PROCEEDINGS BOOK

International Conference on Basic Science (ICBS)

liThe Role of Basic Science in Health, Environment, and Advance Technology"
Faculty of Science, University of Brawijaya, Malang, Indonesia
Widyaloka Convention Hall, February, 17 _18 th 2011

Keynote Speakers
1.
2.
3.
4.

Assoc. Prof. Spas D. Kolev- University of Melbourne (Australia)

Dr. Edgar Paski British Columbia Institute of Technology (Canada)
Prof. Dr. Lukman Hakim Indonesian Institute of Science (Indonesia)
Prof Dr. Ir. Chandrawati Cahyani, MS - University of Brawijaya (Indonesia)

Board of Advisors
Prof. Dr. Ir. Yogi Sugito (UB Indonesia)

Prof. Dr. Marjono, MPhii (UB Indonesia)

Prof. Dr. Ir. Chandrawati Cahyani, MS (UB -Indonesia)

Prof. Dr. drh. Aulanniam, DES (UB -Indonesia)

Prof. Dr. Loekito Soehono, M.Agr (UB - Indonesia)

Prof. Petr Solich (Charles University Rep. of Czech)

Assoc. Prof. Stuart R. Batten (Monash University - Australia)

Dr. Masayuki Sano (AIST -Japan)

Dr. Edgar Paski (British Columbia Institute of Terhnology - Canada)

Board of Editors
Dr. Hermin Sutistyarti (UB - Indonesia) - Editor in chief

Prof. Mick O'Neill (Advisory and Training Service pty, Ltd - Australia)

Prof. Petr Solich (Charles University - Rep. of Czech)

Dr. Edgar Paski (British Columbia Institute ofTechnology - Canada)

Dr. Francois Malherbe (Swinburne University of Technology - Australia)

Dr. lilibeth die. Coo (University of the Philiphine - Philiphine)

Dr. Verasak (King Mongkut's University of Technology - Thailand)

Zubaidah Ningsih, M. Phil (UB -Indonesia)

Irfan Mustafa, MSi (UB Indonesia)

Yuniar Ponca Prananto, MSc (UB - Indonesia)

Design and layout

nary Agustiawan
Armeida Dwi Ridhowati Madjid

?ublisher:
Galaxy Scipnce Publisher, Malang, Inclonesia

.II.

~mdia ~1 \-Ialang
Telp 0111=,:1.\--31035. m413Q069t

ISBN: 978-602-97628-5-3

PREFACE
Proceeding of the International Conference on Basic Science 2011 is a book
containing several papers that have been presented in the seminar, either oral or in
poster. The objective of this proceeding is to collect and to share any useful information
that had been gathered recently in area of Mathematics, Biology, Chemistry and Physics,
which is generally known as the basic science. Hence, through this book the readers are
expected to gain new knowledge or information, especially in health, environment and
advance technology.
In general, the papers are presented in order of health (part A), environment (part
B) and advance technology (part C) in which in each part the papers are divided into two
sections, the oral and poster papers. Many papers in this proceeding discuss the
exploration and the development of natural resources as the medicine based compound
source. Furthermore, the modification of analyzing method and modeling in health and
environmental science, whether it is based on nuclear technology or advance
biotechnology, has also been compiled in this proceeding. In addition, several interesting
topics which present the latest information in environmental field add the usefulness of
information gathered in this proceeding.
Additional information of the first author is also given at the end of this book. Hence
further contact to the author is possible via the email address available at the affiliation
section. Should the readers have further questions, comments or need more information,
please directly contact the authors ofthe papers.
The editorial board has made some editing correction needed in some cases. Most
of the editing correction are conducted and concentrated in the organization of the paper
based on the guideline and the language, i.e. some figures or tables were corrected, or
maybe printed in grayscale, and placed in the last part of the article (appendix). In
addition, the language is the most time-consuming work; hence we apologize for the late
publishing of this book and for any inconvenience as a result of the delay.
Lastly, on behalf of the committee, we would like to say thank you to all the
participants for their kindness to be part of this conference. We also would like to
acknowledge each partnerships and sponsorships that involved during this event. We
bc:lieve. that this proceeding still has some wAaknesses; therefore any constructive
comments are welcome. Once again, thank you to all, have a nice academic life and see
you in the next ICBS.
Malang, May 2011

Message from President of ICBS 2011

th

Praise to Allah SWT, as only of his love and blessing, our lst International
th
conference on Basic Science (lCBS 2011) was successfully held on February 17 _18 , 2011
in Widyaloka Building University of Brawijaya Malang Indonesia, as one of celebration for
th
the 48 Anniversary University of Brawijaya and the International Year of Chemistry 2011.
The conference was projected to facilitate the discussion of the truth and beauty of
science and its application to impact positive improvement in health, environment and
advance technology for prosperity to the local society and worldwide.
We would like to thank and give highest appreciation to Rector University of
Brawijaya and Dean Faculty of Science for their fully support and to Our honourable and
generous keynote and invited speakers: Dr. Edgar Paski from BClT & Analytical
Innovation Canada; Assoc. Prof. Spas Dimitrov Kolev, from The University of Melbourne,
Australia, Prof. Lukman Hakim, Head of Indonesian Institute of Science, Prof. Chandrawati
Cahyani from Chemistry Department University of Brawijaya Malang Indonesia, Prof.
Brenny van Groesen from University of Twente, Netherlands and LabMath-lndonesia,
Bandung Indonesia; Prof. Motoki Kubo and Prof Mamoru Wakayama from Department of
Biotechnology, Ritsumeikan University, Japan; Dr. Francois Malherbe from Swinburne
University of Technology, Australia. Another great appreciation goes to the board of
editors: Assoc Prof. Ulibeth Coo from University of Philippines Manila, Prof. Mick O'Neill,
the Director Statistical Advisory & Training Services Australia, and Prof. Petr Solich from
Charles University Republic of Czech. Many thanks go as well to all national &
international participants for their contributions to the conference program and to this
proceeding. It is our pleasant duty to also acknowledge our sponsors: PT Arfindo Bersinar,
CV Makmur Sejati, Indonesian Forestry Department East Java Division, the Local
Government of Malang City, Indonesian Chemistry Society, PT. Otsuka Lawang, PT.
Amerta Indah Otsuka - Pasuruan, Kristalindo, Trans Zahwaa Travel, Elfara FM and Tugu
st
Hotel as your strong support and active participation have made the 1 ICBS becomes a
reality.
The material in this proceeding is divided into three parts: (1) Health, (2)
Environment, and (3) Advance Technology. We hope that the papers contained in this
proceeding will prove helpful toward improving international collaboration research to
solve the -problems related to heath, environment, and advance technology.
As thiS conference is held annually, we ilre looking forward to the 2 nd International
Conference on Basic Science that will be held on February, 2012 at the same location. We
hope that it will be a more interesting ann enjoying conference.

President
Dr. Hermin Sulistyarti

ii

Message from Dean of Faculty of Science - UB

On behalf of the faculty of Science we are very happy to complete the 1stth
International conference on Basic Science (ICBS 2011) by this proceeding. Our
appreciation to Prof. Dr. Ir. Yogi Sugito, rector of the University of Brawijaya for his
support and all of the keynote and invited speakers who made this conference succeeds.
This proceeding contains as the following. Part A: Health, Part B: Environment, and
Part C: Advanced Technology. Oral papers are followed by posters at each part. Finally,
we would like to thank all of the steering and organizing committee for their efforts in
succeeding this conference, especially to Dr. Hermin Sulistyarti as the chair of the
organizing committee.
Last but not least for all of the participants, we are thankful for your cooperation,
contribution and very valuable support for this event.
Thank you,

Prof. Dr. Marjono, MPhil.

iii

Table of Content

Preface
Message from President of ICBS 2011

ii

Message from the Dean of Science Faculty of UB

iii

Table of Content

iv

Part A. Health Section

A.l. Oral Presentation

1-106

A.2. Poster Presentation

107

181

Part B. Environment Section

B.l. Oral Presentation

182 - 299

B.2. Poster Presentation

300

366

367

490

490

617

Part C. Advance Technology Section

c.1.

Oral Presentation

C.2. Poster Presentation

Bibliography of First Author

xvi

Sponsorships

xxiii

iv

Part A. Health Section

A.I. Oral Presentation

1-106

CD8+CD122+ Regulatory T Cells is a New Therapy for Inflammatory Bowel Disease

Agustina T Endharti, Nobuaki Misawa, Masafumi Ito, Haruhiko Suzuki

Cytotoxic, antioxidant and antibacterial activity of methanol extract of Xylocarpus moluccensis

fruit husk
Asep Awaludin Prihanto ............................................................................................................... .

Research-based on Herbs Exploration and Use of Animal Model~: Nature Materials towards
Supporting Evidence Based Medicine
Aulanni'am .....................................................................................................................................

The Effect of Red Guajava (Psidium guajava) Fruit Extract on Tyrosinase (EC 1.14.18.1) Activity
by Spectrophotometry
Ayik Rosita Puspaningtyas ......................................................................................................... .

10

Study of Toxicity Effect of Formalin on Antioxidant Enzymatic Activities and Oxidative

Damages of Rats Hepar Tissue
Chanif Mahdi, Aulanni'am ..................................................................................................... .

15

Monoclonal Antibodies to Bovine Zonna Pellucida 3 (Mab-bZP3) for Woman

Immunocontraceptive Vaccine
Dedy Kurniawan, Sutiman B Sumitro, Aulanni'am ................................. .

19

Monitoring and Capability Analysis of Hemoglobin Level in Pregnant Women

Dewi Anggraini ................................................................................................... ..

22

Anti-Inflammatory of Methanolic Fraction from 96% Ethanolic Extract of Honey Bee Propolis
on White Male Rats Wistar Strain
Dwi Ningsih, Agustina Wulandari, Gunawan Pamudji Widodo ........................... ..

27

Evaluation on the Phytoestrogenic Effect of Legumes Extract in Binding Competition on

Estrogen Receptor
Edi Priyo Utomo

33

Preparation of Constructs Gene sY86 as the Basis of Antibody Formation for Determination
Method of Male Infertility
Evi Hanizar, Miswar ................................................................................... .

34

Function of hlNSR Mutant Againts Tyrosine Kinase Precede Abnormally on Onset Diabetes
Mellitus: In Silico Study
Fdtchiyah, NMA. Putri , D. W. Soeamadji ......... ..

37

The Analysis of Ca2+ Intensity Profile of M-II Oocyte Natural Activated by Crude Sperm Extract
Gatot Ciptadi .......... .................... ........... ......
.. .............................................................. ..

38

The Effect of Prostaglandin F2aAddition on Sperm Quality in Goat Semen Diluted with Various
Solutions
Herawati .................................................................. ..........................................................

42

Correlation Between AgNOR, MIB-1 and Radiotherapy Response in Lung Cancer

lin Kurllia, Heriawati, Juniarti, Ruth ES, Zubaidah Alatas, Elisna Syahruddin, Made

Widhyasmara..............................................................................................................................

45

Tyrosinase Activity of Piper betle and Piper crocatum Essential Oil

Irmanida Batubara, Min Rahminiwati,Latifah K. Darusman, Tohru Mitsunaga ..............................

50

Immune system impairment in CD122-deficient mice is caused by abnormality of activated T cells

Muhaimin Rifa'i........
.. . ............
..........................
............................................

54

The Simple Anti-oxidant Compound in Anti-cancer Potential Fraction of Kesum leaves Extract
Muhamad Agus Wibowo, Lucy Ariani, Aulanni'am, M. Aris Widodo, Basuki B. Purnomo ..............

59

Cytotoxicity, Antioxidant and Antimicrobial Activity of Methanol Extract of Bark (Xylocarpus

Granatum)
Muhamad Firdaus ........... ............... ...... ...... ..... ......... ....... ............. ....................... .............. ............

62

Developing Malaria Vaccine Candidate with Gamma Rays: Alteration of Heat Shock

Protein Profiles Post Irradiation

Mukh Syaifudin, Devita Tetriana, Sit; Nurhayati, Darlina, Tur Rahardjo, Irawan Sugoro .............. .

65

Polyphenol Extract of Brown Seaweed (Sargassum duplicatum Bory): Phytopharmaco

Exploration for Inflammatory Bowel Disease Theraphy

Nur Lailatul Rahmah, Aulanni'am, Anna Roosdiana

70

Agrobacterium Mediated Transformation of Tomato and Production of Transgenic Plants

Containi ng Gene I ncreased Sucrose Transport SoSUTl

Parawita Dewanti, Bernet Agung Saputra, Tati Wardiyati, Mifin Nur Sugiarto, Bambang

Sugiharto .......................................................................................................................................

75

Cytotoxicity, Antioxidant and Antibacterial Activities of Methanol Extract of Xylocarpus

Moluccensis lam. Fruit Peel

Rahmi Nurdiani ...............................................................................................................................

79

Study of Antibacterial and Cytotoxic Activity of Porphyra Sp Extract

Raja B.D. Sormin. Sukoso. Happy NursyilrTl, Siti Rasminah Ch. Sy ........ .

83

Superoxide Dismutase (SODI Activity and Histological Pancreas Tissue of Type 1 Diabetes

Mellitus Rat Treated with Temu Giring Extract (Curcuma heyneana)

Rosaliila A.L, Aulanni'am, Cha'lif Mahdi ........................................................................................

87

Characterization of Allergen Proteins and Alergenicity of Porang tubers (Amorphophallus

muelleri Blume.) by using IgE-lmmunoblotting

Sofy Pe<mana, Sri Widyarti, Luccy Mutia Ungga Dewi, Indrian Rizka Amalia .................................

92

Growth Differentiation Factor-9 Gene Expression of Mice Oocytes in Vitro

Sri Rahayu, Manami Nishio, Yumi Hoshino, Eimel Sato .............................................................

93

In Vitro Anti-Malarial Activity of Alkaloids from Erythrina Variegata against Plasmodium

Falciparum
Tati Herlina , Unang Supratman . SyafrurJdin , nideo Hayashi .......................................................

97

Recognition Antigen and Antibody Specific Protein 24 and Protein 40 Borna Virus in Serum Patients
Psychiatric Disorders
Tri Maharani ................................................................................... ...........................................................
101

Lactobaci/lus PJantarum S1.30 Isolated from Dadih has Antagonistic Properties and Harbours
Gene Encoding the Production of Bacteriocir,

Yoga Dwi Jatmiko, Miguel Oe Barros Lopes, Mary Barton ...............................................

102

vi

A.2. Poster Presentation

107 -181
Aloe Gel Herbal Therapy on Diabetic Ulcer Healing
Adeodatus Yuda Handaya, Djanggan Sargowo, M, Aris Widodo, Diana Lyrawati,
Askandar Tjokroprawiro" .... ,' ........ " ,.......... , .. ,' ,....... , .. , .. ,..... " ...... , ... , ,..... ,...... ,., .. ,,','

107

The Effect of Teaching of Vitamin C using Problem Based learning and laboratory Works on
Students Achievement
Afnidar, Sri Hamda, Erdawati .............. ,.... , .. "..............................................................................

112

Isomerization and Toxicity Test of Methyl linolenic Ester of a-linolenic Acid Isolated from
Ocimum Basilicum Seeds
A. Ghanaim Fasya , Rurini Retnowati , Moh. Farid Rahman ....................................................

117

Biodegradable Composite Polymer for Medical Application: A Review

Agus Haryono, Sri Budi Harmami ........................ ,........................................................ ,.. ,...........

120

AdhF-36kDa Protein Expression Pattern of Salmonella typhi on Different Environmental

Conditions in Vitro
I Nengah Kundera , Sanarto Santoso , Aulanni'am, Sri Winarsih ,.... ,........... ,................. ,......... ..

126

Evaluation on Antioxidative Activity of Pollard Protein Hydrolysates

Khothibul Umam AI Awwaly, Muhammad Halim Natsir Abdul Manab ,Aris Sri Widati

130

Exogenous Il-2 Promote T Cells Proliferation Under Anti -CD3/CD28 Combination

Muhaimin Rifa'i . . . ......... ', .... ,..................................... ,............. ,.. ,.....

133

Potency of Inhibin B As Male Hormonal Contra<:eption Candidates Based on Sperm Viability

and lH Serum level of Rattu~ norvegicus
Muhammad Hilman F. Amin, Aulan!li'am ,Agung P.W,Marhendra , Muslim Akmal .......

134

Potency of Silicon Dioxide (Si02) as a Denaturator Media of Rabies Virus

M. Misbah Khunur, Rizky Arief Shobirin, Muchid Abdul Miz, ............ ...............................

137

Decrease of Ethanol Content in Urine Wistar Rats after Giving Acute Alcohol
Ni Made Suaniti ........................... ,.... ,.................................................... ,...... .....................

141

Responst of Rhizopus Sp in Ration to the Food Consumption, Body Weight and Feed
Conversion of Chickens layer Grower Period of I
Nur Alim j';atsir ................................................................ ,..................... ,....... " ............ ..

144

Controlling Aedes Aegypti Mosquito Population as DHF Vector with Sterile Insect Technique in
Pasar Jumat Nuclear Research Center
Siti Nurhayati, Budi Santoso ............... ' ...................... ' ..................................................... '.........

147

Radiation Induced Micronuclei in Lymphocyte Cell of Radiation Workers

Sofiat i Purnami, Yanti Lusiyanti, Masnelli Lubis, Dwi Ramadhani, Devita Tetriana, Siti Nurhayati,
Mukh Syaifudin .. " ... " .. " ............ ,................................... ,'., .... ,.............. ,........ ,., ... ',......

152

The Antioxidant Activity of Purple Star Apple (Chrysophyllum cainito L.)

Tagor M. Siregar, Herry Cahyana, Ika Narishantika ... , ,.............. ,.... ,.. ,.... ,.... ,.............................

157

vii

The Influence of Status and The Patterns of Driving License Ownership toward The Gradation
of Head Injury Suffered By Motorcycles Accident Patients in Emergency Department of Saiful
Anwar General Hospital
Tri Maharani .. ,.. ,.. ,............... ," ...... ',' ...... ", .. " ...... ,,, ...... ,.. ''' ......... ,,'',,.,,,.,, .. ,'',, ........ '', "'''' ............ ''''''''

136

Isolation of Active Extract of Tengkawang Seed OillShorea sumatrana Sym.} as Antibacterial

Valentina Adimurti Kusumaningtyas, Ahmad Sulaeman, Yusnelti, Dewi Meliati Agustini...........

164

The Influence of Citrus NobiJis Lour Aqueous Fraction on Mice Fertilization Rate by In Vitro
Fertilization Method
Widjiati, Raden Roro Wulan Oktavia Aryaguna Putri, Diah Kusumawati .. "" ... " .. " .. " .... " .. ".......

167

Acoustic Performance Study of Human Hearing System Due To Noise Potential Damages
Wike Herawaty, Nurida Finahari " ......... ' ....................... ,...... " .. ,... ,..................................... "......

170

Isolation and Characterization of A Gene Involved in DNA Repair of the Extremely

Radioresistant Bacterium Deinococcus Radiodurans
Zubaidah Alatas ..... " .. " ................................................... ,..... ,." .. " .. ,.. ,............................... " ... ",

175

Part B. Environment Section

B.l. Oral Presentation

182 - 299

Utilization of Bagasse Fly Ash for Nickel and Chromium Immobilization in Cement-Solidified
Metal Plating Sludge
Ahmad Husni, Angga Dheta Sirajuddin Aji, Yusi Arisandi" .."" .... " ..... " ..... " ..... " ... " .. ".....................

182

Alkaloids from Marine Sponges: Isolation of a New Aaptamine Related Compound from an
Indonesian Aaptos Aaptos
Ajuk Sapar, I Wayan Mudianta, Andi H. Alimuddin, Mary J. Garson., .... " ........ " ......... "....................

187

The Effect of Refugia Blog to Spatial and Temporal Distribution of Natural Enemies in Rice Field
Asyik Nur Allifah AF, Bagyo Yanuwiadi, Zulfaidah p, Gama, Amin S. Leksono."" ....................... "

192

Airborne Measurements of Particle Concentration from Biomass Burning in Northern Territory

Australia
Arinto Yudi Ponco Wardoyo ...... ".",,,..,, ..........,,,,... ,,,, ........ ,,,,.,,.,,,, ... ,.,, ....,, ...... ".,"".." ............... ".........

196

Zeolite Carbon Composite Polyvinylchloride-Coated Wire Electrode for Lead Detection as an

Environmental Sensor
Atikah, Qonitah F , Chasan Bisri, Bagus Setiawan, Tyas Karya P."" .." ....""".. " .......... " ....... ,,..........

197

Geochemical Fractions of Heavy Metals in the Sediment of Brantas River Downstream

Barlah Rumhayati, Enco Sukarsa"..
""...................... """ .......... " ... "" .. ,, " ".................

202

A Preliminary Study: Towards Molecular Phylogeny of Endiandra (Lauraceae)

Deby Arifiani, Adi Basukriadi, Mien A. Rifai, ,atik Chikmawati "." .... " .. " ...... " .." .. "...........

205

The Adsorption Desorption of Ag(I), Pb(II), Cu(II), CrllU), Nilll) Toward Mercapto-Silica Hybrid by

Coloumn System

Owi Rasy Mujiyanti, Nuryono, Eko Sri !(unart' ""......... " .... " .... " ...... "".......................................

206

Synthesis and Ability Test of Mg/AI Hydrotalcite-like from Artificial Brine Water to Remove

viii

1
Eosin Yellow
Eddy Heraldy , Sri Juari Santosa , Karna Wijaya, Triyono

211

Optimation of Bioethanol Production from Sugar Cane Baggase using Separated Hydrolysis and
Fermentation Method Based on Cellulase System of Bacillus Cireulans
Evi Susanti, Neena Zakia ,Sumari.................

216

Conversion of West Kalimantan's Tropical Peat into Bioethanol as Renewable Energy

Ferry Hadary .................
................. ...............................

222

Synroc Performance for Immobilization of Hig'h Level Liquid Radioactive Waste

Gunandjar ...................................................... .................... ................................................

227

Bambara Groundnut (Vigna subterranea {L.} Verde) as Sustainable Food: Strategic

Consideration Future Prospect
Hayyu Febriani, Endah Sri Redjeki..........................................................................................

233

Damping Concentration Effect Simulation on the Particulate PM10 Average Dynamic Dose Rate
per Year in X Region at Serpong Residency
I(uk Setiyawati, Abdurrouf , Eko Pujadi , P.A Saraswati .................... ................. ......................

238

Determination of Optimum pH and Adsorption Time of Malachite Green on Coal Fly Ash
M. lathifurrijal, Anton Prasetyo, Diana Candra Dewi ..................................................................
Groundwater Mapping in Coastal Plain, North Kelantan Malaysia
Nur Islami, Samsudin Hj Taib, Ismail Yusoff ...................................................................... ..

242

245
The Application of The Gompertz, Richards and Hyperbolastic Growth Models to Describe
Weight Growth
NW Surya Wardhani, Solimun, Era Setiarini ...............................................

249

Nitrogen Leaching on Coffee Based Agroforestry Systems in the Presence of Different S

hade Trees
R. Priyadarshini, K. Hai,iah, D. Suprayogo, J.B.Baon ............................................................. ..

253

Functional Morphology of Deposit Feeder Bivalve Theora lata (Bivalvia: Semelidae)

Reni Ambarwati, Trijoko ..... ............... ..............
............................................ ..

257

Soluble Quinone Reductase from Methanosarcina acetivorans binds a Flavin Adenine

Dinucleotide
Suha,ti .............................................................. ..

262

Monitoring for the Effect of Chlorination in Drinking Water by Using Solid-Phase Spectrometry
Sulistyo Saputro, Kazuhi~a Yoshimura, K6 Takehara, Shiro Matsuoka. Narsito ..........................

26G

Zoning on Vulnerability Potency of Geology Disaster Area if) Malang-East Java Indonesia by
Means of Geophysics Data
Sunaryo............................................... ...................... ..........................................................................

270

Development of Radionuclide Monitoring Stations in Indonesia in 'Anticipating the Increasing of

Peaceful Use5 of Nuclear Energy in ASEAN Region - An Initial Assessment
Susilo Widodo, Syarbaini, Dadong Iskandar, Bunawas ....................................................... " .... "

275

Diversity, Composition, and Community StructurE' of the Teak Canopy Arthropods in Porang
Crop Area Saradan Forest, Madiun, East Java
Syahrudin Agung Permana, Amin ::'etyo leksono, Bagyo Yanuwiadi.. ...... "......................................

280

ix

I
Biology of Fungi's Pelawan Tree (Tristaniopsis Merguensis)
Triadiati ,Anastastia Raditya Hidayanti, Nampiah Sukarno ............................................... .

281

Mathematical Model of Interactions Immune System with Micobacterium Tuberculosis

Usman Pagalay, Marjono, Kusworini Handono, Agus Suryanto ................................................. .

282

Role of Wild Plant as Alternative Habitat for Natural Enemies in Agricultural land
Wiwin Maisyaroh,Bagyo Yanuwiadi, Amin Setyo L., Zulfaidah P.Gama ........................................

290

Biosorption Phenomena of Heavy Metals and Radionuclides by Dispersed Bacterial

Extracelular Polymeric Substances
Zainus Salimin, Endang Nuraeni ....... .........................................................................................

294

B.2. Poster Presentation

300 - 366
The Study of Phosphate Released from Aquatic Sediment and Its Effect on Algal Growth
Asep Saefumillah, Nining Betawati Prihantini, Dini Damayanti, Zaenab Sahamiddina .............. .

300

Normative law Dimension Introduction of Variety Description for Pests and Plant Disease in
Sustainable Food Crop Cultivation
Bambang

301

Approach Method Self Organizing Maps (SOM) for Grouping Zone Season (ZOM) District Ngawi
and Accuracy Evaluation Method ZOM with General Regression Neural Network (GRNN)
Bambang Widjanarko Otok, Muhammad Sjahid Akbar, Agnisa Bhakti Persada ...... " ...... " ....... .

307

Biosorption of lead(lI) And Cadmium(lI) by Biomass of Azalia Microphylla-Silica in Continuous

System
Oanar Purwonugroho, Sri Wardh'3ni, Darjito, Deasi Ari Shandi , Descaniati Chan ..................... .

312

Variation Shape and Color of Gland from Genus Orophea IAnnonaceae) in Purwodadi Botanical
Garden
Dewi Ayu lestari ........ .

315

Single Nucleotide Polymorphism Identification of Porang in East Java

Estri I.aras Arumingtyas .................................. " ................. "."" .......................................................... .

319

logging Impact to Diversity of Epiphytes at Malinau Research Forest (MRF)-CIFOR Malinau

Regency
Ismail, Akas Pinaringan Sujalu." ......... " ............................................................................................ .

320

The Comparative Air Analysis of the Institute of Chemistry, UP Diliman using Passive Sampler
with Activated Charcoal and Commercially Available Adsorbent
lilibeth die. Coo, Christian Mark G. Salvador, Abegail Z. Rasco...................................................

325

Synthesis and Characterization of Nickellll) doped Calcium Tartrate Tetrahydrate

(Ca.Ni{1.)C.H406.4H20) Single Crystals in Metasilicate Gel Using CaCbMade of Achatina fulica
Snail Shell Waste
Moharnmad Misbah Khunur, Muchamat Chasan Basori. Yuniar Ponca Prananto,
Rachmat Triandi Tjahjanto ....................................................................................................................

330

Synthesis and Characterization of Mangan(ll) doped Calcium Tartrate Tetrahydrate

(CaxNil1.x)C4H406.4HzO) Single Crystals from Achatina futica Snail Shell Waste
Mohammad Misbah Khunur, Imam Sakdi, Yuniar Ponco Prananto,
Rachmat Triandi Tjahjanto.... .....................
...........................

334

Epiphytic Orchid Diversity in Wilis Mountain, District of Ponorogo, East Java

Nina Dwi Yulia, Sugeng Budiharta ..........................................................................................................

338

Study of Infrared Spectra in the Interaction of Cr(VI), Mn(lI), Ni(II), Cu(II), Zn(II), Cd(II), Hg(II), and Pb(lI) by
Seaweed (Graci/aria Sp) Biomass Noer Komari ,Filomena
Matilda............................. ........................................ ....................
342
Evaluation of Accuracy Clustering Zom BMKG in Ngawi with Multivariate Adaptive Regression
Spline (MARSI.Approaching
Nur Faizah, Bambang Widjanarko Otok, Sutikno ........................................................................

346

The Effect of Cadmium as Reductor and Reduction Time in the Measurement of NO, Gas in
Ambient Air using KI-Amylum Absorber
Qonitah Fardiyah, Hermin Sulistyarti, Nur Hayba Islamiyah .................................................... .

352

The Optimization Time of Steam Distillation of Vacuum Oven Dried Aceh Patchouli Leaves
(Pogostemon cab/in Benth) and The Characterization by TlC and GC - MS
Sentot Joko Raharjo, Rurini Retnowati .................................................................................... .

356

Potencies of Plants around Fishes Ponds in Karang Sentul Village, Gondang Wetan District
Pasuruan, East Java
Soli kin .................... ......................................................................................................................................

361

Woody Plant Diversity and Structure of Coffee Agroforests in the Recharge Area of Some
Springs in Ngantang Subs District,Malang Regency, East Java
Titut Yulistyarini, Zaenal Kusuma ,Soemarno, Endang Arisoesilaningsih...................................

362

Part C. Advance Technology Section

C.1. Oral Presentation

367 - 485

Analizing The Double Pulse Experiment by Using Fourier Transformation

Abdurrouf .........................................................................................................................

367

Dominant Frequency Analysis and Seismic Vulnerability Index in subdistrict of Klojen, Malang
Regency, using "Horizontal to Vertical Spectral Ratio" for Seismic Microzonation
Adi Susilo, Dwi Wahyudi........................................................ ....................................................

372

Zircon Imprinted Polymer: Synthesis, Characterization and Zircon Ion Absorption Properties
Aladin Sianipar, Amran M.B., Bucna,i, I Made Arcana ................ ,.... ...........................................

380

Effect of Pyrrole (Py) Concentration and the Number of Cycles during Electropolymerization of
Pyrrole (Py) on Platinum Electrode
Anceu Murniati, Buchari, JUryo Gandasasmita, and Zeiiy Nurachman ........................................

386

Dt!velopment of Biomass Stove by Using Brick Refractory Castable Insulator

Bambang Poerwadi ........................................................................ ...........................................

392

xi

Verification of Absorbed Dose Rate To Water Determination For A Co-60 Gamma Beam Using
Farmer Dosemeter and Ptw Unidos in Ulin Hospital, Banjarmasin
C. Tuti Budiantari, Nurman Rajagukguk ........................................ ..

396

Assessing Mud Volcano Vulnerable Area Using Fuzzy Approach

Candra Dewi .................. .

400

Sensitivity Enhancement of Enzyme linked Immunosorbent Assay (ELISA) for Salmonella

Detection Using Multi Walled Carbon Nanotubes (MWCNTS)
Dyah Kinasih Wuragil, SUkunya Oaew, Verasak Surareungchai ..................................................

405

Standardization for Gamma Emitting of Co-60 And Cs-137 Mixed Source Using Gamma
Spectrometry Method
Gatot Wurdiyanto, Hermawan Candra,Wijono ..........................................................................

409

The Diet Effect Using Amorphophallus Sp Raw Flour from East Java on Cholesterol of Rat
(Rattus Novergicus) Wistar Strain
Harijati N, Widyarti S, Azrianingsih R ............................................................................

413

Study on Formation of Fatty Acid Methyl Esters (Fames) From Oil Seed Nyamplung
(Calophyllum Inophyllum): The Effect of Catalyst Homogenous and Heterogenous
Hendro Juwono, Triyono, Sutarno, Endang Triwahjuni ......... ..........................................................

418

Preparation of l51Eu Standard Source in Ah03 Matrix

Hermawan Candra, Gatot Wurdiyanto, Pujadi ........................................................................ ..

423

Estimation Parameters of Regression Spasial Lag by Ordinary Least Square Method

Indah Rahmawati, Sri Harini , Abdul Aziz ..........................................................................

427

Estimation Parameters of Regression Spatial Error by Estimated Generalized Least Square Method
lailiatul Mubtadiah, Sri Harini, Abdul Aziz.. ....................................................................... .

431
The Determination of Skin Resistance Coefficient of Apples Respect To 02 and C02 Exchange
Using SF6 Gas as a Tracer By a C02 Laser Photoacoustic Spectroscopy Method
MAJ. Wasono....................... .... .............................. ...........................................................................

435

Effect of Annealing on the Crystallization and Hysteresis Loop of Pt/TiOz/Si(lOO)/PZT/Au

Structures
Masruroh ................................................................................................................................

439

Resrad Build Code as Supporting Tool to Estimate Radiological Impact from A Concrete
Building Milterial
Moekhamad Alfiyan ..................................................................................................................

443

MicropartiCLIlated Whey Protein Concentrate !Wpc)-Low Metoxyl Pectin (lmp) Complexes

unrler Different Acidic Environment: A Rileology and Confocal laser Scanning Microscopy
(Clsm) Studies
Mokhamad Nul', Todor Vasiljevic, Nicolcta Dragomir ............ .......................................................

448

Comparison of Three Spatial Analyses in Randomized Complete Block De!>ign

Mohammad Masjkur .....................................................................................................................

449

Laboratory Measurements of Electrokinetic Potential to Determine The Fluid Flow Velocity in

Porous Media at Unhas Campus, Tamalanrea, Makassar
Muhammad f-lamzah Syahruddin......................... .....................................................................

453

xii

Polymerization of 8-Pinene using Zirconium 8-diketonato Catalysts

Muhammad YU5uf, Yessi Permana, Ismunandar ......................................................... ..

456

Standardization of 1291 by Photon-Photon Coincidence Method with 1251 Tracer

... ....... ................ .......... ......... ........... ........... ............
Pujadi M, Gatot W, Hermawan C.. .......

460

MLP Radial Basis Functions for Forecasting of the Chaotic McGlass Time Series
Samingun Handoyo ...................................................................................................................

465

Sample Preparation Technique for Total Arsenic in Tuna Fish

Tiny Agustini Koesmawati, Buchari, Aminuddin Sulaiman, Siamet Ibrahim,
Kevin A. Francesconi ...................................................................................................................

470

Test Rate of Evaporation and Oxidation Stability of Synthetic Sex Pheromone Candidate
Molecules Engineered Alpha Linolenic Acid (ALA) of Basil Seed Oil (Ocinum basilicum L)
Warsito, Jumina, Chairil Anwar ............................................................................................................

474

tudy of Structure and Magnetic Properties of Complex Compounds of Cu (IJ) with Nitronil
Nytroxide and Dicyanamide Ion Ligands
I Wayan Dasna .............................................................................................. .............................

479

Characteristics Test and Identification of Radiation Sources from the High Performance
Radioisotope Identifier 75023 using Co-60, Cs-137 a"d Eu-152
Wijono, Gatot Wurdiyanto, Pujadi .......................................................................................... ..

483

Study on Vertex Orders of Almost Moore Digraphs with Self-repeat

Yus Mochamad

488

C.2. Poster Presentation

491- 612

Optimization of Biodiesel Synthpsis by Trans-Esterification of Jatropha Curcas Oil with High

Free Fatty Acid
Aman Santoso ............................................................................................................................

491

Refinement Optimization of Crude Palm Oil (CPO) using Zeolite or Clay and Its Potential As
Biodiesel Raw Materials
Aman Santoso, Sri Kumalaningsih, Susinggih Wijana, Imam Santoso ............................... .

496

Analysis and Numerical Solution of Saint Venant Equations for the 2D Shallow Water Wave
Models with Initial Value Problem and Boundary Value Problems
Ari Kusumastuti, DeWi Erla M, Silva Ahmad A. .............. .................................... .......................

501

Spatial Pattern Analysis of Dengue Fever Incident for Early Warning Disaster Information in S
urabaya City
Arrowiyah, Sutikno, Setiawan ........................................ ............................................................

505

Preliminary Study of Traffic Marking Formulation Using Natural Rubber Grafted Modification
Athanasia Amanda Septevani, Agus Haryono, Dewi Sondari , Ahmad Randy.................................

510

Evaluation of (Justering Season Zone in Ngawi - East Java Using Support Vector Machine (SVM)
Bambang Widjanarko Otok, Agus 5uharsono, Elly Nur Shobihah .............................................

514

xiii

Performance Genetic Algorithm and Simulated Annealing of Case Studies Flow Shop Scheduling

Ratnawati "................ " ................. " .. ,...... " ..... ,............... "......................... ."" .... "." .................. ,.. "

519

Development of Static load Sensor Based on PVDF Film Element

Didik R. Santoso .........................................................................................................................

520

The Profile of the Constituents of White Turmeric Essential Oils (Curcuma zedoaria (Berg)
Roscoe) in the Variety of Distilate Collection Time
Dore Yulia, Rurini Retnowati, Moh. Farid Rahman .....................................................................

521

Dian

Nutrient Status Improvement of Ca and Mg in leaf by Administerir.g Dolomite to Decrease

Acidity levels of Tangerine Fruit (Citrus suhuiensis Tan)
Edi Siswadi, Ariffin, Syekhfani, Sudarmadi Purnomo ................................................................ ..

525

Developing of Solid Phase Extraction Based on Zeolites: Case Studied Cr(VI)

Eti Rohaeti, Betty Marita Soebrata, Putri Ratna Furi, Irmanida Batubara .................................... .

530

Synthesis of Silver (I) Nitrate with Ethylenethiourea and Characterization Using SEM-EDAX
Fariati, Markus Diantoro, Rokiy Alfanaar .................................................................................. ..

535

The Structure of Silver (I) Cyanate and Triphenylphosphine, [AgNCO(PPh,)].

Fariati, Effendy, Lilik Sunaria .............................................................................................. ..

538

Design,lmplementation andAnalysis Performance of XEN Hypervisor Virtual Machine Monitor

Based on linux for Server Technology Solutions in Indonesia
.. ................................... .
Hendarmawan.

541

Study Of Phosphate Coated Wire Electrode Using Chitosan as an Active Material

Hendry Iyabu, Hermin Sulistyarti, Atikah .................................... ..

542

Flow Injection Multichannel Sensor for Nitrate Analysis

Hermin Sulistyarti, Atikah, Setyawan P. Sakti, Spas Kolev, R.W. Cattrall

543

Testing of Radiation Exposure Homogenity of mCs Source Spherical Geometry

Holnisar, Rosdiani, Pujadi. .................................................................................................... ..

547

Comparison of Amobilization Chrome (Cr) in Waste of electroplating with Portland Pozzolan

Cement - Kaolin and Portland Pozzolan Cement Zeolite Use Solidification/Stabilization
Te1chnique
Ika Setyorini, Lies Wuryanita Aciriyani ....................................................................................

550

The Influence of Inoculate Concentration Ratio of lactic Acid Bacteria Streptococcus

thermophilus, Lactococcus lac tis and Lactobacillus bulgaricus toward The Time of pH Decrease
and The Weight of Curd in Cheese Production
Marissa Agnestiansyah, Chanlf Mahdi, Anna Roosdiana .................... ............................

551

Effect of Carbonization Temperature on Physical Properties of Coconut Shell Carbon

Meytij Jeanne Rampe, Bambang Setiaji, Wega Trisunaryanti, Triyono .... ..................................

555

Analysis of Dinamic Behavior on Chua's Circuit

Moh Anas Kurnia R, Erna Apriliani ............................................................................................

560

Immobilization lipa~e from Mucor miehei using Silica Gel Matrix

Ninik Afrizatus Sholichah, Anna Roosdiana, Sutnsr,o ................................................................

566

xiv

Existence of Global Solutions to a System of Nonlinear Klein-Gordon Equations

Ratno Bagus Edy Wibowo
... .,.,., .............................................~.........................................

572

Ranked Clusterability Model of Dyad Data in Social Network

R. B. Fajriya Hakim, Subanar, Edi Winarko ..............................................................................

575

Analysis and Numerical Solutions of 20 Navier-Stokes for Model of Shallow Water Flow with
Initial Value Problem and Boundary Value Problem
Ririn Kusumawati, Ari Kusumastuti, Fitriyanti Rumfot, Silva Ahmad A........................................

581

The Optimum Time of Steam Distillation of Wilted Aceh Patchouli Leaves

(Pogostemon cablin Benth) and The Characterization by Thin Layer Chromatogaphy and Gas
Chromatography-Mass Spectra
Rurini Retnowati, Sentot Joko Raharjo ........................................................................... ....................

585

Investigation the Mediating Variable: What Necessary?

Solimun.......................................................................................................................................

590

Study of Impregnated Co(lI) Content in Zeolite-Co(lI) Catalyst toward Phenol Oxidation

Sri Wardhani, Tutik Setianingsih, Agustina Afi Rahman........... ......................... .........................

593

Recent Seismicity at Guntur Volcano Complex, West Java, Indonesia

Sukir Maryanto ............................................................................... .

595

Isolation of a-Linolenic Acid from Fatty Acids of Basil Seed Oil (Ocimum 8asiJicum L.) using
Urea Inclusion; Variation of Fatty Acid-Urea Ratio and Temperature Crystallization
Suleman Duengo, Ruri'1i Retnowati, M. Farid Rahman ........................... ...................................

596

Synthesis and Characterization of Zinc-Soap Based-on Crude Palm Oil

Sutrisno, Irma Agustina, Ratih Purnamasari .. ., ....................................................................... .

601

The Effect of Alternative Nitrogen Sources on Xylanase Production from Trichoderma Viride
Sutrisno, Anna Roosdiana, Widyasari S ......................................... . .............. .,..........................

606

Effectivity of Ammonium Iron (III) Hexacyanoferrate Decontaminant in eliminating 137Cs

Radionuclides from the Body of Long Tail Monkey (Macaca fascicularis)
Tur Rahardjo .........................................................................................
..........................

610

Preparation of Lead(lI) Coated Wire Electrode Using Chitosan Membrane for Monitoring Lead(lI) in
Water Samples
.................. 616

\tiliwin Rewini Kunusa, Atikah, Hermin Sulistyarti

xv

Proceedings of The International Conference on Basic Science

17-18 Feb 2011

POSTER

Developing of Solid Phase Extraction Based on Zeolites: Case Studied

Cr(VI)
!;ti Rohaeti
rl.2.JA)

I,

Betty Manta Soebrata ,Putri Ratna Furi ,lnl1anida Batubara

Department of Chemistry, Faculty ofMathcmatics and Natural Scicnces, Bogor AgriculturalUnivcrsity,

Bogor, Indoncsia (era4_44(il;hotmail.com: bcttymarita(cygmaiLcom, ime(fl,;ipb.ac.id)

Abstract
Chromium especially hexavalent chromium is hazardous /0 aliI' health. becallse il is carcinogenic. Therefore,
chromium in drinking Imter should be minimized /0 less Ih(/n 50 fig. L One way to decrease chromium contenl
is using solid phase extraction silch as zeolites. Zeolites \ias mod(fied
calionic surj(u:lanl
hex(ldecyllrimelhylamonillfll brOil/ide (HDTl..1ABr) 10 increase ils adsolplion capacily. Adsorplion capacily of
Cr(V/) onlo zeoliles \ias 1.90 mg(f!;, when pH Cr(V/) solutions ,HIS 3 and con/act lillie was 18 hours. Adsorption
Cr(V/) ill/o zeolites jo//oll'ed Freundlich isolherm eqUaIioll. The hest ad.lolplion capacily of IfDT?lA Br (40.99
mglg) onto zeolites was achieved l111en IfDT!vfABr cO/lcentration Ims al 1000 ppm wilh cOli/act time 30 hOllrs.
AdvOIplion HDT!l4ABr inlo zeolites jol/oll'ed Lallgmuir isotherlll c'l/llatioll. NoaH 0.5 M dan ;Va.~COl 0.28 l'vi
(l: J vlv) mixtllre sollitiolls desOIped C,.(Vl) aholll 65.67% (by hatch eXlraetlOn) and 3.93% (by fixed-hed
i
cxlraelion). Properl/(!s ojzeolile a/ier modified Illlh HDTA1ABr lI'cre ShOH'fI al 2856.33 and 2927.65 elll peaks,
originatedji-om CHi 011 HDTl"fABr.
KeJ'lI'ords: Piper hellle, Piper croealllm, esselliialoil. tyrosillose ac/iIin'.

1. Introduction
The hexavalent chromium is present in
nature as CrO/". It is hazardous to our health,
because it is toxic and c:arc:inogenic: [I]. The pn;sc:nt
of chromate ion in the environ.nent caused SOIllC
problems such as how to monitor the chromate
level in the environment especially in water or
eflluent from industrial waste alld \1 hat IS
technology to treat or to reduce the risk of negative
effect from Cr(VI), espec:ially in drinking water
chromium lcyel should bc minilllized to less than
50 ~lglL
Solid phase extraction had been used 10
remove or to get thc hcavy metal residue from
componcnt, either in gas, liquid or solid phase.
Many solid phases had been used tt)r this purpu,,;,
for instance charcoul, resin, and Leolite [2]. Ze(.lite
I'ad been u~ed fClr treutment of waste, It has pore
and rich with cations which can be used as ion
exehunged and also us adsorbent.
To inerr::ase the ability oi zeolite C!S IOn
exehunger, 1l10dify is ne{'ded. On this paper, zeolite
was modit1ed wi!h cation surfa8tant to increase the
udsorption capacity. The cation surfactant which
used
was
hexa-decyl-tro-methyl-arnmonium
(HDTMA) [3], This research U1rns were to mudify
zeolite with HDTMABr and to find the

Faculty of Science, University of 81 uwijayn, Malan!], Indonesia

effectilcllcss of muditied Lcolitc with HDTMAl3r

based on its ;jeti\ ity to absorb Cr(VI).

2. Experimental Details
Sample.~

lIIaterial UIII/ preparatio/l

lcol itc,; wd,hed with water, dried in room

ternperatuc. and the grinded with mortar. The
zeol ite pll\\ de'r:; Ihen filter IIi th tllter 60 mesh.
Then, pll\\'der dril'd at 30WC for 3 hours.
..J eth'utioll of :eolile
Zeolite II:]:; acti\atcd chell1)1,:ally Ilith :Icid.
About 100 g zcolite mixcd with l:'UmL HCI -UJf\.l
for I hour. The mixture then \\:l,!1eJ \llth water till
neutral. The zeolit dried on -IOU'C t,)r :; lwurs.
Ad,;orptio'l
isotherm
of
1I DT\ L\ l3 r
Jilt!
lIloditieution of zeolite with HDT\1:\l3r \I'cre
perfonned with method of Giachi [-II Cation
Klute
ext.:h<lIlge capacity was determined
method [5], ChromIUm analysis was I'L'rttJrJllcd
bascd on Clesceri mcthod [6], while de,;,'rptl')11 of
Cr(VI) was performed based on Zeng 1ll(;!lH.d

'-J

Chromate adsorption
Zeolite and modified zeolite about U." g
e3eh added with Cr(VI) solution iOl different
coneelllmtion (2.0 60.0 ppm) at pH 3, -I, 5,6. and
7. The mixtures then shake at 150 rpm for I~. 1(1,

530

1
POSTER

Proceedings of The International Conference on Basic Science

17-18 Feb 2011
22, 24, and 26 hours. After that the mixture
separated with centrifuge and filtrution method. The
fiitrJte v"as JI1Jiyzed for the concentmtion of
Cr(VI). The adsorption eapaeity then caicuiJted
with equation:

Q=

LOi C

1.0000
0.0 00

1.5000

3. Result and Discussion

The adsorption capacity of HDTMA+
increascd significantly about 20.99 mgig from 0 to
1000 ppm
(Figure
I).
When
HDTMA+
concentration is highcr than 1000 ppm, the
adsorption capacity increascd slowly. HDTMA~
adsorption capacity at concentration 1000 ppm
ohtain at 30 hours contact time, decreascd at 42. 45,
and 48 hours.

'"

8,0000 10,0000

'"

/,
,/
,/

,/

.!!

,,/

2.0000

,/

weight of zeolite (g).

Zeolite characterization
Zeolite was characterized before and
after modificJtion, and also for zeolite after
desoprtion. Characterization was performed with
FT-IR Specfrum aile Perkin Elmer.

6.0000

".

----"---'

Q is adsorption capacity (mg!g), V is volume (L),

Co id initial eoncentratil)n of Cr(Vl) (ppm), C is
final concentration of Cr(VI) (ppm), Jnd m is

4,0000

,/

- C)

V(C

2.0000

2,5000

Figure 3. Curve of Isotherm Freundlich adsorption

of HDTMA on zeolite at different contact time ( _
) 24 h. (_ ) 30 h, (....... ) 42 h, (~ ~ ) 45 h, and
(,~ .. _) 4S h.
Isotherm adsorption of HDTMABr on
Leolite was 3nnlyzed with Langmuir and Freundlich
isotherm pattern (Figure 2 and 3, respectively). Thc
five different contact time on isotherm adsorption
showed that the high linearity found in Langmuir
isothcnn (r: 0.7439, 0.6935, O.99X. 0.9964, 0.9959
compared to 0.3062, (),0403, 0.9614, 0.8704 and
0.5894 on Freundlich isotherm).

,,

A.fter

actIvatIon

Figure L Curve of 'ldsorption capacity of HDTMA

on different contact time (e) 24 hours. (X) 30 hours,
(t) 42 hours. (;') 45

hour~, nnd (t.) 48 hours.

i"igure 4. Cation Exchange Capacity of Zeolite

,I
I

j.

)l

rf
,/'

Figure 2. Curve of Isotherm Langmuir of HD'fMA

on zeolite in differen! contact time ( _ ) 24 h. ( _
) 30 h, (.",.) 42 h, (_ .) 45 h, and ( _ ) 48 n.

Faculty ofScience, University of8rawijllya, Ma/ang, Indonesia

Cation cxchangc capacity (C Eel of initial

zeo:itc is about 74.81 mckllOO g (Figure 4). The
CEC was increased up to 96.24 mel 100 g zeolite
nfter activation process with washing with acid.
Wa;;hillg with acid can remove the impurities ill the
pores of zeolite and turning them into H-zeolite
without changing the position of the framework or
silica-alumina.
CEC value decreased atter moditled zeolite
with HDTMABr (20.76 mekllOO g zeolite). The
decreasing CEC is happen because a number of

531

Proceedings of The international Conference on Basic Science

POSTER

17-18Feb2011
HDTMA+ ions fonned in to bilayer with each
other. This bilayer covered most of zeolite surface
through ion exchange meehanism. The smalh:r
CEC value of zeolite showcd that this zeolite has
ability to absorb ion.

2.00

_.W
/

"/

Surface plotof capacity vs time and pH

0.00

2:0,00

"'.00

Equilibrium concentration (ppm)

Figure 6. Adsorption capacity ofCr(VI) in 18

hours with variation pH (II) 3, ( -"+) 4, (A) 5, (+) 6,
and (t) 7_
Capacity

pH

Figure 5. Response surface area intemetion eurvc

bctween capncity. pH, and eontnet time
Based on Figurc 5, adsorption capacity of
Cr(VI) is intlucllced by pH amI contat:t time
between Cr(VI) and adsorbent. From response
surtace data. the composite desirability value was
about 1000. it means that the model used has the
best
accurate
predictilln.
Bascd
on
the
determination of optimum condition in resp,mse
surface area the adsorption of Cr(VI) by zeolite
moditicd by HDTMABr 1000 ppm has high
capacity at pH 3 with contact time about 18 hours.
Adsorption of Cr(VI) by zeolitc strongly
iniluenced by pH of chromate solution used.
According to Zeng et al (2009)[7], adsorption
capacity of Cr(VI) decreases with increasing pH.
The increasing adsorption capacity of Cr(VI) in
acid may bc due to the cquilibrium of cpromate and
dichromate. Equilibrium reactions which <)Ccur arc
as follows:
rH < _
r! 1< !
~
(rOj-(aLl)
JICr/)::-(llljl .~. Cr:O: (alj) q
I'll"

Ba:;ed on Figure 6, the optimum adsorption

capacity produccd at pH 3 with capacity ahout 1.90
mg/g. It means that I g of zeolite optimum to
absorb Cr(VI) up to 1.9 mg. The compari~on
betwecn adsorption capacity of Cr(VI) on zeolite
with and without moditication at Cr(VI) 60 ppm is
shown in Figure 7. The highest adsorption on
zeolite without moditieation is about 0.64 mg/g,
while for modified zeolite up to 1.9 mg/g (incrcascd
aboutthrce times).
These results showed a significant increase
capacity due to the inscrtion of cation HDTMA+
which form a bilayer on the suriace of zeolite. It in
turn ,tltcr the originally negative chargcd zcolitc
hccOll1e positive, so that it can absorb thc anion
Cr(VI) with larger capacity than thc unnwditied
zeolite. The formation of hilaycr is formed through
hydrophohic
interaction
hetween
tails
of
HDTMABr [8 - II].
Desorption of Cr(VI) were calculated using
hatch system using the same solution, namely a
mixture of NaOH O.SM and Na2CO, 12.28M (I']
v/v), Desorption with batch system is better thnn
fixed bed method (Figure 7). This is hecause the
batch
mclhod
will
contact
strongly
,md
continuously between adsorbent and Cr(VJ).

i.. H >'

Fawlty of Scie'lce, Ullit'prsity of Brnwija)'ll, Maiall[j, Indonesia

532

Proceedings of The international Conference on Basic Science

17-18 Feb 2011
67

Batch

POSTER

'"
'"

Based on IR analysis (Figure 8). the zeolite

after desorption indicated that leaching solution did
not eliminate the HDTMA+ component. Zeolite
still shows absorption bands at 2856.33 em-I,
although v.-ith \ery low intensity.

'"

4. Conclusion

'"
eo
64

61

'"

'"

HO

Time (hour3J

'50
'00
i

'50

151)

"Xl
15"

l
i

"C

Fixed bed
method

300

Modification of zeolite with HDTMABr

could be used as snlid phase extraction of Cr(VI)
with ildsorption capacity about 1.90 mglg in
optimum condition. It gave higher adsorption level
than zeolite without modification. \JaOH O.5M
mixed with Na ZC0 3 O.28M in ration I: I (v/v) is
used as solution for desorption of Cr(VI) in batch
system with 65.67% of Cr(VI) could be removed
from the modi lied zeolite.

100

''''
'''' E~i"tl,
t l'
2
i

,
"
i

Figure 7. Desorption of zeolite and contact time tor

batch method and tixed oed mcthod
Figure 7 showed that desorption process in
ball:h method ootained the best cont3ct time I,)!, 22
hours with the amount of Cr(VI) about 65.67%.
The optimum desorption of Cr(VI) in tixed bl'd
method up to 3.93%.
Ch3facteristics in IR which can distinguish
between natural zeolite with moditied zcolite was
seen in 2927.65 em 1 (3rea lor -N(CH;)-) which
coml'S from HDTMABr. In addition. the strl'teh
pe3k 2856.33 em 1 is rdated to CH;-R. while in
region 3000
3500 cm 1 is rdated to CH3-R
asymmetry. According to Li & Gallus (2007). the
peak appears on 2860 and 2930 em 1 is generated
by themonomers and micelles of HDTMA' [i

"I

After desorptIOn
After modlfo;:allon

After activation
Be-tore activation

Figure 8. IR Spectrum of zeolit

Faculty ofScience, University of Brawijo)'a, Mall1n9, Indonesia

5. References
(I]. Gang D, Bancrji S.K . Clevenger T.E .. (1999),
Chromium (VI) removal by modified PVP
coated silica sel. Proceeding of the 1999
Conference on Hazardous Waste Researche,
Mi~souri. Columbia 64-67.
[2]. Trisunaryanti W, Triwahyuni E, Sudiono S.,
dan
(2005).
Preparasi.
lTloditikasi.
karakterisasi kalalis N i-1vlol zeolit alam dan
Mo-Nil zeolit alam. Tekl/uin 10 (4):269-282.
(3]. Zang P, A vud/.ega M, Bowman R.S . (2007),
Removal of perchlorate from contamined
waters using surfactant-modified zeolite.
Journal of !Il'irol//I/<!ll1a/ Qlllliity 1069-1075.
[4]. Ghiaci M. Kia A. i\bbaspur A. Azau F.S.,
(2004). Adsorption of chromate by surhletant
moditied zeolitcs and MCM -41 molecular
sieve. Separation (/Ii'/ PIIl'llicalioll Technolo,~'Y
W285-295.
[51. Klute A., (1 (86). Methous of Soil Analysis
Pilrt I: Physieill and Mineralogical Methods.
Sccond Edition. Wisconsin: Uniteu States of
Agronomy and Soil Science Society of
America.
[6]. Clcseeri L.S., Greenberg A.E,. Eaton A.D.,
Rice E.W., (2005). Stanuard Mcthods for the
Examination of Water and Wastewater. 21'h
Edition. Washington DC: American Public
Health Association.
[7]. Zeng Y, Woo Heesoo, Lee Gwanghun. Park
lunbourn (2009), Adsorption of Cr(VI) on
hexadecylpiridinium
bromiue
(HDPS)
modi lied nJtural zeolites. A4icroporolls and
J1esoporolls ..... ..
[8]. Chutia P, Kato S, Kojima T, Satokawa S.,
(2009), Adsorption of As(V, on surfactant
Journal of
modified
natural
zeolites.
HazardOl/s Marerial 162: 204-211.

533

Proceedings of The International Conference on Basic Science

POSTER

17-18 Feb 2011

[9]. Cordoves P, Valde's MG, Fernandez JeT.
Luis GP.Calzo JAG, GarclB MED., (2008).
Characterization of the binding site aftinity
distribution
of
surfactant
modified
elinoptilolite. :'vlicroporolls (Ind M".IO!,OroIiS
lv/mertals 109: 38-48.
[10]. Bowman RS, Zhang Pengfei, Xian Tao.
Johnson RL, Johnson TL.. (2000), Surface
altered zeolites as permeable barriers 1"1r In
sitll treatment of contamincd groundwater.
(Research report). Daytona: National Energy
Technology Laboratory.

Faculty ofSde!7cP, University of Brawl;aya, Malarw, fndonesia

[11]. Madjan M, Pikus S, Rzaczyn Z, Iwan

~1.

Maryuk 0, Kwiatkowski R, Skrzypek H"

(2006), Characteristics of chabazite modified
by hexadecyitrimethylammoniulll. JOllrnal
Molecular Siruclllre 791: 53-60.
[12]. Li l, Gallus L., (2007), Adsorption of
dodeeyltrimethylammonium
and
hexadecyltrimethylammonium onto kaolinite
competitive adsorption and chain length
cffect. Applied Clay Science 35: 250-257.

534