Folio Chemistry
Folio Chemistry
Folio Chemistry
Manufactured
Substances
In
Industry
Sulphuric Acid
Ammonia
Alloys
Synthetic Polymers
Composite Materials
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SULPHURIC ACID
• To manufacture fertilizers
2. examples :
a) Ammonium sulphate is formed when sulphuric acid reacts
with ammonia
H2 SO4 (aq) + 2NH3 (aq) (NH4)2 SO4 (aq)
• To manufacture detergents
• To clean metals
CONTACT PROCESS
1. Contact process produces more than 90% of the world’s sulphuric acid
• Sulphur
• Air
• Water
1. temperature : 450 C
2. pressure : 1 atmosphere
3. catalyst : Vanadium (V) oxide, V2O5
1. sulphur dioxide is acidic and poisonous. Inhaling sulphur dioxide causes coughing,
chest pain and shortness of breath. It is the thought to be one of the causes of
bronchitis and lung diseases.
2. acid rain occurs when there is sulphurous acid, sulphuric acid and nitric acid in the
rain. These strong acid will cause the pH of the rain to fall between to fall 2.4 and 5.0
• sulphur dioxide can react with oxygen and water to form sulphuric acid
CaCO3 (s) + H2SO4 (aq) CaSO4 (s) + CO2 (s) + H2O (I)
4. acid rain corrodes metallic structures. The iron from the steel bridges reacts with
sulphuric acid to form iron (II) sulphate.
I. Use low sulphur fuels to reduce emission of sulphur dioxide into the air.
II. Add calcium oxide (lime), CaO, calcium hydroxide, Ca(OH)2 and powdered
limestone, CaCO3 into the acidic lake or river to neutralize the acids present.
• Ammonia is found in small quantities in the atmosphere, being produced from the
putrefaction of nitrogenous animal and vegetable matter.
• Ammonia and ammonium salts are found in small quantities in rainwater, whereas
ammonium chloride and ammonium sulphate are found in volcanic districts.
HISTORY
• The Romans called the ammonium chloride deposits they collected from near the
Temple of Jupiter Amun in ancient Libya’sal ammoniacus’ (salt of Amun)
because of proximity to the nearby temple.
• In the form of sal-ammoniac, ammonia was known to the Arabic alchemists as
early as the 8th century, first mentioned by Geber (Jabir ibn Hayyan).
• Gaseous ammonia was first isolated by Joseph Priestly in 1774 and was termed by
him alkaline air, however it was acquired by the alchemist Basil Valentine.
USES OF AMMONIA
Example :
Ammonium Phosphate
• Ammonia is used as a raw material for the manufacture of nitric acid in the
Ostwald process. This process involves three stages.
a) Ammonia is oxidized to nitrogen monoxide in the presence of platinum as
the catalyst.
4NH3 (s) + 5O2 (s) 4NO (s) + 6H2O (I)
c) the mixture of nitrogen dioxide and air is dissolved in water to form nitric
acid
Material : 0.1 mol dm ammonia solution, 0.1 mol dm sodium hydroxide solution,
ammonium chloride, calcium hydroxide, concentrated hydrochloric acid, soda-lime,
distilled water, red litmus paper, pH paper.
Apparatus : test tubes, beaker, U-tube, Bunsen burner, glass rod, delivery tube, stoppers.
Procedure :
B. Alkalinity of ammonia
1) 5 cm of 0.1 mol dm ammonia solution and 5 cm of 0.1 mol dm sodium
hydroxide solution are poured into two separate test tubes.
2) A piece of pH paper is dipped into the solution in each test tube.
3) The pH values of both solutions are recorded.
D. Density of ammonia
1) A test tube containing ammonia gas is held upright and another test tube
containing ammonia gas is held upside down.
2) The stoppers of the two test tubes are removed.
3) After 20 seconds, a piece of moist red litmus paper is put at the mouth of each
test tube as shown in the figure below.
Testing the density of ammonia gas
Observation :
1) the raw materials for the Haber process are hydrogen and nitrogen.
2) Nitrogen and hydrogen are mixed according to the ratio 1 mole N2 : 3 moles H2
3) The mixture is compressed to 200 atom and heated to a temperature of about 450
C.
4) The mixture is then passed through layers of heated iron catalyst in a reactor.
Ammonia is produced.
5) the ammonia gas produced is liquefied and separated to get a better yield.
6) The unreacted nitrogen and hydrogen are recycled and passed back into reactor
together with the new source of nitrogen and hydrogen.
Ammonium Fertilisers
• Contain ammonium ions. In the soil, the ammonium ions are converted to
nitrate ions by bacteria.
• Examples of ammonium fertilizers :
• The
fertilizers that contain a high percentage of nitrogen are more effective than
those fertilizers with a low percentage of nitrogen.
• Ammoniu
m fertilizers can be prepared by reactions between ammonia solution and
acids.
ALLOYS
PURE METALS
PHYSICAL PROPERTIES
• High density
• High melting and boiling point
• Good conductors of heat and electricity
• Malleable
• Ductile
• Lustrous
Atoms in a pure metal are orderly arranged and closely packed together.
5. the arrangements of atoms in pure metals are not perfect. There are
some empty spaces in between the atoms. When a metal is knocked or pressed, group
of atoms may slide and then settle into new positions. This explains why metals are
malleable or can be shaped.
6. Pure metals are weak and soft due to their ductility and
malleability. Thus, pure metals have limited uses.
ALLOYS
An alloy is a mixture of two or more elements with a certain fixed composition in which
the major component is a metal. Most alloys are mixtures of metals. For example, bronze
is an alloy of copper and tin. Both pure copper and tin are soft. When copper is alloyed
with tin, bronze which is stronger and harder is produced. Some alloys may contain
mixtures of a metals and a non-metal such as carbon. For example, steel is an alloy of
iron and carbon. Iron is a soft metal. When some carbon is added to iron, steel which is
stronger and harder is formed. Pure metals are normally soft and easily oxidized. This is
the reason why monuments or statues are made of branze and not copper. Cutlery is made
of stainless steel and not steel or iron. This is because stainless steel is shiny and does not
rust. Alloys are stronger, harder, resistant to corrosion, have a better finish and lustrous.
By changing the percentage of composition of the metals, the properties of the resulting
alloy can be altered.
• Unreactive metals such as gold and silver can be found in the free state.
This is because they do not react with oxygen and water vapour in the air.
• Most metals such as iron and copper corrode readily in the air.
• Alloying can prevent metals from corrosion. This is because alloying
helps to prevent the formation of oxide layer on the surface of the metal.
• for example, carbon, chromium and nickel are added to iron to make
stainless steel. Cutlery made from stainless steel does not corrode.
• metals have lustrous surfaces. However the formation of dull metal oxide
on the surface of a metal makes it quickly lose its shine.
• Alloying helps to keep the metal surface shiny as its prevents the
formation of the metal oxide.
Alloy Compositon Properties Uses
Bronze 90% copper Hard, strong, does Medals, statues,
10% tin not corrode easily monuments
Brass 70% copper Harder than copper Musical
30% zinc instruments,
kitchenware, door
knobs
Cupro-nickel 75% copper Beautiful surface, Coins
25% nickel shiny, hard
Steel 99% iron Hard, strong Buildings, bridges,
1% carbon body of cars
Stainless steel 74% iron Shiny, strong, does Cutlery, surgical
8% carbon not rust instruments, sink
18% chromium pipes
Duralumin 93% aluminium Light, strong Aircraft’s body,
3% copper bullet trains
3% magnesium
1% manganese
Pewter 96% tin Shiny, strong, does Art objects,
3% copper not corrode souvenirs
1% antimony
Composition, properties and uses of alloy
SYNTHETIC POLYMERS
POLYMERS
The term ‘polymer’ originated from Greek words, ‘poly’ means ‘many’ and ‘mer’ means
‘parts’. Polymers are large long-chain molecules formed by joining together many
identical repeating sub-units called monomers. Polymerization is a process by which the
monomers are joined together into chain-like molecule called polymer. A polymer may
consist of thousands of monomers.
M+M+M+M+M… -M-M-M-M-M
Or
nM M
where M = monomer, n = a big number
a) natural polymers
• obtained from living things such as plants animals.
RUBBER
Rubber is an elastic material obtained by “curdling” the milky sap (latex) of certain
plants. Natives in Central America and Mexico used rubber before Columbus. In 1839,
Charles Goodyear invented vulcanized rubber, a form of natural rubber modified by
cross-linking (vulcanization). The monomer for natural rubber is isoprene or 2-
methylbuta-1, 3-diene. Each isoprene unit has two double bongs. Isoprene molecules
undergo addition polymerization to form poly (isoprene) or natural rubber.
b) synthetic polymers
• polymers made by man through chemical reactions.
• Monomers used for the manufacture of synthetic polymers are
usually obtained from the fractional distillation of petroleum.
• Used to make plastics, fibres, resins, and synthetic rubber.
• Prepared through addition polymerization and condensation
polymerisation.
PLASTICS
The first man-made plastic was invented by Alexander Parkes in 1862. he called this
plastic Parkesine. The development of plastics has come from the use of natural plastic
materials to the use of chemically modified natural materials and finally to completely
synthetic molecules. The raw materials used to make plastics are obtained from the
products of cracking of petroleum fractions. They are normally alkene molecules and are
made into plastics through addition polymerization. Plastics are the largest group of
synthetic polymers. It has low density, strong and inert to chemical too.
Here are some commonly used plastics :
SYNTHETIC FIBRES
Synthetic fibres are long-chain polymers which are not easily stretched and have high
strength. Polyamides and polyesters are two group of synthetic polymers used as fibres
for making textile.
NILON
• The real star of the plastics industry in the 1930s was “polyamide” (PA), far better
known by its trade name nylon. Nylon was the first purely synthetic fibre,
introduced by DuPont Corp at the 1939 World’s fair in New York City.
• Nylon is used to make toothbrushes, ropes, fishing lines, papachutes, carpets,
textile, threads, and electrical insulators.
TERYLENE
• Terylene is an example of polyester polymers and are diol molecules and diacid
molecules.
• Terylene is chemically inert, elastic and can be coloured and easily made into
fibres.
• It is suitable for making textile, stocking, parachutes and fishing nets.
SYNTHETIC RUBBERS
A polymer that was critical in World War II was “synthetic rubber”, which was produced
n a variety of forms. It is not plastics and are elastic materials. These synthetic polymers
are also called elastomers. Produced by addition polymerization, neoprene and styrene-
butadiene are examples of synthetics rubbers.
About 57% of the total production of polymers are used in packaging and building
industries. The uses of synthetic polymer are determined by its structure and properties.
Synthetic polymers are very stable. Unlike metals, wood or paper, they do not rust, rot or
decay. They are very useful but they also difficult to dispose of as they are not easily
biodegradable. Disposal of synthetic polymers has caused environmental pollution
problems.
• Reuse
• Recycle
• Use biodegradable synthetic polymers
• Dispose of unwanted synthetic polymers in a proper manner
Glass
Glass is normally referred to a transparent, shiny substance that breaks rather easily.
Evidence has shown that glass has been used for more than 3000 years ago.
1. silica or silicon dioxide, SiO2 is the major component of glass. It can be found in
sand.
2. glass can be made by heating a mixture of silicon dioxide and metal carbonates to
a temperature above 1500 C.
• when sodium carbonate, Na2CO3 are heated to a high temperature, they
decompose to form metal oxides.
• the metal
oxides then combine with silicon dioxide to form the respective metal
silicates.
SiO2 (s) + Na2O (s) Na2SiO3 (s)
Sio2 (s) + CaO CaSiO3 (s)
• the overall
reaction is as follows.
2SiO2 (s) + Na2CO3 (s) + CaCO3 (s) NaSiO3 (s) + CaSiO3 (s) + 2CO2 (s)
• glass is a
mixture of metal silicates.
3. In silicon dioxide, each silicon atom forms covalent bonds with four adjacent
oxygen atoms in a tetragonal shape. Each oxygen atom is bonded to two silicon
atoms to form a macromolecule.
4. in glass, the SiO3 tetrahedras bond together by sharing oxygen atoms to build up a
giant non-regular 3-D structure containing the Si-O-Si linkages. Sodium ions and
calcium ions balance the negatively-charged silicate ions.
5. the physical properties of glass depend on percentage of the various silicates
present. Generally, all types of glass have the following common properties.
• Transparen
t
• Hard but
brittle
• Impermeab
le to liquid
• Heat
insulator
• Electrical
insulator
• Chemically
inert
Types and uses of glasses
Type of glass Composition Properties Uses
Fused glass • Silicon • High melting • Laboratory
dioxide point glassware
• High temperature • Lenses
and chemically • Optical fibres
durability
Soda-lime • Silicon • Low melting • Containers
glass dioxide point • Flat glass
• Sodium • Easy to mould • Windowpanes
oxide and shape • Mirrors
• Calcium • Transparent to • Light bulbs
oxide visible light
Borosilicate • Silicon • Resistant to • Cookware
glass dioxide chemicals • Laboratory
• Boron • Resistant to glassware
oxide thermal shock • Electrical tubes
• Sodium
oxide
• Calcium
oxide
Lead crystal • Silicon • High density • Tableware
glass dioxide • High refractive • Art objects
• Lead(II) index • Crystals
oxide • Soft and easy to
• Sodium melt
oxide
Ceramic
Pieces of broken ceramics from more than 6000 years ago have been found by
archaelogists. Pottery is the oldest form of ceramic products.
1. ceramics are made from clay such as kaolin. Kaolin is rich in kaolinite
(hydrated aluminosilicate, Al2O3.2SiO2.2H2O).
2. when the clay is heated to a very high temperature, it undergoes a series of
chemical reactions and is hardened permanently to form ceramics.
3. these chemical changes are not reversible and the ceramic cannot be melted
and remoulded.
4. bricks, tiles, mugs, and clay pots are some examples of ceramics.
Glass optical fibre is a pure silica glass thread that conducts light. This fibre can transmit
messages modulated onto ight waves. Using a glass optical fibre, information such as
telephone and tv signals as well as digital data can be transmitted over long distances
without distort and loss of signal. Optical fibre is particularly popular in local area
networks (LAN), control board displays and medical instruments. Fibre optic cables are
much thinner and lighter than the traditional metal cables. They can carry more data and
less susceptible to interference than metal cables.
Photochromic glass
Glass-ceramics
Glass-ceramics are strong materials made by heating glass to rearrange some of its atoms
into regular patterns. It have better mechanical strength and are better electrical insulators
compared to normal glass. They can withstand high temperatures, sudden changes in
temperature and chemical attacks better than the normal glass. Glass-ceramics have been
used in cookware, rockets, tiles and engine blocks.
COMPOSITE MATERIALS
Made by combining two or more materials.
Examples :
reinforced concrete
concrete is a composite material which consists of a mixture of stones, chips and sand
bound together by cement. It is strong but brittle and weak in tensile strength. When
concrete is reinforced with steel wire netting or steel rods, the resulting combination is a
very tough material with high tensile strength.
Superconductors
fiberglass
fiberglass is produced when glass fibres are embedded in plastic resins to produce glass
fibre reinforced plastics. Fibreglass has high tensile strength, can be easily coloured,
moulded and shaped. It is used in the making of water storage tanks, badminton rackets,
helmets, small boats skis and car bodies.