Issue Date: 03-JUN-2011

Supercedes: 22-OCT-2010

Material Safety Data Sheet

PETROMEEN OS-16

1 Identification
Identification of substance or preparation
PETROMEEN OS-16
Product Application Area
Corrosion inhibitor
Company/Undertaking Identification
GE Betz, Inc.
4636 Somerton Road
Trevose, PA 19053
T 215 355-3300, F 215 953 5524
Emergency Telephone
(800) 877-1940
Prepared by Product Stewardship Group: T 215-355-3300

Prepared on: 03-JUN-2011

2 Hazard(s) identification
********************************************************************************
EMERGENCY OVERVIEW
WARNING
May cause moderate irritation to the skin. May cause dermatitis.
Severe irritant to the eyes. May cause irritation to the upper
respiratory tract. Exposure may cause dizziness, headache, CNS
depression and chemical pneumonitis.
DOT hazard: Combustible liquid
Odor: Hydrocarbon; Appearance: Brown-Black, Liquid
Fire fighters should wear positive pressure self-contained breathing
apparatus(full face-piece type). Proper fire-extinguishing media:
dry chemical, carbon dioxide or foam--Avoid water if possible.
********************************************************************************
POTENTIAL HEALTH EFFECTS
ACUTE SKIN EFFECTS:
Primary route of exposure; May cause moderate irritation to the
skin. May cause dermatitis.
ACUTE EYE EFFECTS:
Severe irritant to the eyes.
ACUTE RESPIRATORY EFFECTS:

Substance or Preparation: PETROMEEN OS-16

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Primary route of exposure;May cause irritation to the upper

respiratory tract. Exposure may cause dizziness, headache, CNS
depression and chemical pneumonitis.
INGESTION EFFECTS:
May cause gastrointestinal irritation with possible nausea,
vomiting, diarrhea, mental confusion, dizziness and lethargy. Small
amounts aspirated during ingestion or vomiting may cause lung
injury, possibly leading to death.
TARGET ORGANS:
Prolonged or repeated exposures may cause CNS depression and/or
defatting-type dermatitis. Product or product component may
increase the risk of cancer.
MEDICAL CONDITIONS AGGRAVATED:
Not known.
SYMPTOMS OF EXPOSURE:
Excessive dermal exposure causes defatting and drying of skin.
Excessive inhalation of vapors causes dizziness, headache and
nausea.

3 Composition / information on ingredients

Information for specific product ingredients as required by the
U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to
additional sections of this MSDS for our assessment of the potential
hazards of this formulation. This product is subject to the Pennsylvania
and New Jersey Worker and Community Right to Know Law.
HAZARDOUS INGREDIENTS:
Cas#

Chemical Name

91-20-3

NAPHTHALENE
Irritant; absorbed by skin; sensitizer; possible
human carcinogen (IARC=2B; NTP=anticipated); toxic
to liver, kidney, and blood; causes nasal tumors in
rats

7-13

71-43-2

BENZENE
Flammable liquid; irritant (eyes); human carcinogen
(IARC=1; NTP=known); toxic to blood and nervous
system; potential reproductive toxin

0.1-1.0

64742-94-5

SOLVENT NAPHTHA, PETROLEUM, HEAVY AROMATIC

Combustible liquid; irritant (eyes)

40-70

TRADE SECRET INGREDIENT(E142);TSRN 125438 - 5103P

Toxic (by inhalation); irritant (eyes)

95-63-6

1,2,4-TRIMETHYLBENZENE
Flammable; irritant (respiratory); CNS depressant

10-20

526-73-8

1,2,3-TRIMETHYLBENZENE
Combustible liquid; CNS depressant; may affect blood
system

5-10

Substance or Preparation: PETROMEEN OS-16

Range(w/w%)

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108-67-8

BENZENE, 1,3,5-TRIMETHYL-; MESITYLENE

Combustible liquid; CNS depressant; may affect blood
system

1-5

Naphthalene is not intentionally added to this product but is a component

of the aromatic naphtha solvent. It is not a WHMIS regulated component of
this controlled product.
NON-HAZARDOUS INGREDIENTS:
CAS#

CHEMICAL NAME
NONE

4 First-aid measures
SKIN CONTACT:
Wash thoroughly with soap and water for at least 15 minutes.
Remove contaminated clothing. Thoroughly wash clothing before
reuse. Get immediate medical attention.
EYE CONTACT:
Remove contact lenses. Hold eyelids apart. Immediately flush eyes
with plenty of low-pressure water for at least 15 minutes. Get
immediate medical attention.
INHALATION:
Remove to fresh air. If breathing is difficult, give oxygen. If
breathing has stopped, give artificial respiration. Get immediate
medical attention.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive
victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 2-8 fluid ounces (60-240 mL) of
milk or water. If vomiting occurs naturally have victim lean
forward to reduce risk of aspiration.
NOTES TO PHYSICIANS:
This product contains a hydrocarbon solvent. Aspiration into the
lungs will result in chemical pneumonia and may be fatal.

5 Fire-fighting measures
FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing
apparatus (full face-piece type).
EXTINGUISHING MEDIA:
dry chemical, carbon dioxide or foam--Avoid water if possible.
HAZARDOUS DECOMPOSITION PRODUCTS:
oxides of carbon and nitrogen
FLASH POINT:
~ 150F
~ 66C P-M(CC)
MISCELLANEOUS:
Combustible liquid
NA 1993;Emergency Response Guide #128

6 Accidental release measures

Substance or Preparation: PETROMEEN OS-16

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PROTECTION AND SPILL CONTAINMENT:

Ventilate area. Use specified protective equipment. Contain and
absorb on absorbent material. Place in waste disposal container.
Remove ignition sources. Flush area with water. Spread sand/grit.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer
treatment facility,in accordance with any local agreement,a permitted
waste treatment facility or discharged under a permit. Product
as is - Incinerate or land dispose in an approved landfill.

7 Handling and storage

HANDLING:
Combustible. Bond and ground containers during filling or
discharge. Do not use near sparks, flames or sources of ignition.
STORAGE:
Keep containers closed when not in use. Store in cool ventilated
location. Store away from oxidizers. Keep away from flames or
sparks.

8 Exposure controls / personal protection

CHEMICAL NAME

EXPOSURE LIMITS

NAPHTHALENE
PEL (OSHA): 10 PPM
TLV (ACGIH): 10 PPM
BENZENE
PEL (OSHA): TWA = 1 PPM; STEL = 5 PPM
TLV (ACGIH): TWA (SKIN) = 0.5 PPM; STEL = 2.5 PPM; A1
MISC: NIOSH REL = 0.1 PPM; NIOSH STEL = 1 PPM; NIOSH IDLH = 500 PPM
SOLVENT NAPHTHA, PETROLEUM, HEAVY AROMATIC
PEL (OSHA): LIMITS HAVE NOT BEEN ESTABLISHED BY US OSHA.
TLV (ACGIH): LIMITS HAVE NOT BEEN ESTABLISHED BY ACGIH.
MISC: Note- manufacturers recommended exposure limit: 100 ppm.
TRADE SECRET INGREDIENT(E142);TSRN 125438 - 5103P
PEL (OSHA): LIMITS HAVE NOT BEEN ESTABLISHED BY US OSHA.
TLV (ACGIH): LIMITS HAVE NOT BEEN ESTABLISHED BY ACGIH.
1,2,4-TRIMETHYLBENZENE
PEL (OSHA): LIMITS HAVE NOT BEEN ESTABLISHED BY US OSHA.
TLV (ACGIH): 25 PPM(TRIMETHYLBENZENE MIXED ISOMERS)
1,2,3-TRIMETHYLBENZENE
PEL (OSHA): LIMITS HAVE NOT BEEN ESTABLISHED BY US OSHA.
TLV (ACGIH): TWA = 25 PPM
BENZENE, 1,3,5-TRIMETHYL-; MESITYLENE
PEL (OSHA): LIMITS HAVE NOT BEEN ESTABLISHED BY US OSHA.
TLV (ACGIH): LIMITS HAVE NOT BEEN ESTABLISHED BY ACGIH.
8) EXPOSURE CONTROLS/PERSONAL PROTECTION (continued)
ENGINEERING CONTROLS:

Substance or Preparation: PETROMEEN OS-16

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Adequate ventilation to maintain air contaminants below exposure

limits.
PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHAS 29 CFR
1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER
WORKPLACE CONDITIONS WARRANT A RESPIRATORS USE.
USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED
WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS.
If air-purifying respirator use is appropriate, use organic
vapor cartridges and any of the following particulate
respirators: R95, R99, R100, P95, P99 or P100.
SKIN PROTECTION:
viton gloves-- Wash off after each use. Replace as necessary.
EYE PROTECTION:
splash proof chemical goggles

9 Physical and chemical properties

Density
7.4 lbs/gal
Freeze Point (F)
< -30
Freeze Point (C)
< -34
Viscosity(cps 70F,21C)
18
Odor
Appearance
Physical State
Flash Point
P-M(CC)
pH 1% Disp. (approx.)
Evaporation Rate (Ether=1)
Percent VOC:
NA = not applicable

Vapor Pressure (mmHG)

Vapor Density (air=1)

~ 5.0
< 1.00

% Solubility (water)

0.0

Hydrocarbon
Brown-Black
Liquid
~ 150F ~ 65C
7.3
< 1.00
75.0

ND = not determined

10 Stability and reactivity

CHEMICAL STABILITY:
Stable under normal storage conditions.
POSSIBILITY OF HAZARDOUS REACTIONS:
Friction, heat or other sources of ignition may cause a reaction
releasing heat and toxic fumes. Contact with oxidizers may cause
fire.
INCOMPATIBILITIES:
May react with strong oxidizers.
DECOMPOSITION PRODUCTS:
oxides of carbon and nitrogen

11 Toxicological information
Oral LD50 RAT:
>5,000 mg/kg
NOTE - Calculated value according to GHS additivity formula
Dermal LD50 RABBIT:
2830 mg/kg
NOTE - Calculated value according to GSH additivity formula

Substance or Preparation: PETROMEEN OS-16

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12 Ecological information
AQUATIC TOXICOLOGY
Daphnia magna 48 Hour Static Acute Bioassay
LC50= 7; No Effect Level= 3.7 mg/L
Fathead Minnow 96 Hour Static Acute Bioassay
LC50= 8.3; No Effect Level= 7.5 mg/L
BIODEGRADATION
BOD-28 (mg/g): 999
BOD-5 (mg/g): 198
COD (mg/g): 2080
TOC (mg/g): 831

13 Disposal considerations
If this undiluted product is discarded as a waste, the US RCRA
hazardous waste identification number is :
D018=Benzene.
Please be advised; however, that state and local requirements for
waste disposal may be more restrictive or otherwise different from
federal regulations. Consult state and local regulations regarding
the proper disposal of this material.

14 Transport information
Transportation Hazard: Combustible liquid
DOT:
COMBUSTIBLE LIQUID, N.O.S.(NAPHTHALENE SOLUTION)
NA 1993, PG III, RQ
DOT EMERGENCY RESPONSE GUIDE #: 128
Note: Some containers may be DOT exempt, please check BOL for
exact container classification
IATA: Not Regulated
IMDG:

Not Regulated

15 Regulatory information
TSCA:
All components of this product are included on or are in
compliance with the U.S. TSCA regulations.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):
163 gallons due to NAPHTHALENE;1,992 gallons due to BENZENE;
Treat as oil spill
NSF Registered and/or meets USDA (according to 1998 Guidelines):
Registration number: Not Registered
SARA SECTION 312 HAZARD CLASS:
Immediate(acute);Delayed(Chronic);Fire
SARA SECTION 313 CHEMICALS:
CAS#
CHEMICAL NAME
RANGE
91-20-3
NAPHTHALENE
6.0-10.0%
95-63-6
1,2,4-TRIMETHYLBENZENE
11.0-15.0%
CALIFORNIA REGULATORY INFORMATION

Substance or Preparation: PETROMEEN OS-16

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CALIFORNIA SAFE DRINKING WATER AND TOXIC

ENFORCEMENT ACT (PROPOSITION 65):
This product contains one or more ingredients known to the state of
California to cause cancer and reproductive toxicity.
MICHIGAN REGULATORY INFORMATION
CAS#
91-20-3

CHEMICAL NAME
NAPHTHALENE

16 Other information
HMIS vII
Health
Fire
Reactivity
Special
(1) Protective Equipment

CODE TRANSLATION
2
2
0
NONE
B

Moderate Hazard
Moderate Hazard
Minimal Hazard
No special Hazard
Goggles,Gloves

(1) refer to section 8 of MSDS for additional protective equipment

recommendations.
CHANGE LOG
EFFECTIVE
DATE
--------MSDS status: 22-AUG-1995
23-AUG-1996
01-APR-1997
02-SEP-1997
08-JAN-1998
24-APR-1998
02-JUN-2000
21-AUG-2001
05-MAY-2006
01-JUN-2009
22-OCT-2010
03-JUN-2011

REVISIONS TO SECTION:
--------------------REVISED FORMAT
5,14;EDIT:9
12
2
2,8,15
2,8,15
3,4,5,14
2
2
10
2,3,7,8,13,14,15
8,15

Substance or Preparation: PETROMEEN OS-16

SUPERCEDES
---------** NEW **
22-AUG-1995
23-AUG-1996
01-APR-1997
02-SEP-1997
08-JAN-1998
24-APR-1998
02-JUN-2000
21-AUG-2001
05-MAY-2006
01-JUN-2009
22-OCT-2010

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