12.thermal Properties of Matter
12.thermal Properties of Matter
12.thermal Properties of Matter
com
Important Points:
SI - Joule
C. G. S - Calorie
1 cal = 4.2 J
2.
3.
4.
F 32 C 0 K 273
=
=
180
100
100
5.
(l 2 l 1 )
l1 (t2 t1 )
/ 0C.
6.
(a 2 a 1 )
a1 (t2 t1 )
/ 0C.
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=
7.
( V2 V1 ) / 0C.
V1 ( t 2 t1 )
8.
9.
Platinum is used to seal with glass due to same co-efficient of linear expansion.
10.
If two rods of different materials have the same difference between their lengths (X) at all
temperatures.
l11 = l2 2
l1 =
11.
X 2
X 1
, l2 =
1 ~ 2
1 ~ 2
Invar steel (steel + nickel) has very low . So it is used in making pendulum clocks,
balancing wheels and measuring tapes.
12. Linear and a real expansion have no significance for a liquid since shape of liquid depends on
shape of vessel.
13. Anomalous Expansion of Water:
When water at 0C is heated, its volume decreases up to 4C and from 4C its
volume increases with the increase of temperature. This peculiar behavior of water is
called anomalous expansion of water.
14. Water has maximum density and minimum volume at 4C (or) 277 K
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15. Anomalous expansion of water can be demonstrated with Hopes apparatus (or) Dilatometer.
16. Volume Co-Efficient of a Gas ( ):
The ratio of increase in volume of a gas per degree rise of the temperature to the volume at
00C at constant pressure is called Volume Coefficient
=
vt v0
v v
Or = 2 1
v0t
v1t2 v2t1
pt p0
p p
Or = 2 1 .
p0t
p1t2 p2t1
1
= 0.00367 / 0 C
273.15
1
or PV = k (T = constant)
V
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21. Charless -II Law:
At constant volume, the pressure of a given mass of a gas is directly proportional to its
absolute temperature.
P1 P2
P
= constant ( or )
=
T
T1 T 2
Where P is the pressure, V is the volume of 1gram mole of a gas, T is the absolute temperature
and R is the universal gas constant.
R = 8.31 Joule /gm/K = 2 cal/gm/mole/K
24.
PV
PV
1 1
= 2 2
T1
T2
R
N
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c=
Units:
1 dQ
.
m dt
S.I.: J kg K
C. G. S:
Cal
gm
Units
: S.I.: J/kg
C. G. S
: cal/ gm
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31. Co-Efficient of Thermal Conductivity:
a) At steady state the quantity of heat Q flowing through a metal rod of l length and crosssection A in a time t when its ends are at temperature 1 and 2 (1 > 2 ) is given by
Q=
KA ( 1 2 )
t
l
It is defined as the rate of flow of heat per unit area and per unit temperature
gradient in steady state.
d)
Junction Temperature:
In steady state,
( K11 + K 2 2 )
( K1 + K 2 )
l
KA
33. Radiation:
The process of transfer of heat that takes place without the help of the intervening medium is
called Radiation.
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Ex. Heat received by the earth from the sun.
34. Black Body:
A body completely absorbing the radiation of all wavelengths falling on it is called a black
body.
35. Emissive Power:
a) The amount of energy emitted per second per unit surface area of a body at a given
temperature for a given wavelength range is called emissive power.
b) At a given temperature if the radiations emitted have a wave length difference, then the
emissive power is equal to e d .
c) Unit -Wm-2
D.F. - MT-3
36. Emissivity (e):
a) The ratio of radiant energy emitted by a surface to radiant energy emitted by a black
body under same conditions is called Emissivity.
b) For a perfect black body emissivity e = 1.
37. Absorptive Power (a ) :
a) At a given temperature, for a given wavelength range, the ratio of energy absorbed to the
energy incident on the body is absorptive power.
a =
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c) If the body emits more radiant energy. Than absorbed, its temperature decreases.
d) If the body absorbs more radiant energy than it emits, its temperature increases.
39. Kirchhoffs Laws:
a) At a given temperature, for a given wave length range, the ratio of emissive power to
absorptive power of a substance is constant.
b) This constant is equal to the emissive power of a perfect black body at the given
temperature and wavelength.
i.e.
e
=const = E ,
a
Where E is the emissive power of perfect black body. e And a are emissive and
absorptive powers of a given substance respectively.
c) Good absorbers are good emitters.
40. Stefans Law:
The amount of heat radiated by a black body per second per unit area is directly proportional
to the fourth power of its absolute temperature.
E T4 E = T4.
Where
= Stefans constant
= 5.67 108Wm 2 K 4
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41. Stefan - Boltzmanns Law:
a) If a black body at absolute temperature T is surrounded by an enclosure at absolute
temperature To , then the rate of loss of heat energy by radiation per unit area is given by.
E = (T 4 T0 4 )
0
dt 2
1 , 2 are the initial and final temperatures of the body respectively. 0 is temperature of
surroundings .
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Very Short Answer Questions
1.
A.
Heat
Temperature
2.
What are the lower and upper fixed points of Celsius and Fahrenheit scale?
A.
Celsius Scale:
Lower fixed point: 00C
Upper fixed point: 1000C
Fahrenheit scale:
3.
320F
2120F
Do the values of coefficients of expansion differ, when the temperatures are measured on
Centigrade scale or on Fahrenheit scale?
A.
4.
Yes.
C F 32
=
5
9
A. Yes, Lead, cast iron, pure water when heated from, rubber etc. contract on heating.
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5.
A.
A gap should be left between two successive rails to allow for linear expansion of the rails in
summer.
6.
A.
Liquids do not have a specific size or shape. The shape of a liquid depends on the shape of
the container. Hence the liquids do not have linear and areal expansions.
7.
A.
8.
A.
9.
A.
i) For 1 gm of a gas
PV
=r.
T
PV
= mr r is the specific gas
T
constant. ii) The specific gas constant is different for different gases.
10. What are the units and dimensions of specific gas constant?
A.
Units:
J Kg-1 K-1
Dimensions: M0 L2T-2K-1
11.
A.
Why utensils are coated black? Why the bottoms of the utensils are made of Copper?
i) Black surface is a good absorber and good emitter. Hence utensils are coated black.
ii) Copper is a good conductor of heat .Hence copper is used at the bottom of cooking utensils.
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12. State weins displacement Law.
A.
Ventilators are placed below the roof in rooms to allow hot air to escape.
15. State the different modes of transmission of heat. Which of these modes require medium?
A.
Thermal Conductivity:
It is the quantity of heat flowing normally per unit time through unit area of the substance per
unit temperature gradient.
K=
Qd
A(2 1 )t
If A = 1m2, 2 1 =10 c/m and t = 1s, then K = Q
d
Temperature Gradient:
Temperature difference per unit length is called temperature gradient.
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Temperature gradient =
2 1 0
c/m
d
A.
l
KA
Thermal resistance of a body depends on length and area of cross-section of the conductor.
18.
A.
Units
Wm2 K 1
Dimensions :
MT 3 K 1
19.
A.
Emissive power ( e ):
i) The amount of energy emitted per second per unit surface area of a body at a given
Temperature for a given wavelength range ( and +d ) is called emissive power.
ii) At a given temperature if the radiations emitted have a wavelength difference d , then the
Emissive power is equal to e d .
iii) S.I unit of emissive power is Wm-2 and its dimensional formula is MT-3.
Emissivity (e): The ratio of radiant energy emitted by a surface to radiant energy emitted by
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a black body under same conditions is called emissivity.
i)
The surface of the earth and atmosphere gets heated up due to absorption of radiation from
sun by green house gases, namely Carbon dioxide, Methane, Nitrous oxide, etc. This is known
as green house effect.
Hence the earth becomes warmer and the average temperature of the earth increases. This is
known as global warming. This global warming may cause problem for human life, plants
and animals. Because of global warming, ice caps are melting faster, sea level is rising and
weather pattern is changing.
21. Define absorptive power of a body. What is the absorptive power of a perfect black body?
A.
Absorptive Power ( a ):
i) At a given temperature, for a given wavelength range, the ratio of energy absorbed to the
energy incident on the body is absorptive power.
ii)
0
dt 2
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23.
A.
24.
The roof buildings are often painted white during summer. Why?
A.
The roof buildings are often painted white during summer, because white is a poor absorber.
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Short Answer Questions
1.
Explain Celsius and Fahrenheit scales of temperature. Obtain the relation between
Celsius and Fahrenheit scales of temperature.
A.
2.
C -0 F 32
=
100
180
C F 32
=
5
9
Two identical rectangular strips one of copper and the other of steel are riveted together
to form a bimetallic strip. What will happen on heating?
A.
Bimetallic Strip:
A bimetallic strip consists of strips made of two different metals of different coefficients of
expansion, riveted together. When heated, it bends such that the strip with more expansion
(copper) lies on the convex side.
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Uses:
A bimetallic strip is used
(i) For continuous recording temperature
(ii) As a thermostat to control the temperature of a body
(iii) As a fire alarm.
3.
A.
T = 2
l
or T
g
Time period of a pendulum clock is directly proportional to square root of the length of the
Pendulum.
i) In winter the length of the pendulum decreases and its time period decreases. So clock goes
fast.
ii) In summer the length of the Pendulum increases and its time period increases. So the clock
goes slow.
4.
A.
5.
A.
Conduction:
The process of transfer of heat that takes place without the movement of the particles of the
medium is called conduction.
Ex. Heating up of a metal rod
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Convection:
The process of transfer of heat with the bodily movement of the particles of the medium is
called convection.
Ex. Heating up of a liquid
Radiation:
The process of transfer of heat that takes place without the help of the intervening medium is
called radiation.
Ex. Heat received by the earth from the sun.
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Long Answer Questions
1.
State Boyles law and Charles law. Hence derive ideal gas equation. Which of the two
laws is better for the purpose of thermometry and why?
A.
Boyles Law:
At constant temperature, the pressure (P) of a given mass of a gas is inversely proportional to
its volume (V).
1
V
Or
PV = constant
V T
Or
V / T = constant
P T Or
P
= Constant
T
PV
1 1
P2
.......................... (1)
ii) Now Keeping pressure P2 constant, the temperature of the gas is changed from T1 to
T2.Then let its volume changes from V1 to V2.
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From Charles law
V V2
= ,
T1 T2
V =
V2T1
............................. (2)
T2
PV
VT
PV PV
PV
1 1
= 2 1 1 1= 2 2
=r
P2
T2
T1
T2
T
The constant r is called specific gas constant which is different for different gases. For one
mole of gas,
PV = RT
PV = nRT
Gas Thermometers:
Charles law is better for the purpose of measurement of temperature because in Boyles law
temperature is constant.
2.
A.
Thermal Conductivity:
Definition:
The ability of a solid to conduct heat is called thermal conductivity.
Explanation:
When one end of a metal rod is heated, the amplitude of vibration of the atoms at that end
increases. These atoms collide with the adjacent atoms by sharing their energy with them.
Thus heat energy flows from higher temperature end to lower temperature end of the rod.
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Coefficient of Thermal Conductivity (K):
The amount of heat (Q) flowing through a rod is directly proportional to
i. The area of cross section (A) of the rod
ii. Temperature difference ( 2 1 ) between the ends of the rod
iii. The time (t) of flow the heat through the rod and
iv. is inversely proportional to the length ( l ) of the rod.
Where K is called the co-efficient of thermal conductivity of the rod
Definition of K:
K =
Q /t
A( 1 2 )/ l
If A = 1 and
( 1 2 )
Q
=1 , then K =
l
t
It is defined as the quantity of heat flowing normally per second through unit area of crosssection of the rod per unit temperature gradient.
Problem:
K = 401 w/mk ; L = 0.1 m ; A = 1 10-6 m2 ; 2 1 = 104 - 24 = 80C
Q
Rate of heat conduction (P) = =
t R
3.
L
K cu A
0.1
= 249.3
401x106
80
=
= 0.32 W
R 249.3
State and explain Newton's Law of cooling. State the conditions under which Newton's
Law of cooling is applicable.
A body cools down from 60C to 50C in 5 minutes and to 40C in another 8 minutes.
Find the temperature of the surroundings.
A.
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Explanation:
Let a body cools from a temperature 2 to 0 the temperature .Let be the temperature of
the surroundings. Then the rate of fall of temperature of the body
d
is given by
dt
d 1 + 2
0
dt 2
Or
d
+ 2
=K 1
0
dt
2
Where K is a positive constant that depends on area and the nature of the surface of the
body
The amount of heat lot is given by Q = ms
Or
dQ
d
= ms
dt
dt
d
1 d
d
1
=
(or ) = A (T 4 T04 )
dt ms dt
dt ms
Conditions:
Newtons law of cooling is applicable when (i) the heat lost by conduction is negligible and
heat lost by the body is mainly by convection (ii) the hot body is cooled in uniformly stream
lined flow of air or forced convection (iii) the temperature of every part of the body is same.
Problem:
From Newtons law of cooling,
( 60 50 ) 60 + 50
5
Dividing,
and
50 40 50 + 40
8
2
= 28.34C
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Problems
1.
What is the temperature for which the readings on Kelvin and Fahrenheit scales are
same?
A:
K 273.15 F 32
=
100
180
Here K = F
F 273.15 F 32
=
100
180
F = 574.60 C
2.
A:
l2 l1
l l
( t2 t1 ) = 2 1
l1 ( t2 t1 )
l1
1 = 25 106 ( t2 t1 ) 100
( t2 t1 ) =
3.
1
1
= 400o C.
6
25 10
100
A:
P1 = 76cm of mercury;
P1
P
= 2
1T1 2T2
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2 =
4.
The volume of a mass of gas at 37C and a pressure of 75cm of mercury is 620 c.c. Find
the volume at N.T.P
A:
Or
5.
75 620 76 V
=
V = 538.8 C.C
310
273
How much steam at 1000 C is to be passed into water of mass 100g at 200 C to raise its
temperature by 50 C ? (Latent heat of steam is 540 cal/g and specific heat of water is
1cal / g 0C )
A:
500 = m (615)
m=
6.
500
= 0.813 gm
615
2kg of air is heated at constant volume. The temperature of air is increased from 293K to
313K. If the specific heat of air at constant volume is 0.718kJ/kg K, find the amount of
heat absorbed in kJ and kcal. (J = 4.2 kJ/kcal)
A:
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Q = mCv (T2 T1 ) = 2 0.718 (313 273) = 28.72kJ
=
7.
28.72
= 6.838 K cal
4.2
A clock, with a brass pendulum, keeps correct time at 200C, but loses 8.212 s per day,
when the temperature rises to 300C. Calculate the coefficient of linear expansion of
brass?
A:
1
1
( t2 t1 ) 86400 8.212 = 10 86400
2
2
= 19 106 / 0 C
8.
If the volume of nitrogen of mass 14kg is 0.4m3 at 300 C . Calculate the pressure?
A:
P=
9.
m
RT
M
A body cools from 60C to 40C in 7 minutes and what will be its temperature
after next 7 minutes, if the temperature of its surroundings is 10C?
A.
( 60 40 ) 60 + 40 10 and 40 40 +
7
= 28 C
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10
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10.
A.
2.90 103
max
2.90 103
=
= 1094 K
2.65 106
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