds some degree of complexity to power station operation.
Alternatively, sodium-containing compounds such as sodium carbonate or sulfate can be added
to the coal in the bunkers prior to combustion. A word of caution about increasing the sodium
concentration in the fuel supply: Higher concentrations of alkali metals in the fuel can sometimes
aggravate boiler slagging and fouling. Be sure to carefully monitor the furnace during any
experiments involving higher sodium content.
For cold-side units, options for coal switching are quite limited. Fly ash resistivity for cold-side
units is usually governed by the sulfur content of the coalthe higher the sulfur content, the
lower the resistivity. Yet switching to a higher-sulfur coal is generally not an option given acid
rain regulations restricting SO2 emissions. Thus, flue gas conditioning is the corrective measure
of choice for cold-side units suffering from high ash resistivity.
Flue Gas or Fly Ash Conditioning
In cold-side units, modifying the flue gaswith SO3, moisture, ammonia, or other agentscan
reduce fly ash resistivity and thereby improve ESP collection efficiency. To get a rough idea of
the potential performance improvement for your unit, assume a resistivity value of 1 x 1010 -cm
on Figure 2-2, select the corresponding average current density, and use the appropriate curve
among Figures 2-3 through 2-8. The ESP models discussed in Chapter 3 provide a much more
accurate prediction of unit performance improvement with flue gas conditioning.
Various flue gas conditioning technologies are discussed in detail in Volume 2 of this guide.
negative polarity (for ESPs with negatively charged discharge electrodes), causing the collected
layer to be pressed toward the collecting electrode by the applied electric field. The electric field
distribution in the inter-electrode space and in the ash layer is illustrated in Figure 6-4.
Contrast this situation with the case where the ash resistivity is low and the electric field in the
ash layer is less than that in the adjacent space. This condition leads to the formation of a
positive surface charge layer on the ash. The action of the electric field on the positive surface
charge layer is to change the electrical force from a clamping force to one that is directed back
into the gas stream. When this electrical force is greater than the combined mechanical and Van
der Waals forces, the particles will be electrically reentrained. Erosive forces from the gas flow
can also contribute to this reentrainment.
This mechanism for particle reentrainment was demonstrated and identified in a pilot-scale test
of a spray dryer operating ahead of an ESP, when the system was operated near the moisture dew
point. These conditions produced a composite ash and spray dryer residue resistivity of about
107 -cm; significant electrical reentrainment occurred. A small increase in temperature to
increase the resistivity eliminated the problem.
This type of reentrainment mechanism is responsible for the high emission or opacity problems
sometimes encountered in plants with significant quantities of unburned
6-20
Figure 6-4
Electric Field as a Function of Position in the Inter-electrode Space
carbon in the fly ash. Typically, if the loss on ignition (LOI) is less than 56%, the unburned
carbon does not cause a problem. (In some cases where the ash resistivity is marginally high, the
higher LOI conditions can actually improve ESP performance). But, if the LOI due to unburned
carbon exceeds 910%, the carbon particles may be preferentially reentrained and contribute
significantly to overall particulate emissions. In this case, the percent LOI for an outlet mass
sample from an ESP will be significantly greater than that for an inlet mass sample. The
problem of carbon carryover into the ESP outlet is frequently found in plants that have converted
to low-NOX burners.
6-21
Combustion engineers may be pursuing solutions to reduce LOI for other performance
objectives, and in this case, high reentrainment due to low resistivity will likely be corrected as
well. Otherwise, flue gas conditioning with ammonia or a combination of ammonia and SO3
may be required; see Volume 2 for discussion of flue gas conditioning options.
6-22
A
DATA SETS USED TO GENERATE PERFORMANCEESTIMATING CURVES
The graphs presented in Chapter 2 for estimating the expected best performance of a normally
operating ESP were derived from a statistical analysis of performance data from numerous fullscale precipitators. These data were collected over several years in projects conducted for EPRI
and EPA.
The data sets consisted of measurements of inlet and outlet mass loadings, particle size
distributions, electrical resistivity as measured in situ and in the laboratory, and the electrical
readings from the power supply controllers. In most cases, the secondary voltages were
measured with calibrated voltage dividers and the current meters were verified by measuring the
value of the resistor in the ground return leg of the power supplies.
The electrical data were obtained from 17 field tests on 13 different cold-side ESP units at 12
plant sites. The ESP units had 3 to 6 electrical fields in the direction of gas flow. The electrical
resistivity of the fly ash ranged from the mid-1010 -cm to the mid-1012 -cm level. Four of the
units were tested with and without flue gas conditioning for resistivity modification. Table A-1
provides the actual value of current densities for each data set together with the in situ resistivity.
Where the ESPs were operating with back corona, the voltage vs. current curves were examined
to estimate the useful current density. The current density selected was that value where the V-I
relationship changed curvature noticeably.
The secondary voltages were evaluated in a similar fashion. The collecting fields plate-to-plate
spacing varied from 9 to 12 inches (23 to 30 cm). The operating voltages for each electrical field
are given in Table A-2.
The operating current densities for the first three fields of the ESPs in Table A-1 are plotted in
Figures A-1, A-2, and A-3 against the measured in-situ resistivity. The solid curve fit lines
(one per figure) indicate the relationships between current density and resistivity for wellperforming ESPs. They can be used to estimate the useful current density in a field when in situ
resistivity is known, or conversely, to estimate resistivity when a useful current density value
(i.e., no back corona or arcing) for one of the first three fields is known. Included in these
figures are lines representing an electric field in the ash layer of 1 kilovolt per centimeter and 15
kilovolts per centimeter, based on average values of current density (breakdown would occur
based on the higher local value of current density, but current density distributions were not
known).
A-1
The data summarized in this appendix were analyzed to develop a set of generalized voltage vs.
current curves for the test ESPs. The voltages were adjusted for the different plate spacings to be
appropriate for a generic ESP with 10-inch (25-cm) plate spacing. These voltage vs. current
density curves are presented in Figure A-4.
Table A-1
Fly Ash Resistivity and Estimated Useful Current Densities
(see Appendix E for metric conversion factors)
Test
Resistivity cm
Inlet
2
A/ft
Section 2
2
A/ft
1.5E12
3.0
3.0
1.6E10
11.5
17.5
5.0E11
5.0
03.0
1.0E11
18.6
25.2
3.6E11
11.4
15.3
2.6E10
14.5
6.9E12
A-2
Section 3
2
/ft
Section 4
2
A/ft
Section 5
2
A/ft
Section 6
2
A/ft
10.8
16.3
26.8
31.1
16.2
16.2
16.4
14.5
32
0.5
1.5
3.0
5.5E12
0.7
0.8
2.0
2.2
5.4E11
4.0
5.0
8.0
13.0
10
2.2E10
18.8
28.4
38.6
46.0
11
1.0E12
1.7
4.0
7.0
8.0
12
6.0E10
6.2
11.0
24.3
25.3
13
2.0E11
8.5
6.0
8.0
12.0
13.0
14
7.0E11
4.4
6.0
16.0
22.0
23.0
15
2.1E10
12.8
45.5
53.0
54.0
58.0
49.4
16
5.8E11
6.0
10.0
10.0
10.0
17
4.1E10
16.1
24.9
13.8
23.8
29.8
36.8
23.6
17.0
17.0
Inlet
Section 2
Section 3
Section 4
Section 5
Section 6
35
35
11
56
44
43
38
51
40
38
37
40
39
43
39
40
41
41
41
35
44
25
29
26
12
39
31
40
34
9.75
37
40
36
37
10
10
48
50
48
48
11
33
31
26
24
12
38
35
36
32
13
12
41
39
52
38
36
36
14
12
56
59
59
15
10
45
49
46
40
38
35
16
34
40
38
33
17
39
41
36
41
37
40
43
34
A-3
Figure A-1
Current Density vs. Ash Resistivity for Inlet Section of an ESP
A-4
Figure A-2
Current Density vs. Ash Resistivity for Second Section of an ESP
A-5
Figure A-3
Current Density vs. Ash Resistivity for Third Section of an ESP
A-6
Figure A-4
Voltage vs. Current Curve Composite From Seventeen ESP Tests Used for Correlation (All
Normalized to 10-inch Plate Spacing)
A-7
B
PRECIPITATOR PERFORMANCE EVALUATION USING
ESP MODEL
This appendix offers a step-by-step example of using an ESP model to evaluate an existing ESP.
The example applies to all versions of the core model developed by Southern Research
Institutethe SRI/EPA version, and EPRIs ESPert and ESPM models. ESPM is the simplest to
use and therefore recommended unless you already have experience with one of the other
models.
The ESP model is a useful tool for comparing the actual performance of an ESP to that which
could be expected for the conditions existing in any coal-burning power station. If the actual
performance is less than predicted, the model is also useful for investigating the reasons for the
substandard performance. Before any upgrade is undertaken, a systematic evaluation program
such as that described in the body of this volumeshould be used to determine if the ESP is in
good mechanical and electrical condition.
In order to evaluate a precipitator, certain data are required for the analysis. Mandatory inputs
are listed in Table 3-1; these include gas temperature and velocity distributions in the inlet and
outlet ducts, inlet particle size distribution, fly ash resistivity, T-R secondary voltage-current
readings, and electrical operating points. These data, in addition to careful inspection of
precipitator components, can be used in a variety of methods to evaluate a precipitator.
Comparing measured precipitator data with the ESP performance predicted by the model
provides the opportunity to diagnose the possible reasons for a degraded level of precipitator
performance. There are various ways to conduct such an analysis; this appendix demonstrates
one such approach. Note that the sequence of data gathering referred to in this appendix does not
always match the sequence of data gathering described in the body of this guide; however, the
necessary steps are identified and can be re-sequenced as needed to match the logistics of a
particular situation.
The procedure adopted in this example begins with the assumption that the precipitator is in
good mechanical and electrical condition and is operating with maximum useful current density.
If the actual performance is less than the model-estimated performance under these conditions,
the following steps are taken to examine the potential causes for the degraded performance.
B-1
resistivity is greater than 1 x 1011 -cm, flue gas conditioning to reduce the resistivity may be
considered as an option. This should result in significantly higher operating voltages and
currents without excessive sparking or back corona.
B-3
Step 4.1. Determine if the operating currents are completely useful in the
precipitation process.
At this point, the electrical operating conditions should be examined to determine whether or not
the operating currents are completely useful in charging and collecting particles. If excessive
sparking or back corona is occurring in the ESP, then the measured currents will not be
completely useful in the precipitation process. On the contrary, the currents may actually be
detrimental to the performance. ESP model input data, which use the values of currents
measured under these conditions, may result in the prediction of much higher collection
efficiencies than can be achieved in practice.
Excessive Sparking
Sparking consists of highly localized currents that are not effective in charging particles.
Furthermore, excessive sparking can lead to increased particle reentrainment. Excessive
sparking disrupts the surface of the collected fly ash layer and reduces the electrical holding
force over large regions of the layer because of decreased currents to those regions. If sparking
is occurring, then the extent of the sparking should be measured with spark rate meters.
Acceptable levels of sparking are in the range of 1060 sparks per minute. If excessive sparking
is occurring, then the operating voltage should be lowered; the power supply controllers should
be adjusted or upgraded. Although the operating voltages and currents will be lower, the ESP
performance may improve (unless the problem is caused by severe ESP mechanical problems)
and the use of the lower operating electrical conditions in the ESP model will give better
agreement between estimated and measured collection efficiencies.
Back Corona
In a condition of severe back corona, both positive and negative ions move in the inter-electrode
space. The measured current can be very much greater than the current that is actually useful in
the precipitation process. The detection of back corona was discussed in Chapter 4. The
measured value of fly ash resistivity can be used with Figure 2-2 to estimate the maximum
allowable average current density. The curves shown in that figure are based on the average of
17 sets of measurements of in situ fly ash resistivity and useful current density in each electrical
section of fly ash ESPs. If the average current density in the ESP greatly exceeds those values
indicated for a given fly ash resistivity, the ESP may be operating in back corona.
As a second check, the secondary voltage-current curve for each electrical section can be
examined to see if at some point on the curve increased current is obtained with decreased
voltage (see Figure 4-21, 4-22, or 4-23). If the ESP is operating on this portion of the voltagecurrent curve, then it is operating in back corona. As another check, the secondary voltage
waveform can be displayed on an oscilloscope. A rectified voltage waveform that periodically
dips near or below the voltage value at corona start (where ripples in the voltage waveform first
appear) indicates back corona (see Figure 4-19).
B-4
If severe back corona is occurring, the operating voltage should be lowered to operate with a
lower current density that will not lead to the formation of back corona. The reduced voltages
and currents will usually result in improved performance, and the use of the lower electrical
operating points in the ESP model will give better agreement between estimated and measured
collection efficiencies. These operating points suggested for high-resistivity fly ash can be more
readily obtained with one of the more modern PC-based power supply controls. Since back
corona and sparking caused by high fly ash resistivity will degrade the ESP collecting efficiency,
flue gas conditioning can be considered as a means for improving the performance.
Electrode Misalignment
If the spacing between plates or between discharge electrodes and plates is out of alignment by
over 1/2 inch (1/4 preferred), then corrective measures should be taken. Significant
misalignment of the electrodes is detectable from secondary voltage-current curves obtained
under air load conditions. The air load V-j curves should be the same for different electrical
sections with similar geometry, up to the current limits of the T-R sets. If these curves differ
significantly, then misalignment of some of the electrodes is expected. Warped plates can result
in very low secondary voltages with high values of localized currents. The electrode alignment
should always be checked to avoid reaching wrong conclusions. For example, low secondary
voltages may be attributed wrongly to high fly ash resistivity, when mechanical deformation of
the electrodes may be responsible.
value. If the measured value of gas is greater than 0.25, then improving the gas velocity
distribution will likely improve the ESP performance. The gas flow above and below the
electrified fields should also be measured during the gas flow measurement. These data apply to
the following section.
Estimates of the degradation of precipitator performance caused by poor inlet gas velocity
distribution are illustrated in Figure 5-4. These curves for collecting efficiency vs. gas were
computed by the ESP model using the input data described in Table 2-1. The example curves
were computed for SCA values of 250 and 500 ft2/kacfm, corresponding to 3 and 6 sections in
the direction of gas flow. The gas sneakage fraction was set at 0.10. Each value of gas was set
the same throughout each field of the ESP. For older units with poor inlet ductwork or with
partially plugged diffuser plates, it is not unusual to find a gas values of 0.40 or more. At the
point on the curve for SCA 250 ft2/kacfm and fly ash resistivity 1 x 1011 -cm, the collection
efficiency is 98.6%. If the gas velocity distribution is improved to gas = 0.25 (efficiency
99.05%), the emissions would be reduced to 0.68 times the original value.
The fraction of gas bypassing the electrified fields should be determined from measurements of
the total gas flow and the gas flow above and below the electrified fields during the gas flow
distribution tests. If the sneakage fraction S is greater than 0.10, then the baffling to control the
gas sneakage through the non-electrified regions should be upgraded. The effect on ESP
performance by gas and fly ash particles passing above or below the electrified fields is similar
to the effect of non-rapping reentrainment. Both non-ideal effects are mathematically simulated
in the ESP model by an approximate correction to the precipitation rate parameter, using the
specified numerical value of the sneakage fraction S. Estimates of the degradation of
precipitator performance by both kinds of non-ideal effects are illustrated in Figure 5-5.
If the measured values of gas and S are not large enough to cause poor performance, or if
improvements in gas and S do not cause a match between measured and estimated efficiencies,
then particle reentrainment should be investigated. Collection efficiency measurements should
be made with and without the rappers in operation to determine the fraction of the total emissions
from rapping reentrainment. If rapping reentrainment accounts for more than 40% of the total
emissions, then efforts should be made to reduce the rapping reentrainment by changing the
rapping frequency or rapping intensity. (Note that ESP performance may take several days or
weeks to stabilize after changing the rapping in outlet fields.)
If rapping reentrainment is not a significant problem, then particle reentrainment without rapping
may be limiting the performance. Non-rapping reentrainment can result from high average gas
velocity, a very non-uniform gas velocity distribution, a low value of fly ash resistivity,
excessive sparking, low operating current densities, hopper ash buildup, air in-leakage through
the hoppers, or malfunction of the hopper emptying mechanism. The measured gas velocity
distribution and the measured gas flow below the electrified fields (above the hoppers) should be
analyzed to see if reentrainment is resulting from poor gas flow. The ash collection hoppers
should be checked to see if they are functioning properly. Sporadic reentrainment without
rapping can be detected by a continuous opacity monitor at the precipitator outlet.
B-6
As precipitator performance is improved with new design and new retrofit technology, the role
of the various non-ideal effects escalates in importance. Thus, Step 4.3 in the evaluation
procedure is of great significance in the upgrade studies for the higher efficiency designed ESPs.
The various non-ideal effects become the limiting factor on ESP performance as the efficiency is
increased.
Summary
In summary, the precipitator evaluation method described in this section can be a valuable aid in
diagnosing the causes of poor precipitator performance. Costly modifications to the precipitator
that will not result in a significant improvement in performance can be avoided. Again, a
precipitator should be placed in good mechanical condition and its performance should be
properly diagnosed before initiating flue gas conditioning or any other type of upgrade.
B-7
C
ELECTROSTATIC PRECIPITATOR PRINCIPLES
C-1
C-2
Two-Stage ESP
Single-Stage ESP
Figure C-1
Depiction of Single-Stage and Two-Stage Electrostatic Precipitators
C-3
Figure C-2
Schematic Example of Wire-in-Pipe Electrostatic Precipitator
C-4
Figure C-3
Example of Fly Ash Resistivity as a Function of Temperature
Selection of the hot-side units started with the increased utilization of low-sulfur coals, where the
electrical resistivity of the ash at the conventional temperature of 300F (150C) was higher than
that for the higher-sulfur coals customarily burned. In many instances, these hot-side units have
worked as expected, but there is a class of low-sodium coals that developed an increased ash
resistivity with operating timea phenomenon that has been associated with sodium depletion
in the collected ash layer. This characteristic, identified by Dr. Roy E. Bickelhaupt of Southern
Research Institute, is discussed in Appendix D on electrical conduction mechanisms in fly ash.
C-5
appearance is caused by the different directions of flow for the free electrons and positive ions
generated in the electrical breakdown process. In a negative corona, the electrons, which move
with much greater velocity than the more sluggish positive ions, are flowing toward the
collecting electrode. They must flow some distance before they form negative ions by attaching
to an electronegative gas molecule such as SO2, H2O, or oxygen. In a positive corona system,
conduction toward the collecting electrode is by the motion of positive ions formed in the corona
process. The positive ions provide a more ordered flow with a smooth transition from the corona
region to the quiescent zone in the electric field. The free electrons in positive corona flow
rapidly to the corona electrode without forming tufts.
There is one condition where negative corona appears as a smooth glow. When the ESP is
energized with very fast rise-time voltage pulses, the entire surface of the corona electrode is
brought well above the electric field strength for electrical breakdown, causing all the region of
space adjacent to the corona electrode to break down simultaneously. This fast rise-time
energization forces the negative corona to develop over the entire corona electrode surface,
yielding an appearance very similar to a positive corona.
C-7
As the applied voltage is further increased, the electric field near the next rough spot increases
until breakdown occurs there and proceeds as described above. The increased voltage
establishes a new equilibrium value of current from the first breakdown point as well. Increasing
the voltage from corona startup to the appropriate operating voltage, usually about 40 kV or
more, causes the corona electrode to develop tufts over its entire surface. An electrode system in
flue gas will reach an operating current density in the range of 40 to 50 microamperes of current
per square foot of collecting area (unless some other factor limits current). The numeric values
are about the same for metric units, as 1 A/ft2 equals 1.08 nA/cm2. Figure C-4 illustrates the
general shape of the voltage vs. current curve for the above sequence of events.
Figure C-4
Idealized Secondary Voltage vs. Current Curve
C-8
C-9
Figure C-5
Idealized Electric Field vs. Radial Position, With and Without Current Flow (Pipe Diameter
= 8 inches, Wire Diameter = 0.109 inches)
The value of the electric field and the characteristics of the flue gas determine the velocity of
charged particles moving under the influence of that electric field. The electrical force on the
particle, ion, or electron causes the charge carrier to accelerate and increase in velocity. The
motion of the carriers through the gas stream causes a frictional retarding force caused by the
collisions between the charge carrier and the gas molecules in the gas stream. The carrier
velocity increases until this frictional drag force just balances the force from the electric field on
the charge carrier.
The electrical mobility of the different charge carriers varies. Free electrons are extremely small,
so the drag force from molecular collisions is small. The mobility of ions is on the order of 1000
times less than that of the free electrons, but much greater than that of the charged ash particles.
In most industrial gases and especially power station flue gases, there is an abundance of
electronegative gases (molecules that readily attach free electrons); thus the free electrons
flowing from the corona zone quickly become attached, forming ions. Therefore, free electrons
only contribute significantly to the flow of current in the very narrow region near the corona
electrode.
C-10
The charged particles are much more sluggish than the ions. Even though the total electrical
charge attached to fly ash particles may be approximately the same as, or perhaps greater than,
that which resides on the ions, the velocities of the ash particles are negligible relative to that of
ions. Therefore, the ions carry essentially all of the current in an operating utility ESP. The
charged particles do contribute significantly to the space charge between the electrodes, but
because of their very low electrical mobility, they carry a negligible amount of current.
the particle decreases with time at a rate diminishing to zero as the saturation value of charge is
approached. The charging rate (inversely related to the charging time constant) for particles is
proportional to the free ion density in the vicinity of the particles. The total charge on the
particles is proportional to the surface area of each particle. Thus, large particles will acquire
more charge than small ones, proportional to the square of the radius. Therefore, the electrical
force to remove large particles will be greater than for small ones. The charging rate (see above
on time constant) is usually such that large particles acquire a saturation charge after passing
only a few feet into an ESP.
Figure C-6
Particle Charging Sequence Depicted for Field Charging
C-12
C-13
Figure C-7
Comparison of Field Charging Rates for Half-Wave and Pure DC Electrical Energization
is attained, both mechanisms are active. In this case, the charging rates for both systems must be
added. After the saturation value for field charging is attained, only the diffusion charging
component need be considered. Thus, the charging behavior for this intermediate size range can
be described as augmented field charging initially, followed by diffusion charging. The charging
equations in the ESP models take this into account for the intermediate-size particles.
and reactive components from the power supply and distribution system. Thus, the
instantaneous applied voltage and the free ion density change with time. Hence, the charging
rate changes with time, and in fact charging may be interrupted during portions of the voltage
cycle. The time-varying secondary voltage and an estimate of the charge vs. time for a range of
conditions are shown in Figure C-7.
A further complication is brought about by the introduction of large quantities of ash into the
precipitator inlet. The available charge is quickly bound to the particulate matter, which causes
an immediate reduction in the current. The highly mobile gas ions are quickly attached to the
relatively sluggish particles. Because the charging rate is proportional to free ion density, the
current quenching in the inlet section causes a decrease in the charging rate. For very low
current densities, such as those encountered in precipitators collecting high-resistivity ash or very
fine fume, charging times can be significantly long, resulting in a reduced collection efficiency.
If ash resistivity is low, charging times are usually short enough to be insignificant, often on the
order of a few milliseconds.
C-15
C-16
Figure C-8
Illustration of ESP Collection With Laminar Flow
Because the migration velocity for field charging is proportional to the particle radius, a
composite ash with a range of particle sizes would behave differently from one with a single
particle size. The distance required for 100% collection of small particles, say 1 m diameter,
would be 10 times as great as the distance for particles with a diameter of 10 microns. Thus, for
a particle size range that includes particles from the larger to the smaller, the ash concentration
would decrease as the precipitator was traversed, with the larger particles completely removed
first and progressively smaller ones collected subsequently. Thus, a concentration gradient, as
suggested in Figure C-9 would develop in the longitudinal as well as the transverse direction.
Research sponsored by DOE is currently being conducted (19961999) on the development of
laminar flow ESPs. The current interest is in developing a Laminar Flow Agglomerator that is
discussed in Volume 2 of this report.
C-17
Figure C-9
Illustration of the Development of a Particle Concentration Gradient for ESP Collecting a
Wide Particle Size Range With Laminar Flow
Within the inter-electrode space outside the boundary region, the magnitude of the electrical
migration velocity is small compared with the magnitude of the turbulent gas velocity. In this
region, the effect of the electrical velocity is to apply a small bias to the overall turbulent flow
toward the collecting electrode. The electrical velocity can be neglected in all but that region of
space immediately adjacent to the collecting electrode.
The consequence of this turbulent flow situation is that the collection efficiency, which could be
expressed as a linear function of the precipitator length for laminar flow, is modified to an
exponential relationship in the case of turbulent flow. In the distance where 100% collection
would occur with laminar flow, the concentration is reduced to [1 - 1/e] (~63%) for turbulent
flow, where e is the base of the natural logarithm system. The collection efficiency for the ideal
case where a given particle is moving with a given migration velocity is:
= 1 - exp{-(A /V)}
where is the efficiency, A is the collection surface area, V is the gas volume flow rate, and is
the migration velocity.
This exponential efficiency equation is known as the Deutsch-Anderson (D-A) equation.
Deutsch derived the exponential relationship, which was discovered experimentally by Anderson
in 1919, from theoretical considerations in 1922. Deutsch made several simplifying assumptions
in his original work. These include:
1. The particles are fully charged immediately on introduction into the collection system.
2. Turbulent and diffusive forces cause the particles to be distributed uniformly in any cross
section. (This assumption is more restrictive than necessary in actual practice.)
C-18
3. The velocity of the gas stream does not affect the particle migration velocity.
4. Particle motion is governed by viscous drag where Stokes law applies.
5. The particle always moves at its electrical terminal velocity relative to the gas stream.
6. Ash particles are separated enough for mutual repulsion to be neglected.
7. The effect of collisions between ions and gas molecules can be neglected.
8. There are no disturbing effects present such as erosion, reentrainment, uneven gas flow
distribution, or back corona.
Derivations of this equation are included in several texts (see Oglesby and Nichols, op. cit., and
H. E. Rose and A. J. Wood, Electrostatic Precipitation, London, Constable, 1956).
The D-A equation pertains specifically to the efficiency of the collection of particles with a given
migration velocity and hence of a given size. Because precipitators typically collect particles
with a wide range of sizes, no single equation is sufficient to describe the composite collection
efficiency for the system. A range of particle sizes will have a range of associated migration
velocities. The collection efficiency for the composite could be expressed as a summation of the
products of the ash load within an increment of size distribution with the collection efficiency
associated with that size interval, or by a definite integral for continuous particle size
distributions. Dr. Harry White performed this calculation for a log-normal size distribution in
Industrial Electrostatic Precipitation. Dividing the specific particle size distribution into a
number of small size increments and then determining the overall collection efficiency from a
summation of the individual incremental computations can make a very close approximation to
the actual performance. This technique forms the basis for computer models commonly used to
estimate ESP performance.
Reentrainment. Reentrainment can occur from erosion by either electrical or mechanical forces
during the collection process, from reentrainment during plate rapping, or from a pickup by the
gas stream of material in the ash hoppers. All forms of reentrainment constitute a reduction in
the collection efficiency by reintroducing previously collected particles into the exit gas stream.
Uneven gas flow. Uneven gas flow reduces the collection efficiency in two ways. First, the DA equation shows that the collection efficiency is inversely related to the gas velocity or volume
flow rate. Second, the region experiencing the high gas velocity also carries a greater percentage
of the total suspended fly ash material.
Sneakage. The hopper regions that store the collected fly ash in a utility ESP provide a nonelectrified region for the fly ashladen gas stream to bypass a portion of the ESP collecting
zones. This portion of the total gas flow is re-mixed with the main gas flow at the end of the
hoppers. The portion of the gas that bypassed through the hopper was not subjected to collection
in that particular collecting field. Gas sneakage was not considered in the original idealized
equations.
Particle size distribution. The particular particle size distribution fed into the precipitator also
has an effect on collection efficiency. If a mechanical collector precedes the precipitator, the
larger particles will be removed ahead of the precipitator. In the absence of a mechanical
collector, the large particles, which are easier to collect, will still be present in the precipitator.
The effect of particle size distribution can be illustrated by an example from an actual ESP in
service, operating with and without a mechanical collector. The power plant is a pulverized-coal
boiler burning an average bituminous coal with an ash loading of 2 grains per actual cubic foot
of flue gas. The ESP is a four-field unit with a specific collecting electrode area of 320 square
feet per thousand cubic feet per minute of flue gas. The particle size distribution from the
furnace has an mmd (mass mean diameter) of 14.4 microns with a geometric standard deviation
(p) of 3.6. There is no performance limitation imposed by high resistivity.
Particle collection was modeled for two cases: (1) the ESP alone, with no mechanical collector
and (2) a mechanical collector with a D50 of 8.5 microns and a collecting efficiency of 66.35%
installed before the ESP. The performance model built into EPRIs ESPert software was used to
compare the two examples. The particle collection characteristics for the mechanical collector
were estimated from the EPA student training manual Control of Particulate Emissions (Draft
September 1978), Air Pollution Training Institute, Research Triangle Park, NC 27711. The
ESPs were modeled with a gas sneakage of 10% and a gas velocity standard deviation of 12%,
indicative of an ESP that has been in service for several years, but is still in good condition.
In the first case, the ESP alone is the particle collection device. The ESP alone will provide a
collection efficiency of 99.917%, yielding an outlet loading of 0.0044 pounds per million Btu,
which corresponds to 0.0017 grains per actual cubic foot of gas and an opacity of 2%. The
model data are summarized in Table C-1.
The mechanical collector installed in front of the ESP will remove about 63.5% of
the fly ash before the entrance of the ESP, providing for an inlet loading of 0.73
C-20
Units
ESP
ESP + Cyclone
ESP + Cyclone
Gas Velocity
ft/sec
ft /kcfm
320
320
320
99.917
99.759
99.919
cm/sec
11.297
9.606
11.316
gr/acf
2.00
0.673
2.00
gr/acf
0.00166
0.00162
0.00162
99.950
99.837
99.945
ESP Efficiency
Precip. Rate Parameter
Inlet gr/acf
Cyclone
ESP Alone
ESP +
ESP Alone
ESP+Cyc.%
0.0875
0.00018
0.00018
4E-7
3E-7
99.766%
99.768%
0.145
0.00034
0.00034
2.1E-6
2.2E-6
99.368%
99.372%
0.205
0.00086
0.00086
7.2E-6
8.3E-6
99.163%
99.169%
0.285
0.00182
0.00182
2.06E-5
2.55E-5
98.868%
98.875%
0.465
0.00990
0.00985
0.0001240
1.64E-4
98.747%
98.755%
0.725
0.01408
0.01397
0.0001408
1.85E-4
99.000%
99.006%
1.025
0.02524
0.02494
0.0001725
2.14E-4
99.317%
99.321%
1.45
0.04294
0.04208
0.0001773
2.1E-4
99.587%
99.590%
2.05
0.06660
0.06227
0.0001462
1.45E-4
99.781%
99.782%
2.85
0.08824
0.07942
0.0001019
8.6E-5
99.885%
99.885%
3.85
0.10464
0.08790
0.0000676
4.7E-5
99.935%
99.936%
5.20
0.13972
0.10200
0.0000333
1.88E-5
99.976%
99.977%
7.25
0.18644
0.10441
0.0000030
1.3E-5
99.998%
99.998%
10.25
0.20624
0.08662
0.0000002
1.0E-7
99.999%
99.9999%
14.5
0.21638
0.05842
0.0000002
1.0E-7
99.9999%
99.9999%
20.5
0.20694
0.03104
0.0000002
1.0E-7
99.9999%
99.9999%
28.5
0.17276
0.01555
0.0000002
1.0E-7
99.9999%
99.9999%
51.0
0.29626
0.00889
0.0000002
1.0E-7
99.9999%
99.9999%
84.5
0.22042
0.00220
0.0000002
1.0e-71
99.9999%
99.9999%
Total
2.00
0.733
0.0010
0.0011
Note: Appropriate significant figures are exceeded in large particle ESP outlet load and in
efficiency/migration velocity, effective migration velocity, and precipitation rate parameter
grains per actual cubic foot of gas. The mechanical collector exhibits a 50% collecting
efficiency for particles with 8.5-micron diameter, with higher collecting efficiencies for large
particles and lower for small ones. The mechanical collector removes the large particles
C-21
preferentially, changing the inlet particle size distribution to the ESP to an mmd of 4.5 microns
and a p of 2.8. This change in particle size distribution causes the collecting efficiency of the
ESP to drop to 99.76%, with an outlet loading of 0.0043 pounds per million Btu or 0.0016 grains
per actual cubic foot, essentially the same as that without the mechanical collector.
This example indicates that the collecting efficiency of a good ESP alone will essentially match
that of a mechanical collector and ESP in series. This is because the mechanical collector
primarily removes the larger particles that will be easily collected in the ESP. The smaller
particles establish what material will actually exit the stack. (It should be noted, however, that
the ash loading in the inlet field hoppers of the ESP would be significantly reduced with the
addition of a mechanical collector). Table C-1 summarizes the results of this ESP model
comparison.
The term migration velocity refers specifically to the terminal velocity with which an individual
particle moves through the gas stream under the forces resulting from the action of the local
electric field on the charged ash particle and from the viscous drag of the flue gas stream. This is
the migration velocity as defined in the Deutsch-Anderson equation. This Deutsch migration
velocity represents the actual velocity for particles used in electrostatic precipitators. Other
expressions are used that can have the units of distance per unit time, but these are in fact
measures of performance, rather than a real velocity.
A generic or overall migration velocity is sometimes used to describe the performance of a
given ESP in a particular situation. However, in this usage, even though the term has the units of
velocity, the parameter should be identified differently from migration velocity because in
these instances the parameter is only a relative measure of performance. A more precise
identification for this parameter is either effective migration velocity or precipitation rate
parameter (PRP). This parameter, usually presented with the units of centimeter per second or
feet per minute, results from a simple calculation of the value of the parameter by the use of the
Deutsch-Anderson equation. As such it is at best a relative measure of performance. If the
collecting electrode area, gas volume flow rate, and collection efficiency are known, a
migration velocity can be calculated. However, in this usage, the migration velocity is not that
as defined in the original derivation of the D-A equation. Its value is not constant with respect to
changes in efficiency in any given ESP installation.
The previous example for a given ESP collecting fly ash from a pulverized-coal boiler both with
and without a mechanical collector illustrates this point. For the case where no mechanical
collector is installed, the collection efficiency is 99.917% with an SCA of 320 square feet per
thousand cubic feet per minute of flue gas, which provides a precipitation rate parameter (PRP)
of 22.24 feet per minute (11.3 cm/sec). When the mechanical collector is installed, the ESP
efficiency drops to 99.76% for a PRP of 18.9 ft/min (9.6 cm/sec). Note that the collection
efficiency for the ESP alone and the combination of the ESP and mechanical collector is
calculated to be the same (i.e., about 99.95%).
A second example employs an ESP model to compute the collection efficiency for the ESP
above with the gas velocity varying from 3 to 8 feet per second (0.9 to 2.4 meter/sec.). The
results of this exercise are summarized in Table C-2, including those from the previous example
C-22
with and without the mechanical collector. As the gas velocity is decreased, the collecting
efficiency for the ESP increases as indicated in the table. However, the increase in collecting
efficiency is primarily because of an increase in the collection of the smaller size fraction of the
particles, which have a lower Deutsch migration velocity. This increase in collection of the finer
size fraction results in a decrease in the PRP or effective migration velocity with increasing
SCA and efficiency. The migration velocities reported in Table C-2 neglect rapping
reentrainment. The migration velocities corrected for rapping reentrainment will decrease for the
higher gas velocities because of the greater amount of material collected in the outlet field, where
the major portion of the emitted reentrained material originates. There is also a small increase in
the charge on the particles because of the increased space charge from the uncollected particles
in the higher-velocity model runs.
Changing the gas velocity through the ESP while maintaining other factors constant establishes a
range of specific collecting areas (SCA) from 200 at 8 ft/s to 400 at 4 ft/s. The collecting
efficiency ranges from 99.985% at 4 ft/s to 99.65% at 8 ft/s. Note that the precipitation rate
parameter (PRP) increases from 11.21 cm/sec at the higher collecting efficiency up to 14.36
cm/sec at the lower collecting efficiency. This apparent contradiction results from the fact that at
high gas velocities, the percentage of large particles collected is high, and the larger particles
have a higher Deutsch migration velocity. However, note that the Deutsch migration velocity for
the ultrafine particles (smaller than about 1.5 micron in diameter) actually increases as the gas
velocity decreases. This increase is because the fine particles are primarily charged by diffusion
charging and the longer residence time allows these small particles to actually attain a greater
value of charge.
This contrasts sharply with the larger particles. The particles larger than 5 microns have
essentially the same migration velocity for the complete range of SCAs, as these particles reach a
saturation value of charge rather quickly for the electrical conditions used in the model. There is
a small increase for the larger particles as the space charge contributes to the saturation value of
charge for these particles.
The reason why the PRP decreases with increasing specific collecting area and efficiency is
somewhat more subtle. Compare the computed collection efficiency for particles 20.5 microns
in diameter with the efficiency for particles at 5.2 microns and 2.05 microns, over the range of
gas velocities.
C-23
5 (w/cyc)
SCA
399
319
319
266
228
200
Res. Time
9 sec
7.2 sec
7.2 sec
6 sec
5.14 sec
4.5 sec
Efficiency
99.985%
99.952%
99.86%
99.890%
99.79%
99.65%
PRP cm/s
11.21
12.17
10.46
13.01
13.74
14.36
Particle Dia.
Mig. Vel.
Mig. Vel.
Mig. Vel.
Mig. Vel.
Mig. Vel.
Mig. Vel.
0.0875
10.114
9.925
9.933
9.755
9.596
9.456
0.145
8.636
8.451
8.459
8.283
8.130
7.994
0.205
8.235
8.076
8.084
7.934
7.800
7.679
0.285
7.764
7.640
7.647
7.517
7.419
7.322
0.465
7.670
7.581
7.587
7.508
7.433
7.365
0.725
8.155
8.115
8.121
8.061
7.997
7.934
1.025
8.822
8.857
8.863
8.884
8.815
8.772
1.45
9.727
9.849
9.855
9.883
9.905
9.887
2.05
10.476
11.012
11.017
11.162
11.247
11.271
2.85
11.689
12.181
12.186
12.475
12.624
12.748
3.85
12.352
13.132
13.117
13.584
13.903
14.127
5.20
15.048
14.942
14.946
15.527
16.071
16.430
7.25
20.394
20.107
20.070
19.974
19.791
20.673
10.25
41.850
41.686
41.694
41.382
27.213
27.048
14.50
57.735
57.513
57.353
57.150
56.665
56.075
20.50
80.103
79.487
79.502
78.526
77.796
77.837
C-24
Table C-3
Collecting Efficiencies for Selected Particle Sizes as a Function of SCA
(see Appendix E for SI conversion factors)
SCA
399
319
266
228
200
Gas Velocity
4 ft/sec
5 ft/sec
6 ft/sec
7 ft/sec
8 ft/sec
Part. Size
0.0875
99.964
99.804
99.395
99.653
97.562
0.145
99.886
99.504
99.691
97.395
95.665
0.285
99.772
99.169
98.033
96.396
94.326
0.465
99.751
99.129
98.001
96.390
94.380
1.025
99.887
99.580
98.962
97.979
96.656
2.05
99.959
99.853
99.622
99.218
98.606
5.20
99.983
99.950
99.893
99.804
99.670
10.25
99.989
99.973
99.950
99.920
99.884
28.5
99.997
99.991
99.984
99.975
99.964
51.0
99.998
99.996
99.992
99.988
99.983
Overall Sizes
99.985
99.952
99.89
99.79
99.65
Even though the specific collecting electrode area varies from 200 to 400 square feet per
thousand cubic feet per minute in the example, the collecting efficiency for the large particles
remains about 99.99%which means the collecting efficiency for these particles remains
essentially constant. However, the collecting efficiency for the 5.2 micron particles varies from
99.98% to 99.67% whereas the efficiency for the 2.05 micron particles varies from 99.96% to
just over 98.61%. Clearly, the difference in collection over this very wide range in specific
collecting areas and efficiencies is the difference in the collection of the small particles. Because
these small particles have much lower migration velocities, the ensemble average for all particles
causes the PRP or effective migration velocity to decrease with increasing SCA and efficiency.
The efficiency data for selected particle size bands are summarized in Table C-3.
it. Several types of wet removal systems are in current use. One type uses a flooded header with
either cylindrical or parallel plate collecting electrodes. The tops of the electrodes are designed
to form a weir with water flowing down the electrode to carry the collected material with it.
Other types of wet collectors use water sprays to atomize water into the precipitator section,
where the water droplets precipitate onto the collecting surface and subsequently drain, carrying
the collected ash with them. Figure C-10 illustrates two configurations of precipitators with wet
removal systems.
The principal advantages claimed for wet removal systems are (1) reentrainment losses are
eliminated or kept to a minimum, and (2) resistivity problems are eliminated. These factors are
in part related to the wetability of the ash. Other claims are made for wet systems, including
condensation on small particles for better collection, and space charge enhancement. The
principal difficulties with wet collection systems are avoiding dry spots on the collecting
electrode, internal corrosion and scaling problems, loss of plume buoyancy (possibly requiring
reheat), and problems with handling the slurry that results from wet collection. Wet ESP aftercollectors are under consideration for applications downstream of wet scrubbers in units burning
high-sulfur coals, where acid mist condensation may present an opacity problem.
Dry ash removal is accomplished by either periodic or continuous rapping of the collecting
electrodes. If the ash deposit on the electrodes is allowed to accumulate until an appropriate
layer thickness is collected, it will tend to fall into the hopper in sheets or large clumps when
rapped. The majority of precipitators collecting solid particulate matter are of the dry ash
removal type. The principal problem with dry ash removal is reentrainment of the collected ash,
which must be maintained at a minimum for good overall collection efficiency.
Ash reentrainment can occur as a result of several factors. If gas velocity is high, ash can be
scoured from the surface. However, studies indicate that for most fly ash particles, scouring is
not a serious problem at gas velocities below about 12 ft/sec. Large particles tend to be scoured
more easily than small ones, so some scouring of large particles may occur if the gas velocity
distribution is very non-uniform (creating regions of high velocity).
Reentrainment losses, however, are primarily associated with ash removal during plate rapping.
Minimizing rapping reentrainment requires careful attention to establishing the appropriate
rapping frequency and intensity. Rapping frequency is of importance in preventing too thick a
deposit from accumulating on the plate. Under these conditions, the ash layer might fall of its
own weight. When ash voluntarily falls from the plate, it can achieve a relatively high velocity
in free fall, with reentrainment losses becoming quite severe as the ash breaks up when falling
into the hopper. If, on the other hand, rapping is too frequent, the ash layer will be too thin and
rapping will tend
C-26
Figure C-10
Two Examples of Methods for Providing Wet Collecting Electrodes
to powder the ash, where it will be picked up and carried away by the gas stream. Figures 4-2
through 4-5 illustrate opacity meter traces indicating reentrainment.
For rapping systems that permit rapping intensity adjustment, tests should be conducted to ensure
optimum performance. Too soft a rap can fail to dislodge the ash at the proper time, so that
before the succeeding rap, the ash can fall freely because of the weight of the collected ash layer.
Too severe a rap can also cause poor performance, as the ash layer may be fragmented and
thrown into the gas stream where a significant amount of the fly ash may be reentrained.
C-27
Figure C-11 shows the relationship between rapping intensity and efficiency. The curve,
developed by Wayne Sproull in the late 1960s, shows that the optimum rapping intensity is
affected by ash resistivity.
Because the collection efficiency of a precipitator is exponential in nature, the rate of ash layer
buildup on the first sections will be much higher than that on subsequent ones. Consequently,
rapping cycles are usually varied between sections, the first sections being rapped several times
for each rap of the last section. For typical fly ash installations, the inlet fields should be rapped
in intervals from 5 to 15 minutes while outlet fields in 99+% collectors may only require rapping
every several hours.
Ash properties determine optimum rapping conditions. A low-resistivity ash is held to the plates
principally by mechanical and molecular adhesive and cohesive forces and is relatively easy to
dislodge. Strong electrical forces in addition to those mentioned for low-resistivity ash, on the
other hand, hold a high-resistivity ash. The rapping intensity required to dislodge the highresistivity ash can be quite high. Very-high-resistivity ash often cannot be removed by
conventional rapping, and power-off or reduced-power rapping is used. In ESPs with 5 or 6
fields, power-off rapping for a single field at a time could be used with very little loss in
collecting efficiency, if the gas velocity is sufficiently low. In an ESP with 3 or 4 fields, the
reentrained ash might not be recollected and a rather heavy discharge of ash would follow such a
power-off rap. As noted below, reentrainment losses for very-low-resistivity material cannot be
effectively controlled and may be significantly higher than for an ash in a more favorable
resistivity range.
Reentrainment losses can adversely affect precipitator performance if they are unacceptably
high. In Industrial Electrostatic Precipitation, White points out several methods for detecting
abnormally high reentrainment losses: (1) particle size analysis, (2) analysis of the charge on the
particles, and (3) an abrupt change in the precipitation rate parameter with gas velocity. Because
large particles are more easily reentrained, their presence at the precipitator exit indicates
reentrainment losses. Reentrained particles of intermediate- to low-resistivity tend to take on the
opposite electrical charge polarity due to the pith-ball effect, so that the appearance of large
numbers of oppositely charged particles suggest significant reentrainment. Plots of the
C-28
Figure C-11
Illustrative Relationship Between Collecting Efficiency and Rapping Intensity for Two
Values of Ash Resistivity
precipitation rate parameter as a function of gas velocity can also indicate reentrainment. A
sudden decrease in precipitation rate parameter as the gas velocity is increased signifies
reentrainment.
Reentrainment losses usually can be kept within acceptable limits if the rappers are properly
designed and adjusted. However, even with a well designed and operated rapping system, poor
gas flow quality or unfavorable ash properties can cause a severe degradation in ESP
performance.
Very-low-resistivity ash can be electrically reentrained. An electric field (E) is established in the
ash layer, by the electrical current flow through the layer and the resistivity of the layer. This
field can be described by the following equation:
C-29
E = j
where is the resistivity of the deposited ash layer (ohm-cm) and j is the current density
(amps/cm2). If the resistivity of the layer is very low, the electric field in the layer is less than
that in the inter-electrode space adjacent to the layer. Thus there is a discontinuity in the electric
field at the ash surface. A surface charge layer brings about this discontinuity or step function in
the electric field at the ash surface. In negative-polarity systems with the electric field in the
layer less than in the adjacent space, the surface charge is positive, which develops an electrical
force on the surface of the ash to reentrain the material. This phenomenon was identified in a
pilot-scale project where a spray dryer preceded an electrostatic precipitator. Attempts to operate
the system near the moisture dew point resulted in significant reentrainment. Observing the
surface of the ash layer, particles were reentrained when reducing the temperature to the
moisture dew point reduced the resistivity. Increasing the temperature a small amount could stop
the reentrainment process. (See Figure 6-3 and corresponding discussion in Section 6.8.2.)
C-30
D
CONDUCTION MECHANISMS IN FLY ASH
Because the resistivity of fly ash has such a large effect on ESP performance, it is helpful to
understand the electrical conduction mechanisms in the fly ash material. The flow of corona
current begins with the generation of free electrons in the negative corona process used in most
industrial applications. These free electrons quickly attach to electronegative gases, thereby
forming negative ions. These ions either flow directly across the inter-electrode space or attach
to ash particles that are subsequently collected when they impinge on the previously collected
ash layer. The electrical current must then flow through the ash layer to reach the grounded
collecting electrode, and back to the power supply, completing the circuit. The current flow in
the ash layer could be either as negative charges flowing toward the collecting electrode or as
positive charges flowing in the opposite direction.
D-1
Figure D-1
Resistivity vs. Temperature for Ash Used in Electrical Conduction Mechanisms Study
Prior to about 1972, volume conduction was thought to be electronic. Harry White in Industrial
Electrostatic Precipitation described it as such, with the fly ash particles considered to be
intrinsic semiconductors or insulators. The conduction was thought to be related to the freeing of
electrons in the conduction bands by thermal energy, yielding the linear relationship between
resistivity and reciprocal absolute temperature. This belief was not challenged until 1974, when
Dr. Roy Bickelhaupt conducted studies at the Southern Research Institute (SRI) to develop
definitive relationships to better understand the conduction of electricity in fly ash. Bickelhaupt
conjectured that the prior attribution to thermal energy evolved from the misconception that fly
ash was principally crystalline oxides, sulfates, and alumino-silicates, rather than the glassy
material that it was later found to be. White placed special emphasis on the linearity between
resistivity and reciprocal temperature (Arrhenius relationship) as an indication of semiconductor
behavior, although this same linearity applies to ionic conduction in solids.
D-2
A misconception also existed about the surface conduction mode. Surface conduction was
considered to be ionic or electrolytic in nature, related to the physical or chemical adsorption of
water vapor or sulfuric acid on the surface of inert fly ash particles. The conduction was
considered to be through the adsorbed film on the fly ash particles. Surface conduction was
thought to be essentially independent of the chemical composition of the fly ash.
In 1968, Shale, at the Bureau of Mines (now DOE) in Morgantown, West Virginia, noted that
even though volume conduction was thought to be electronic in nature, higher concentrations of
alkali metals led to reduced resistivities at higher temperatures. He suggested that composition
may also influence the resistivity of fly ash at lower temperatures. Bucher, in his dissertation
from the University of North Dakota, also noted a reduction in the resistivity of fly ash from
lignitic coal with higher sodium content. He concluded that the sodium was principally related
to the volume conduction regime, but did not consider sodium to actually be a charge carrier.
Bucher referred to Shales work and to Duries observation that the ESPs from the Liddell Power
Station in England experienced improved performance when collecting fly ash with higher
sodium content.
The first formal study of the electrical conduction mechanisms in fly ash was performed at SRI
for Transalta Utilities (at that time, Calgary Power, Ltd.), with Bickelhaupt and Nichols working
jointly on this project. Bickelhaupt, a ceramics engineer, recognized the similarity between fly
ash and glass, and designed and conducted experiments that proved conclusively that the
principal electrical charge carrier for volume conduction in fly ash is the actual migration of
sodium ions in the fly ash layer. These experiments suggested that the conduction was ionic
rather than electronic as previously assumed.
After laboratory work identified sodium migration as the conduction mechanism, sodium salts
were added to the feed coal at Transalta Utilities Wabamun Station. This material immediately
reduced the resistivity of the fly ash from the stations low-sulfur coal when operating at 340F
(170C), a temperature where surface conduction would be expected to dominate.
In 1973, Bickelhaupt and Nichols suggested the use of sodium conditioning as a means for
combating high-resistivity problems in ESPs. Holyoak also discussed the improvement in ESP
performance obtained when burning coal with high sodium contents in Burning Western Coals
in Northern Illinois at the November 1973 Winter Annual Meeting of the American Society of
Mechanical Engineers, referring to Bickelhaupt and Nichols work for an explanation. White
presented an extensive discussion of resistivity problems in the April 1974 Journal of the Air
Pollution Control Association. He mentioned the results of the SRI work at Transalta Utilities
and formally presented the results of this first sodium conditioning experiment conducted by
Bickelhaupt and Nichols.
Based on these observations and experiments, and subsequent research at SRI, Bickelhaupt
formulated theories for both volume and surface conduction mechanisms in amorphous fly ash
material. Fly ash was shown to be glass-like with the conduction primarily ionic in nature. The
explicit relationship between resistivity and alkali metals, principally lithium and sodium, was
verified. A phenomenological description of the conduction mechanisms was given by
paraphrasing the fundamental research on silicate glasses. The numerical data from chemical
D-3
transference experiments and photographs of the sodium were offered as proof of the nature of
this conduction mechanism.
Temperature of the layer. Higher temperatures contribute thermal energy to the glassy
material freeing a greater number of ions to participate in the conduction process as well as
facilitating their ability to migrate through the fly ash. This factor causes the decrease in
electrical resistivity of the fly ash with increasing temperature.
Alkali metal ion concentrations. Since the sodium ion is the principal charge carrier
(lithium concentrations tend to be negligibly small), the greater their concentration, the lower
the resistivity of the ash.
Factors that influence the glassy structure of the amorphous material in the ash. The
iron concentration in the ash, combustion zone characteristics (temperature, residence time,
coal particle size, etc.), and the cooling rate of the particles leaving the combustion zone also
D-4
influence the amorphous structure of the ash and perhaps modify the number and migration
rates of the alkali metal charge carrier ions and the resulting resistivity.
Electric field strength. The resistivity of fly ash usually decreases with increasing electric
field strength. The electric field distorts the glass structure, reducing the energy barriers at
the charge carrier sites, which allows ions to be released and move more freely through the
layer. This reduction in the energy barrier causes a decrease in resistivity.
Particle size distribution. The finer the particle distribution, the lower the resistivity, as
there are a greater number of contact points between the particles. The greater the number of
conduction paths, the lower the resistivity.
Porosity of the ash layer. The greater the porosity, the less material is present in any cross
section of the conduction path. The resistivity of the fly ash material is less than the gas in
the interstitial regions of the deposit, causing the resistivity to increase with increasing
porosity. Typical fly ashes exhibit porosities in the range of 55% to 70% by volume. The
change in specific resistivity change caused by this range of porosity is small.
Fly ash resistivity was at one time considered low enough above 575F (300C) to pose no
limitation on ESP performance. However, this has proven not to be the case for certain ashes
that are low in sodium content. The resistivity of newly formed fly ash is usually in the mid-1010
ohm-cm range, a value that produces satisfactory ESP operation. However, a residual layer of
fly ash remains on the collecting electrodes, which is not removed by rapping. A continued flow
of electrical current through this layer, which is in fact a physical migration of sodium ions,
effectively removes a portion of the sodium ions in that residual layer. This depletion of charge
carriers in the residual layer causes an increase in the layers resistivity, so that a high-resistivity
behavior pattern develops over time. In cases where the sodium concentration in the ash layer is
sufficiently high, this sodium depletion phenomenon does not lead to degradation in ESP
performance. However, some fly ashes low in sodium concentration develop symptoms of highresistivity problems in periods from a few weeks to a few months.
The depletion of charge carriers adjacent to the collecting electrodes causes a carrier
concentration gradient to develop in the ash layer. The newly deposited layer has a higher
concentration of sodium than the depleted layer adjacent to the collecting electrodes. Thermal
energy tends to drive the sodium ions from the higher-concentration region into the lowerconcentration region by diffusion, while electrical migration tends to drive them from the lower
concentration region toward the surface of the ash. These competing mechanisms work toward
establishing an equilibrium condition, where one flow just matches the other. If the layer
adjacent to the plate develops a sufficiently high resistivity before this equilibrium is established,
the ESP performance becomes limited either by sparking at reduced voltages or by back corona.
The high-resistivity problem described above can be alleviated either by thoroughly cleaning the
collecting electrodes (i.e., water washing or blasting with sand or grain) or by injecting a
conditioning agent to modify the ash resistivity. Conditioning agents such as sodium carbonate
or sodium sulfate, as well as proprietary agents, are potential candidates.
The volume mode of conduction is active over the entire temperature range and is represented by
a straight line in a plot of log resistivity vs. reciprocal absolute temperature. Thus, at lower
D-5
temperatures, the volume conduction becomes very small, leading to a very high resistivity from
volume conduction alone.
Temperature
Water vapor and sulfuric acid concentrations in the flue gas stream
With respect to ash composition, high alkali metal concentrations reduce resistivity. Also, high
iron concentrations may reduce the chemical durability of the ash, making it more susceptible
to attack by acid and water vapor, freeing larger numbers of ions to move under the influence of
the electric field. Alternatively, higher concentrations of silica and alkaline earth materials may
increase the chemical durability, causing an increase in the ash surface resistivity.
Chemical transference experiments for fly ash in a standard resistivity cell in the presence of 9
ppm of SO3 indicated no significant migration of sodium ions, as was apparent with water vapor
and lower values of SO3. With 38 coulombs of electricity transmitted through the cell, only
about 6% of the sodium ions migrated. This suggests that only volume conduction contributed to
sodium migration, while surface conduction did not. During this transference experiment, the
current remained constant for a fixed operating voltage across the cell, indicating that the
D-6
resistivity remained constant during the experiment. However, another experiment, which also
started with 9 ppm of SO3, showed an immediate increase in resistivity with time when the acid
was removed. Figure D-2 shows the results of this experiment.
These experiments support the view that surface conduction results from two possible
mechanisms. For very low concentrations of sulfuric acid, the mechanism is the migration of
alkali metal ions, similar to that in volume conduction but enhanced by the water vapor and trace
acid attack of the ash surface. (It is possible that the sodium depletion phenomenon may occur
for this mechanism.) For higher concentrations of sulfuric acid, hydrogen ions may directly
participate in the conduction process with little or no physical migration of carrier ions from the
fly ash structure. There is also the possibility that there are acid concentrations where both
surface conduction mechanisms are active.
Figure D-2
Resistivity vs. Time for Experiment With 9 ppm of Sulfur Trioxide Injected Into Resistivity
Cell for a Period of Time and Then Turned Off
D-7
E
SI AND U.S. UNIT CONVERSION FACTORS
Table E-1
Unit Conversion Factors
To Obtain
actual cubic feet/minute (acfm)
Btu/kWh
Btu/lb
centimeters (cm)
degrees Celsius (C)
3
cubic meters/second (m /s)
degrees Farenheit (F)
feet/second (ft/s)
grains/actual cubic foot (gr/acf)
3
grams/cubic meter (g/m )
inches (in)
inches (in)
kJ/kg
kJ/kWh
meters (m)
meters/second (m/s)
millimeters (mm)
millimeters (mm)
3
normal cubic meters/second (nm /s)
2
square centimeters (cm )
2
square feet (ft )
2
square feet (ft )
square feet per thousand actual
2
cubic feet/minute (ft /kacfm)
2
square meters (m )
square meters per cubic
2
3
meter/second (m -s/m )
standard cubic feet/minute (scfm)
tons (metric)
tons (short)
Multiply
3
cubic meters/second (m /s)
kJ/kWh
kJ/kg
inches (in)
degrees Farenheit (F)
actual cubic feet/minute (acfm)
degrees Celsius (C)
meters/second (m/s)
3
grams/cubic meter (g/m )
grains/actual cubic foot (gr/acf)
centimeters (cm)
millimeters (mm)
Btu/lb
Btu/kWh
feet (ft)
feet/second (ft/s)
inches (in)
mils
standard cubic feet/minute (scfm)
2
square feet (ft )
2
square centimeters (cm )
2
square meters (m )
square meters per cubic
2
3
meter/second (m -s/m )
2
square feet (ft )
square feet per thousand actual
2
cubic feet/minute (ft /kacfm)
3
normal cubic meters/second (nm /s)
tons (short)
tons (metric)
By
2120
0.948
0.43
2.540
9/5*
0.000472
5/9*
3.2808
0.437
2.288
0.3937
0.03937
2.325
1.055
0.3048
0.3048
25.4
0.02540
0.000438
929.0
0.00108
10.764
5.077
0.0929
0.197
2282
0.9072
1.1023
E-1