Estimates
Estimates
Estimates
08/2004
08/2004
Density (Gallon Weight) - ASTM "D 1475, Standard Test Method for Density of Liquid
Coatings, Inks, and Related Products"
Epoxide Equivalent - ASTM "D 1652, Standard Test Methods for Epoxy Content of
Epoxy Resins"
Flash Point, COC - ASTM "D 92, Standard Test Method for Flash and Fire Points by
Cleveland Open Cup"
Gloss - ASTM "D 523, Standard Test Method for Specular Gloss"
Grind - ASTM "D 1210, Standard Test Method for Fineness of Dispersion of PigmentVehicle Systems by Hegman-Type Gage"
Infrared Spectrum "Tex-888-B, Obtaining the Infrared Spectrum of Organic
Materials"
Iodine Number, WIJS - ASTM "D 5768, Standard Test Method for Determination of
Iodine Value of Tall Oil Fatty Acids"
Leafing - ASTM "D 480, Standard Test Methods for Sampling and Testing of Flaked
Aluminum Powders and Pastes" (with the exception that the test solution will be that of
the paint vehicle system)
Melt Point (Ring and Ball) - ASTM "E 28, Standard Test Methods for Softening Point of
Resins Derived from Naval Stores by Ring-and-Ball Apparatus"
Percent Solids - ASTM "D 2369, Standard Test Method for Volatile Content of
Coatings"
Refractive Index - ASTM "D 1747, Standard Test Method for Refractive Index of
Viscous Materials"
Sag - "Tex-812-B, Evaluating Sag Resistance of Coatings"
Saponification Number - ASTM "D 1962, Standard Test Method for Saponification
Value of Drying Oils, Fatty Acids, and Polymerized Fatty Acids"
Skinning - "Tex-811-B, Skinning Characteristics of Coatings"
Specific Gravity (Density) - ASTM "D 1963, Standard Test Method for Specific Gravity
of Drying Oils, Varnishes, Resins, and Related Materials at 25/25C"
Viscosity (Ford Cup) - ASTM "D 1200, Standard Test Method for Viscosity by Ford
Viscosity Cup"
Viscosity, Gardner - ASTM "D 1545, Standard Test Method for Viscosity of
Transparent Liquids by Bubble Time Method"
Viscosity, Brookfield (Poises) - ASTM "D 2196, Standard Test Method for Rheological
Properties of Non-Newtonian Materials by Rotational (Brookfield type) Viscometer"
Viscosity, Krebs-Stormer - ASTM "D 562, Standard Test Method for Consistency of
Paints Measuring Krebs Unit (KU) Viscosity Using a Stormer-Type Viscometer."
08/2004
08/2004
Allow the inspector free access to areas in the manufacturing facility where products are
manufactured or where raw materials are stored. In all other ways, facilitate the inspector in
performing his duties. When stored, raw materials and finished products will be in an
orderly fashion to permit proper and correct inventory of these materials at all times.
Product Conformance
Conform the finished products on a weight basis to the composition requirements of the
Standard Formulae. No variation from the Standard Formulae will be permitted except for
the replacement of volatiles lost in processing, unless approved by the Director of
CST/M&P.
Conform the finished products to all requirements stipulated for each Standard Formula,
such as color, drying, flow, settling, brushability, can stability, hiding, etc., and film
characteristics such as gloss, hardness, light permanence, adhesion, etc.
Under parallel conditions with a Wet Standard, test coatings in accordance with the
Specification. CST/M&P will make this standard coating using the raw materials listed in
the Standard Formulae.
Manufacturing Procedures
The manufacturer has the discretion of manufacturing procedures unless specified otherwise
in the Specification. The manufacturer is responsible for ensuring that the proposed raw
materials and manufacturing procedure will produce a product meeting the Specification
requirements.
Finished Products
Skins and foreign materials are not allowed in the finished product. Fill containers by weight
based on actual density (gallon weight) of the product at 25C (77F).
Note: Make consistency, drying, and density (gallon weight) determinations on coatings at
25C (77F). Measure the consistency with a Krebs Stormer Viscometer as per ASTM
"D 562, Standard Test Method for Consistency of Paints Measuring Krebs Unit (KU)
Viscosity Using a Stormer-Type Viscometer." Run density in accordance with ASTM
"D 1475, Standard Test Method for Density of Liquid Coatings, Inks, and Related
Products."
Containers and Markings
Ship the finished products in suitable strong, well-sealed containers that meet specification
and federal requirements and are sufficiently sturdy to withstand normal shipping and
handling.
08/2004
Label the finished product containers and cases with a durable label, legibly printed with the
following:
"TxDOT"
date of manufacture
gross weight
Label the sides of containers and cases. Labels must be sufficiently moisture resistant to
withstand outdoor storage for a minimum of 1 yr. When the finished product is palletized,
place the containers with the labels facing to the outside for easy identification. Once
properly labeled, do not modify or change the label in any manner without specific approval
of the Director of CST/M&P.
Supply a Material Safety Data Sheet to comply with OSHA's Hazard Communication
Standard 29 CFR 1910.1200.
Raw Materials
Substitutions
The exact brands and types of raw materials used in the Wet Standard are listed to facilitate
the selection of parallel materials equal not only in quality and composition, but also in
physical and chemical behavior after aging in the finished product.
Since evaluation of the finished product containing questionable materials may require 60
days and since meeting the delivery schedule is the responsibility of the manufacturer, the
manufacturer is reminded to schedule material procurement and production to permit
delivery commitments.
The Director of CST/M&P will make the final decision as to the equality of materials. After
the Department has agreed to the brand names and types of raw materials proposed by the
manufacturer, no substitution is allowed during the manufacture without prior agreement
with the Department.
Note: It is the responsibility of the manufacturer to select raw materials, which not only meet
the individual raw material specification, but also produce a finished product meeting
the specific formula requirements.
Materials of Foreign Origin
Texas Department of Transportation
08/2004
White
Titanium Dioxide - ASTM "D 476, Standard Classification for Dry Pigmentary
Titanium Dioxide Products," Type IV
Lead-free Zinc Oxide - ASTM "D 79, Standard Specification for Zinc Oxide
Pigments," American or French Process
Yellow
Yellow Iron Oxide - ASTM "D 768, Standard Specification for Yellow Iron Oxide
Hydrated"
Metallic
Aluminum Paste - ASTM "D 962, Standard Specification for Aluminum Powder
and Paste Pigments for Paint," Type II, Class B (test of aluminum paste in
accordance with ASTM "D 480, Standard Test Methods for Sampling and Testing
of Flaked Aluminum Powders and Pastes." Exception: Make up the leafing test
vehicle, described in Section 6.5 of ASTM D 480, with 30 g [0.066 lb.] of Neville
LX-685-125 resin, 20 mL [0.0053 gal.] of xylene, and 80 mL [0.0211 gal.] of
mineral spirits).
Zinc Dust - ASTM "D 520, Standard Specification for Zinc Dust Pigment," Type II
Extender Pigments
Talc - ASTM "D 605, Standard Specification for Magnesium Silicate Pigment
(Talc)"
Inhibitive Pigments - Materials listed below will be similar and equal to the standard
sample submitted to the Department by the manufacturer. The Department must approve
the material before scheduling production.
Resins
1.025 to 1.035
1.553 to 1.563
130 to 140
6.0 maximum
60 to 110
25 to 55
14 to 40
40%
33-1/3%
30%
Twenty-five m (1 mil) dry film cast from the 30% solution will be colorless and
transparent.
Match the infrared spectra with the spectra on file with CST/M&P.
Resin Basis
Requirements
450 to 525
Epoxide Equivalent
1.210 to 1.222 kg/L
Density, 25C (77F)
(Gallon Weight)
(10.10 to 10.20 lb./gal.)
4 Maximum
Color, 40% in Butyl Carbitol, Gardner
D to G
Viscosity, 40% in Butyl Carbitol, Gardner
5 Maximum
Z4 to Z6
74.0 to 76.0
Color, Gardner
Viscosity, 25C (77F), Gardner
Percent solids
08/2004
5 Maximum
Z1 to Z4
74.0 to 76.0
Xylene 35%/MiBK 65%
1.078 to 1.090 kg/L
(9.00 to 9.10 lb./gal.)
Color, Gardner
Viscosity, 25C (77F), Gardner
Percent solids
Solvent
Density, 25C (77F)
(Gallon Weight)
185 to 192
1.156 to 1.168 kg/L
(9.65 to 9.75 lb./gal.)
3 Maximum
110 to 150 Poises
99.5 Minimum
Epoxide Equivalent
Density, 25C (77F)
(Gallon Weight)
Color, 100% Gardner
Viscosity
Percent solids
Polyamide Resin
Amine Value
Density, 25C (77F)
(Gallon Weight)
Flash Point, C, COC
Viscosity, 75C (167F)
Color, Gardner
Viscosity, 25C (77F), Gardner
Percent solids
Density, 25C (77F)
(Gallon Weight)
08/2004
Requirements
3.0 Maximum
115 to 130
190 to 199
1.483 to 1.491
Z2 to Z3
0.955 to 0.965
99.5 Minimum
Solvents
Dipentene
Mineral Spirits
n-Butyl Alcohol
Methyl Alcohol
Requirements
166 to 173C (331 to 343F)
0.899 to 0.901
Water White
Clear, Sediment Free
C4H9-O-C2H4OH
ASTM "D 235, Standard Specification for Mineral Spirits (Petroleum Spirits)
(Hydrocarbon Dry Cleaning Solvent)," Type I or Type IV
Xylene
Miscellaneous Materials
Materials listed below will be similar and equal, or meet the applicable specification, to the
standard sample submitted to the Department by the vendor. The Department must approve
the materials before the award of contracts for coatings in which the material is proposed for
use.
Driers - ASTM "D 600, Standard Specification for Liquid Paint Driers"
10
08/2004
Soya Lecithin
Urea Formaldehyde
Cymel U-1054
020-2000 (McWhorter)
Wetting Agent
Bentone 38 (Rheox)
Tixogel VZ (Sud-Chemie)
Tixogel VP (Sud-Chemie).
Formulae
Formula
Solid Petroleum Resin, LX-685-125
Polymerized Linseed Oil OKO S-70
Aluminum Paste E-30-B
6% Cobalt Drier
6% Manganese drier
6% Zirconium Drier
Xylene
Mineral Spirits
Totals
11
(Pounds)
(120)
(300)
(170)
(2)
(2)
(2)
(100)
(132)
(828)
08/2004
Specifications
Consistency
Density
(Gallon Weight)
Leafing
Moisture
Labeling
Mixing Instructions
Formula
Formula for #742h
Vinyl Toluene Acrylate Copolymer, VTAC-L
Chlorinated Paraffin, Type I, Paroil 40E
Chlorinated Paraffin, Type II, Chlorez 700
Soya Lecithin
Titanium Dioxide, Rutile, Type IV, R-960
Lead-free Zinc Oxide, AZO-66
Diatomaceous Silica, Dicalite WB-5
Bentonite Clay, Tixogel VP
Dipentene
Methyl Isobutyl Ketone
Butyl Cellosolve, Glycol Ether EB
Xylene
Totals
12
Kilograms
86.2
27.2
38.6
2.3
79.4
22.7
68.0
1.4
6.8
36.3
11.3
111.1
491.3
(Pounds)
(190)
(60)
(85)
(5)
(175)
(50)
(150)
(3)
(15)
(80)
(25)
(245)
(1,083)
08/2004
Specifications
Consistency
Grind
Density
(Gallon Weight)
Color
Gloss, 60
Skinning
Labeling
Mixing Instructions
Kilograms
85.0
11.3
5.4
68.0
52.21
53.61
49.9
49.9
54.4
2.7
2.7
1.4
28.4
67.2
14.1
439.0
423.201
424.601
(Pounds)
(187.5)
(25)
(12)
(150)
(115)1
(118)1
(110)
(110)
(120)
(6)
(6)
(3)
(62.5)
(148)
(31)
(968)
(933)1
(936)1
13
08/2004
Base Component
Consistency
Grind
Density
(Gallon Weight)
Curing Agent
Curing Agent Formula for 800e
Polyamide Resin, 100%, Versamid 115
Xylene
Totals
Percent Solids
Complete Paint
Sag
(Pounds)
(123.2)
(52.8)
(176.0)
Curing Agent
Density
(Gallon Weight)
Kilograms
55.9
24.0
79.9
Packaging
Base Component
Packaging
Curing Agent
Packaging
Labeling
Label each 18.9 L (5 gal.) container with all requirements specified in the
Containers and Markings section of this Specification. Permanently affix
to each container, a legible label containing the following mixing
instructions.
Mixing Instructions One complete kit consists of 13.2 L (3-1/2 gal.) of base component and 3.8
L (1 gal.) of curing agent. Mix 1 can of curing agent into 1 bucket of
thoroughly mixed base component and mix at least 30 min. (induction
time) before using. Strain the complete mixed plant before using.
The volume of finished paint, when a kit is mixed, is approximately 17.0 L
(4-1/2 gal.). For smaller amounts, mix 3-1/2 parts by volume of base
component with 1 part by volume of curing agent.
One 3.8 L (1 gal.) quantity of thoroughly mixed unthinned paint (56%
volume solids) should theoretically cover 83.6 m2 (900 sq. ft.) at 25 m (1
mil) thick.
Use glycol ethers, ketone solvents or combinations for thinning and
cleaning purposes.
Note: Do not thin this paint more than 62 mL per liter (1/2 pt. per gallon) of
paint. This gives a volatile organic compound (VOC) of 390 g/L (3.25
lb./gal.) of thinned paint
14
08/2004
Base Component
Base Component Formula for #810e
Solid Epoxy Resin, 100%, Epon 1001
Urea Formaldehyde Resin, 60%, Cymel U-216-8
Yellow Iron Oxide, YLO-2288D
Bentonite Clay, Tixogel VZ
Wetting Agent, Anti-Terra U
Xylene
Methyl Isobutyl Ketone
Totals
(Pounds)
(138)
(8)
(30)
(11)
(6)
(46)
(63)
(302)
Base Component
Consistency
Grind
Density
(Gallon Weight)
Kilograms
62.6
3.6
13.6
5.0
2.7
20.9
28.6
137.0
Curing Agent
Curing Agent Formula for 810e
Polyamide Resin, 100%, Versamid 115
Xylene
Butyl Cellosolve, Glycol Ether EB
Totals
15
Kilograms
25.0
49.9
38.6
113.5
(Pounds)
(55)
(110)
(85)
(250)
08/2004
Curing Agent
Density
(Gallon Weight)
Percent Solids
Sag
(Pounds)
(2,552)
Packaging
Base Component
Curing Agent
Liquid Portion
Zinc Dust Portion
Complete Paint
Density
(Gallon Weight)
(Pounds)
(2,000)
Kilograms
907.2
Labeling
Base Component
Curing Agent
Liquid Portion
16
08/2004
Mixing Instructions
Label each container with all the requirements in the Container and
Markings section of this Specification and designate as the "Zinc Dust
Portion." Permanently affix to each container a legible label containing the
mixing instructions.
One complete kit consists of one 7.6 L (2 gal.) carton containing the liquid
portions and one 13-1/4 L (3-1/2 gal.) bucket containing the zinc dust.
Thoroughly mix the liquid portions before pouring them together into a
suitable clean mixing container. Allow the mixed liquids to stir for at least
30 min. (induction time) before adding the zinc dust component. While
stirring the liquids, add the zinc dust slowly. Continue to stir until all the zinc
dust is completely dispersed. If further thinning is needed, a small amount of
ketone, glycol ether, combinations thereof or similar approved solvent may
be used. Strain before using.
The volume of the finished paint, when the 3 parts of 1 kit are mixed
together is approximately 11.4 L (3 gal.). One 3.8 L (1 gal.) of unthinned
finished paint (56% volume solids) should theoretically cover 83.6 m2 (900
sq. ft.) at 25 m (1 mil) thick.
Note: Do not thin this paint more than 62 mL per liter (1/2 pt. per gallon) of
paint. This gives a VOC content of 400 g/L (3.34 lb./gal.) of thinned
paint.
For small quantities of paint, use 1.2 parts of base, 1.0 parts of catalyst and
8.0 parts of zinc dust, all by weight.
17
08/2004
Cleanup
Yellow
Flat to Semigloss
56% (unthinned)
3.6 mils wet film thickness (unthinned)
Dries to 2.0 mils dry film thickness
60F
400 g/L when thinned to 1/2 pt. per gal.
3.3 lb./gal. when thinned to 1/2 pt. per gal.
Using a mechanical mixing device, stir the base component thoroughly. Add the
curing agent slowly while continuing mixing.
Allow the mixed paint to "sweat in" while continued stirring for 30 min. before
applying.
Class "B" Blast Cleaning (similar to SSPC SP-7)
Spray application required. (Not recommended for brush or roller application
except for small touch-up spots.)
2,000 psi
1/4 in. ID
0.015 - 0.019 in.
60 mesh
up to 1/2 pt. per gal.
Binks 95
66
63PB
60 psi
25 psi
60 mesh
up to 1/2 pt. per gal.
Ketone (MEK, MiBK, etc.) or glycol ether (e.g., Butyl Cellosolve) type solvents
may be used to thin for spraying. (Aromatic solvents [toluene, xylene, etc.] will
work but are not as effective.)
Use ketone solvents for cleanup. (Aromatic solvents [toluene, xylene, etc.] will
work but are not as effective.)
18
08/2004
Induction time
Surface Preparation
Application
Airless Spray
Pressure
Hose
Tip
Reduction
Conventional Spray
Spray Gun
Fluid Nozzle
Air Nozzle
Atomization pressure
Fluid Pressure
Strainer
Reduction
Thinner
Cleanup
19
08/2004
Archived Versions
The following archived versions of "DMS-8100, Structural Steel Paints Formula"
(formerly DMS-8100, Structural Paints) are available:
8100-1199 for the specification effective November 1999 through May 2003.
8100-0603 for the specification effective June 2003 to July 2004.
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08/2004