Final Detail Report On Project No - 1 - 11 PDF
Final Detail Report On Project No - 1 - 11 PDF
Final Detail Report On Project No - 1 - 11 PDF
on
DEVELOPMENT OF SUITABLE
PRODUCTION SYSTEM FOR
NATURAL RUBBER COATED
JUTE FABRIC FOR NOVEL
END USES (RCJ)
ON
Sponsored by:
Contents
SECTION A: GENERAL INTRODUCTION
A.1. Introduction
A.2. Background
A.3. Deliverable
A.4. Scope and objectives
A.5. Work plan
SECTION B: FORMULATION OF NATURAL RUBBER (NR) LATEX COMPOUND
B.1. Formulation of natural rubber (NR) latex compound
SECTION C: NR LATEX COMPOUNDING WITH ADDITIVES AS PER THE
DEVELOPED FORMULATION
C.1.
Project team
Acknowledgement
The project team thankfully acknowledges National Jute Board for
financial support, M/s. KE Technical Textiles Pvt. Ltd. for pilot scale trial,
and Indian Institute of Technology Kharagpur for infrastructural facilities.
SECTION A
General introduction
A.1. Introduction
The exploitation of coated textiles/fabrics for protective clothing, shelters, covers, liquid
containers, etc., dates back to antiquity. From ancient history it is recorded that the use of
coated textiles was by the natives of Central and South America, who applied latex to a fabric
to modify it as waterproof substance. Other materials, viz., tar, rosin and wax emulsions have
been used over the years to prepare water-resistant fabrics. For their broad spectrum of
properties, rubber and other polymeric materials have become the preferred coatings and now
polymer is the essential coating material. Coated fabrics are now in an important place in
technical textiles and its manufacturing processes are one of the important technological
innovations in modern industry. The properties of a coated fabric depend on the type of
polymer used and its formulation, the nature of the textile substrate, and the coating method
employed. The approach for natural rubber coating on jute fabric pays attention because both
are from natural resource, thereby good ecological balance and no additional carbon
footprint. But, there is no exploratory research on ultra-thin coating. Most of the reported
works are based on thick coating and lamination which varies from 30 to 50 wt percent
polymer content. Fabric coating technology has passed long runway. Due to the versatility of
the design of the substrate fabric and coated polymer and subsequent end uses, fabric coating
technology exhibits interest in long way in research and industry.
Chronological history of fabric coating:
1742:
1754:
1791:
1832:
The incidence of coating is explained by the science of adhesion bonding. Adhesion of the
polymer to the textile substrate is an important aspect of coating technology, especially when
the articles are put to dynamic applications. The reported mechanisms of adhesion are as
follows:
1. Mechanical interlocking: this mechanism operates when the adhesive interlocks
around the irregularities or pores of the substrate, forming a mechanical anchor. A
rough surface has a higher bonding area.
2. Adsorption: the attractive forces may be physical, i.e., physical adsorption by van
der Waals forces, H-bonding, or chemical bonding (chemisorptions).
3. Diffusion: the adhesive macromolecules diffuse into the substrate, i.e.,
interpenetration occur at the molecular level. It requires that the macro-molecules
of the adhesive and the adherents have sufficient chain mobility and are mutually
compatible.
The mostly used man-made fibers for coating are polyester, nylon, rayon, aramid, rayon etc.
and natural fibers are cotton and jute. By choosing the right fabric substrate and coating
material, the fabric can exhibit desired mechanical properties, such as flexibility over a wide
temperature range, good formability without loss of barrier properties, and good tear and
tensile strength without significant weight increase. NR has a very uniform microstructure
that provides the material with very unique and important characteristics, viz., the ability to
crystallize under strain, a phenomenon known as strain-induced crystallization, and very
low hysteresis. Over the last few years, a number of researchers have been involved in
investigating the exploitation of natural fibers as load bearing constituents in composite
materials. The use of such lignocellulosic materials has increased due to their relative
cheapness, ability to recycle and they can compete well in terms of strength per weight of
material. The structure, microfibrillar angle, cell dimensions, defects and the chemical
composition of fibers are the most important variables that determine the overall properties of
the fibers and polymer-fiber composites. There is a wide spectrum of application for coated
fabrics, viz., foul weather protection (clothing comfort, impermeable coating, breathable
fabrics), non-apparel coating (synthetic leather, architectural textile, fluid container, tarpaulin,
automotive air bag fabric, carpet backing, textile foam laminates for automotive interior,
flocking) and hi-tech applications like fabrics for chemical protection, thermochromic fabric,
temperature adaptable fabric, camouflage net and metal and conducting polymer coated
fabric. This investigation is exclusively for ultra-thin natural rubber latex coating on jute
hessian cloth (burlap) suitable for modern eco-friendly packaging, food grain packaging,
fashion materials, multipurpose bags, etc. Packaging industry plays an important role in
almost all domains of business because of its uniqueness in material, design and texture.
Depending upon the product, the mode of transportation and logistics requirement there are
various types of fabrics among which jute based woven fabrics are in an increased rate of
demand due to its abundance and as a green resource. However, rigidity and high hydrophilic
nature of jute restrict its applications. Effort has been done to modify the overall properties of
conventional jute fabrics by an ultra-thin coating with natural rubber (NR) latex by a suitable
production system. The key advantages of these novel NR coated fabrics are
biocompatibility, minimizing hairiness of fabric surface, smooth surface finish and no
rubbery odour.
A.2. Background
Jute is an agricultural crop, which contains basically a lignocellulosic fiber with a complex
internal structure and considerable amount of free volume. The specific gravity of jute is ~1.2
and its tensile strength is found in the range 600-900 MPa. Since it is a natural fiber, its
properties vary widely and biodegrade over a period of months to year. Its resistance to
moisture/humidity is also low. Before the development of synthetic fibers, jute was the only
natural fiber for composite products in domestic as well as in industrial sectors apart from its
wide usage in packaging sector for food grains, fertilizer, cement, etc. The major reason for
switching over from jute to synthetic fiber was ascribed to its brittleness, low resistance to
moisture and environmental degradation. To overcome such shortcomings jute was used to be
treated/coated with bituminous products which provided a partial success. On the contrary
other textile fibers showed good adhesion to both natural and synthetic polymers and such
coating caused tremendous improvement of their mechanical and durability properties. For
example, nylon and polyester chords coated with resorcinol-formaldehyde resin are excellent
materials as carcass in heavy duty rubber tyres and conveyor belts. Such coating makes the
chord stronger and provides good adhesion to hydrophobic rubber as well as producing a
strong reinforced composite. Natural rubber is a high molecular weight strong hydrophobic
viscoelastic polymer, which can be ideally exploited for reinforcing as well as increasing
durability of natural fiber like jute. Rubberized fabric is an example for various water
proofing applications. Being a potentially strong fiber, if coated with rubber all the
shortcomings of jute can be removed and a range of excellent strong and durable products
can be made. If coated in a fabric form depending on the coating thickness jute can regain its
lost market in flexible packaging of cement, fertilizer as well as food grains. So, this needs an
optimized process development for coating of jute fabric by rubber.
A.3. Deliverable
a) Process deliverables
i)
ii)
iii)
b) Product deliverables
Water/moisture resistant, durable, strong and user friendly thin NR coated jute fabric
for packaging and fancy goods.
A.4. Scope and objectives
1) Development of production system for NR coated jute products, viz., fabrics for fancy
carry bags for shopping, bags for water/wine bottles, packaging material for
consumable items, and packaging of agricultural products satisfying different
environmental requirements. The rubber coated jute fabric should be adequately
flexible and strong enough to meet respective service demands.
2) Preparation of suitable natural rubber coating compositions with functional chemical
additives, which can help adhesion bonding with jute fabric as well as increase
mechanical and durability properties after curing of the NR coated jute fabric.
3) Evaluation of the properties of NR-coated jute fabrics for improving the functional
properties for shopping/carry bags and other applications.
4) Standardization of quality and process parameters for NR coating of jute fabric under
industrial conditions.
5) The proposed product should be manufactured either in a rubber-coating unit or in a
suitable set-up installed within the premises of a jute mill/JDP unit.
6) To optimize cost of NR compound as well as the NR coated jute fabric so that the
development can meet the specialized needs of products at a low cost.
7) To prepare a compendium on industrial trials containing process details as well as a
cost analysis for guiding the potential entrepreneurs.
A.5. Work plan
a) Milestones planned for first year
i) Manpower Recruitment
ii) Materials Procurement
iii) Market Survey
iv) Pretreatment of jute fabric for surface activation and standardization of
treatment compositions
v) Formulation of natural rubber (NR) latex compound
b) Milestones planned for second year
i) NR latex compounding with additives as per the developed formulation
ii) NR latex coating of jute fabric, curing, properties evaluation and optimization
c) Milestones planned for third year
i) Prototype product development and market testing
ii) Report preparation and dissemination of project findings
10
SECTION B
11
Weight (phr)
100
0.2-0.5
1.0-2.0
1.0-1.5
1.0-2.5
2.0-4.0
This formulation is subject to minor variation depending upon the product category.
Achievement
9 Formulation of natural rubber compound
12
SECTION C
13
Achievement
9 Compounding as per developed formulation
9 Monitoring appropriate dilution of NR compound to
achieve the target rubber content in coated jute fabric
14
SECTION D
15
The cloth was then dried in an oven at 70C until it got dried completely
Dipping of dried jute fabric was done in compounded NR latex and the fabric was drawn from another side
The latex dipped fabric was dried into a hot air circulated oven at 70C till moisture content of the fabric was
found to be 10 to 15wt %
The latex dipped jute cloth was then cut into three equal pieces and was placed within a two plate flat mold and
the mold was placed between the platens of a hot hydraulic press for simultaneous heating and pressing
The rubber coated jute cloth was thus cured under pressure (500 psi) at a convenient temperature (100C) for 1
min
The above process was repeated for the remaining two pieces
16
The final product was odourless, water repellent and non sticky.
The product texture is as follows:
Wt. (g)
4.71
4.73
17
0
19
1
18
2
14
3
13
4
12
5
11
0
365
1
281
2
279
3
262
4
254
5
247
Water absorption of uncoated jute fabric was found to be 365%. From Table D3, it is clear
that water absorption is decreasing continuously with increase in NR coating percentage. This
study indicates that NR coated jute fabric has better water repellent property compared to that
of the uncoated jute fabric.
D.2.3. Tensile strength (TS) and elongation at break (EB)
Tensile strength and elongation at break were measured by universal testing machine, model:
H10KS, made by Hounsfield according to ASTM D 638. The results are given in the Table
D4.
Table D4: Tensile strength and elongation at break
Percent (w/w) NR content
Tensile strength (MPa)
Elongation at break (%)
0
9.2
7.3
1
12.6
8.5
2
19.9
8.7
3
24.5
11.1
4
26.6
12.8
5
31.3
13.2
Tensile strength and elongation at break of uncoated jute fabric was found to be 9.2 MPa and
7.3%. So, increasing trend of tensile strength and elongation of coated jute fabric with
increase in rubber content indicates the better mechanical performance due to better coating
adhesion.
D.2.4. Bursting strength
Test for measurement of bursting strength of NR coated fabric was done with diaphragm
bursting tester according to ASTM D 751. The test results are shown in Table D5.
18
0
1210
1
1225
2
1254
3
1264
4
1284
5
1431
Bursting strength test is a good performance test of a fabric when it is under three
dimensional load. This value is 1210 kPa for uncoated jute fabric. So, with increase in NR
content the fabric becomes more and more strong.
D.2.5. Abrasion resistance
Abrasion resistance test is the excellent experiment on coated fabric to justify the abrasion
behaviour of coated fabric during use (especially for bags and packaging materials) either by
calculating the weight change or by peeling behavior of the fabric. This study was done
using Martindale method according to ISO 12947-3: 1999 by calculating percent mass loss in
the range 5000 to 25000 rubs. The results are shown in Table D6.
Table D6: Abrasion resistance
Percent (w/w) NR
content
Abrasion resistance
(percent wt loss)
Wt loss in the uncoated fabric was found to be 4.66-13.69. From the Table D6 it is clear that
gradual wt loss occurred with increase in NR content in the fabric. This is the indication of
good adhesion bonding of NR with jute fibrils.
D.2.6. Tear strength
Trapezoidal tear test was performed in accordance with ASTM D 751 to evaluate the uneven
tearing behaviour of the NR coated fabric. Table D7 shows the results of tear strength.
Table D7: Trapezoidal tear strength
Percent (w/w) NR content
Trapezoidal tear strength (N)
0
80
1
100
2
102
3
133
4
137
5
150
For uncoated jute fabric tear strength was found to be 80 N. A gradual increasing trend of tear
strength with the NR content signifies better performance of NR coated fabric.
D.2.7. Accelerated weathering test
Accelerated weathering test was performed using Atlas Suntest weatherometer instrument
according to ASTM D 4355 with an exposure of 25186 kJ/m2 in a total duration of 120 h.
The results are shown in Table D8.
19
0
17.44
6.7
7.1
1
11.70
8.1
8.1
2
5.94
9.7
8.5
3
2.63
10.1
8.8
4
2.04
13.9
9.2
5
1.98
14.8
9.4
For uncoated fabric, wt loss, TS and EB are 17.44%, 6.7 MPa and 7.1% respectively. These
results indicate that coating of NR improves the stability of the jute fabrics against
degradation under UV exposure. Again, more is the NR coating, less is the loss of TS and
EB. So, the durability of the NR coated fabric is enhanced by increasing the percentage of
NR coating.
D.2.8. Test for microbial degradation
Microbial biodegradation test was performed in a combination of standards G 160 and IS
1623: 1992 with respect to time. Jute fabrics are liable to deterioration by the action of
microorganisms. Since they are often stored, transported and used under conditions favorable
for the growth of microorganism, various preservative treatments have been developed and
their number is constantly increasing.
Two methods for testing jute fabrics for resistance to attack by microorganisms have been
prescribed in this standard, namely, mixed culture method and soil burial method. We have
performed the second one using a thoroughly compost mix of fertile garden soil, cow dung
manure and sand in the proportion of 2:1:1. The test results are reported as percent wt loss
with time in Table D9.
0
57
73
80
84
88
1
54
63
75
78
81
2
52
60
73
74
77
3
50
59
68
73
75
4
45
57
66
72
73
5
42
55
64
70
71
Biodegradation test in soil burial method shows that the rate of biodegradation is decreased
with increase in NR coating percentage. In turn, this test is an indication of eco-friendliness
of the natural rubber coated jute fabric.
20
After biodegradation
21
Raw jute
fabric
0.0
19
365
206
9.2
7.3
4.6613.69
1210
80
17.44
6.7
7.1
57
73
80
84
88
18.75
Product
type-I
0.8
18.2
281
192
12.6
8.5
2.3012.60
1225
100
11.70
8.1
8.1
54
63
75
78
81
18.19
Product
type-II
1.8
13.8
279
173
19.9
8.7
3.829.03
1254
102
5.94
9.7
8.5
52
60
73
74
77
18.02
Product
type-III
2.6
12.6
262
168
24.5
11.1
3.608.20
1264
133
2.63
10.1
8.8
50
59
68
73
75
17.44
Product
type-IV
3.9
12.5
254
150
26.6
12.8
1.906.60
1284
137
2.04
13.9
9.2
45
57
66
72
73
17.05
Product
type-V
4.7
11.6
247
117
31.3
13.2
0.905.40
1431
150
1.98
14.8
9.4
42
55
64
70
71
16.48
One side
PP/ PE
lamination
Weight increase 15 20%
One side
thick rubber
coating
30% and above
Hairiness
Hairiness remains
Hairiness remains
Environmental
impact
Feel
Texture
Smell
Water
repellency
Moisture
absorbance
Flammability
Printability
Rough feel
Differ in both sides
Polyolefinic smell
One side repellent
Moderate feel
Differ in both sides
Foul smell
One side repellent
Smooth feel
Evenly textured
Negligible smell
Bulk repellent
Bulk resistance
High
One side printable
High
One side printable
De-lamination
property
Aesthetics
Flexibility
Stretch ability
Drapability
Stitchability
Abrasiveness
Thin NR
coating
1-5%
Remarks on thin
NR coating
22
Hot stamping
23
Achievement
9 Compounded NR latex coating of jute fabric
9 Latex curing at soaked condition in the fabric
9 Prototype NR coated jute hessian development
9 Characterization, properties evaluation and optimization
of rubber coated jute fabric
9 Development of the excellent user friendly properties
24
SECTION E
Cost analysis
25
Table E1: Composition of one sq. m. (250 GSM) coated jute fabric having different NR
percent
NR coating wt%
Jute (g)
1
2
3
4
5
6
7
8
9
10
250
250
250
250
250
250
250
250
250
250
Table E2: Cost break up of NR latex compound on 100 g dry rubber basis
Compounding
ingredient
Price/Kg (Rs)
Price/g
(Rs)
Dry Natural
rubber (NR)
Natural polymer
Dispersion aid
170
0.17
100
170
350
0.17
0.35
0.30
1.5
5.10
0.53
Curing agent
Accelerator
Accelerator
activator
25
200
90
0.03
0.20
0.09
1.5
2.0
2.5
0.05
0.40
0.25
107.8 g
(single batch of compound )
23.00
TOTAL
26
Table E3: Process cost analysis of one sq. m. rubber coated jute fabrics (250 GSM)
Column I
*Market price of
Hessian (Rs) per
m2
22
22
22
22
22
22
22
22
22
22
Column II
Rubber
coating (%)
1
2
3
4
5
6
7
8
9
10
Column III
Compound
qty in g
2.53
5.10
7.73
10.42
13.16
15.96
18.82
21.75
24.73
27.80
Column IV
Compound cost
(Rs)
(@
Rs
230/kg)
0.60
1.20
1.80
2.40
3.02
3.70
4.35
5.00
5.70
6.40
Column V
Compound cost
+
cost
of
coating process
(Rs)**
0.90
1.80
2.70
3.60
4.50
5.50
6.50
7.50
8.50
9.60
Column VI
Final cost of
rubber coated
fabrics:
column (I + V)
22.90
23.80
24.70
25.60
26.50
27.50
28.50
29.50
30.50
31.60
Achievement
9 Technically feasible and economically viable NR
compound and coating process development
27
SECTION F
28
Pilot scale trial of natural rubber (NR) coated jute hessian fabric at M/S KE Technical
Textiles Pvt. Ltd., Rupnarayanpur, Kharagpur
Trial 1.
Date: 06.02.2011
Name of industry: M/s KE-Technical Textiles Pvt. Ltd., Rupnarayanpur, Kharagpur, West
Bengal.
The process of latex dipping comprises of the following steps:
1. Preparation of natural rubber (NR) latex compound
2. Latex dipping and curing unit comprise a combination of the following equipments:
i)
ii)
iii)
Squeeze rollers
iv)
3. Drawing rollers
4. Metering device
5. Winding roller
NR latex compounding was made according to the predefined formulation. This latex with
appropriate dilution was kept in the latex bath and used for coating purpose. The hessian
cloth was dipped into the latex and was drawn with the help of a guiding fabric through the
oven at a speed of 3 m/min and cured at 90C before the exit zone of the oven. Total length
of the coated fabric was measured with a metering device attached with the rolling coated
fabric. Finally the finished coated fabric (8 wt% rubber content) was winded on a card board
bobbin.
Cost of 5 wt% NR coating of 100 m x 1.3 m, i.e., 130 sq m jute hessian fabric (15 x 13)
Production rate: 180 meter (width: 1.3 meter)/h (i.e., 234 sq m) (variable)
Cost of electricity and LPG consumption per hour for a production rate of 180 m/h:
a) Electricity consumption : 6 kWh (2 HP motors: 4 nos)
Electricity cost: Rs. 45.00/h (Electricity charges: Rs. 7.50/kWh)
b) LPG consumption: @6.5 kg/h
Cost of LPG: Rs. 423.00/h (LPG Price: Rs. 65.00/kg)
Total energy (electricity + LPG) cost per hour: Rs. 468.00
29
Total energy cost for coating of 234 sq m jute fabric: Rs. 468.00
Cost of NR coating of 100 meter x 1.3 meter jute fabric, i.e., 130 sq m
Cost of raw materials (NR compound) (A): Rs. 650.00 (@ Rs. 5/sq m)
Cost of energy consumption (B)
: Rs. 260.00 (@ Rs. 2/sq m)
Labour (C)
: Rs. 26.00 (@Rs. 0.20/sq m)
Total (A + B + C)
: Rs. 936.00
Overhead @ 20% of (A + B + C)
: Rs. 187.00
Total cost of NR coating of 130 Sq. m. of jute hessian of 250 gsm (15x13): Rs. 1123.00.
Total cost of NR coating of 100 Sq. m. of jute hessian 250 gsm (15x13): Rs. 864.00.
So, cost of NR coating for one square meter is Rs. 8.64.
Comment:
Cost of coating will be further reduced by:
a) Increasing the speed of coating by a more efficient machine
b) Bulk procurement of raw material
Sequential views of pilot trial of NR coating on jute hessian fabric
1
30
10
FABRIC METERING
31
Trial 2.
Date: 27.06.2011
Second trial was carried out on different categories of jute fabrics on 27.06.2011 in the same
factory in presence of the delegates came from National Jute Board, Kolkata.
Photographs on field trial held on dated 27.06.2011
32
Achievement
9 Pilot scale trial of NR coating of jute fabric is successful
9 The rubber coating process appears to be viable
33
SECTION G
34
Summary:
Thin coating of rubber on a particular grade of jute fabric has been done by varying the
rubber concentration. All the performance tests of coated fabric have been carried out. The
following findings have been drawn at the end of this project:
A) Process development (Batch process) and product testing
For this particular project 250 GSM jute Hessian fabric was procured from market
and used for the development of rubber coating process.
Commercial grade of natural rubber (NR) latex (having 60% solid content) and
laboratory grade compounding ingredients were used for coating on jute fabric.
Optimized the NR latex compound formulation varying the proportion of different
ingredients in the batch.
NR latex compounding with different auxiliary chemical ingredients was done as per
the optimum compound formulation.
Jute fabric was dip coated with the compounded latex for a specific duration in a
laboratory scale.
This dipped fabric was dried in an oven at a temperature below the rubber curing
temperature.
The dried rubber coated fabric was cured in a hot press applying light pressure.
Finally very thin layer coating of natural rubber on jute fabric has been achieved.
Upto 5 wt% NR coating has been done with optimized process parameters and
optimized compounding formulation.
Mechanical, weathering, biological, thermal and other performance tests of NR coated
jute fabric have been done. Few of these tests were carried out in National Test House
(NTH), Indian Institute of Packaging (IIP), Regional Laboratory of Textile Committee
(Ministry of Textiles).
Foul odor of rubber coating on jute fabric has been removed by using a suitable
additive during latex compounding.
Jute fabric samples having varied rubber coating were developed and shown to
different traders and manufactures through M/S Roots and Yards, Kolkata for market
awareness.
Few industries approached for a field trial.
Two times field trial have been done in M/s KE Technical Textiles Pvt. Ltd.,
Rupnarayanpur, Kharagpur.
B) Market survey
Detail market survey/need assessment on this project has been accomplished by M/s Roots
and Yards, Kolkata, a professional organization in this domain.
35
Achievement:
a) Achieved a very thin layered natural rubber coating on jute fabric in a cost
effective manner
b) Improvement in the weather resistance properties of coated jute fabric
c) Removal of hairiness of jute fabric
d) Substantial reduction in abrasion loss of jute fabric
e) Good drape property of jute fabric
f) Improvement of mechanical properties (tensile, bursting strength, tear strength)
g) Removal of foul smell of rubber
h) NR coated jute fabric became printable and stitchable
i) Lamination can also be done on NR coated jute fabric
j) Biodegradation rate of NR coated jute fabric was almost unaffected compared to
uncoated jute fabric
The process of coating is feasible at industrial level with minor modifications of machineries
and techniques which will depend upon the area of application.
FINISHED
36
SECTION H
37
H.1. Background
Jute and Jute Textiles
The Jute industry occupies an important place in the national economy. It is one of the major
industries in the eastern region, particularly in West Bengal. Jute, the golden fiber, meets all
the standards for 'safe' packaging in view of being a natural, renewable, biodegradable and
eco-friendly product.
The total area under jute cultivation in India varies between 6.38 lakh hectares to 10 lakh
hectares, which is the highest in the world. This constitutes 0.6 per cent of the total area sown
during the Kharif crop season. There is no significant change in area under jute cultivation
since 1992-93 onwards.
Jute is an important cash crop, which is as an intercrop before paddy transplantation in most
parts of the country. This has significant contribution to the income of a large section of rural
households. Production of raw jute and mesta has witnessed a steady increase since 1951-52.
It was 13.2 lakh M.T. in Jute year 1990-91 (July-June), which rose to 14.76 lakh M.T. in the
Jute year 2008-09.
Globally, India is the largest producer and second largest exporter of jute goods and this
sector supports the livelihood of about 40 lakh farm families, and provides direct and indirect
employment to 4 lakh workers. There are 78 Jute mills in the country. Of these 61 are in West
Bengal, 3 each in Bihar and Uttar Pradesh, 7 in Andhra Pradesh, and one each in Assam,
Orissa, Tripura and Chhattisgarh.
Exports
The exports of jute and jute products during current financial year 2009-10 (upto October
2009) are estimated at US$ 1 billion. Cumulative exports during April-October 2009 are of
the order of 75,999 M.T.
The use of coated textile for protective clothing, shelters, covers, liquid containers, etc., dates
back to antiquity. Historically, the earliest recorded use of coated textiles was by the natives
of Central and South America, who used to apply latex to a fabric to render it waterproof.
Other materials such as tar, resin and wax emulsions have been used for the years to prepare
water resistant fabrics. Due to their vast superior properties, rubber and other polymeric
materials have become the preferred coatings. Today coated fabrics are essentially polymer
coated textiles. Advances in polymer and textile technologies have led to phenomenal growth
in the application of coated fabrics for many diverse end uses.
Textiles are made impermeable to fluids by two processes, coating and laminating. Coating is
a process of applying a viscous liquid (fluid) or formulated compound on a textile substrate.
Lamination consists of bonding of pre-prepared polymer film or membrane with one or more
textile substrates using adhesive, heat or pressure.
Several methods of production are used to manufacture a wide range of coated or laminated
fabrics. Broadly they are spread coating, dip coating, melt coating and lamination. Paste or
38
solutions are required for spread coating, solutions are required for dip coating and solid
polymers such as powders, granules and films are required for melt coating and lamination.
H.2. Use of rubber in jute textile application
H.2.1. Uses
The use of rubber is widespread, ranging from household to industrial products, entering the
production stream at the intermediate stage or as final products. Tires and tubes are the
largest consumers of rubber. The remaining 44% are taken up by the general rubber goods
(GRG) sector, which includes all products except tires and tubes.
Uses of latex coated fabric
o
Latex is usually blended with other fibers and it is used as foundation garments
o
Latex mattress pads
o
Latex gloves
o
Latex wrist cuffs and integral socks
o
Latex armor
o
Latex soles
o
High fashion bags
H.2.2. Coating jute fabrics with natural rubber latex
Latex coated fabric has high waterproofing and dry cleaning property. It is resistant to heat
and light.
H.2.3. Characteristics of latex coated fabric
o
It is waterproof.
o
It has dry cleaning property.
o
It is heat and light resistant.
H.2.4. Physical properties of coated fabrics
General Characteristics: Tensile strength, elongation, adhesion, tear resistance, weathering
behaviour, microbial degradation, yellowing.
H.2.5. Coating methods
Roll coating, dip coating, transfer coating, rotary screen printing, calendaring, hot melt
coating.
39
Status of organization
Supplying and exporting of
latex that includes natural
latex, industrial natural latex
and footwear natural latex.
2. Gurumurthy
Contact
No:54/27, Amman Koil Street, Athipet Kuppam, Chennai
Phone: 91-44-26250820, Fax: 91-44-26247722
Status of organization
--
3. Alpha Elastomer
Contact
Status of organization
65/2, Rama Mandir Road, Magadi Main Road, Kaveripura, -Kamakshipalya, Bangalore 560079.
Phone: +91-80-23480715, Fax: +91-80-23480715
Website: http://www.alphaelastomer.com/
40
Status of organization
--
Status of organization
Retailer of natural latex
including natural latex sheets.
Status of organization
Engaged in manufacturing all
types of transparent natural latex.
Status of organization
Manufacturer and supplier of
rubber and synthetic rubber
products that includes natural
rubber sheet and rubber latex.
Status of organization
Exporters and supplier of natural
rubber latex and natural latex gum.
H.5. IITs major work under the project: Development of Suitable Production System
for Natural Rubber Coated Jute Fabrics for Novel End Uses.
H.5.1. First stage
a) Development of production system for NR coated jute products, viz., fabrics for
fancy carry bags for shopping, bags for water/wine bottles, packaging material for
consumable items and packaging of agricultural products are satisfying different
environmental requirements. The rubber coated jute fabric should be adequately
flexible and strong enough to meet respective service demands.
b) Preparation of suitable NR coating compositions with functional additives, which
can help adhesion bonding with jute fabric as well as increase mechanical and
durability properties after curing of the NR coated jute fabric.
c) Pretreatment of jute fabric and coating with the developed NR coating
composition.
d) Evaluation of the properties of NR-coated jute fabrics for improving the
functional properties for shopping/carry bags and other applications.
41
End user
Agriculture sector,
Furniture sector,
Linoleum packaging
Fancy jute
product
Households, swimmers,
students, children,
corporate & govt.
offices, common
people
Upholstery
Automotive
Automobile
manufacturer
Furniture
Households, offices,
hospitals, automobile
sector, aviation, railway
Building &
Construction
Civil engineers,
irrigation, forest
department, private &
public houses
All sectors to protect
from weather for
covering a broad area,
mines
Canvas
42
20 x 20
15 x 13
Dipping process
Press cure
24/1
260.42
30 x 30
125-135
1
1
Weakness (W)
1. Initial high R & D cost
2. Improper market access
3. Improper training in design and
value addition
4. Improper governmental
interventions & information sharing.
Threats (T)
1. Synthetic fiber
2. Threat from Plastics &
Petrochemical sector
43
Status of organization
Manufacturers of all kinds of
laminating machines.
Status of organization
Deals in lamination machine, smartcard making
machines and smartcard laminating machines.
Status of organization
Manufacturers of machineries for printing,
rotogravure printing machine, flexographic
machines and laminating machines.
4. Rhine Polymers
Contact
5/1 2 Cross, Lalbagh Road, Bangalore
Phone: 080-22133206, Fax: 080-41496767.
nd
Status of organization
The importers and distributors of Graphtec
cutting plotters, cold laminating machines.
Status of organization
Paper, film and foil converting machinery.
Rotogravure printing machines - for flexible
packaging,
decorative
&
speciality
applications. Laminating machines.
44
45
Roots & Yards, Kolkata conducted the survey amongst jute mills and the diversified
sectors. It is observed that the companies took interest to see the further development towards
implementation in project form. It is hoped that trial run of the product in commercial scale
would take place in the interested companies. After the trial run, future prospect could be
figured out and future plan could be sorted out by the companies that were surveyed.
List of companies that we visited, their feedbacks and advice are laid below.
1. MNR Exports Pvt. Ltd.
Contact
Doshi Niketan, 1/3A, Ballygunge
Place East, Kolkata -700 019.
Phone: 91-33-2460 1938, 2460 1940
Contact: Mr. Nilesh Doshi.
Mobile: +91 9831095989
Assessment of
Rejoinder
company
Showed interest in
Interested in PP
rubber coated fabrics lamination substitute
46
Assessment of company
Rejoinder
Remarks of
R&Y
171/A, Mahatma Gandhi Road, Took interest in NR coated
Samples showed.
In regular contact.
1st. Floor, Kolkata - 700 007.
fabrics.
Concern about the PP. Motivating towards.
Phone: 91-33 2241 0505
Demand for NR coated fabrics Looking for new things. NR coated fabrics.
Email: [email protected] as substitute of PP lamination.
Arranging IIT visit.
Web: www.nationalrubber.net
3. Glory Polytex
Contact
226, Rabindra Sarani,
Kolkata - 700007.
Contact: Mr. Arun Kumar
Agarwal (Manager)
Mobile: 919830028913
Assessment of company
Took interest in NR coated
fabrics.
Demand for NR coated
fabrics as substitute of PP
lamination.
Rejoinder
Concern about the NRs
performance and price.
Trying for PPs substitute.
Remarks of R & Y
In regular contact.
Motivating towards rubber
coated jute.
Sharing ideas for export
quality.
Status
Assessment of
Rejoinder
company
Manufacturer & Have interest in
Sharing major
exporter of jute, rubber coated fabrics. issues of rubber
cotton bags &
Rubber has to
coating.
different fashion compete with PP.
Concern about
accessories.
Concern about bio- market of NR
degradation
coated fabrics.
Remarks of
R&Y
Showing samples.
Giving feedback
from market.
5. Ashoka Exports
Contact
Assessment of
company
110, Dharamtalla Road, Ghusuri
NR is their concern.
Howrah-711 107, West Bengal.
Liked the thin layer
Phone : 91-33 2655 7059, 3252 5850 coated samples.
(Extn. 22)
Fax: 91-33 2655 3908
E-mail: [email protected]
Rejoinder
Remarks of
R&Y
Asked the pros and
Company seems
cons of the product.
responsive.
Spoken about the merit May look for
of the fabrics.
technology.
Likes to come into
project.
6. Sunil Enterprises
Contact
Status
Assessment of
Rejoinder
Remarks of R& Y
company
31 Ganesh Chandra Avenue, 4th Manufacturing
Took good interest Like to see more Interest in trading
floor, Kolkata - 700013.
and export of jute, in the product line. samples to show but not
Phone : 91-33-2225 1711/1712 canvas & velvet
buyers.
manufacturing.
Fax: 91-33-2225 2098
designer bags
Price shall not be Interest in designer
Contact: Mr. Sunil Kumar Goel. having in-house
major factor.
bags.
Cell: 9198300 52386
production
Want bulk samples.
Email: [email protected]
facility.
47
7. AI Champdany Industries
Contact
Status
Assessment of
company
25, Princep Street, Kolkata Wellington Jute Mill is Concerned about
700 072.
modern to produce
demand of NR coated
Telephone: 91-33-22377880-85 diversified jute products fabric worldwide.
/ 2225 1050 /7924
aimed at export with a Concerned about eco
Fax: 91-33-22363754 /22
production capacity of friendly fabrics.
Email:[email protected] 100 tones/day. AI
Contact: Nirmal Pujara,
Champdani is in flax,
Executive Director
ramie, viscose and wool
(Marketing),
spinning along with jute.
Cell: 9831016405
Rejoinder
Remarks of
R&Y
Wants to see Focused but
prototype
regular
products with interaction is
proper pricing. required.
May open room
for trial run.
Need technology
and product
service.
Status
Assessment of
company
BCL have modern spinning
Liked
Birla Building
technology, skilled workforce. technological
9/1, R. N. Mukherjee Road,
Their product range is jute yarn, development.
Kolkata-700 001.
Have quality
Phone : 91-33-2213 0379/1680, floor & wall covering, Leno
Hessian, decorative fabrics,
thoughts for
2248 0135, 3022 7200
nursery cloth, scrim, jute
modifications.
Fax: 91-33-22482872/ 7988
carpets, non-woven jute felt,
There is export
E-mail :
hydrocarbon-free bags/cloth,
demand.
[email protected]
D.W.
canvas
carpet
backing
Contact: D C Patni, Vice
cloth, hessian cloth/bags,
President (Export), Cell:
sacking bags/cloth.
093314 31287.
Rejoinder
Remarks of
R&Y
Shall go into
May ask for
diversification. technology.
Shall enjoy
May work on
getting PP
pricing.
substitute in
Have plan for
good cost break other uses.
up.
Status
Assessment of
company
Chatterjee International Centre Leading manufacturer and Liked samples.
33A Jawarharlal Nehru Road exporter of jute products Discussed
Kolkata 700 071.
from Eastern India, e.g., application
Tel.: 91-33 2227 4954
Anges Bags, which is the area.
Fax. 91-33 2227 4955
fashion bags division of
E-mail: [email protected] the company.
Contact: Ashwini Kariwala,
E.D. Cell: 098309 20341
Rejoinder
Remarks of
R&Y
Involved the project They may come
people to
as major taker.
brainstorm.
Shall diversify.
Like to see further
development.
Needs samples to
show buyers.
Status
Assessment of
company
A vision to produce Liked the product.
environment friendly Wants to see more
products. All
diversified
manufacturing take products with NR.
place at one place
under skilled
technical
supervision.
Rejoinder
Remarks of
R&Y
Expressed interest Interested in the
to start plant.
products and
Had meeting with project.
the PI of the project Keeps contact
in their office.
with R & Y.
Shared technical
Have land and
views with the PI. capital to invest.
48
Assessment of company
Liked the products
May keep in the retail line
if supply is assured.
Have doubt about supply.
Rejoinder
Interested in plant at later
phase.
Interested in NR supply.
Interested in rubber
processing.
Seeing scope of business.
Remarks of R & Y
Has good sales of
jute fabrics in bulk.
Good contact with
mills.
Keeping in touch.
Rejoinder
Came to IIT for right hand
information about products.
Seen the PI in his factory to
give presentation.
Have plan to diversify.
Have shared views on future
prospect.
Remarks of R & Y
Keeping regular
contact.
Giving updates.
Trial may take place
in his factory.
Seems good future.
Status
Assessment
of company
519/1 G.T. Road, Room No. 2, Manufacturer and exporter of
Took
2nd floor, Howrah - 7111 01, quality bags and fashionable items, outstanding
West Bengal.
e.g., dyed and printed jute bags,
interest.
Phone: 91-33 2641 2079
canvas bags, beach bags, hand bag, Liked to get
Fax: 91-33 2638 0409
summer bags, evening bags, tote
associated
Email: [email protected] bags, non woven bags, calico bag, with project.
Contact: Mr. Mukesh Goyal. wine bag, bottle bags, apron, gloves,
Cell: 91 9903137942
scarves, bandana and fabrics, etc.
Rejoinder
Remarks of
R&Y
Like to invest Giving
in NR based
updates of
textiles. Trying development.
to find PP
Liked to
lamination
come to IIT.
substitute.
Status
Assessment of
company
Less interest in
21, Strand Road, Kolkata - 700001. Manufacture hessian,
sacking fabrics, canvas fabrics.
Phone: 91-33 2230 9601
& tarpaulin, chemical
Fax: 91-33 2210 6167
treated fabrics, woven
91-33 2231 4222
flat bed carpet.
Email: [email protected]
Remarks of
R&Y
1. Satisfied in regular line
2. Can come after price assurance
3. Can come after product trials
Status
Assessment of
company
BE 380, Sector I, Salt Lake Equipped with the State-of-the- Liked the
City, Kolkata 700 064.
Art technology, viz., latest jute sample.
Ph: 33-23210554/ 23210555 yarn and fabric dying machines, Price point was
Fax: 91-33automatic driers, power looms, major concern.
23342434/23210556
handlooms, sewing machines,
Their de-haring
Mobile: 919831182760
and printing machines, wellis more
Email: [email protected] equipped laboratory, silkscreen effective.
printing and heat-transfer
technology. Manufacturing
capacity: 30,000 bags/day.
Rejoinder
Remarks of
R&Y
Price of rubber Have required
coat is biggest set up for
issue.
diversification.
Adhesiveness Interested to go
is biggest
for trial.
difficulty for
shipment and
logistics.
49
Status
Assessment of
company
Shilpangan, Unit 203 & 204, Block 14 years experience in Interested in NR
LB-1, Sector 3, Salt Lake, Kolkata manufacturing jute
coated fabrics.
700098.
shopping bags.
Looking for new
E-mail:[email protected]
Jute bags accounting products.
Ph: 91-33-2335 6161 / 9830021006 for 100% of the
Have land and
Fax: 91-33-2335 5487
turnover of the
capital to invest.
Contact: Anurag Himatsingka
company.
Cell: 98300 21006
Rejoinder
Remarks of
R&Y
Much interest
Keeping regular
in development. contact.
Have plan to
Interested in
diversify.
rubber products.
Status
Assessment of
company
16-A, Brabourne Road, 8th The Company has Interest in NR coated
Floor, Kolkata 700001.
high standards of
fabrics.
Phone: 91-33-4021 1900, 91- quality at all levels. Have unit for
33-4021 1901
Meeting the
lamination.
Fax: 91-33-2221 5887
challenges of a
Wants samples.
Email: [email protected] fiercely competitive Concern about PP
Contact: S K Agarwal
market.
threat.
Rejoinder
Remarks of
R&Y
Needs bulk
Keeping regular
samples.
contact.
Have plans to
Updating with recent
diversify.
developments.
Look for PP/ PE Trial can be done.
substitute.
No immediate plan
to start project.
Rejoinder
Good market base
for new product line.
Advised for
diversified sector.
Interested to come to
project at later phase.
Remarks of R & Y
Maintain regular
contact.
Updating with new
development.
Status
Assessment of
company
Rejoinder
Remarks of
R&Y
Took major
interest in NR
coated fabrics.
Exported rubber
coated fabrics
previously to
Europe.
Concern about
PP laminated
fabrics.
Involved
project
people for
presentation.
Have plans to
diversify.
Trying to find
PP substitute.
Keeping
regular
contact.
Have plan to
manufacture
thin NR
coated
fabrics.
50
Status
Assessment of
company
OSB Overseas create, redefine Shown interest in
33A, Jawahar Lal Nehru
NR coated
Road, 7th Floor, Suite A-7, and reengineer the use of
natural golden fiber, jute by fabrics.
Kolkata 700 071.
making environment friendly Have client base
Phone: 91-33 30288817
products from natural, biofor NR coated
Fax: 91-33 3023 2970
fabrics.
Email: [email protected] degradable and fascinating
Contact: Sandip Bhojgarhia fibers.
Mobile: 91-9339523043
Rejoinder
Remarks of
R&Y
Planning for
Keeps contact.
setting up
Interested in thin
rubber coating NR coated fabric.
unit.
Have plans to
diversify.
Status
Hessian, D.W.
tarpaulin, sacking,
plain Hessian bags,
Hessian spiral bags,
Hessian box bags,
Scrim Cloth, Tobacco
Sheets, Tree Wraps.
Assessment of
company
Interest in NR
coated fabric.
Shall look for new
developments.
Rejoinder
Remarks of
R&Y
Want samples to Keeping contact.
show customers. Giving IITs
Concern about feedback.
NR fabrics
Getting sample
performance.
prototypes.
Have plans to
diversify later.
Status
Assessment
of company
Reliance Jute Mills (International) Ltd, Ideal Plaza,
Sacking bags Took good
interest in
South Block, 4th Floor, Kolkata-700 020.
in double
fabrics.
Phone: 033-2280 7017, 22807018, Fax: 033 2280 7016 warps and
Concern
Mail: [email protected],
heavier
about NR
[email protected] Web: www.reliancejute.com fabrics in
use instead
Contact: R C Saboo, Director-Technical
plain and
Mobile: 098301 61747
twill weaves. of PP/PE.
Rejoinder
Remarks
of R & Y
Thoroughly
Kept
studied the
contact.
products.
Updating
Plan to diversify. IITs
Seeking samples Progress.
for customer.
Assessment of company
Took interest in fabrics. Huge
export market. Concern about
NR use instead of PP/PE
Rejoinder
Studied the products.
Seeking samples for
customer.
Remarks of R & Y
Kept regular contact.
Updating IITs
progress.
51
H.7.3. Analysis of most interested companies who wish to have Field Trial and Project
Formation on NR coated fabrics
Companies verbally agreed for commercial trial: List of companies who took interest to
have commercial trials for NR coated fabrics in thin layers.
1. KE Technical Textiles Pvt. Ltd.
2. Ganges Jute Pvt. Ltd.
3. APL Polyfab Pvt. Ltd.
4. Ashim Kar & Industries Pvt. Ltd.
5. Ludlow Jute & Specialties Ltd.
6. OSB Overseas Pvt. Ltd.
Companies interested in fresh project: Below the list of companies who took interest in
fresh project of NR coated jute fabrics and looking for further development towards the same.
1. Ecoline Exim Pvt. Ltd.
2. Camilla International
3. Sunil Enterprises
4. Birla Corporation Ltd.
5. Ganges Jute Pvt. Ltd.
6. Kadambari Mercantile Pvt. Ltd.
7. OSB Overseas Pvt. Ltd.
8. Reliance Jute Mill
H.8. Plausible process flow diagram for prototype production line
RAW JUTE
FABRIC
SQUEEZE
ROLLER
COMPOUNDED
NR LATEX
EXCESS NR COMPOUND
RECYCLE
NR COATED
FABRIC WINDING
52
H.9. References
1. Sen, A.K. (2001), Coated Textiles: Principles and Applications, Lancaster, Pennsylvania
17604 USA: Technomic Publishing Company, Inc., First Edition.
2. Das, D., Datta, M., Chavan, R.B., Datta, S.K. (2005), Coating of jute with natural rubber:
Journal of Applied Polymer Science, Vol. 98, 484-489.
3. The Chemical Fabrics & Film Association (CFFA)(2007). Standard Test Methods:
Chemical Coated Fabrics and Film, Cleaveland, Ohio, USA: Chemical Fabrics and Film
Association, Inc., www.chemicalfabricsandfilm.com.
4. Cheng, B., Zhu, Na, Fan, R., Zhou, C., Zhang, G., Li, W., Ji, K. (2002), Computer aided
optimum design of rubber recipe using uniform design, Polymer Testing, Vol. 21, pp. 8388.
5. Lukas, D., Soukupova, V., Pan N., Parikh, D.V. (2004), Computer simulation of 3-D liquid
transport in fibrous materials, The Society for Modeling and Simulation International, Vol.
80, Issue 11, pp. 547-557.
6. Zhong, Wen, Pan, Ning, Lukas, David, (2004), Stochastic modeling of tear behaviour of
coated fabrics: Modelling and Simulation in Materials Science and Engineering. Mater, 12,
293-309.
7. Opinion on natural rubber latex allergy (2000), USA: The Scientific Committee on
Medicinal
Products
and
Medical
Devices,
European
Commission.
http://ec.europa.eu/health/archive/ph_risk/committees/scmp/documents/out31_en.pdf.
8. Chen, Julie, Lowell, UMass, et al, Substrate-Coating Interaction in Coated Fabrics
(November 2003), NTC Project: F00-MD06. National Textile Center Annual Report.
9. Thomas, Sabu, Pothan, Laly A (2009), Natural Fibre Reinforced Polymer Composites:
from Macro to Nanoscale, Paris: Archives contemporaines,
10. Sobhy, Maged S., Tammam, M.T. (2010), The influence of fiber length and concentration
on physical properties of wheat husk fibers rubber composites: International Journal of
Polymer Science,vol 2010, 1-8.
11. Hoffmann, W. (1989), Rubber Technology Handbook, Munich: Hanser Publishers.
12 Menga, Qing Bo, Leeb, Sung-I, Nahc, Changwoon, Lee, Youn-Sik (2009), Preparation of
waterborne polyurethanes using an amphiphilic diol for breathable waterproof textile
coatings, Progress in Organic Coatings, Vol. 66, pp. 382386.
13. Kaynaka, A., Hkanssonb, E., Amiet, A. (2009), The influence of polymerization time
and dopant concentration on the absorption of microwave radiation in conducting polypyrrole
coated textiles Synthetic Metals, Vol. 159, pp. 13731380.
14. G.E. Collins, L.J. Buckley (1996), Conductive polymer-coated fabrics for chemical
sensing, Synthetic Metals, Vol. 78, pp. 93-101.
15. Skinkle, John H. (1949), Textile Testing, Brooklyn, New York: Chemical Publishing Co.,
Inc., Second Edition.
53
SECTION I
54
I.2. WORKSHOP
This workshop was arranged at Indian Institute of Technology Kharagpur for the purpose of
mid-term review of all the projects sponsored by National Jute Board (NJB, formerly JMDC)
with the title Research and Development Focus on Jute Mini Mission IV Projects,
sponsored by JMDC (2009), Date: 21.12.2009, Venue: Gargi Hall, Vikramshila Complex, IIT,
Kharagpur. Organizers: Materials Science Centre, Department of Civil Engineering and
Department of Mechanical Engineering, IIT Kharagpur.
55
56