196 5-95 PDF
196 5-95 PDF
196 5-95 PDF
Methods of testing
cement
Part 5: Pozzolanicity test for pozzolanic
cements
BS EN
196-5:1995
BS EN 196-5:1995
Cooperating organizations
The European Committee for Standardization (CEN), under whose supervision
this European Standard was prepared, comprises the national standards
organizations of the following countries:
Austria
Belgium
Denmark
Finland
France
Germany
Greece
Iceland
Ireland
Italy
Luxembourg
Netherlands
Norway
Portugal
Spain
Sweden
Switzerland
United Kingdom
Oesterreichisches Normungsinstitut
Institut belge de normalisation
Dansk Standard
Suomen Standardisoimisliito, r.y.
Association franaise de normalisation
Deutsches Institut fr Normung e.V.
Hellenic Organization for Standardization
Technological Institute of Iceland
National Standards Authority of Ireland
Ente Nazionale Italiano di Unificazione
Inspection du Travail et des Mines
Nederlands Normalisatie-instituut
Norges Standardiseringsforbund
Instituto Portugus da Qualidade
Asociacin Espaola de Normalizacin y Certificacin
Standardiseringskommissionen i Sverige
Association suisse de normalisation
British Standards Institution
Date
Comments
BS EN 196-5:1995
Contents
Cooperating organizations
National foreword
Foreword
Text of EN 196-5
National annex NA (informative) Determination
of endpoints
National annex NB (informative) Committees responsible
National annex NC (informative) Cross-references
BSI 02-1999
Page
Inside front cover
ii
2
3
Inside back cover
Inside back cover
Inside back cover
BS EN 196-5:1995
National foreword
This British Standard has been prepared under the direction of Technical
Committee B/516, Cement and lime. It is the English language version of
EN 196-5:1994 Methods of testing cement Part 5: Pozzolanicity test for
pozzolanic cement published by the European Committee for Standardization
(CEN). EN 196-5 was drawn up by CEN Technical Committee 51, Cement and
building limes, as Part 5 of a series on testing cement which was originally
accepted by CEN on 15 November 1985 and made available on 12 May 1987. The
UK gave a negative vote at the final voting stage and, under the CEN Rules then
in force, was not obliged to implement this Part. A second formal vote was taken
in November 1992 when the UK again gave a negative vote but, under the CEN
Rules now in force, is obliged to implement this Part. This British Standard
supersedes clause 15 of BS 4550-2:1970 and this clause is now deleted.
In this Part the reference procedure requires the endpoint of titrations to be
determined visually. However, for the standardization of the EDTA solution and
the determination of the calcium oxide concentration a more satisfactory
photometric procedure using the same indicator exists in EN 196-2. In the UK
this photometric endpoint determination, as indicated in National annex NA, is
preferred as an alternative.
A British Standard does not purport to include all the necessary provisions of a
contract. Users of British Standards are responsible for their correct application.
Compliance with a British Standard does not of itself confer immunity
from legal obligations.
Summary of pages
This document comprises a front cover, an inside front cover, pages i and ii,
the EN title page, pages 2 to 6, an inside back cover and a back cover.
This standard has been updated (see copyright date) and may have had
amendments incorporated. This will be indicated in the amendment table on
the inside front cover.
ii
BSI 02-1999
EUROPEAN STANDARD
EN 196-5
NORME EUROPENNE
December 1994
EUROPISCHE NORM
Supersedes EN 196-5:1987
ICS 91.100.10
Descriptors: Cements, pozzolans, chemical tests, determination of content, calcium hydroxide, EDTA, chemical reagents, apparatus
English version
Prfverfahren fr Zement
Teil 5: Prfung der Puzzolanitt von
Puzzolanzementen
CEN
European Committee for Standardization
Comit Europen de Normalisation
Europisches Komitee fr Normung
Central Secretariat: rue de Stassart 36, B-1050 Brussels
1994 Copyright reserved to CEN members
EN 196-5:1994
Foreword
Contents
Page
Foreword
2
1 Scope
3
2 Normative references
3
3 General requirements for testing
3
4 Preparation of a cement sample
3
5 Principle
3
6 Reagents
3
7 Apparatus
4
8 Standardization of solutions
4
9 Procedure
5
10 Results
6
Figure 1 Diagram for assessing pozzolanicity 6
BSI 02-1999
EN 196-5:1994
1 Scope
This European Standard describes the method of
measuring the pozzolanicity of pozzolanic cements
conforming to ENV 197-1. This standard does not
apply to Portland pozzolana cements or to
pozzolanas.
This method constitutes the reference procedure.
2 Normative references
This European Standard incorporates by dated or
undated reference, provisions from other
publications. These normative references are cited
at the appropriate places in the text and the
publications are listed hereafter. For dated
references, subsequent amendments to or revisions
of any of these publications apply to this European
Standard only when incorporated in it by
amendment or revision. For undated references the
latest edition of the publication referred to applies.
EN 196-2, Methods of testing cement
Part 2: Chemical analysis of cement.
EN 196-7, Methods of testing cement
Part 7: Methods of taking and preparing samples of
cement.
ENV 197-1, Cement Composition, specifications
and conformity criteria Part 1: Common cements.
ISO 385-1:1984, Laboratory glassware
Burettes Part 1: General requirements.
ISO 835-1:1981, Laboratory glassware
Graduated pipettes Part 1: General requirements.
ISO 3534:1977, Statistics Vocabulary and
symbols.
5 Principle
6 Reagents
1)
2)
8 days are sufficient if the test is positive at this stage (see 10.2).
BSI 02-1999
EN 196-5:1994
8 Standardization of solutions
8.1 Standardization of the EDTA solution
Weigh approximately 1 g of calcium carbonate (6.8)
to the nearest 0,0001 g and introduce into
the 250 ml beaker (7.6). Add approximately 100 ml
of water and, very carefully, 50 ml of dilute
hydrochloric acid (6.3) keeping the beaker covered
with a watch glass.
Stir with a glass rod and ensure that dissolution is
complete. Then transfer the solution into the 500 ml
volumetric flask (7.10), wash the beaker and watch
glass carefully with water, adding the washings to
the solution and make up the volume with water.
Pipette 50 ml of the solution into the 400 ml
beaker (7.6), dilute with approximately 150 ml of
water and add the quantity of sodium hydroxide
solution (6.7) necessary to achieve pH 13 (check the
pH by means of a pH meter or by indicator papers).
Add approximately 50 mg of murexide
indicator (6.11) and titrate by means of the
burette (7.8) against the EDTA solution (6.13) until
there is a steady colour change from purple to violet.
From the volume of EDTA solution used, calculate
the factor f1 of the EDTA solution by the formula:
7 Apparatus
7.1 500 ml cylindrical polyethylene container of
about 70 mm diameter with a pressure seal-plug
locked by a screw plug.
7.2 Wide stem funnel
7.3 Porcelain Buchner funnel of 60 mm inner
diameter.
7.4 Filter paper with low porosity (mean pore
diameter of about 2 4m).
7.5 250 ml vacuum flask.
7.6 250 ml and 400 ml beakers.
7.7 50 ml and 100 ml precision pipettes (class A of
ISO 835-1:1981).
7.8 50 ml precision burette (class A of
ISO 385-1: 1984).
7.9 Uniform temperature enclosure controlled
thermostatically at (40 0,5) C.
7.10 500 ml and 1 000 ml volumetric flasks.
7.11 250 ml conical flask.
(1)
where
f1
m1
V1
BSI 02-1999
EN 196-5:1994
where
f2
m2
V2
(3)
where
9 Procedure
V3
f2
3)
(4)
where
[CaO] is the calcium oxide concentration in
millimoles per litre;
V4
f1
8 days are sufficient if the test is positive at this stage (see 10.2).
BSI 02-1999
EN 196-5:1994
10 Results
BSI 02-1999
BS EN 196-5:1995
National annex NA (informative)
Determination of endpoints
NA.1 Standardization of the EDTA solution
A standardized solution of EDTA (see 8.1) is required for the determination of the calcium oxide
concentration (see 9.3). This standard specifies that the titration endpoint is determined visually, using
murexide as the indicator. However, the method described in 4.53.3 a) of BS EN 196-2:1995 utilizes a
photometric endpoint detector (see 5.11 of that standard), set at 620 nm when murexide indicator is used,
and is the preferred technique for EDTA standardization in the UK.
NA.2 Determination of the calcium oxide concentration
The determination of calcium oxide in cement (see 9.3) is described in 13.14 of BS EN 196-2:1995. That
method also utilizes a photometric endpoint detector (see NA.1) and is the preferred technique for calcium
oxide determination in the UK.
ISO 3534:1977
The British Standards corresponding to the European Standards referred to in the text are identical in
number and title with those given in clause 2.
BSI 02-1999
BSI
389 Chiswick High Road
London
W4 4AL
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|