PETSOC 09-07-18.PDF Gas Condensate Reservoir Performance
PETSOC 09-07-18.PDF Gas Condensate Reservoir Performance
PETSOC 09-07-18.PDF Gas Condensate Reservoir Performance
F.B. THOMAS
G. ANDERSEN
Chevron/Texaco
D.B. BENNION
Background
This paper discusses performance of gas condensate reservoirs.
These reservoirs have a reservoir temperature located between the
critical point and the cricondentherm on the reservoir fluids pressure-temperature diagram. This is the only unique and accurate
means of identifying gas condensate reservoirs; any other definition [condensate-gas ratio, C7+ molecular weight (MW) or C7+
API gravity] is specious and ersatz.
In these reservoirs, as the pressure drops, vapour and liquid
phases result. Capillary pressure causes phase interference which
usually reduces gas productivity. A cross-section of interesting
topics that show the complexities of gas-condensate reservoir production have been reported in the literature(1-7). All of the relevant
parameters, if well understood, will lead to more accurate evaluation of the amount of hydrocarbon in place, the rate at which the
resource can be produced and the optimization strategies as the
reservoir matures.
the very specific nature of this paper in quantifying phase behaviour-fluid flow coupling in the laboratory, it was considered important to provide a short commentary on sampling of gas condensate
fluids that form the foundation on which experimental gas condensate testing is built. Extensive treatment of this theme was beyond
the scope of the current paper.
Mole Fraction
Abstract
0.016
0.014
0.012
0.01
0.008
2 Months
4 Months 7 Months
0.006
0.004
0.002
0
Introduction
In this paper, retrograde condensate characterization and properties measurement, explicit relative permeability and two-phase dynamic steady-state measurements are discussed. Notwithstanding
C12 C13 C14 C15 C16 C17 C18 C19 C20 C21 C22 C23
Component
FIGURE 1: Heavy-end compositional changes.
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18
-320.4
-109.3
-76.6
-259.1
-128.0
-44.0
10.9
30.9
82.0
97.0
97 - 156
156 - 208.9
208.9 - 258.1
258.1 - 303.1
303.1 - 345
345 - 385
385 - 419
419 - 455
455 - 486
486 - 519.1
519.1 - 550
550 - 557
557 - 603
603 - 626
626 - 651.9
651.9 - 675
675 - 696.9
696.9 - 716
716 - 736
736 - 755.1
755.1 - 774
774.1 - 792
792.1 - 809.1
809.1 - 826
Above 826
120.0
162.0
178.0
214.0
Component
Name
Chemical
Symbol
Mole
Fraction
Mass
Fraction
Nitrogen
Carbon Dioxide
Hydrogen Sulphide
Methane
Ethane
Propane
i-Butane
n-Butane
i-Pentane
n-Pentane
Hexanes
Heptanes
Octanes
Nonanes
Decanes
Undecanes
Dodecanes
Tridecanes
Tetradecanes
Pentadecanes
Hexadecanes
Heptadecanes
Octadecanes
Nonadecanes
Eicosanes
Heneicosanes
Docosanes
Tricosanes
Tetracosanes
Pentacosanes
Hexacosanes
Heptacosanes
Octacosanes
Nonacosanes
Tricontanes Plus
N2
CO2
H2S
C1
C2
C3
i-C4
n-C4
i-C5
n-C5
C6
C7
C8
C9
C10
C11
C12
C13
C14
C15
C16
C17
C18
C19
C20
C21
C22
C23
C24
C25
C26
C27
C28
C29
C30+
0.0024
0.0201
0.0000
0.8243
0.0509
0.0346
0.0067
0.0106
0.0036
0.0025
0.0016
0.0022
0.0058
0.0036
0.0027
0.0024
0.0019
0.0022
0.0023
0.0015
0.0013
0.0011
0.0010
0.0006
0.0006
0.0005
0.0004
0.0004
0.0004
0.0004
0.0003
0.0003
0.0004
0.0004
0.0020
0.0026
0.0334
0.0000
0.4997
0.0578
0.0576
0.0146
0.0234
0.0098
0.0069
0.0053
0.0084
0.0248
0.0175
0.0146
0.0132
0.0116
0.0148
0.0162
0.0116
0.0109
0.0097
0.0093
0.0064
0.0061
0.0050
0.0050
0.0044
0.0044
0.0047
0.0043
0.0045
0.0053
0.0060
0.0428
C5H10
C6H12
C6H12
C7H14
0.0003
0.0012
0.0015
0.0022
0.0007
0.0039
0.0048
0.0082
Calculated Properties
Total Sample
Molecular Weight
26.48
C6+ Fraction
Molecular Weight
Mole Fraction
Density (g/cc)
176.28
0.0442
0.8303
C7+ Fraction
Molecular Weight
Mole Fraction
Density (g/cc)
172.08
0.0423
0.8338
C12+ Fraction
Molecular Weight
Mole Fraction
Density (g/cc)
270.68
0.0179
0.8746
C30+ Fraction
Molecular Weight
Mole Fraction
Density (g/cc)
554.15
0.0020
0.9807
Recombination Parameters
Gas-Oil Ratio (cc/cc)
Dead Oil Density (g/cc)
Dead Oil MW (g/mol)
2324.56
0.8265
167.84
NAPHTHENES
Cyclopentane
Methylcyclopentane
Cyclohexane
Methylcyclohexane
0.70
0.60
0.40
0.0015
0.0001
0.0006
0.0002
0.0004
1.0000
0.0045
0.0003
0.0024
0.0009
0.0017
1.0000
Note: Physical properties are calculated based on GPA 2145-00 physical constants.
0.80
0.50
AROMATICS
176.0
Benzene
C6H6
231.1
Toluene
C7H8
277 - 282
Ethylbenzene & p,m-Xylene C8H10
291.9
o-Xylene
C8H10
336.0
1, 2, 4-Trimethylbenzene
C9H12
Total
0.90
0.30
0.20
0.10
0.00
N2
CO2
H2S
C1
C2
C3
C4
C5
C6
C7
C8
C9
C10
C11
C12
C13
C14
C15
C16
C17
C18
C19
C20
C21
C22
C23
C24
C25
C26
C27
C28
C29
C30+
Boiling Point
(F)
ID.: 433-174
300
MW
API Gravity
Linear (MW)
250
V/Vtot
V/Vdp
Liquid MW
Retrograde Liquid
Accumulation (%)
16
14
12
10
8
6
4
2
0
Pressure (kPa)
200
45
40
35
30
25
API Gravity
y = -0.0001477x + 39.6578907
20
R2 = 0.9932095
+ 164.171257
15
100 y = 0.001573x
R2 = 0.996099
10
50
5
0
0
0
10,000 20,000 30,000 40,000 50,000 60,000 70,000
150
MOLECULAR MASS
Pressure (kPa)
MW
300
250
200
150
100
50
0
259.7
82.2
61.4
MW low
228.08
74.0
199.13
Flashed
165.01
163.61
113.3
40.7
48.6
20
Syn 40.7
57.8
Sep Liq
2,900
5,900
8,900
10,600
12,000
13,000
19,995
40,679
61,363
73,084
82,737
89,632
0.620
0.400
0.350
0.076
Gas
Viscosity
(mPas)
0.031
0.050
0.066
0.076
0.083
0.087
IFT
(mN/m)
3.40
0.95
0.25
0.00
times this volume or, in other words, 430 sequential recombinations of 700 cc and 43 l of separator liquid would be required.
As seen from Figure 3, the separator liquid possesses an MW
of 165 and, as shown, simply adding gas to the separator condensate in order to increase the bubblepoint of the condensate
phase to 40,679 kPa results in a MW of 164 instead of 228; essentially no significant selection has occurred in the components that
drop out. If one approaches the creation of the equilibrium lower
phase by trying to synthesize directly from the separator liquid
without complete vapourization and selective condensation, then
the lower phase will not be representative. The synthetic liquid at
40,679 kPa and 119C exhibited an IFT 25% lower than the actual
value, and the synthetic liquid had a GOR of 491 m3/m3 instead of
249 m3/m3.
Table 2 reports the properties that were measured for the phases
generated from the appropriate recombination and subsequent depletion path.
Provided
Plug#
, %
K, mD
, %
203A
209A
210AH
212AH
18.4
17.9
18.5
18.5
151
101
120
166
18.9
18.6
19.4
19.2
Stack 1
After Cleaning
Provided
K, mD
Stack 2
6.31
6.33
6.50
6.44
25.58
Khavg
136.06
Order*
After Cleaning
Plug#
, %
K, mD
, %
K, mD
216A
224B
225
225AH
17.3
17.0
17.1
16.3
32.2
25.0
31.0
25.3
18.0
17.6
17.8
17.7
39.9
34.4
40.7
32.7
* Huppler Ordering - 1 at injection and 4 at production end.
injected into the core. The pressure of 20,684 kPag (3,000 psi)
was thought to be conservative from a bottomhole flowing pressure over the first years of the field project. It was also thought
that phase interference effects would not be expected to be this serious for many years [reservoir pressure of 82,909 kPag (12,025
psi)]. Although there would be an initial distribution of condensate
along the stack, eventually the condensate would reach a critical
saturation above which it would start to flow. It was considered
that, due to the relatively homogeneous stack, the average critical
condensate saturation (CCS) measured would be representative of
the overall stack. Once the specific volume of dew point fluid was
injected, with its corresponding volume of condensate, equilibrium
gas was injected and the end-point permeability to equilibrium gas
was measured. Figure 5 shows the relative permeability relationship for the second stack. It shows a critical condensate saturation
of about 19% at which point the gas permeability had decreased to
17% of its original value. This Scc was considered high, but some
porous media has been reported with Scc values well in excess of
this(1).
Once the Scc had been attained, the stack was then flooded
with equilibrium condensate at 3,000 psi and the displacement
history-matched with a two-phase compressible relative permeability model. The trapped gas saturation was 12.6% of the pore
volume or 16.6% of the initial hydrocarbon in place. Following
the condensate saturation the equilibrium gas was then injected at
increasing rates up to a rate corresponding to field rates of 1274
E3M3 STP [45 MMscfD; wellbore of 21.6 cm (8.5 inches) and a
completion interval of 61 m (200 feet) 309 m3/ m2-day (1,013
scf/ft2-day)]. The residual condensate saturation to this high rate
was 43.3% of the trapped gas end-point condensate saturation. The
high-rate gas permeability was Forchheimer corrected to provide
a value of 24.8 mD or a regain permeability of 87.5% of the initial Kg value. Figure 6 shows the same relationship, but at 62,053
25.0
25.0
25.0
25.0
1-Swi
Hysteresis Gas
Liquid Perm
35
30
Scr
25
20
15
Scc = 19.4%
10
5
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
Gas Saturation
FIGURE 5: Results of condensate interference testing; Stack #2 Temperature = 246F and Pressure = 20,684 kPa.
July 2009, Volume 48, No. 7
6.49
6.23
6.34
6.35
3
4
1
2
Khavg
36.63
kPag (9,000 psi). Very little change was observed from the perspective of gas permeability reduction. For the higher pressure
regime, however, with only 2.2% liquid drop out, insufficient separator liquid was available and so a synthetic liquid was prepared.
It had properties that were not representative (GOR too high, IFT
too low). This synthetic liquid resulted, when flooded into the core
stack, in a high mass transfer displacement and was not deemed as
representative of hydrocarbon liquid imbibition.
Similar testing was done for the higher permeability stack. The
results from this testing are summarized as follows:
1. The high and low permeability stacks exhibited Scc values
of 14 and 19% respectively. Critical condensate saturation
changed very little as a function of IFT change from 3.4 to
0.25 mN/m (20,684 and 62,053 kPag 3,000 and 9,000 psi).
This is not unexpected since the larger porous features are
thought to govern the first condensate mobilized and is not
expected to be a strong function of IFT. Residual condensate saturation is considered to be a strong function of IFT,
although the data measured herein were insufficient to judge
conclusively (lack of available low IFT condensate phase).
2. The gas phase permeability at critical condensate saturation
(Scc) decreased by 60 and 84% for the high and low permeability stacks, respectively.
3. Trapped gas saturations were 13.5% PV for the high permeability stack at 20,684 kPag (3,000 psi) and 12.6% PV for the
low permeability stack. This may appear to be counterintuitive, but if the condensate phase is more wetting than the gas,
then the smaller porous features might exhibit a degree of
spontaneous imbibition that could reduce trapped gas more
than a more permeable core. The higher pressure trapped
gas saturations were not measured since the synthetic liquid
Gas Permeability
2
1
4
3
25.41
Gas Permeability
40
40
Order*
169
15.0
116
15.0
118
15.0
157
15.0
1-Swi
Liq. Perm
Hyst. Kg
35
30
25
20
15
Scc = 19.3%
10
5
0
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
Gas Saturation
FIGURE 6: Results of condensate interference testing; Stack #2 Temperature = 246F and Pressure = 62,053 kPa.
21
2000 cc/hr at
10,400 psi
200
300 cc/hr at
10,400 psi
150
100
160 cc/hr at
10,400 psi
50
0
0
refill pump
1,000
2,000
3,000
4,000
5,000
6,000
Time (s)
FIGURE 7: Differential pressure history - injection at 10,400 psi
and BPR at 6,000 psi.
Delta P (psi)
250
7
6
5
4
3
y = 0.7541711Ln(x) +
12.0105453
R2 = 0.5342982
2
1
0
0.00E+00
1.00E-05
2.00E-05
3.00E-05
4.00E-05
5.00E-05
Capillary Number
FIGURE 8: Gas permeability vs. capillary number.
fluid type, differential pressure, and superficial and pore-scale capillary numbers. The superficial capillary numbers were corrected
for porosity and immobile water saturation to reflect pore-scale
velocities; this corresponds to the columns of pore-scale capillary numbers. The viscosities of the phases were reported earlier
in Table 2.
Contrasting the permeabilities for the gas to those measured as
part of the critical condensate experimentation provides corroboration of the different methods. Figure 5 shows the gas-phase
permeability to be approximately 5 mD at the critical condensate
saturation, whereas Table 2 reports gas-phase permeabilities of 1
to 3 mD. The value of 2.9 mD would be expected to occur at about
25% condensate saturation from Figure 5, which may be the equilibrium saturation at which the accumulation of condensate ceased.
This would be expected since the residual condensate saturation is
always higher than the critical condensate saturation and the residual condensate saturation will largely dictate the end-point gas
permeability. The two techniques agree very well with each other.
On the basis of flux calculations, the highest capillary number that
was possible to run in the laboratory corresponded to rates of 318
E3m3 (11.25 MMscfD) compared to 1,274 E3m3 (45 MMscfD)
which was contemplated as the expected production rate at which
the operator would produce the well. Figure 8 shows the plot of
permeability as a function of capillary number. This relationship
suggests that, although rate may be increased, the permeability to
gas is already approaching asymptotic and, therefore, the rate used
in the experimentation is thought to yield gas permeabilities that
would be representative.
Table 4: Calculations for two-phase injection at 20,684 kpa (3,000 psi) back pressure.
Rate (cc/hr)
22
150
150
2,000
2,000
150
150
2,800
2,800
1,000
1,000
500
500
2,000
2,000
2,800
2,800
1,000
1,000
500
500
150
150
Kg (mD)
Kc (mD)
1.046709901
1.515201521
2.647926833
3.833099087
1.482839027
2.146535489
2.913648614
4.217753943
2.118341466
3.06647927
1.577488326
2.283548392
2.67178203
3.867631511
2.94987515
4.270194933
2.118341466
3.06647927
1.579168292
2.285980286
1.034538856
1.497582899
Fluid Type
Gas
Condensate
Gas
Condensate
Gas
Condensate
Gas
Condensate
Gas
Condensate
Gas
Condensate
Gas
Condensate
Gas
Condensate
Gas
Condensate
Gas
Condensate
Gas
Condensate
dP (psi)
Nca Gas Nca Liquid
85
6.996E-07
85
448
9.328E-06
448
60
6.996E-07
60
570
1.306E-05
570
280
4.664E-06
280
188
2.332E-06
188
444
9.328E-06
444
563
1.306E-05
563
280
4.664E-06
280
187.8
2.332E-06
187.8
86
6.996E-07
86
Pore Level
Nca Gas
4.910E-06
1.013E-06
6.546E-05
1.350E-05
4.910E-06
1.013E-06
9.165E-05
1.891E-05
3.273E-05
6.752E-06
1.637E-05
3.376E-06
6.546E-05
1.350E-05
9.165E-05
1.891E-05
3.273E-05
6.752E-06
1.637E-05
3.376E-06
4.910E-06
1.013E-06
Pore Level
Nca Liquid
7.107E-06
9.476E-05
7.107E-06
1.327E-04
4.738E-05
2.369E-05
9.476E-05
1.327E-04
4.738E-05
2.369E-05
7.107E-06
Table 5: Calculations for two-phase injection at 41368 kpa (6000 psi) back pressure.
Rate (cc/hr)
Kg (mD)
Kc (mD)
Fluid Type
dP (psi)
Nca Gas
Nca Liquid
Pore Level
Nca Gas
2.542E-06
1.464E-06
4.767E-06
2.744E-06
3.178E-05
1.830E-05
4.449E-05
2.561E-05
2.542E-06
1.464E-06
4.767E-06
2.744E-06
3.178E-05
1.830E-05
4.449E-05
2.561E-05
1.784E-05
3.345E-05
2.230E-04
3.122E-04
1.784E-05
3.345E-05
2.230E-04
3.122E-04
14.8
14.8
58.2
58.2
220.5
220.5
300
300
38
38
56.4
56.4
217.5
217.5
292.65
292.65
The values that derive from this plot place the permeabilities
in the range of gas-phase permeabilities that were observed just
above critical condensate saturation in the critical condensate
testing. This seems intuitively consistent and corroborates both experimental procedures.
Ultimately, flow in porous media should yield to quantification
by use of an expression, such as Equation (1). However, the function K(r) is not known and appears to be relatively specific to each
fluid and rock system. Some simulators use explicit relative permeability curves such as those in Figures 5 and 6, whereas others
use permeability as a function of capillary number (Figures 8
to 10).
dQ =
P
L
R Max
() ()
K r f r 2 rdr
............................................................... (1)
05
00
5.
05
E-
E-
50
4.
05
00
4.
05
E50
3.
05
E-
E-
00
3.
05
50
2.
05
E-
E-
00
2.
05
00
0.
Discussion
1.797E-04
Nca
1.284E-04
2.500E-05 3.000E-05
Capillary Number
E+
00
0.000E+00 5.000E-06
1.926E-05
50
0.5
1.027E-05
1.
06
1.5
1.797E-04
E-
1.284E-04
00
3
2.5
1.926E-05
1.
3.5
1.027E-05
E-
00
Gas
Condensate
Gas
Condensate
Gas
Condensate
Gas
Condensate
Gas
Condensate
Gas
Condensate
Gas
Condensate
Gas
Condensate
Permeability (mD)
Liquid Permeability
4.5
6.076439975
3.498076011
2.897271638
1.667897067
5.098146918
2.934893706
5.245993179
3.020005623
2.366613464
1.362408552
2.989737754
1.721127825
5.168466186
2.975374998
5.377748005
3.095854047
5.
160
160
300
300
2,000
2,000
2,800
2,800
160
160
300
300
2,000
2,000
2,800
2,800
Pore Level
Nca Liquid
Summary
The results of this work can be summarized as follows:
1. For explicit measurement of relative permeability in retrograde condensate reservoirs, the compositional path of the
flowing fluid in the reservoir must be followed in the preparation of fluids for the experiments.
2. Retrograde condensate resulted in a very rapid decrease in
gas permeability 60 and 84% reduction in Krg by the attainment of critical condensate saturation.
3. End-point saturations, such as trapped gas and residual condensate saturation, are sensitive to the level of interfacial tension (therefore, pressure). Critical condensate saturation was
much less sensitive to levels of IFT (pressure).
4. Two-phase testing as a function of capillary number indicated
an effective gas permeability very close to that measured by
the explicit relative permeability measurements at saturations
just higher than the critical condensate saturation.
5. The condensate and gas permeabilities measured during the
gas-phase hysteresis injection did not agree with those measured during the two-phase injection.
6. The two-phase injection approach and the protocol whereby
explicit measurements of relative permeability are performed
provide a very thorough gas-condensate reservoir data set
which are amenable for use in simulation and reservoir production forecasting.
Nomenclature
GCR
GOR
PBHF
Scc
=
=
=
=
REFERENCES
1. Chen, H.L., Wilson, S.D. and Monger-McClure, T.G., Determination of Relative Permeability and Recovery for North Sea
Gas-Condensate Reservoirs; SPE Reservoir Evaluation & Engineering, Vol. 2, No. 4, pp. 393-402, August 1999.
2. Melean, Y., Bureau, N. and Broseta, D., Interfacial Effects
in Gas-Condensate Recovery and Gas-Injection Processes; SPE Reservoir Evaluation & Engineering, Vol. 6, No. 4, pp. 244-254, August
2003.
3. Mott, R., Engineering Calculations of Gas-Condensate-Well Productivity; SPE Reservoir Evaluation & Engineering, Vol. 6, No. 5,
pp. 298-306, October 2003.
4. Kokal, S., Al-Dokhi, M. and Sayegh, S., Phase Behavior of
a Gas-Condensate/Water System; SPE Reservoir Evaluation & Engineering, Vol. 6, No. 6, pp. 412-420, December 2003.
5. Jessen, K. and Orr, JR., F.M., Gas Cycling and the Development
of Miscibility in Condensate Reservoirs; SPE Reservoir Evaluation
& Engineering, Vol. 7, No. 5, pp. 334-341, October 2004.
6. Fevang, O. and Whitson, C.H., Modeling Gas-Condensate Well
Deliverability; SPE Reservoir Engineering, Vol. 11, No. 4, pp. 221230, November 1996.
7. Saevareid, A., Whitson, C.H. and Fevang, O., An Engineering Approach to Measuring and Modeling Gas Condensate
Relative Permeabilities; paper SCA 9930 presented at the International Symposium for the Society of Core Analysts, Golden, CO, 1-4
August 1999..
8. Carlson, M.R. and Myer, J.W.G., Reduced Productivity Impairment for Fracture Stimulated Gas Condensate Wells; Journal of
Canadian Petroleum Technology, Special Edition, Vol. 38, No. 13,
Paper 97-10-19, pp. 1-9, 1999.
Appendix A
Calculation of Capillary Number
N CA =
kg
s2
kg
and =
m s
cc
hr
1 hr
1
1m
36, 005 11.401 cm2 100 cm
mN
kg
3.401
0.001
m
s2
(2.253) (0.9322)
0.031 0.001
kg
ms
N
mN
m
= 6.9963 10-7
Authors Biographies
Brent Thomas is Director of Phase Behaviour and EOR Research for Hycal Energy Research Laboratories Ltd., and a
Project Engineer working in the area of numerical analysis, phase interference in porous media and gas injection. He received
his Ph.D. from Washington University in
chemical engineering. Brent has over 25
years of domestic and international experience in the area of numerical simulation,
gas injection, phase behaviour, solids precipitation and chemical and thermal applications. He has authored/
co-authored numerous technical papers and received the 1992
Best Technical Paper of the Year award from the Petroleum Society (Experimental and Theoretical Studies of Solids Precipitation
from Reservoir Fluids). He was selected as a Distinguished Author
for the Petroleum Society in 1995. Brent was chosen to be a Distinguished Lecturer for the SPE in the area of gas condensate reservoirs in 2003/2004.
G. Andersen biography and photo not available.
Brant Bennion received his B.Sc. and
Ph.D. degrees in chemical and petroleum
engineering from the University of Calgary.
He has served in the Petroleum Society in a
number of capacities over the last two decades, including having been a Director of
the Petroleum Society on both the Calgary
Section and National Boards, and holding
various positions such as Continuing Education Director, Student Affairs Director, Secretary, CIPC Technical Program Chairman,
CIPC General Co-Chairman and Chairman, Chairman-Elect and
2002 Chairman of the Society. He is the former Chairman of the
Editorial Review Board of the JCPT and currently serves as a
member of the Board of Directors of the Petroleum Society Educational Trust Fund. He has served as a Distinguished Lecturer for
the Petroleum Society in 2003 and also as a Distinguished Lecturer for the SPE in 2001-2002. Brant has presented/co-authored/
published over 200 technical papers on a variety of topics related
to formation damage, flow in porous media, phase behaviour, over
and underbalanced drilling and enhanced oil recovery over the last
two decades. He received Best JCPT Published Technical Paper
of the Year awards from the Petroleum Society in 1993, 1995 and
2001 and also several Best Presented Paper awards from the CIPC.
Brant has lectured at the University of Calgary, as well as taught
courses on a worldwide basis in the petroleum industry in over 40
different countries.
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