Usg Cal Seal w60 Gypsum Cement Sds en 52000000037 PDF

SAFETY DATA SHEET
1. Identification
Product identifier
CAL-SEAL W-60 Gypsum Cement
Other means of identification

SDS number
52000000037
Synonyms
Oil Well Cement
Recommended use
Oil Well Cementing.
Recommended restrictions
Use in accordance with manufacturer's recommendations.
Manufacturer/Importer/Supplier/Distributor information
Company name
Address
Telephone
Website
Emergency phone number
United States Gypsum Company

550 West Adams Street
Chicago, Illinois 60661-3637
1-800-874-4968
www.usg.com
1-800-507-8899
2. Hazard(s) identification
Physical hazards
Not classified.
Health hazards
Skin corrosion/irritation
Category 2
Serious eye damage/eye irritation
Category 1
Sensitization, skin
Category 1
Carcinogenicity
Category 1A
OSHA defined hazards
Not classified.
Label elements
Signal word
Danger
Hazard statement
Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. May
cause cancer.
Precautionary statement
Prevention
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Avoid breathing dust. Wash thoroughly after handling. Contaminated work
clothing must not be allowed out of the workplace. Wear protective gloves/clothing and eye/face
protection.
Response
If exposed or concerned: Get medical advice/attention. If on skin: Wash with plenty of water. If in
eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. Immediately call a poison center/doctor. If skin irritation or rash occurs:
Get medical advice/attention. Take off contaminated clothing and wash before reuse.
Storage
Store locked up.
Disposal
Dispose of in accordance with local, state, and federal regulations.
Hazard(s) not otherwise

classified (HNOC)
None known.
3. Composition/information on ingredients
Mixtures

920267 Version #: 01 Revision date: -
SDS US
Issue date: 06-August-2014
1/8
Chemical name
CAS number
Plaster of Paris (Calcium

Sulfate Hemihydrate CAS
10034-76-1)
26499-65-0
> 95
Portland Cement
65997-15-1
<1
CAS number
14808-60-7
< 0.5
Impurities
Chemical name
Crystalline silica (Quartz)
Composition comments
All concentrations are in percent by weight unless ingredient is a gas.

Raw materials in this product contain respirable crystalline silica as an impurity. The weight
percent of respirable crystalline silica found in this product is < 0.5%. Exposures to respirable
crystalline silica during the normal use of this product must be determined by workplace hygiene
testing.
4. First-aid measures
Inhalation
Skin contact
Eye contact
Ingestion
Most important
symptoms/effects, acute and
delayed
Dust irritates the respiratory system, and may cause coughing and difficulties in breathing. Move
injured person into fresh air and keep person calm under observation. Get medical attention if
symptoms persist.
Contact with wet or dry product: Wash area with cold running water immediately. Open sores or
cuts should be thoroughly flushed and covered with suitable dressings.
Dust in eyes: Flush with cold tap water for at least 15 minutes. If irritation persists, seek medical
attention immediately.
Plaster of Paris hardens and if ingested may result in stomach and intestinal blockage. Drinking
gelatin solutions or large volumes of water may delay setting. Get medical attention if symptoms
occur.
Dust may irritate throat and respiratory system and cause coughing. May cause serious chemical
burns to the skin. May cause chemical eye burns. Permanent eye damage including blindness
could result.
Indication of immediate
medical attention and special
treatment needed
Provide general supportive measures and treat symptomatically.
General information
Ensure that medical personnel are aware of the material(s) involved.
5. Fire-fighting measures
Suitable extinguishing media
Use fire-extinguishing media appropriate for surrounding materials.
Unsuitable extinguishing
media
Not applicable.
Specific hazards arising from

the chemical
Not a fire hazard.
Special protective equipment

and precautions for firefighters
Selection of respiratory protection for firefighting: follow the general fire precautions indicated in
the workplace. Self-contained breathing apparatus and full protective clothing must be worn in
case of fire.
Use standard firefighting procedures and consider the hazards of other involved materials.
Fire-fighting
equipment/instructions
Specific methods
Cool material exposed to heat with water spray and remove it if no risk is involved.
6. Accidental release measures

Personal precautions,
protective equipment and
emergency procedures
See Section 8 of the SDS for Personal Protective Equipment.
Methods and materials for

containment and cleaning up
Vacuum up the spilled material. Vacuums used for this purpose should be equipped with HEPA
filters. Containers must be labeled. Collect in approved containers and seal securely. For waste
disposal, see Section 13 of the SDS.
Avoid discharge to drains, sewers, and other water systems.
Environmental precautions

SDS US
2/8
7. Handling and storage

Precautions for safe handling
Conditions for safe storage,

including any incompatibilities
Wear appropriate personal protective equipment (See Section 8). Do not get in eyes and avoid
contact with skin and clothing. Avoid inhalation of dust. Minimize dust production when mixing, or
opening and closing bags. Use with adequate dust control and local ventilation. Wear appropriate
NIOSH respirator when ventilation is inadequate and occupational exposure limits are exceeded.
Wash hands thoroughly after handling. Use a non-alkaline soap such as Neutralite Safety Solution
or Mason's Hand Rinse.
Store in a cool, dry, well-ventilated place. Store away from incompatible materials. Avoid contact
with acids, water, and moisture.
8. Exposure controls/personal protection

Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
Type
Value
Form

10034-76-1) (CAS
26499-65-0)
PEL
5 mg/m3
Respirable fraction.
Portland Cement (CAS

65997-15-1)
PEL
15 mg/m3
5 mg/m3
Total dust.
15 mg/m3
Total dust.
US. OSHA Table Z-3 (29 CFR 1910.1000)

Components
Type
Value

65997-15-1)
Impurities
TWA
50 mppcf
Type
Value
Form

(CAS 14808-60-7)
TWA
0.3 mg/m3
Total dust.
0.1 mg/m3
2.4 millions of
particle
Respirable.
Respirable.
US. ACGIH Threshold Limit Values

Components
Type
Value
Form

10034-76-1) (CAS
26499-65-0)
65997-15-1)
Impurities
TWA
10 mg/m3
Inhalable fraction.
TWA
1 mg/m3
Type
Value
Form

(CAS 14808-60-7)
TWA
0.025 mg/m3
US. NIOSH: Pocket Guide to Chemical Hazards

Components
Type
Value
Form

10034-76-1) (CAS
26499-65-0)
TWA
5 mg/m3
Respirable.

65997-15-1)
TWA
10 mg/m3
5 mg/m3
Total
Respirable.
Impurities
Type
10 mg/m3
Value
Total
Form

(CAS 14808-60-7)
TWA
0.05 mg/m3
Respirable dust.
Biological limit values
No biological exposure limits noted for the ingredient(s).

SDS US
3/8
Appropriate engineering
controls
Provide sufficient ventilation for operations causing dust formation. Observe occupational
exposure limits and minimize the risk of exposure.
Individual protection measures, such as personal protective equipment

Wear approved safety goggles.
Eye/face protection
Skin protection
Hand protection
Other
Respiratory protection
Thermal hazards
General hygiene
considerations
Wear appropriate chemical resistant gloves.

Wear long-sleeved shirts, pants and rubber boots.
If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. Use a NIOSH/MSHA approved air
purifying respirator as needed to control exposure. Consult with respirator manufacturer to
determine respirator selection, use, and limitations. Use positive pressure, air-supplied respirator
for uncontrolled releases or when air purifying respirator limitations may be exceeded. Follow
respirator protection program requirements (OSHA 1910.134 and ANSI Z88.2) for all respirator
use.
None.
During work avoid kneeling in fresh mortar or concrete wherever possible. If kneeling is absolutely
necessary, then appropriate waterproof personal protective equipment must be worn. Do not eat,
drink or smoke when working with cement to avoid contact with skin or mouth. Immediately after
working with cement or cement-containing materials, workers should wash or shower. Remove
contaminated clothing, footwear, watches, etc, and clean thoroughly before re-use.
9. Physical and chemical properties

Appearance
Physical state
Solid.
Form
Powder.
Color
Gray to off-white.
Odor
Low to no odor.
Odor threshold
Not applicable.
pH
11 - 12
Melting point/freezing point
Not applicable.
Initial boiling point and boiling

range
Not applicable.
Flash point
Not applicable.
Evaporation rate
Not applicable.
Flammability (solid, gas)
Not applicable.
Upper/lower flammability or explosive limits

Not applicable.
Flammability limit - lower
(%)
Flammability limit - lower
(%) temperature
Not applicable.
Flammability limit - upper

(%)
Not applicable.
Flammability limit - upper

(%) temperature
Not applicable.
Explosive limit - lower (%)
Not applicable.
Explosive limit - lower (%)

temperature
Not applicable.
Explosive limit - upper (%)
Not applicable.
Explosive limit - upper (%)

temperature
Not applicable.
Vapor pressure
Not applicable.
Vapor density
Not applicable.
Relative density
2.96 - 3.15 (H20 = 1)
Solubility(ies)
Solubility (water)
0.15 - 1 g/100g (in water)

SDS US
4/8
Partition coefficient
(n-octanol/water)
Not applicable.
Auto-ignition temperature
Not applicable.
Decomposition temperature
2642 F (1450 C)
Viscosity
Not applicable.
Other information
Bulk density
75 - 85 lb/ft
Flammability
Not applicable.
VOC (Weight %)
0 g/l
10. Stability and reactivity

Reactivity
Not available.
Chemical stability
Material is stable under normal conditions.
Possibility of hazardous
reactions
Hazardous polymerization does not occur.
Conditions to avoid
Contact with incompatible materials. Exposure to moisture. When mixed with water this product
can become very hot. Encasing or making moulds of any body part can cause serious burns that
may require surgical removal of affected tissue and even amputation of encased body part.
Acids. Exposure to water and acids must be supervised because the reactions are vigorous and
produce large amounts of heat. Crystalline silica in contact with powerful oxidizing agents, such as
fluorine, chlorine trifluoride and oxygen difluoride, may cause fires. Crystalline silica will dissolve in
hydrofluoric acid and produce a corrosive gas, silicon tetrafluoride.
Calcium oxides. Sulfur oxides.
Incompatible materials
Hazardous decomposition
products
11. Toxicological information

Information on likely routes of exposure
Ingestion may cause irritation and stomach discomfort.
Ingestion
Inhalation
Inhalation of dusts may cause respiratory irritation. Prolonged and repeated exposure to airborne
respirable crystalline silica can cause silicosis and/or lung cancer.
Skin contact
Exposure to dry product may cause drying of the skin and mild irritation, or more significant
effects from the aggravation of other conditions. Wet product is caustic (pH 12) and dermal
exposure may cause more severe skin effects, including thickening, cracking or fissuring of the
skin. Prolonged exposure can cause severe skin damage in the form of chemical (caustic) burns.
Some individuals who are exposed to wet or dry product may exhibit an allergic response, which
can result in symptoms ranging from mild rashes to severe skin ulcers.
Eye contact
Exposure to airborne dust may cause immediate or delayed irritation of the eyes. Depending on
the level of exposure, effects may range from redness to chemical burns and blindness.
Symptoms related to the

physical, chemical and
toxicological characteristics
Dust may irritate throat and respiratory system and cause coughing. May cause serious chemical
burns to the skin. May cause chemical eye burns. Permanent eye damage including blindness
could result.
Information on toxicological effects

Acute toxicity
Not expected to be a hazard under normal conditions of intended use.
Skin corrosion/irritation
Causes skin irritation.
Serious eye damage/eye

irritation
Causes serious eye damage.
Respiratory or skin sensitization

Not classified but possible due to skin sensitization effect.
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicity
Trace amounts of Cr(VI) compounds from Portland Cement may cause allergic skin reaction even
after one exposure.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Repeated and prolonged exposures to high levels of respirable crystalline silica may cause
cancer.
IARC Monographs. Overall Evaluation of Carcinogenicity

Crystalline silica (Quartz) (CAS 14808-60-7)
1 Carcinogenic to humans.
SDS US
5/8
NTP Report on Carcinogens

Known To Be Human Carcinogen.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Not expected to be a reproductive hazard.
Reproductive toxicity
Specific target organ toxicity single exposure
No data available, but none expected.
Specific target organ toxicity repeated exposure
Not classified. For detailed information, see section 16.
Aspiration hazard
Due to the physical form of the product it is not an aspiration hazard.
Chronic effects
Prolonged and routine inhalation of high levels of respirable crystalline silica particles can lead to
the lung disease known as silicosis. Some studies show excess numbers of cases of
scleroderma, connective tissue disorders, lupus, rheumatoid arthritis, chronic kidney diseases and
end-stage kidney disease in workers exposed to respirable crystalline silica. Pre-existing skin and
respiratory conditions including dermatitis, asthma and chronic lung disease might be aggravated
by exposure. Occupational exposure to respirable dust and respirable crystalline silica should be
monitored and controlled. May cause eczema-like skin disorders (dermatitis).
12. Ecological information

The product is not expected to be hazardous to the environment. Large amounts of the product
may affect the pH-factor in water with possible risk of harmful effects to aquatic organisms.
Ecotoxicity
Components
Species
Test Results
Plaster of Paris (Calcium Sulfate Hemihydrate CAS 10034-76-1) (CAS 26499-65-0)

Aquatic
Fish
LC50
Fathead minnow (Pimephales promelas) > 1970 mg/l, 96 hours
Persistence and degradability
No data available.
Bioaccumulative potential
Bioaccumulation is not expected.
Mobility in soil
No data available.
Other adverse effects
None expected.
13. Disposal considerations

Disposal instructions
Dispose in accordance with applicable federal, state, and local regulations. Recycle responsibly.
Local disposal regulations
Dispose of in accordance with local regulations.
Hazardous waste code
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused

products
Contaminated packaging
14. Transport information

DOT
Not regulated as dangerous goods.
IATA
IMDG
Not applicable.
Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information

US federal regulations
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication

Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

Not regulated.

SDS US
6/8
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)

Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - Yes
Hazard categories
Delayed Hazard - Yes
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
Yes
SARA 313 (TRI reporting)

Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Not regulated.
Safe Drinking Water Act
(SDWA)
US state regulations
WARNING: This product contains chemicals known to the State of California to cause cancer.
US. Massachusetts RTK - Substance List

Portland Cement (CAS 65997-15-1)
US. New Jersey Worker and Community Right-to-Know Act
US. Pennsylvania Worker and Community Right-to-Know Law
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
International Inventories
Country(s) or region
United States & Puerto Rico
Inventory name
Toxic Substances Control Act (TSCA) Inventory
On inventory (yes/no)*
Yes
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision

Issue date
06-August-2014
Revision date
Version #
01

SDS US
7/8
Further information
Crystalline silica: Raw materials in this product may contain respirable crystalline silica. Exposures
to respirable crystalline silica are not expected during the normal use of this product. However,
actual levels must be determined by workplace hygiene testing. Prolonged and repeated exposure
to airborne free respirable crystalline silica can result in lung disease (i.e., silicosis) and/or lung
cancer.
Plaster of Paris: Is classified as a hazardous substance but is generally considered a safe material
for routine use. When plaster of Paris is used responsibly it is not considered as a dangerous
material. However, when mixed with water this product can become very hot. DO NOT attempt to
make a cast enclosing any part of the body. Encasing any body part can cause serious burns and
even amputation of the encased body part.
OSHA's "Preventing Skin Problems from Working with Portland Cement" provides excellent
guidance and can be downloaded at: https://www.osha.gov/dsg/guidance/cement-guidance.html
NFPA Ratings:
Health: 2
Flammability: 0
Physical hazard: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
NFPA ratings
0
2
Disclaimer
This information is provided without warranty. The information is believed to be correct. This
information should be used to make an independent determination of the methods to safeguard
workers and the environment.

SDS US
8/8

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SAFETY DATA SHEET

CAL-SEAL W-60 Gypsum Cement

Other means of identification

Oil Well Cement

Oil Well Cementing.

Use in accordance with manufacturer's recommendations.

United States Gypsum Company

Serious eye damage/eye irritation

OSHA defined hazards

Store locked up.

Dispose of in accordance with local, state, and federal regulations.

Hazard(s) not otherwise

CAL-SEAL W-60 Gypsum Cement

Plaster of Paris (Calcium

All concentrations are in percent by weight unless ingredient is a gas.

Provide general supportive measures and treat symptomatically.

Ensure that medical personnel are aware of the material(s) involved.

Use fire-extinguishing media appropriate for surrounding materials.

Specific hazards arising from

Not a fire hazard.

Special protective equipment

6. Accidental release measures

See Section 8 of the SDS for Personal Protective Equipment.

Methods and materials for

CAL-SEAL W-60 Gypsum Cement

7. Handling and storage

Conditions for safe storage,

8. Exposure controls/personal protection

Plaster of Paris (Calcium

Portland Cement (CAS

US. OSHA Table Z-3 (29 CFR 1910.1000)

Portland Cement (CAS

Crystalline silica (Quartz)

US. ACGIH Threshold Limit Values

Plaster of Paris (Calcium

Crystalline silica (Quartz)

US. NIOSH: Pocket Guide to Chemical Hazards

Plaster of Paris (Calcium

Portland Cement (CAS

Crystalline silica (Quartz)

Biological limit values

No biological exposure limits noted for the ingredient(s).

CAL-SEAL W-60 Gypsum Cement

Individual protection measures, such as personal protective equipment

Wear appropriate chemical resistant gloves.

9. Physical and chemical properties

Melting point/freezing point

Initial boiling point and boiling

Flammability (solid, gas)

Upper/lower flammability or explosive limits

Flammability limit - upper

Flammability limit - upper

Explosive limit - lower (%)

Explosive limit - lower (%)

Explosive limit - upper (%)