Dycote : Manual

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COATINGS FILTRATION FEEDING SYSTEMS MELT SHOP REFRACTORIES METAL TREATMENT BINDERS CRUCIBLES

DYCOTE*
M ANUAL

Equal filling of the die

Controlled heat transfer

Good surfaces of the castings

Long life time

Introduction
Although various aspects of the permanent
mould casting process have been studied
and developed, such as alloy selection,
machine automation, etc., little attention has
been given to the products and methods for
preparing the surfaces of the die.
It is often the operator that selects and
prepares the coating material, and the
final choice is based almost exclusively on
practical experience rather than technical
and theoretical considerations. This manual
aims to provide foundry engineers and
operators involved in die preparation with
the information required for the correct use
of coating materials, in order to optimise
efficiency and so improve foundry production.
This latest revised and illustrated edition of
the Foseco DYCOTE Manual comprises: An
analysis of the functions of coating materials,
preparation and application methods, and
examples of die preparation for the most
common castings.
The tables with the characteristics of
DYCOTE products have been extended,
rationalised and now include a new
family of DYCOTEs, the DURA group.
This offers extended coating life, to improve
productivity.

Where a special coating is only available in


some countries it has not been included in
the table. Also not every mentioned coating
is available in every country. For more details,
please contact your local Foseco company.
The manual is completed with appendices on
cryogenic sandblasting, coating application
defects and defects in die-cast parts.
Die casting and the role of coatings
Die casting is a process that uses permanent
moulds made of metal (dies) enabling large
batches of identical castings to be produced.
Contrary to sand moulds, in which the
permeability of the compacted sand allows
the air to escape freely during casting, metal
moulds are impermeable and therefore must
be designed with suitable air vents. The
advantages of the die process over sand are:
n 
superior structural characteristics
n 
better appearance of the casting
n 
greater dimensional accuracy
n 
reduced feed demand
n 
higher production rates
n 
lower cost (for larger batches)

Function of DYCOTE
The principal functions required of a coating
for die casting are:
n 
Control of the metal flow to

ensure that it reaches all parts of the die


at a sufficient temperature to prevent the
formation of seams, cold laps, etc.
n 
Control of heat transfer to obtain better

solidification and ensure that the castings


are properly fed.
Compared to sand moulds, the use of a
permanent metal mould requires completely
different conditions for filling the metal alloy
and for its solidification; the function of the die
coating a semi-permanent layer deposited on
the walls is to control these processes and
to facilitate release of the casting, prolong die
life, etc. In die casting, coating selection and its
method of application are at least as important
as other factors, such as the design of the die,
type of alloy, temperature of the metal and so
on. Foseco produces a vast range of die coating
products under its DYCOTE brand as well as
other products and systems which have long
been used in all areas of the modern metal
foundry. In addition, Foseco is constantly
seeking new products and systems to make
casting production safer, more environmentally
friendly and more economic.

n 
Easy release: since castings are

extracted at just below the solidification


temperature, easy release ensures that
castings do not come out deformed.
n 
Good surfaces, and therefore a reduction

in finishing costs.
n 
Longer die life, therefore increased

productivity and reduced maintenance.


These results are directly in line with the
characteristics of DYCOTE.

Heat transfer control


The control of heat dispersal through the
various sections of the die is undoubtedly
the most important characteristic of DYCOTE,
because it permits control of both directional
solidification and die filling (which will be
discussed in the section Metal flow control).

Bonding agents: in the majority of cases


sodium silicate with an appropriate SiO2/Na20
ratio, although sometimes other materials are
used, such as certain types of clays, starch, etc.
The DYCOTE DURA family is based on a new
binder system, which offers improved bond
toughness

The degree of insulation depends on:

Water: with controlled hardness.

n 
the properties of the raw material

The degree of compaction of the layer, which


depends on the application method, affects
the property of thermal insulation: if the layer
is not very compact, contact between particles
is slight, and therefore the permeability and
insulation properties are greater.DYCOTE
products are usually supplied in the form of
a paste for dilution with water depending
on the type of application (and therefore the
degree of insulation) desired, i.e. with brush
or spray application; the dilution ratio is
relatively unimportant from this point of view,
since excess water is removed by heat from
the warm die surface (120-140 C with brush
application and around 180-250 C for spray
application).

used
n 
the method used to apply DYCOTE to the

surface of the die


n 
the thickness of the layer.

The basic ingredients of DYCOTE are:


Fillers: composed generally of refractory
powders such as TiO2, talc, mica, silica
flour, iron oxide, AI2O3, etc. At the normal
casting temperature of aluminium alloys
in the die-casting process (650 - 800 C),
the refractoriness of the fillers is such as to
ensure that no chemical reaction takes place.
Their function therefore remains exclusively
physical, i.e. only thermal conductivity and
particle form and dimensions are involved
(the importance of the latter factors will
be discussed when dealing with metal flow
control).

Brush application leaves the die with a very


rough surface full of air pockets. This gives a
high degree of insulation, ideal for the surfaces
not requiring special finishes (such as runners
and risers).
In spray application, DYCOTE products are
applied in several thin layers until the desired
thickness is obtained. In this case the layer
also comprises air pockets but they are smaller
than in the previous case, and are due to
the accumulation of particles rather than the
formation of bubbles in the bonding agent.
Air pressure and distance of the pistol from
the surface of the die must be sufficient to
overcome the phenomenon of evaporation
and permit the DYCOTE to adhere completely
to the die surface. Air pressure of 0,4-0,5 MPa
and a distance of 25-30 cm from the die is
recommended (see figure 6).
Good quality castings with no, or at least only
a controlled level of, solidification shrinkage
are obtained if the concept of directional
solidification is observed, i.e. if solidification
proceeds steadily towards the risers from the
parts of the casting farthest from them.

An appropriate coating, with the thickness


varying with those of the casting, allows the
control of heat transfer, favouring directional
solidification. For example, by applying on a

thin section of the casting a thick layer of a


coarse insulating DYCOTE, the solidification
rate will be reduced. On a thick section of
the casting, a thin layer of a fine DYCOTE can
be applied, thereby accelerating solidification,
the cooling characteristics of the metal can be
rendered sufficiently uniform to give a sound
casting. The larger the difference between the
sections of a casting, the greater should be the
insulating properties of the DYCOTE applied.
In extreme cases, the desired effect can be
obtained by removing or rubbing down the
coating from thick sections. Runners and risers,
where metal has to remain molten for a certain
time to feed the casting during solidification,
normally require a thick layer of an highly
insulating DYCOTE.

Controlling metal flow


Since the coating is thin (50-150 microns)
and the temperature differential between the
molten alloy and the die varies between 400
and 500 C, the thermal conductivity stays
relatively high and the transmission of heat
from the metal to the die is instantaneous
and intense. The physical characteristics
of DYCOTE (coarseness, filler size), have
a marked effect not only on the surface
quality of the casting, but also on the
flow of metal and degree of insulation.
For example, a thin layer with ample
contact with the metal increases the

transmission of heat and rapidly reduces


fluidity; this can result in incomplete
filling, cold laps, etc., especially when the
metallostatic pressure is low, as for example in
the case of castings with thin sections.

Figure 1: Directional Solidification

Figure 2:
Metal flow
starting from
the centre

Metal path favours the rougher


surface

Smooth
DYCOTE 32

Rough
DYCOTE 34

Source: Daniel Whitrow, University Birmingham

Figure 3: Formation of Cold Lap

Conversely, with a layer of DYCOTE with a


coarse surface, the contact between molten
metal and DYCOTE is significantly reduced,
because the metal, due to its surface tension,
is first in contact with only the peaks of
the layer, and only after a time, though this
is extremely short, does it penetrate into the
valleys, after which the air escapes through
the channels in the permeable coating. The
result of this phenomenon is to reduce heat
loss to a minimum in the molten metal,
which thus maintains its fluidity at the critical
moment to fill the die completely.
The roughness of the refractory particles also
influences the flow of metal. Given that the
surface tension of aluminium is high, its flow
characteristics and wettability are low; as a

Figure 4: Fine coating

consequence of this, if a refractory filler with


sharp edges is used, the aluminium oxide
skin will be continuously broken down during
pouring, and the metal will run much more
easily over the surfaces. Unfortunately coarse
coating layers with sharp-edged particles tend
to become smoother with each casting. Indeed,
the sharp projections of the layer bind to the
surface of the casting during solidification and
break off during extraction: it may therefore
be necessary to touch up regularly to obtain
better results consistently.

Figure 5: Coarse coating

Easy release
Regardless of the design of the die, release
can be made easier by using graphite in a
colloidal and semi-colloidal form. Graphite can
be used as a component of the refractory base
of the DYCOTE, in the coating itself, or applied
separately on top of a standard DYCOTE.
When graphite is used in the composition
of refractory DYCOTE, care must be taken
to avoid weakening the coating due to the
thin layers of graphite flaking off. If a DYCOTE
flakes it will tend to lose its thermal insulation.
Graphite for application over a layer of DYCOTE
base is often used on areas of a die where
release is difficult, or on its moving parts. The
composition of the DYCOTE must be accurately
controlled since, if the bonding agent forms a
hard shell around each graphite particle, its
lubricating properties will be reduced or even
completely destroyed. When a graphite-based
DYCOTE is applied the lamellae are spread in
a disorderly manner, and therefore numerous
tiny blisters may form in the lining, with the
effect of reducing the thermal conductivity of
the layer. After a few castings, however, there is
a tendency for the graphite film to become flat
and impermeable (this can be seen from the
shiny appearance of the film after release) as
a result of continual friction against the metal
caused by shrinkage during solidification.
Therefore the bonding agent must be weak,
allowing part of the overlaid film to break
off, exposing the underlying layer over which
the application of graphite is repeated. The

drawback here, which arises from having to


apply a second coating, is that this tends to
cancel out the advantages of particle size in
base coats. What happens is that the graphite
tends to collect in the valleys, so that
the layer takes on a smoother appearance,
reducing the fluidity of the metal.
Recently, insulating coatings have been
introduced with a composition that includes
Boron Nitride (BN), which has a hexagonal
graphite-like structure. The presence of Boron
Nitride reduces the wettability to molten
aluminium while increasing the refractories
of the coating. Boron Nitride allows excellent
release while the white colour prevents the
discolouration of the casting, which is often
seen with graphite.

Good surface
As seen from the information above, a good
surface will be linked to the choice of DYCOTE;
for example flat thin surfaces require a coarse
angular layer which favours the flow of metal.
This is because the metallostatic pressure
is low and filling the die is facilitated by the
continual breakdown of the aluminium oxide
film. The surface of the casting will be relatively
rough but sound, while a smooth layer would
cause filling to be incomplete. The parts of
the mould corresponding to thick sections of
the casting can be coated with finer DYCOTE
products, since the metallostatic pressure
in these areas is higher. Also the type of
application will affect the final result: brush
application produces an uneven surface, while
spray application produces a smooth even
surface.

Coating thickness after abrasion test

Figure 6:

Lifetime
The factors that contribute to the life of a
coating layer are:
n 
Type of bonding agent
n 
Method of application
n 
Type of refractory

The bonding agent must not only resist high


temperatures but also the high temperature
changes that cause tensile stresses in the
coating layer.
Very often sodium silicate is used with a
well determined Na20/SiO2 ratio, as it not
only resists thermal cracking, but over time
becomes more resistant to high temperatures
and therefore is long-lasting. As stated initially,
the application method is important and the

SPRAY DISTANCE VS. ABRASION

Die Temperature - around 200 C


Spraying Pressure - 0,5 MPa
Dillution Ratio Coating:Water - 1:5

Spray distance (cm)

die temperature is the most critical factor. If


the temperature is too low and consequently
water evaporation is retarded, the coating
forms an impermeable film that detaches from
the die forming blisters, due to steam forming
under the layer. Then the layer can contract
and detach when it is completely dry, leaving
part of the die exposed. If the temperature is
too high and water evaporation too violent,
the refractory particles, surrounded by a film
of water and sodium silicate, will become
separated from each other and also from the
surface of the die by tiny explosions which take
place when the steam is released into the air.
The result is a weak, coarse, powdery layer that
peels off easily. Although, as has been said,
the ratios of the constituents remain constant
despite being diluted with water, the ratio of
dilution influences the final appearance of the
coating. As a general rule, insufficient dilution
results in a weaker bond between the coating
and the die, but the layer will be rough will
have lower thermal conductivity and therefore
will have better insulating properties.
Magnesium alloys
DYCOTE also adapts to magnesium alloys,
where prior to casting, the procedure for
preventing the oxidation of the metal is carried
out by saturating the die cavity with inert gas.
The DYCOTE BN coatings are compatible with
Magnesium alloys.

Copper alloys
The major difficulty encountered when die
casting in these materials is the deposit of zinc
oxide on the die surface. If it is not removed,
it rapidly forms a thickness that renders the
surface of the castings unacceptable. The
dies are therefore designed so they can be
dismantled and immersed in a bath containing
a suspension of a carbonaceous material that
inhibits the formation of zinc oxide as well
as coating the die this practice also cools the
die. The carbonaceous material is deposited
on the surface in a porous structure, giving
it both insulating and lubricating properties.
The inhibitor to a certain extent prevents
the formation of zinc oxide on the surface.
Another advantage of this process is the high
production derived from the simplicity of the
immersion application method.
Aluminium bronze
In this case DYCOTE products can be used for
light alloys, together with a second graphitebased coat to facilitate release. Use can also
be made of the immersion method described
above.

Low pressure casting


In this process the metal is injected into a
mould mounted on a sealed furnace. The air
or nitrogen pressure applied to the surface of
the metal causes it to rise and pass into the
mould through a tube. The pressure required
to move the metal is slightly higher than the
metallostatic pressure. Normally the same
DYCOTE products are used as for gravity
casting.
Preparing the Die
Cleaning
A fundamental requirement is cleaning the
surface to be coated: no residue of previous
coatings must remain and also no oil, grease
or soot. Cleaning can be performed with wire
brushes or by blasting with sand, alumina steel
shot etc. Recently, dry ice cleaning systems

Coating thickness after abrasion test

Figure 7:

have been developed that allow blasting in


situ without having to dismantle the die, with
clear advantages from the environmental point
of view but with problems getting into deep
parts of the die. Also a big problem is the loud
noise. The disadvantage is, that not all coating
types can be removed.
Die temperature
Dies generally operate at a temperature of
around 300 to 400 C, but the coating must
be first appliedin a variable range between
180 and 250 C, depending on the type of
DYCOTE and the degree of adherence desired.
During operation local areas may require
repair, this operation must be done at the
running temperature and needs a special
procedure, which is described in Figure 7.

DIE TEMPERATURE VS. ABRASION

Dillution Ratio Coating:Water - 1:5


Spray Distance - 20 cm
Spraying Pressure - 0,5 MPa

Die Temperature (C)

10

As the application temperature increases,


the adherence is reduced. Therefore the
temperature of the die should be controlled
accurately during application, using a contact
thermocouple. The temperature to which the
die is heated before coating should preferably
be higher (250-300 C), after which it is
left to cool, preferably under a cover, to the
correct coating temperature: this improves
the uniformity of the die temperature and
avoids intermediate heating when successive
layers must be applied. After the die has
been coated and before the first casting
is poured, it must be heated to working
temperature. To get the best results when
retouching the coating, it would be preferable
first to bring the die temperature down to
the recommended coating temperature.

INSULATION

Insulation value

Figure 8:

Figure 9: Effect of coating thickness on insulation and fluidity

Coating thickness
The coating thickness must be defined and
controlled on the basis of the insulation
required. Thicknesses in the order of 50 m
and 150 m (see figure 8) are sufficient to get
the maximum degree of insulation typical for
the product used.
For castings and risers, brush application
can achieve a thickness of up to 4-5 mm.
The coating thickness is the principal factor
in the heat exchange between casting and
die. Coatings applied carelessly over previous
coatings result in thick layers with a number
of negative consequences, such as alteration
of the thickness, poor layer tightness and
hot spot defects on the casting. The effect of
coating thickness on filling ability is illustrated
in figure 9 which shows the effect on fluidity.

Coating thickness (microns)

11

Coating life
This is certainly the aspect of greatest interest
and it is linked to the quality of the carefull
preparation of the die and the die coatings.
Absolute thorough cleaning and correct
heating are needed to ensure that all types
of DYCOTE adhere properly to the die metal.
A carefully applied coating could last at least
one day, potentially one week depending on
the casting design.
Those able to achieve these results will see
the benefits especially since the long life of
the coating is essential for dies to operate
consistently. Recently new compositions of
DYCOTE have been formulated. A range of
fine, medium and coarse DYCOTE coatings
with extended life have been developed. In
most cases further improvements in coating
life can also be achieved by curing DYCOTE
coatings at 350 to 400 C for over one hour
immediately after coating.

Preparing the Materials


Adequate storage and appropriate preparation
of the coating materials are of vital importance
for obtaining optimum performance from the
products used.
DYCOTE must be stored and applied in an
enclosed, cool, dry place not exposed to direct
sunlight.
DYCOTE coatings are sensitive to frost.
DYCOTE must be stored at ambient
temperature (10-25 C).
Storage at a stable temperature will keep the
viscosity and density of the product constant.
Too high a temperature leads to changes in
viscosity and accelerated biodegradation.
Too low a temperature will alter the viscosity
and may prevent the use of DYCOTE products
which, being generally water-based, will freeze
if the temperature falls below 0 C, causing it
to lose its binding property.

Figure 10: Example of DYCOTE preparation room, seperated from production

12

Stocks are used on the basis of their age


(priority is given to materials stored for the
longest period), so that the DYCOTE will be
as fresh as possible. The quantity of stored
product must be such as to enable it to be used
according to the date on the label. In particular,
purchasing the necessary material one month
in advance will provide an adequate level of
stock.

Preparing the Mixtures


Proper mixing and preparation of DYCOTE is
essential for obtaining the correct density, and
also for obtaining optimum characteristics of
use and reproducibility. Careful and controlled
preparation of the DYCOTE is an essential part
of the process and to ensure this the DYCOTE
should be mixed and stored in a separate,
clean and controlled room remote from the
production area. Using an appropriate mixer is
the best way to prepare DYCOTE.
Foseco has developed a system called Carry
& Mix which helps to dilute and store the
premixed coating. Carry & Mix is available in a
fixed and trolley mounted version.

Figure 11: Carry & Mix

13

The mixing procedure is as follows:


n 
Add approximately 1/3 to 1/2 of the total

water to the container


n 
Start the mixer
n 
Gradually add the correct quantity of paste

Checking and Control


DYCOTE products are subjected to strict
quality controls to ensure that they reach
the customer in optimum condition, however
further controls are required when the product
is used. Many of these controls fit easily into
the control programmes of the foundry.

to form a thick mixture without lumps


n 
Gradually add water until the mixture is

slightly thicker than the density of use


n 
Once

the mixture has a uniform


appearance, increase the quantity of water
to the required density for the application.

The mixed product must be kept covered.


Covering it reduces water evaporation and
reduces the risk of contaminants entering
the container. The container must be cleaned
regularly at least once a month. This is required
with water-based products to prevent the
formation of biological encrustation.

Figure 12: Density measured by weight and volume

14

Other checks:
n 
The appearance of DYCOTE, as is or mixed,

should always be similar.


n 
The presence of lumps or foreign matter

can be identified by examining the product.


n 
Checking the label / production date.

Figure 13: Baum densimeter

Test

Method
Baum

Density measurement using a gauge rod with a


bulb of calibrated weight at one end, which is
inserted into the mixture; the denser the mixture,
the less the rod sinks.

Weight/Vol.

Measurement of the weight of a known volume of


material.

Dry residue

A weighed quantity of the mixture is dried in an


oven and weighed again. The dry residue is the %
ratio between the final weight and initial weight.

Density

Solid Contents

Note

15

Application Method
The coating can be applied using several
methods:

Spray application
Essentially there are two different types of
spray devices:

n 
Brush

n 
Siphon pistol (air at high pressure), which

uses compressed air to create a partial


vacuum that forces the fluid through the
pistol, transforming the coating into tiny
droplets.

n 
Spray
n 
Immersion

For dies the quickest and most suitable


method is spray application. Brush application
is reserved for plain areas (runners and risers)
where the lining must be much thicker, or for
small details that must be coated in a different
way from the rest of the die. Immersion
application is mainly used for copper alloys,
where the coating also has to cool the die.

Coating thickness after abrasion test

Figure 14:

n 
Air-less systems, pumping the mixture at

high pressure into the pistol where it is


forced through a narrow portion and then
atomised by expansion.

DILUTION RATIO VS. ABRASION THICKNESS


Die Temperature - around 200 C
Spray Distance - 20 cm
Spraying Pressure - 0,5 MPa

Dilution Ratio (Water Parts)

16

The operations that must be performed to


obtain a correct coating are:
n 
The pistol must be completely clean

throughout, particularly the nozzle.


n 
Fill the tank only with the quantity of

mixture necessary. Discard the excess


quantity or put it back in the mixer for
application.
n 
Use the product in the pistol without

lengthy stops (>10 minutes).


n 
Set the line pressure to

0,4-0,5 MPa
(depending on the dilution of the mixture).
Too much or too little pressure causes the
formation of drops instead of a mist.

n 
Start the coating runs from outside the die

Figure 15: Krautzberger spraygun

n 
If the distance of application is too great,

part of the water medium evaporates


before contact with the die (dry spray),
producing coarse surfaces on the
resulting casting and poor coating
adhesion.

and avoid spraying intermittently. Make


short passes and keep the pistol moving
all the time.

n 
It is preferable to apply the coating in

n 
Maintain a distance of 20-30 cm between

n 
Between one layer and the next, the

pistol and die.


n 
Work quickly but carefully. Each pass cools

the die a little.


n 
If the distance of application is too close,

the coating tends to become thicker, slow


to dry and can cause stains on the casting;
the layer tends to become too thick.

several thin layers rather than in one or


two thick layers.

coating must be allowed to dry.


n 
Depending on the type of casting a typical

coating thickness for insulation should be


150 to 250 m, whilst for smooth surface
finish a coating thickness of 30 to 50 m
is applied.
n 
For optimum performance the thickness of

the coating should be measured at various

17

stages of application.
n 
The operator should move around the

die to coat from several directions and


so reach the surfaces to be coated from
different angles, thus avoiding the
shadow effect. This practice also avoids
accumulating too much coating material
on the operators side and getting dry
spray on the opposite side.
n 
Do not allow the coating to run on the die.
n 
Always clean the equipment after use.

18

Controlling the Thickness of the Coating


The thickness of the coating is a difficult
parameter to control, because of the difficulty
of working on very hot surfaces, therefore
operators have always been left to work it out
from experience, the result being inconsistency
from one die to the next and between surfaces
of the same die. Thickness gauges are currently
available which can be used on hot dies, at all
points.
This allows the caster to relate the coating
thickness to the metallurgical structure of the
casting and, by adopting the correct spraying
system, to correct the thickness, adapt it to
requirements and avoid scrap. Controlling the
coating thickness also permits better control
of directional solidification, important for
ensuring sound castings.

Figure 17: Ultrasonic system Sonacoat F

Figure 16: Magnetic system Pull off Gauge 157


Elcometer Instruments Ltd. Manchester

19

Controlling Die Temperature


Die temperature is a parameter that must
be controlled, in order to get the best bond
between the coating and the die. Although
an experienced operator may be able to
judge to temperature, best results are
obtained by using a suitable thermocouple.
Contact thermocouples and infrared or laser
thermometers are now available for controlling
die temperature. This enables the caster to
apply the coating at the correct temperatures.
Figure 18: Infrared thermometer

Figure 19: Contact thermocouple

20

Foseco DYCOTE Coatings


Average
grain size

Dillution
Vol water
Vol coating

25

1:1 to 3:1

Base coating for all applications, apply at 180 C

DYCOTE 6

70

3:1 to 4:1

High insulation coating for general engineering


castings.

DYCOTE D6ESS

85

3:1 to 5:1

Very highly insulating coating for thin section


castings. Textured casting finish.

DYCOTE D6ESSB

85

3:1 to 5:1

Very highly insulating coating for thin section


castings. Textured casting finish. Extra binder.

DYCOTE 32ESS

30

3:1 to 5:1

Medium insulating coating, effective for alloy


wheels.

DYCOTE 34

80

3:1 to 5:1

Very highly insulating coating for thin section


castings typically automotive. Textured casting
finish.

DYCOTE 34ESS

80

3:1 to 5:1

Very highly insulating coating for thin section


castings typically automotive. Textured casting
finish. With extra binder.

DYCOTE D34

80

3:1 to 5:1

Highly insulating coating for thin section castings


typically automotive. Textured casting finish.

DYCOTE D34ESS

80

3:1 to 5:1

Highly insulating coating for thin section castings


typically automotive. Textured casting finish. With
extra binder.

DYCOTE F34

50

3:1 to 5:1

General use. Good insulation for thin and large


sections.

DYCOTE 39

3:1 to 5:1

Low insulation, very good surface finish, used on


front face of wheels where no machining allowed.

DYCOTE D39

15

3:1 to 5:1

General use, good surface finish. Special for


wheels.

DYCOTE D39ESS

15

3:1 to 5:1

General use, good surface finish. Special for


wheels. Extra binder.

DYCOTE

Description

Primer
DYCOTE DR87
Insulating Coatings

21

Average
grain size

Dillution
Vol water
Vol coating

DYCOTE 140

30

3:1 to 5:1

Average insulation average surface finish, used for


general engineering castings.

DYCOTE 140ESS

30

3:1 to 5:1

Average insulation, average surface finish, used


for general engineering castings. Extra binder.

DYCOTE F140

35

3:1 to 5:1

Insulating DYCOTE with medium particles for


general applications.

DYCOTE 2040

35

1:1 to 3:1

Insulating DYCOTE with medium particles for


automotive castings offering longer lifetime.

DYCOTE 2050

35

1:1 to 3:1

Medium insulation. DYCOTE for thicker section


automotive castings offering longer lifetime, better
surface finish than 2040.

DYCOTE 3950

10

1:1 to 3:1

Low insulation, very good surface finish, used on


front face of wheels where no machining allowed.
Offering longer lifetime.

DYCOTE 3975

30

1:1 to 3:1

Very smooth coating where release is vital. Contains Boron Nitride.

DYCOTE D7039

75

3:1 to 5:1

Coarse coating with good surface finish.

DYCOTE DBN120

35

10:1 to 20:1

Smooth surface finish with long life. Contains


Boron Nitride. Wheel castings.

DYCOTE DBN130

50

10:1 to 20:1

Good surface finish with long life.


Contains Boron Nitride. Wheel castings.

DYCOTE DBN7039

75

3:1 to 5:1

Coarse coating with good surface finish. Contains


Boron Nitride.

DYCOTE

22

Description

DYCOTE

Average
grain size

Dillution
Vol water
Vol coating

Description

Heat conducting coatings


DYCOTE 40

Only use
mineral oil.

Oil graphite blend for slides and moving parts.

DYCOTE 11

15

DYCOTE E11

20

DYCOTE 11 I

70

5:1 to 15:1

Semi-colloidal graphite. For fast cooling and good


release. Without binder.

DYCOTE 36

35

3:1 to 5:1

Coating with low insulating for dies with low draft


angles, ie difficult to extract casting.

DYCOTE F36

50

3:1 to 5:1

Medium insulating DYCOTE / good surface finishing


and good release for small pins with low draft
angles.

DYCOTE 38

25

10:1

Water-based graphite for release purposes. Thinner


than DYCOTE 11.

DYCOTE D38

10:1

Fully colloidal graphite lubricating coating without


binder.

DYCOTE D212F

70

5:1 to 15:1

Coarse graphite-based coating for release. Without


binder.

DYCOTE G26

10:1 to 30:1

Water based coating for brass, special for release


and cooling the die.

DYCOTE 61

30

10:1 to 30:1

Water based coating for brass, special for release


and cooling the die.

5:1 to 15:1

Water-based semi colloidal graphite for release of


castings from die. Without binder.

5:1 to 15:1

Similar application to DYCOTE 11.


Semi-colloidal graphite. Without binder.

23

Other

Description

DYCOTE HARDENER

Extra hardener for DYCOTE coatings. To add to DYCOTE coatings to


further improve adhesion on die.

DYCOTE 7029

High insulating paste for feeder and runner systems. Use with brush a
layer up to 3mm is possible. Application at
110-140 C. If necessary, dilute with water.

DYCOTE W

Coating for automatic ladles.

DYCOTE DURA

Average
grain size

Dillution
Vol water
Vol coating

Description

DYCOTE DURA is new family of coatings containing a novel binder system. These will offer
extended lifetime and therefore higher productivity.
DYCOTE DURA 300

See
datasheet

Very fine coating with extra good lifetime.


Typical application: wheel production in LPDC.

DYCOTE DURA 400

50

See
datasheet

Medium insulating coating with very


long lifetime. Example for an application:
automotive castings.

DYCOTE DURA 410

50

See
datasheet

Medium insulating coating with very long


lifetime.

DYCOTE DURA 420

35

See
datasheet

Fairly insulating coating with good surface


finish and very long lifetime.

DYCOTE DURA 500

78

See
datasheet

Highly insulating coating with very long lifetime, where good release in required. Example
for an application: automotive castings, tilt
castings.

DYCOTE DURA 510

78

See
datasheet

Insulating coating with very long lifetime.


Example for an application: automotive
castings, cylinder.

DYCOTE coatings are available in different pack sizes.


All DYCOTE coatings are frost sensitive, store between 5 and 25 C.

24

Selection of DYCOTE coatings


A number of factors must be taken into
consideration when selecting a DYCOTE.
The section thickness of the casting. One of
the main properties of a coating is its ability
to aid the filling of the die. When the casting
concerned has a thin section then a coarse
DYCOTE with high insulation properties should
be considered.
The surface finish requirement of a casting is
very important but coatings which give very
good surface finish make it more difficult to fill
the die because of the smooth surface of the
coating and because the insulation is not as
good as with a coarser coating. The balance of
surface finish and insulation will therefore be
a compromise.
The geometry of casting can also be critical
for good feeding. If a casting has certain

thick sections then a specific coating may be


required to help directional solidification.
Where a casting has small draft angles, because
of design, then a coating with excellent release
may be required.
The casting process may also influence DYCOTE
selection. For example low-pressure castings
can be made with smoother coatings as the
process enables the die to be filled more easily.
Some causes of problems experienced with
permanent die coatings
n 
Flaking Of Coating
n 
Coating Wears Away Quickly
n 
Coating Wont Stick To The Die
n 
Coating Is Too Rough
n 
Misruns / Cold Shuts

Coating wears away


quickly

Coating will not


adhere to the Die

Coating surface is
too uneven

Misruns / Cold
Shuts

Layer too thick

Spray distance too


great

Coating has been


frozen

Coating is underdiluted

Incorrect coating
selection

Coating underdiluted

Die too hot

Lack of die surface


preparation

Spray distance too


short

Insulating coating
layer too thin

Lack of surface
preparation - poor
cleaning

Coating underdiluted

Die temperature too


low / high

Plugged or worn
spray nozzle

Coating too smooth

Die temperature
too low

Coating has been


frozen

Coating layer too


thick

Contaminated
coating

Flaking of Coating

Low spray pressure

25

Appendix 1 Die cleaning with CO2


The technique known as cryogenic blasting
is carried out by projecting pellets of solid
carbon dioxide (dry ice) onto the die, instead
of the usual sand or metal shot. Use of nonabrasive dry ice removes the coating without
causing damage or wear to the die. In fact
the action performed is exclusively kinetic and
thermal. Carbon dioxide pellets, after striking
the surface of the die, sublimate (pass into the
vapour state) without producing deposits or
wetting the die. The temperature loss of the
die is very limited, and it is possible to proceed
with another coating in a short time.
With this system, which is becoming
increasingly popular in foundries, frequent
coatings can be applied, increasing the life of
the die and avoiding the problems met when
using sand or shot. A further advantage of this
process is that the die can be cleaned directly
on the casting machine, which reduces down
time. The disadvantage is, coatings with long
lifetimes may be difficult to remove with this
technique.

Figure 20: Sanblasting system

Figure 21: Parts of the sandblasting system

26

Appendix 2 - Coating Method Defects


Cause
Build up of coating material restricts airflow in
hole A, with consequent increase of air flow
in the hole opposite and direction of spray to
the obstructed side.
Remedy
Remove the build up (with diluents) without
using metal instruments that could damage
the nozzle.
Cause
1) Build up of coating material around the
nozzle on side B restricting the flow of
atomising air.
2) Air loss, or nozzle tilted or dented, or bent
needle.
Remedy
1) Remove the build up (with diluents) without
using metal instruments that could damage
the nozzle.
2) Change the nozzle and/or needle.

Cause
Air trapped in coating material, due to
absence or wear of the seals, defective collar
or punctured aspiration pipe.Remedy
Check all seals for tightness and check all
points where air might be sucked into the
coating material.

27

Cause
Spray split in two:
1) Air pressure too high.
2) Coating diffuser aperture too large in relation
to the dilution of the coating.
3) Shortage of product in the tank.
Remedy
1) Reduce air pressure.
2) Reduce aperture of diffuser (regulators C
and D).
Cause
Salt and pepper spray effect caused by
insufficient pressure or coating too thick.
Remedy
Increase spray pressure.

28

Foseco International Limited


Drayton Manor Business Park,
Tamworth, Staffordshire,
England B78 3TL
Phone: +44 (0)1827 262021
Fax:
+44 (0)1827 283725
www.foseco.com
Please contact your local Foseco team

*Foseco, the Logo and DYCOTE are trade marks of the Vesuvius Group,
registered in certain countries, used under licence. All rights reserved. No part
of this publication may be reproduced, stored in a retrieval system of any
nature or transmitted in any form or by any means, including photocopying and
recording, without the written permission of the copyright holder or as expressly
permitted by law. Applications for permission shall be made to the publisher at
the address mentioned.
Warning: The doing of an unauthorised act in relation to a copyright work may
result in both a civil claim for damages and criminal prosecution. All statement,
information and data contained herein are published as a guide and although
believed to be accurate and reliable (having regard to the manufacturers
practical experience) neither the manufacturer, licensor, seller nor publisher
represents nor warrants, expressly or impliedly: (1) their accuracy/reliability, (2)
that the use of the product(s) will not infringe third party rights, (3) that no
further safety measures are required to meet local legislation. The seller is not
authorised to make representations nor contract on behalf of the manufacturer/
licensor. All sales by the manufacturer/seller are based on their respective
conditions of sale available on request.
Foseco International Limited 05/11.

COMMITTED TO FOUNDRIES

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