MSDS Pu-300

One Part Polyurethane
MATERIAL SAFETY DATA SHEET
Pentens
1. Product and Company Identification

Product Name
One Part Polyurethane
Synonyms
Chemical Formula
Product Codes
PENTENS PU-300/PU-101
Supplier Information
8F, No. 2, Lane 348, Sec. 2 ,Chung-Shang Rd., Chung-Ho City ,Taipei
Hsien, Taiwan
Emergency phone
numbers
886-2-22400220 ext116
2. Composition / Information on Ingredients

Ingredient
CAS Number
Percent (by weight)
101-68-8
Trade Secret
Diphenyimethane
Diisocyanate
20447-40-5
Trade Secret
Di-n0butyl pthlatc
84-74-2
Trade Secret
4,4 DiphenylmethaneDusocyanate
3. Harzards Identification
Emergency overview
--
Human health hazards Toxic by inhalation and ingestion. Irritation to eyes, respiratory
systems and skin. May cause sensitization by inhalation. Hazards
polymerization may occur. Possible evolution of carbon dioxide gas
may rupture closed containers.
Environmental Effects No environmental hazards are known.
Physical and Chemical Fire produces toxic and corrosive fumes.
Hazards
Specific Harzars
--
4. First-Aid Measures
a. Effects and symptoms
Inhalation
May lead to mucous membrane irritation, tightness of chest, respiratory

tract irritation, coughing, headache, shortness of breath. May lead to
allergic sensitive in some individuals resulting in asthma-like symptoms
upon exposure below TLV. Sensitized ersons should be removed from
any further exposure. Persons with asthma-type conditions or other
chronic respiratory diseases should be excluded from working with the
chemical.
Ingestion
Skin Contact
Localized irritation and discoloration may occur. Occasionally contact

dermatitis is produced as a manifestation of a specific skin allergy.
Eye Contact
Liquid can cause eye irritation, tearing, reddening and swelling.

Permanent cornea injury is unlikely. In addition, vapors in excess of
0.02ppm may cause irritation.
Ingestion
Ingestion is unlikely, the acute oral LD 50 is greater than 15g/kg.

Ingestion can cause irritation and corrosive action in the month, stomach
and digeslive tract.
b. Effects and
symptoms
Inhalation
Move to uncontaminated area, administer oxygen if necessary.

Asmathic-like symptoms, if manifested, may developed immediately, or
be delayed for up to several hours. Obtain medical attention.
Treatment is symptomatic.
Ingestion
Skin Contact
Wash area thoroughly with soap and water.

reuse.
Eye Contact
Flush with water for at least 15 minutes holding lids open with fingers
consult a physician.
Ingestion
Do not induce vomiting. Drink water to reduce corrosity.

physician Treatment is symptomatic.
Launder clothing before
Consult a
5. Fire-Fighting Measures
Extinguishing Media
Large quantity water, foam, dry chemical, Carbon Dioxide.
Special Firefighting
Procedures
Wear self-contained breathing apparatus and full protective clothing.

Fire fighting equipment must be thoroughly cleaned and decontaminated
after use.
Unusual Fire And

Explosion Hazards
Reaction with water may foam.

Avoid water contamination in closed containers or confined areas.
6. Accidental Release Measures

Personal Precaution
Wear appropriate protective clothing and recommended respiratory

equipment.
Environmental
Do not allow to enter sewerage systems or open watercourses.
Precautions
Methods for Cleaning
Spilled should be covered with loose, ahsorbent, non-biodegradable
Up
material. Deactivation solution (90% water, 8% concentrated

ammonia, 2% detergent) over spilt area; allow to react 10 minutes or
longer. Collect materials in open containers and treat with additional
deactivating solution ; allow to stand uncovered for 24-48 hours. Wash
area with deactivating solution. Respiratory, eye and skin protection
should be worn during spill, clean-up and ventilation maintained.
7. Handling and Storage

Handling
Avoid contact with eyes, skin and clothing. Avoid breathing vapor or
mist. Use adequate ventilation.

handing.
Storage
Wash hand and face thoroughly after
Do not stare drums uncovered out of doors. Do not reseal container

unless it is certain that no moisture contamination has occurred.
8. Exposure Controls/ Personal Protection

Engineering Measure
Local exhaust required to keep airborne concentration below the TLV.

Explosion protected electrical equipment. Follow guidelines in the
ACGTH publication <Industrial Ventilation> Exhaust air may need to
be cleaned by scrubbers or filters to reduce environmental
contamination.
Respiratory protection Because of the low vapor pressure, ventilation is sufficient to keep vapors
below the TLV at room temperature. Exception is when the material is
sprayed or heated. If airborne concentrations exceed or are expected to
exceed the TLV, use MSHA/NIOSH approved positive pressure supplied
air respirator with a full face piece or an air supplied hood. For
emergencies, use a positive pressure self-contained breathing apparatus.
Air purifying (cartridge type) respirators are not approved for
protection against isocyanates.
Hands
Productive gloves/rubber gloves
Eyes
Chemical resistant goggles.
Skin and body
Impermeable coveralls and boots as necessary to Prevent eye and skin

contact. Safety shower, eyewash station in work area.
Other protective
measures
Clean protective clothing should be worn daily, Shower after work is

recommended.
9. Physical and Chemical Properties

Physical State and
appearance
Amber Liquid
Odor
Aromatic
Intensity
Slight
Boiling Point (F)
625
Melting Point
Nil
Specific Gravity (at

25C)
1.23
Solubility in Water
Reachts with water
Vapor pressure (mm Hg 10 -5

at 25C)
Vapor Density (AIR=1) 8.5
10. Stability and Reactivity

Stability
Stable under normal conditions
Incompatibility (Materials to
avoid)
Water, amines, strong bases, alcohol, surface active materials.
Hazardous Decomposition
Product
Carbon dioxide, carbon monoxide, nitrogen oxide,

Combustion products ammonia, trace amount of hydrogen
cyanide, acetaldehyde, CH, Toluene & irritating fumes.
11. Toxicological Information

Acute toxicity
LD 50, Oral : 15g/kg ( Rats )

LC 50, inhalation : 370mg/m3 (Rats-4hrs)
Carcinogenicity
No data available.
12. Ecological Information

Product and wastes
Do not allow to escape into waters, waste water or soil.
Possible Environmental
Effects ,Behavior and Fate
No date available on any potential adverse effect on

environment.
13. Disposal Considerations

Product and wstes disposal
Incinerate or dispose of in accordance with existing federal,

state and local environment control regulation.
Contain disposal
1. Containers should be neuralized with liquid

Decontaminant, decontaminated containers must remain
open for at least 48 hours to allow carbon dioxide gas
evolved to escape. Drums may then be disposed off in a
licensed facility.
14. Transport Information

Land Road / Railway
ADR/RID Class
Not classified
Inland waterways
ADNR CLASS
Sea
IMDG Class
Air
IATA-DGR Class
15. SPECIAL PRECAUTIONS

Special comments
Prevent skin and eye contact. Observe TLV limitations.

Avoid breathing vapors and aerosols. Workers should
shower and change to fresh clothing after each shift.
A sensitized individual should not be Exposed to the
product which caused the sensitization. Stored in
tightly sealed containers to protect From atmospheric
moisture. Stored in cool area. Individuals with
existing respiratory disease such as chronic bronchitis,
emphysema or asthma should not be exposed to
isocyanates. These individuals should be identified
through baseline and annual evaluation and removed
from further exposure. Medical examination should
include medical history, vital capacity and forced
expiratory volume at one second.
Literature Reference
1. NIOSH/OSHA .Occupational Health Guidelines for

Chemical Harzards,1981
2. Material Safety Data Sheet (of the raw material
manufacture)
ALL OF THE MSDS DATA ARE FOR REFERENCE ONLY. THE USER SHOULD
JUDGE THE USABILITY THEMSELVES.
COPYRIGHT 2003 UFON NANO-CHEMICAL CORP.
http://www.pentens.com

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One Part Polyurethane

MATERIAL SAFETY DATA SHEET

1. Product and Company Identification

One Part Polyurethane

2. Composition / Information on Ingredients

Percent (by weight)

May lead to mucous membrane irritation, tightness of chest, respiratory

Localized irritation and discoloration may occur. Occasionally contact

Liquid can cause eye irritation, tearing, reddening and swelling.

Ingestion is unlikely, the acute oral LD 50 is greater than 15g/kg.

Move to uncontaminated area, administer oxygen if necessary.

Wash area thoroughly with soap and water.

Do not induce vomiting. Drink water to reduce corrosity.

Launder clothing before

Large quantity water, foam, dry chemical, Carbon Dioxide.

Wear self-contained breathing apparatus and full protective clothing.

Unusual Fire And

Reaction with water may foam.

6. Accidental Release Measures

Wear appropriate protective clothing and recommended respiratory

Do not allow to enter sewerage systems or open watercourses.

Spilled should be covered with loose, ahsorbent, non-biodegradable

material. Deactivation solution (90% water, 8% concentrated

7. Handling and Storage

mist. Use adequate ventilation.

Wash hand and face thoroughly after

Do not stare drums uncovered out of doors. Do not reseal container

8. Exposure Controls/ Personal Protection

Local exhaust required to keep airborne concentration below the TLV.

Productive gloves/rubber gloves

Chemical resistant goggles.

Skin and body

Impermeable coveralls and boots as necessary to Prevent eye and skin

Clean protective clothing should be worn daily, Shower after work is

9. Physical and Chemical Properties

Boiling Point (F)

Specific Gravity (at

Reachts with water

Vapor pressure (mm Hg 10 -5

10. Stability and Reactivity

Stable under normal conditions

Water, amines, strong bases, alcohol, surface active materials.

Carbon dioxide, carbon monoxide, nitrogen oxide,

11. Toxicological Information

LD 50, Oral : 15g/kg ( Rats )

12. Ecological Information

Do not allow to escape into waters, waste water or soil.

No date available on any potential adverse effect on

13. Disposal Considerations

Incinerate or dispose of in accordance with existing federal,

1. Containers should be neuralized with liquid

14. Transport Information

15. SPECIAL PRECAUTIONS

Prevent skin and eye contact. Observe TLV limitations.

1. NIOSH/OSHA .Occupational Health Guidelines for

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