NiCd Batteries PDF
NiCd Batteries PDF
NiCd Batteries PDF
Technical manual
July 2004
Contents
Introduction
2.
4
4
4
4
4
4
4
4
4
4
4
4
4
4
3.
4.
5.
6.
10
11
11
11
11
Operating features
6.1 Capacity
6.2 Cell voltage
6.3 Internal resistance
6.4 Effect of temperature on performance
6.5 Short-circuit values
6.6 Open circuit loss
6.7 Cycling
6.8 Effect of temperature on lifetime
6.9 Water consumption and gas evolution
12
12
12
12
13
14
14
14
15
16
7.
17
17
17
17
17
17
18
8.
Battery charging
8.1 Charging generalities
8.2 Constant voltage charging methods
8.3 Charge acceptance
8.4 Charge efficiency
8.5 Temperature effects
8.6 Commissioning
19
19
19
20
22
22
22
9.
23
23
23
24
24
24
24
25
26
26
26
29
1.
1. Introduction
The nickel-cadmium battery is
the most reliable battery system
available in the market today. Its
unique features enable it to be
used in applications and
environments untenable for
other widely available battery
systems.
2. Benefits of the
block battery
The block battery does not suffer
from the sudden death failure
associated with the lead acid
battery (see section 4.1 Plate
assembly).
2.7 Resistance to
mechanical abuse
The block battery is designed to
have the mechanical strength
required to withstand all the
harsh treatment associated with
transportation over difficult
terrain (see section 9.2
Mechanical abuse).
3. Electrochemistry of
nickel-cadmium batteries
The nickel-cadmium battery uses
nickel hydroxide as the active
material for the positive plate,
and cadmium hydroxide for the
negative plate.
2 Ni(OH)2 + Cd(OH)2
charge
4. Construction features
of the block battery
Connector covers
Material: hard PVC
plastic.
Cell container
Material: translucent
polypropylene.
Plate tab
Spot-welded both to
the plate side-frames
and to the upper edge
of the pocket plate.
Separating grids
Separate the plates and
insulate the plate frames
from each other. The grids
allow free circulation of
electrolyte between the
plates.
Plate frame
Seals the plate pockets
and serves as a current
collector.
Plate
Horizontal pockets
of double-perforated
steel strips.
Flame-arresting vents
Material:
polypropylene.
4.3 Electrolyte
The electrolyte used in the block
battery, which is a solution of
potassium hydroxide and lithium
hydroxide, is optimized to give
the best combination of
performance, life, energy
efficiency and a wide
temperature range.
The concentration of the
standard electrolyte is such as
to allow the cell to be operated
to temperature extremes as low
as 20C (4F) and as high as
+50C (+122F). This allows the
very high temperature fluctuation
found in certain regions to be
accommodated.
For very low temperatures a
special high density electrolyte
can be used.
Interpretation of density
measurements is difficult and
could be misleading.
In most applications the
electrolyte will retain its
effectiveness for the life of the
battery and will never need
replacing. However, under certain
conditions, such as extended use
in high temperature situations,
the electrolyte can become
carbonated. If this occurs the
battery performance can be
improved by replacing the
electrolyte.
The standard electrolyte used for
the first fill in cells is E22 and for
replacement in service is E13.
4.2 Separation
Plate module
123
194
123
264
195
349
195
405
Use of battery
Applications
Railways
intercity &
urban transport
Stationary
Utilities
electricity, gas,
water production
& distribution
Oil and gas
offshore & onshore,
petrochemical
refineries
Industry
chemical, mining,
steel metal works
Buildings
public, private
Medical
hospitals,
X-ray equipment
Telecom
radio,
satellite, cable,
repeater stations,
cellular base stations
Railroad
substations
& signalling
Airports
Military
all applications
SBL
SBM
SBH
3h
30 min
1s
100 h
3h
30 min
7.5
11
8.3
1540
1390
920
Power
Power
Starting,
backup
backup
Power
Bulk energy
backup
storage
Engine starting - Switchgear - UPS - Process control Data and information systems - Emergency lighting Security and fire alarm systems Switching and transmission systems - Signalling
10
Saft Battery
types
mini
Autonomy
maxi
Capacity mini
range
maxi
5.1 Type L
5.3 Type H
5.2 Type M
The SBM is designed for
applications where the batteries
are usually required to sustain
electrical loads for between
30 minutes to 3 hours or for
mixed loads which involve a
mixture of high and low discharge
rates. The applications can have
frequent or infrequent discharges.
The range is typically used in
power backup applications.
Final voltage
1.14 V
1.10 V
1.05 V
1.00 V
10 min
15 min
30 min
60 min
2h
Discharge time
11
3h
5h
8h
6. Operating features
6.1 Capacity
Cell type
SBL
84
105
123
142
SBM
55
62
78
86
SBH
N/A
30
39
43
12
13
6.7 Cycling
14
15
Figure 5 - Water consumption values for different voltages and cell types
16
17
7.3 Temperature
The maximum and minimum
temperatures and the normal
ambient temperature will have
an influence on the sizing of
the battery. The performance
of a battery decreases with
decreasing temperature and
sizing at a low temperature
increases the battery size.
Temperature de-rating curves
are produced for all cell types
to allow the performance to
be recalculated.
7.5 Ageing
Some customers require a value
to be added to allow for the
ageing of the battery over its
lifetime. This may be a value
required by the customer, for
example 10%, or it may be a
requirement from the customer
that a value is used which will
ensure the service of the battery
during its lifetime. The value to
be used will depend on the
discharge rate of the battery and
the conditions under which the
discharge is carried out.
Table 4(a) - Typical floating de-rating factors from fully charged data for H type cells
EOD*
Time
Hours
Minutes
Seconds
V/cell
8h
5h
3h
2h
1.5 h
1h
30 s
5s
1s
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.97
0.93
0.88
1.05
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.95
0.92
0.88
0.83
0.84
0.84
0.84
0.84
0.81
0.81
0.81
1.10
1.00
1.00
1.00
1.00
1.00
0.99
0.92
0.87
0.85
0.81
0.81
0.77
0.76
0.76
0.76
0.76
1.14
1.00
1.00
1.00
1.00
1.00
0.94
0.85
0.81
0.79
0.75
0.72
0.71
0.71
0.71
0.71
* End of Discharge
Table 4(b) - Typical floating de-rating factors from fully charged data for M type cells
EOD*
Time
Hours
Minutes
Seconds
V/cell
8h
5h
3h
2h
1.5 h
1h
30 s
5s
1s
1.00
1.00
1.00
1.00
1.00
0.93
0.87
0.82
0.81
0.80
0.80
0.80
0.80
0.80
0.80
1.05
1.00
1.00
1.00
0.90
0.85
0.82
0.78
0.76
0.76
0.76
0.75
0.75
0.75
0.75
0.75
1.10
1.00
1.00
0.93
0.84
0.80
0.77
0.74
0.73
0.72
0.71
0.71
0.71
0.71
0.71
0.71
1.14
1.00
1.00
0.85
0.77
0.75
0.72
0.69
0.68
0.67
0.67
0.67
0.67
0.67
0.67
0.67
* End of Discharge
Table 4(c) - Typical floating de-rating factors from fully charged data for L type cells
Time
Hours
Minutes
Seconds
V/cell
10 h
8h
5h
3h
2h
1.5 h
1h
5s
1s
1.00
1.00
1.00
1.00
1.00
0.95
0.90
0.87
0.83
0.82
0.81
0.80
0.80
0.79
0.79
0.79
0.79
1.05
1.00
1.00
1.00
0.91
0.86
0.84
0.81
0.78
0.77
0.76
0.76
0.75
0.74
0.74
0.74
0.74
1.10
1.00
0.97
0.90
0.83
0.80
0.78
0.76
0.73
0.73
0.72
0.71
0.70
0.70
0.70
0.70
0.70
1.14
1.00
0.95
0.81
0.76
0.74
0.73
0.71
0.68
0.68
0.67
0.66
0.65
0.65
0.65
0.65
0.65
* End of Discharge
18
EOD*
8. Battery charging
8.1 Charging generalities
The block battery can be
charged by all normal methods.
Generally, batteries in parallel
operation with charger and load
are charged with constant
voltage. In operations where
the battery is charged
separately from the load,
charging with constant current
or declining current is possible.
High-rate charging or
overcharging will not damage
the battery, but excessive
charging will increase water
consumption to some degree.
19
Cell
type
min
max
min
max
floating
SBH
1.43
1.50
1.45
1.70
1.40 0.01
SBM
1.43
1.50
1.45
1.70
1.40 0.01
SBL
1.43
1.50
1.47
1.70
1.42 0.01
Table 5 - Charge and float voltages for the block battery ranges
20
21
8.6 Commissioning*
22
23
Ripple effects
The nickel-cadmium battery is
tolerant to high ripple and will
accept ripple currents of up to
0.2 C5 A I eff. In fact, the only
effect of a high ripple current is
that of increased water usage.
Thus, in general, any
commercially available charger
or generator can be used for
commissioning or maintenance
charging of the block battery.
This contrasts with the valveregulated lead acid battery
(VRLA) where relatively small
ripple currents can cause
battery overheating, and will
reduce life and performance.
Over-discharge
If more than the designed
capacity is taken out of a battery
then it becomes deep-discharged
and reversed. This is considered
to be an abuse situation for
a battery and should be avoided.
Vibration resistance
The block battery concept
has been tested to IEC 77 for
2 hours at 1 g, where
g = acceleration.
Shock loads
The block battery concept has
been tested to IEC 68-2-29
(bump tests at 5 g, 10 g and
25 g) and IEC 77 (shock test
3 g), where g = acceleration.
External corrosion
The block battery is
manufactured in durable
polypropylene. All external metal
components are nickel-plated or
stainless steel, protected by an
anti-corrosion oil, and then
protected by a rigid plastic cover.
10.2 Storage
Store the battery indoors in a dry,
clean, cool location (0C to +30C/
+32F to +86F) and well-ventilated
space on open shelves.
Do not store in direct sunlight or
expose to excessive heat.
10.3 Installation
10.3.1 Location
Install the battery in a dry and clean
room. Avoid direct sunlight and heat.
The battery will give the best
performance and maximum service life
when the ambient temperature is
between +10C to +30C (+50F to
+86F).
Block batteries can be fitted on to
stands, floor-mounted or fitted into
cabinets.
Important recommendations
Never allow an exposed flame or
spark near the batteries
particularly while charging.
Never smoke while performing any
operation on the battery.
For protection, wear rubber gloves,
long sleeves, and appropriate
splash goggles or face shield.
The electrolyte is harmful to skin
and eyes. In the event of contact
with skin or eyes, wash
immediately with plenty of water.
If eyes are affected, flush with
water, and obtain immediate
medical attention.
Remove all rings, watches and
other items with metal parts
before working on the battery.
Use insulated tools.
Avoid static electricity and take
measures for protection against
electric shocks.
Discharge any possible static
electricity from clothing and/or
tools by touching an earthconnected part ground before
working on the battery.
the battery to avoid any risk of shortcircuits. Flip-top vents may be turned
through 180 to achieve the most
convenient position for topping-up.
10.3.2 Ventilation
Special regulations for ventilation may
be valid in your area depending on the
applications.
Recommended
bolts are:
M 6 = 11
M 8 = 20
M 10 = 30
1.1
2
3
N.m
N.m
N.m
Example:
A battery of 98 cells, type SBH 79
on a three step, two tier stand, is
placed in a room of dimensions 2 m
x 2 m x 3 m.
When the battery is housed in a
cubicle or enclosed compartment, it is
necessary to provide adequate
ventilation.
During the last part of high-rate
charging, the battery is emitting gases
(oxygen and hydrogen mixture).
25
10.3.3 Mounting
Verify that cells are correctly
interconnected with the appropriate
polarity. The battery connection to load
should be with nickel-plated cable lugs.
10.4. Commissioning
Verify that the ventilation is adequate
during this operation.
A good commissioning is important.
Charge at constant current is
preferable.
When the charger maximum voltage
setting is too low to supply constant
current charging, divide the battery
into two parts to be charged
26
11.1 Cleanliness/mechanical
11.2 Topping-up
27
11.4 Recommended
maintenance procedure
In order to obtain the best from
your battery, the following
maintenance procedure is
recommended.
Yearly
check charge voltage settings
check cell voltages
(30 mV deviation from average
is acceptable)
check float current of the battery
check electrolyte level
high voltage charge if agreed
for application
Every 2 years
clean cell lids and battery area
28
29
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Australia
Saft Australia Pty Ltd,
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Germany
Saft Batterien GmbH,
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Tel: +49 911 94 174-0
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Statron GmbH, Wien
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Hong Kong
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AEG Belgium SA, Brussels
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www.saftbatteries.com
Doc N 21081-2-0704
Edition: July 2004
Data in this document is subject to change without
notice and becomes contractual only after written
confirmation.
Photo credit: Saft, Photodisc, Digitalvision.
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Prepared by Arthur Associates Limited.
Russia
ZAO Alcatel, Moscow
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Saft Batteries Pte Ltd,
Singapore
Tel: +65 6512 1500
Fax: +65 6749 7282
Spain
Saft Baterias S.L.
San Sebastian de los Reyes
Tel: +34 916 59 34 80
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Sweden
Saft AB,
Oskarshamn
Tel: +46 491 680 00
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Switzerland
Statron AG,
Mgenwil
Tel: +41 62 887 4 887
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United Kingdom
Saft Ltd,
Harlow
Tel: +44 1279 772 550
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USA
Saft America Inc.,
North Haven (CT)
Tel: +1 203 239 4718
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Telecom applications
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Venezuela
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Tel: +58 212 9631122