Safety Data Sheet: Fendona 6 SC

Safety data sheet
Page: 1/16
BASF Safety data sheet according to Regulation (EC) No. 1907/2006
Date / Revised: 18.11.2013
Version: 2.0
Product: FENDONA 6 SC
(ID no. 30278853/SDS_GEN_GB/EN)
Date of print 20.11.2013
SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1. Product identifier
FENDONA 6 SC
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: biocide
1.3. Details of the supplier of the safety data sheet

Company:
BASF SE
67056 Ludwigshafen
GERMANY
Telephone: +44 161 485-6222

E-mail address: [email protected]
1.4. Emergency telephone number

International emergency number:
Telephone: +49 180 2273-112
SECTION 2: Hazards Identification

2.1. Classification of the substance or mixture
According to Regulation (EC) No 1272/2008 [CLP]
Aquatic Acute 1
Aquatic Chronic 1
According to Directive 67/548/EEC or 1999/45/EC
Contact address:
BASF plc
PO Box 4, Earl Road, Cheadle Hulme,
Cheadle, Cheshire
SK8 6QG, UNITED KINGDOM
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Version: 2.0
Possible Hazards:
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
May cause paraesthesia.
For the classifications not written out in full in this section the full text can be found in section 16.
2.2. Label elements

Globally Harmonized System, EU (GHS)
Pictogram:
Signal Word:
Warning
Hazard Statement:
H400
H410
Very toxic to aquatic life.

Very toxic to aquatic life with long lasting effects.
Precautionary Statements (Prevention):

P262
Do not get in eyes, on skin, or on clothing.
Precautionary Statements (Response):
P391
Collect spillage.
Precautionary Statements (Disposal):
P501.1
Dispose of contents/container in accordance with local regulations.
Labeling of special preparations (GHS):

May cause paraesthesia. ALPHA-CYPERMETHRIN
According to Directive 67/548/EEC or 1999/45/EC
Classification/labelling in accordance with UK regulations.
Hazard symbol(s)
N
Dangerous for the environment.
R-phrase(s)
R50/53
S-phrase(s)
Very toxic to aquatic organisms, may cause long-term adverse effects

in the aquatic environment.
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Version: 2.0
S2
Keep out of the reach of children.
S13
Keep away from food, drink and animal feeding stuffs.
S20/21
When using do not eat, drink or smoke.
S23
Do not breathe gas/fumes/vapour/spray (appropriate wording to be
specified by the manufacturer).
S24
Avoid contact with skin.
S29
Do not empty into drains.
S35
This material and its container must be disposed of in a safe way.
S36/37
Wear suitable protective clothing and gloves.
S57
Use appropriate container to avoid environmental contamination.
The product contains: ALPHA-CYPERMETHRIN

May cause paraesthesia.
2.3. Other hazards

According to Regulation (EC) No 1272/2008 [CLP]
See section 12 - Results of PBT and vPvB assessment.
If applicable information is provided in this section on other hazards which do not result in
classification but which may contribute to the overall hazards of the substance or mixture.
SECTION 3: Composition/Information on Ingredients

3.1. Substances
Not applicable
3.2. Mixtures
Chemical nature
suspension concentrate (SC)
Biocidal product
Hazardous ingredients (GHS)

according to Regulation (EC) No. 1272/2008
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Version: 2.0
.alpha.-cypermethrin (ISO); racemate comprising (R)-.alpha.-cyano-3-phenoxybenzyl (1S,3S)-3-(2,2dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate; (S)-.alpha.-cyano-3-phenoxybenzyl (1R,3R)-3(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate
Content (W/W): 5.8 %
Acute Tox. 4 (Inhalation - dust)
CAS Number: 67375-30-8
Acute Tox. 3 (oral)
INDEX-Number: 607-422-00-X
STOT SE 3 (irr. to respiratory syst.)
STOT RE 2
Aquatic Acute 1
Aquatic Chronic 1
M-factor acute: 10000
M-factor chronic: 1000
H301, H332, H335, H373, H400, H410
Propane-1,2-diol
Content (W/W): < 15 %
CAS Number: 57-55-6
EC-Number: 200-338-0
REACH registration number: 012119456809-23
Hazardous ingredients
according to Directive 1999/45/EC
.alpha.-cypermethrin (ISO); racemate comprising (R)-.alpha.-cyano-3-phenoxybenzyl (1S,3S)-3-(2,2dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate; (S)-.alpha.-cyano-3-phenoxybenzyl (1R,3R)-3(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate
Content (W/W): 5.8 %
CAS Number: 67375-30-8
Hazard symbol(s): T, N
R-phrase(s): 20, 25, 37/38, 48/22, 50/53
Propane-1,2-diol
Content (W/W): < 15 %
CAS Number: 57-55-6
REACH registration number: 01-2119456809-23
For the classifications not written out in full in this section, including the indication of danger, the
hazard symbols, the R phrases, and the hazard statements, the full text is listed in section 16.
SECTION 4: First-Aid Measures

4.1. Description of first aid measures
Show container, label and/or safety data sheet to physician.
If inhaled:
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Keep patient calm, remove to fresh air.
On skin contact:
Wash thoroughly with soap and water.
On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open.
On ingestion:
Rinse mouth and then drink plenty of water.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms: numbness and tingling of hands and feet, lung oedema, convulsions
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Symptomatic treatment (decontamination, vital functions).
SECTION 5: Fire-Fighting Measures

5.1. Extinguishing media
Suitable extinguishing media:
water spray, foam, dry powder, carbon dioxide
5.2. Special hazards arising from the substance or mixture

carbon monoxide, Carbon dioxide, hydrogen cyanide; hydrocyanic acid, hydrogen chloride, nitrogen
oxides, organochloric compounds
The substances/groups of substances mentioned can be released in case of fire.
5.3. Advice for fire-fighters

Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if
exposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewage
or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with
official regulations.
SECTION 6: Accidental Release Measures

6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective clothing. Do not breathe vapour/spray. Avoid contact with the skin, eyes and
clothing.
6.2. Environmental precautions

Do not allow contamination of public drains or surface or ground waters. Inform local water plc if
spillage enters drains and the Environment Agency (England & Wales), the Scottish Environmental
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Version: 2.0
Protection Agency (Scotland), or the Environment and Heritage Service (Northern Ireland) if it enters
surface or ground waters. Keep people and animals away.
6.3. Methods and material for containment and cleaning up

For small amounts: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose
binder, kieselguhr).
For large amounts: Dike spillage. Pump off product.
Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers,
which can be labeled and sealed. Clean contaminated floors and objects thoroughly with water and
detergents, observing environmental regulations.
6.4. Reference to other sections

Information regarding exposure controls/personal protection and disposal considerations can be
found in section 8 and 13.
SECTION 7: Handling and Storage

7.1. Precautions for safe handling
No special measures necessary if stored and handled correctly. Ensure thorough ventilation of
stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed
before breaks and at the end of the shift.
Protection against fire and explosion:
No special precautions necessary. The substance/product is non-combustible. Product is not
explosive.
7.2. Conditions for safe storage, including any incompatibilities

Segregate from foods and animal feeds.
Further information on storage conditions: Keep away from heat. Protect from direct sunlight.
Storage stability:
Storage duration: 36 Months
Protect from temperatures below: -10 C
Changes in the properties of the product may occur if substance/product is stored below indicated
temperature for extended periods of time.
Protect from temperatures above: 40 C
Changes in the properties of the product may occur if substance/product is stored above indicated
temperature for extended periods of time.
7.3. Specific end use(s)

For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be
observed.
SECTION 8: Exposure Controls/Personal Protection

8.1. Control parameters
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Version: 2.0
Components with occupational exposure limits
57-55-6: Propane-1,2-diol
TWA value 10 mg/m3 (WEL/EH 40 (UK)), Particulate
TWA value 474 mg/m3 ; 150 ppm (WEL/EH 40 (UK)), Total vapour and
particulates
Refer to the current edition of HSE Guidance Note EH40 Occupational Exposure Limits (United
Kingdom). For normal use and handling refer to the product label/leaflet. In all other cases the
following apply.
8.2. Exposure controls

Personal protective equipment
Respiratory protection:
Suitable respiratory protection for higher concentrations or long-term effect: (Particle filter EN 143 P2
or FFP2)
Hand protection:
Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact
(Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to
EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and other
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work
clothing is recommended. Store work clothing separately. Keep away from food, drink and animal
feeding stuffs.
SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties
Form:
Colour:
Odour:
Odour threshold:
suspension
white
faintly aromatic
Not determined due to potential
health hazard by inhalation.
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Version: 2.0
pH value:
approx. 6 - 8
(water, 1 %(m), 20 C)
(measured with the undiluted
substance)
crystallization temperature:
-5.7 C
Boiling point:
approx. 100 C
Information applies to the solvent.
Flash point:
> 100 C
(DIN EN 22719; ISO 2719)
No flash point - Measurement made
up to the boiling point.
Evaporation rate:
not applicable
Flammability:
Based on the structure or
composition there is no indication of
flammability
Lower explosion limit:
As a result of our experience with this
product and our knowledge of its
composition we do not expect any
hazard as long as the product is used
appropriately and in accordance with
the intended use.
Upper explosion limit:
As a result of our experience with this
product and our knowledge of its
composition we do not expect any
hazard as long as the product is used
appropriately and in accordance with
the intended use.
Ignition temperature:
425 C
(Directive 92/69/EEC, A.15)
Vapour pressure:
approx. 23 hPa
(20 C)
Information applies to the solvent.
Density:
approx. 1.03 g/cm3
(OECD Guideline 109)
(20 C)
Relative vapour density (air):
not determined
Solubility in water:
dispersible
Partitioning coefficient n-octanol/water (log Kow):
not applicable
Thermal decomposition: No decomposition if stored and handled as prescribed/indicated.
Viscosity, dynamic:
28 mPa.s
(OECD 114)
(20 C)
Explosion hazard:
not explosive
(Directive 92/69/EEC, A.14)
Fire promoting properties: not fire-propagating
9.2. Other information

Other Information:
If necessary, information on other physical and chemical parameters is indicated in this section.
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Version: 2.0
SECTION 10: Stability and Reactivity

10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
10.2. Chemical stability

The product is stable if stored and handled as prescribed/indicated.
10.3. Possibility of hazardous reactions

No hazardous reactions if stored and handled as prescribed/indicated.
10.4. Conditions to avoid

See MSDS section 7 - Handling and storage.
10.5. Incompatible materials

Substances to avoid:
strong bases, strong acids, strong oxidizing agents
10.6. Hazardous decomposition products

Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.
SECTION 11: Toxicological Information

11.1. Information on toxicological effects
Acute toxicity
Assessment of acute toxicity:
Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact. Virtually
nontoxic by inhalation.
Experimental/calculated data:
LD50 rat (oral): > 5,000 mg/kg (Guideline 92/69/EEC, B.1)
LC50 rat (by inhalation): > 2.08 mg/l 4 h (OECD Guideline 403)
Highest concentration available for testing. No mortality was observed. An aerosol was tested.
LD50 rat (dermal): > 2,000 mg/kg (Directive 92/69/EEC, B.3)
No mortality was observed.
Irritation
Assessment of irritating effects:
Not irritating to the eyes. Not irritating to the skin.
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Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404)
The product has not been tested. The statement has been derived from substances/products of a
similar structure or composition.
Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405)
Respiratory/Skin sensitization
Assessment of sensitization:
There is no evidence of a skin-sensitizing potential.
modified Buehler test guinea pig: Non-sensitizing. (OECD Guideline 406)
Germ cell mutagenicity
Assessment of mutagenicity:
The product has not been tested. The statement has been derived from the properties of the
individual components. Mutagenicity tests revealed no genotoxic potential.
Carcinogenicity
Assessment of carcinogenicity:
individual components. The results of various animal studies gave no indication of a carcinogenic
effect.
Reproductive toxicity
Assessment of reproduction toxicity:
individual components. The results of animal studies gave no indication of a fertility impairing effect.
Developmental toxicity
Assessment of teratogenicity:
individual components. Animal studies gave no indication of a developmental toxic effect at doses
that were not toxic to the parental animals.
Repeated dose toxicity and Specific target organ toxicity (repeated exposure)
Assessment of repeated dose toxicity:
individual components.
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Version: 2.0
Information on: -cypermethrin (ISO); racemate comprising (R)--cyano-3-phenoxybenzyl (1S,3S)-3(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxyl ate; (S)--cyano-3-phenoxybenzyl (1R,3R)-3(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate
Assessment of repeated dose toxicity:
Repeated oral exposure may affect certain organs. Damages the peripheral nerve system.
---------------------------------Other relevant toxicity information
Misuse can be harmful to health.
SECTION 12: Ecological Information

12.1. Toxicity
Assessment of aquatic toxicity:
individual components. Very toxic to aquatic organisms. May cause long-term adverse effects in the
aquatic environment.
Information on: .alpha.-cypermethrin (ISO); racemate comprising (R)-.alpha.-cyano-3-phenoxybenzyl
(1S,3S)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate; (S)-.alpha.-cyano-3phenoxybenzyl (1R,3R)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate
Toxicity to fish:
LC50 (96 h) 0.00093 mg/l, Pimephales promelas (OPP 72-1 (EPA-Guideline), Flow through.)
---------------------------------Information on: .alpha.-cypermethrin (ISO); racemate comprising (R)-.alpha.-cyano-3-phenoxybenzyl
Aquatic invertebrates:
EC50 (48 h) 0.000013 mg/l 12,6 ng/L, Chironomus riparius (OECD Guideline 202, part 1, static)
---------------------------------Information on: .alpha.-cypermethrin (ISO); racemate comprising (R)-.alpha.-cyano-3-phenoxybenzyl
Aquatic plants:
EC50 (72 h) > 1 mg/l (growth rate), Scenedesmus subspicatus (OECD Guideline 201, static)
No observed effect concentration (7 d) >= 1,39 g/L (growth rate), Lemna gibba (OECD guideline
221, static)
----------------------------------
12.2. Persistence and degradability

Assessment biodegradation and elimination (H2O):
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Assessment biodegradation and elimination (H2O):
Not readily biodegradable (by OECD criteria). Poorly biodegradable.
----------------------------------
12.3. Bioaccumulative potential

Assessment bioaccumulation potential:
Bioaccumulation potential:
Bioconcentration factor: 155 - 910 (73 d), Cyprinus carpio (OECD Guideline 305 C)
Accumulation in organisms is not to be expected.
----------------------------------
12.4. Mobility in soil

Assessment transport between environmental compartments:
Assessment transport between environmental compartments:
Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of
groundwater is not expected.
----------------------------------
12.5. Results of PBT and vPvB assessment

The product does not contain a substance fulfilling the PBT (persistent/bioaccumulative/toxic) criteria
or the vPvB (very persistent/very bioaccumulative) criteria.
12.6. Other adverse effects

The product does not contain substances that are listed in Regulation (EC) 1005/2009 on
substances that deplete the ozone layer.
12.7. Additional information

Other ecotoxicological advice:
Do not discharge product into the environment without control.
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Version: 2.0
SECTION 13: Disposal Considerations

13.1. Waste treatment methods
Must be sent to a suitable incineration plant, observing local regulations.
The UK Environmental Protection (Duty of Care) Regulations (EP) and amendments should be noted
(United Kingdom).
This product and any uncleaned containers must be disposed of as hazardous waste in accordance
with the 2005 Hazardous Waste Regulations and amendments (United Kingdom)
Contaminated packaging:
Contaminated packaging should be emptied as far as possible and disposed of in the same manner
as the substance/product.
SECTION 14: Transport Information

Land transport
ADR
UN number
UN proper shipping name:
UN3082
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains ALPHA-CYPERMETHRIN)
Transport hazard class(es): 9, EHSM
Packing group:
III
Environmental hazards:
yes
Special precautions for
Tunnel code: E
user:
RID
UN number
UN3082
Packing group:
III
yes
None known
user:
Inland waterway transport

ADN
UN number
UN3082
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Version: 2.0
Packing group:
III
yes
None known
user:
Transport in inland
Not evaluated
waterway vessel:
Sea transport
IMDG
UN number:
UN 3082
Packing group:
III
yes
Marine pollutant: YES
None known
user:
Air transport
IATA/ICAO
UN number:
UN 3082
Packing group:
III
yes
None known
user:
14.1. UN number
See corresponding entries for UN number for the respective regulations in the tables above.
14.2. UN proper shipping name

See corresponding entries for UN proper shipping name for the respective regulations in the tables
above.
14.3. Transport hazard class(es)

See corresponding entries for Transport hazard class(es) for the respective regulations in the
tables above.
14.4. Packing group

See corresponding entries for Packing group for the respective regulations in the tables above.
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Version: 2.0
14.5. Environmental hazards

See corresponding entries for Environmental hazards for the respective regulations in the tables
above.
14.6. Special precautions for user

See corresponding entries for Special precautions for user for the respective regulations in the
tables above.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Regulation:
Shipment approved:
Pollution name:
Pollution category:
Ship Type:
Not evaluated
Not evaluated
Not evaluated
Not evaluated
Not evaluated
Further information
This product is subject to the most recent edition of "The Carriage of Dangerous Goods and Use of
Transportable Pressure Equipment Regulations" and their amendments (United Kingdom).
SECTION 15: Regulatory Information

15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
To avoid risks to man and the environment, comply with the instructions for use.
The data should be considered when making any assessment under the Control of Substances
Hazardous to Health Regulations (COSHH), and related guidance, for example, 'COSHH Essentials'
(United Kingdom).
This product is classified under the Chemicals (Hazard Information and Packaging) Regulations,
(CHIP) (United Kingdom).
This product may be subject to the Control of Major Accident Hazards Regulations (COMAH), and
amendments if specific threshold tonnages are exceeded (United Kingdom).
15.2. Chemical Safety Assessment

Advice on product handling can be found in sections 7 and 8 of this safety data sheet.
SECTION 16: Other Information

For proper and safe use of this product, please refer to the approval conditions laid down on the
product label.
Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases,
and the hazard statements, if mentioned in section 2 or 3:
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Version: 2.0
T
Toxic.
N
Dangerous for the environment.
20
Harmful by inhalation.
25
Toxic if swallowed.
37/38
Irritating to respiratory system and skin.
48/22
Harmful: danger of serious damage to health by prolonged exposure if
swallowed.
50/53
Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
Aquatic Acute
Hazardous to the aquatic environment - acute
Aquatic Chronic
Hazardous to the aquatic environment - chronic
Acute Tox.
Acute toxicity
STOT SE
Specific target organ toxicity single exposure
STOT RE
Specific target organ toxicity repeated exposure
H301
Toxic if swallowed.
H332
Harmful if inhaled.
H335
May cause respiratory irritation.
H373
May cause damage to organs through prolonged or repeated exposure.
H400
Very toxic to aquatic life.
H410
Very toxic to aquatic life with long lasting effects.
If you have any queries relating to this MSDS, it's contents or any other product safety related questions,
please write to the following e-mail address: [email protected]
The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. The data do not describe the product's
properties (product specification). Neither should any agreed property nor the suitability of the product for
any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility
of the recipient of the product to ensure any proprietary rights and existing laws and legislation are
observed.
Vertical lines in the left hand margin indicate an amendment from the previous version.

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Safety data sheet

SECTION 1: Identification of the substance/mixture and of the

1.3. Details of the supplier of the safety data sheet

Telephone: +44 161 485-6222

1.4. Emergency telephone number

SECTION 2: Hazards Identification

2.2. Label elements

Very toxic to aquatic life.

Precautionary Statements (Prevention):

Labeling of special preparations (GHS):

Very toxic to aquatic organisms, may cause long-term adverse effects

The product contains: ALPHA-CYPERMETHRIN

2.3. Other hazards

SECTION 3: Composition/Information on Ingredients

Hazardous ingredients (GHS)

SECTION 4: First-Aid Measures

SECTION 5: Fire-Fighting Measures

5.2. Special hazards arising from the substance or mixture

5.3. Advice for fire-fighters

SECTION 6: Accidental Release Measures

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

6.4. Reference to other sections

SECTION 7: Handling and Storage

7.2. Conditions for safe storage, including any incompatibilities

7.3. Specific end use(s)

SECTION 8: Exposure Controls/Personal Protection

8.2. Exposure controls

SECTION 9: Physical and Chemical Properties

9.2. Other information

SECTION 10: Stability and Reactivity

10.2. Chemical stability

10.3. Possibility of hazardous reactions

10.4. Conditions to avoid

10.5. Incompatible materials

10.6. Hazardous decomposition products

SECTION 11: Toxicological Information

SECTION 12: Ecological Information

12.2. Persistence and degradability

12.3. Bioaccumulative potential

12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment

12.6. Other adverse effects

12.7. Additional information

SECTION 13: Disposal Considerations

SECTION 14: Transport Information

Inland waterway transport

14.2. UN proper shipping name

14.3. Transport hazard class(es)

14.4. Packing group

14.5. Environmental hazards

14.6. Special precautions for user

SECTION 15: Regulatory Information

15.2. Chemical Safety Assessment

SECTION 16: Other Information

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