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Test 3 Atomic

The document contains a 20 question multiple choice test on atomic structure. The questions cover topics like the number of electrons in different atomic orbitals, identifying orbitals based on quantum numbers, electron configurations that obey or violate rules like Hund's rule and Aufbau principle, permissible and non-permissible sets of quantum numbers, ordering of atomic orbitals by energy, and identifying ions based on their electron configuration.

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Rajeev Gangwar
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197 views4 pages

Test 3 Atomic

The document contains a 20 question multiple choice test on atomic structure. The questions cover topics like the number of electrons in different atomic orbitals, identifying orbitals based on quantum numbers, electron configurations that obey or violate rules like Hund's rule and Aufbau principle, permissible and non-permissible sets of quantum numbers, ordering of atomic orbitals by energy, and identifying ions based on their electron configuration.

Uploaded by

Rajeev Gangwar
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Test-3

Atomic Structure
1. Number of d-electrons present in Fe+2[Z = 26] are not equal to:
(A) Number of p-electrons in Ne [Z = 10]
(B)Number of s-electrons in Mg [Z
= 12](C) (C) Number of d-electrons in Fe [Z = 26]
(D)Number of
p-electrons in Cl [Z = 17]
2. Which orbital is designated by the quantum numbers [l = 2 and m = 0] ?
(B) dx2 y2

(A) dxy

(C) dz2 (D) dyz

3. The group not showing similarity in unpaired electrons is:


(A) d3, d7

(B) f4, f10

(C) d7, p3

(D) d4, d8

4. Which electron is associated with the least energy:

(A) n = 3, l = 2, m = 2, s = +

(C) n = 4, l = 1, m = 1, s = +

1
2

(B) n = 4, l = 0, m = 0, s = +

1
2

(D) n = 5, l = 0, m = 0, s = +

5. Following electronic configuration violates :


2s

2p

(A) Paulis rule

(B) Hunds rule

(C) Aufbau rule

(D) All of these

6. Number of unpaired electrons associated with


respectively are:
(A) 2, 3 and 4

(B) 1, 2 and 3

25

Mn+4,

24

Cr+2 and

(C) 3, 4 and 5

(D) 2, 3 and 1

7. Which atom is the largest:


(A) 1s2, 2s2, 2p6, 3s2
(C) 1s2, 2s2, 2p6, 3s2, 3p3

(B) 1s2, 2s2, 2p6, 3s2, 3p1


(D) 1s2, 2s2, 2p6, 3s2, 3p5

8. Match List-I with List-II and choose the correct codes given below:
ListI

ListI

l(l 1)
A. Orbital angular momentum

a.

B. No. of orbitals in a sub shells

b. n

Fe+3

26

h
2

1
2
1
2

C. No. of sub-shells in an orbit

c. 2l + 1

Codes:
A

(A)

(B)

(C)

(D)

9. Orbital angular momentum of d-electron is:


(A)

(B)

(C)

(D)

10.Match list-I with list-II and choose the answer from the code given below:
List-I

List-II

A. Total values of l for a given n

a. 0, 1, 2(n-1)

B. Actul values of l for a given n

b. +l, .+2, +1, 0, -1, -2,-l

C. Total values of m for a given l

c. (2l + 1)

D. Actual values of m for a given l

d. n

Code is
A.

C.

D.

(A)

(B)

(C)

(D)

11.Arrange the orbitals of H-atom in the increasing order of their energy:


3px, 2s, 4dxy, 3s, 4pz, 3py, 4s
(A) 2s < 3s = 3px = 3py < 4s = 4pz = 4dxy
= 4dxy

(B) 2s < 3s < 3px = 3py < 4s = 4pz

(C) 2s < 3s < 3px = 3py < 4s < 4pz = 4dxy


< 4dxy

(D) 2s < 3s < 3px = 3py < 4s < 4pz

12.Which of the following are not permissible sets of quantum numbers for an
electron in an atom:
n

(A)

(B)

(C)

(D)

1
2

1
2

1
2

1
2

-1

-2

13.The inter-electronic repulsion is minimum in the configuration:


(A) 2px22py1,2pz0
2pz1

(B) 2px12py2, 2pz0

(C) 2px22py0, 2pz1

(D) 2px12py1,

14.(A) 1s22s22p63s1
(B) 1s22s22p66s1
Review the configuration of the two atoms A and B given above and show that
which one is a incorrect statement:
(A) Energy is needed to convert A to B
(B) Configuration A represents sodium atom
(C) To remove one electron from B less energy is needed as compared to that of
A
(D) A and B represent two different elements
15.Which sub-shell of the hydrogen atom is capable of absorbing a photon but
unable to emit photon?
(A) 3s

(B) 2p

(C) 1s

(D) 2s

16.Magnetic moment of X3+ ion of 3d series is


X3+ ?
(A) 25

(B) 26

(C) 27

35

BM. What is atomic number of

(D) 28

17.Quantum numbers of 13th electron of silicon (Z = 14) are 3, 1, 1, + . Which one


of the following is true set of quantum numbers for the 14 th electron?
(A) 3, 1, 0, + 1/2

(B) 3, 0, 1, + 1/2

(C) 3, 1, 1, 1/2

18.Five valence electrons of nitrogen are shown as:


2p

2s
AB

(D) 3, 1, 1, +

If the spin quantum number of B and E is . The group of electrons with three
same quantum numbers are :
(A) Only AB
these

(B) Only CDE

(C) Both the above (D) None of

19.Using Hunds rule to decide which of the following is not the ground state
electronic configuration:
2s

2p

(A) [He]
(B) [He]
(C) [He]
(D) [He]
20.Four quantum numbers of 19th electron of

Cr are:

24

(A)

+1/2

(B)

1/2

(C)

1/2

(D)

+1/2 or

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