MATERIAL SAFETY DATA SHEET

1. Product and Company Identification

Material name

Iso-Octenes

Revision date

04-27-2011

Version #

01

CAS #

Mixture

MSDS Number

418

Product use

This product is intended for use as a refinery feedstock, fuel or for use in engineered processes.
Use in other applications may result in higher exposures and require additional controls, such as
local exhaust ventilation and personal protective equipment.

Synonym(s)

isoctene; isooctene (dot); 1-pentene, 2,2,4-trimethyl

See section 16 for complete information.

Manufacturer/Supplier

Valero Marketing & Supply Company and Affiliates

P.O. Box 696000
San Antonio, TX 78269-6000
General Assistance 210-345-4593

Emergency

24 Hour Emergency 866-565-5220

1-800-424-9300 (CHEMTREC USA)

2. Hazards Identification
Physical state

Liquid.

Appearance

Colorless liquid.

Emergency overview

WARNING!
Flammable liquid and vapor. Will be easily ignited by heat, spark or flames. Heat may cause the
containers to explode.
Harmful if swallowed. Aspiration may cause lung damage. May cause skin and eye irritation. Mist
or vapor may be irritating to eyes and respiratory tract. In high concentrations, vapors and spray
mists are narcotic and may cause headache, fatigue, dizziness and nausea. Prolonged exposure
may cause chronic effects.

OSHA regulatory status

This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).

Potential health effects

Routes of exposure

Inhalation. Ingestion. Skin contact. Eye contact.

Eyes

Contact may cause eye irritation.

Skin

May cause skin irritation. Frequent or prolonged contact may defat and dry the skin, leading to
discomfort and dermatitis.

Inhalation

May be irritating to the respiratory tract. In high concentrations, vapors and spray mists are
narcotic and may cause headache, fatigue, dizziness and nausea. May cause breathing disorders
and lung damage. Prolonged inhalation may be harmful.

Ingestion

Harmful if swallowed. Ingestion may result in vomiting; aspiration (breathing) of vomitus into lungs
must be avoided as even small quantities may result in aspiration pneumonitis. Irritating to mouth,
throat, and stomach.

Target organs

Eyes. Liver. Respiratory system. Skin. Kidneys. Central nervous system.

Chronic effects

Liver injury may occur. Kidney injury may occur. May cause central nervous system disorder (e.g.,
narcosis involving a loss of coordination, weakness, fatigue, mental confusion and blurred vision)
and/or damage. Frequent or prolonged contact may defat and dry the skin, leading to discomfort
and dermatitis.

Signs and symptoms

Irritation of nose and throat. Irritation of eyes and mucous membranes. Skin irritation.
Unconsciousness. Corneal damage. Narcosis. Cyanosis (blue tissue condition, nails, lips, and/or
skin). Decrease in motor functions. Behavioral changes. Edema. Liver enlargement. Jaundice.
Conjunctivitis. Proteinuria. Defatting of the skin. Rash.

Potential environmental effects

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Iso-Octenes
902748
Prepared by 3E Company

CPH MSDS NA

Version #: 01

Revison date: 04-27-2011

Print date: 04-27-2011

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3. Composition / Information on Ingredients

Components

CAS #

Percent

2,4,4-Trimethyl-1-pentene

107-39-1

70 - 85

2,4,4-Trimethyl-2-pentene

107-40-4

15 - 30

4. First Aid Measures

First aid procedures
Eye contact

Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if symptoms persist.

Skin contact

Remove contaminated clothing and shoes. Wash off immediately with soap and plenty of water.
Get medical attention if irritation develops or persists. Wash clothing separately before reuse.
Destroy or thoroughly clean contaminated shoes. If high pressure injection under the skin occurs,
always seek medical attention.

Inhalation

Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.
Get medical attention.

Ingestion

Rinse mouth thoroughly. Do not induce vomiting without advice from poison control center. Do not
give mouth-to-mouth resuscitation. If vomiting occurs, keep head low so that stomach content
does not get into the lungs. Get medical attention immediately.

Notes to physician

In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation.
Symptoms may be delayed.

General advice

If exposed or concerned: get medical attention/advice. Ensure that medical personnel are aware
of the material(s) involved, and take precautions to protect themselves. Show this safety data
sheet to the doctor in attendance. Wash contaminated clothing before re-use.

5. Fire Fighting Measures

Flammable properties

Flammable by OSHA criteria. Containers may explode when heated.

Extinguishing media
Suitable extinguishing
media

Water spray. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).

Unsuitable extinguishing
media
Protection of firefighters
Specific hazards arising
from the chemical
Protective equipment and
precautions for firefighters

Do not use a solid water stream as it may scatter and spread fire.

Vapor may cause flash fire. Vapors can flow along surfaces to distant ignition source and flash
back. Sensitive to static discharge.
Wear full protective clothing, including helmet, self-contained positive pressure or pressure
demand breathing apparatus, protective clothing and face mask.

Fire fighting
equipment/instructions

Wear full protective clothing, including helmet, self-contained positive pressure or pressure
demand breathing apparatus, protective clothing and face mask. Withdraw immediately in case of
rising sound from venting safety devices or any discoloration of tanks due to fire. Fight fire from
maximum distance or use unmanned hose holders or monitor nozzles. Move containers from fire
area if you can do it without risk. In the event of fire, cool tanks with water spray. Cool containers
exposed to flames with water until well after the fire is out. For massive fire, use unmanned hose
holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Vapors may
form explosive air mixtures even at room temperature. Prevent buildup of vapors or gases to
explosive concentrations. Some of these materials, if spilled, may evaporate leaving a flammable
residue. Water runoff can cause environmental damage. Use compatible foam to minimize vapor
generation as needed.

Specific methods

In the event of fire and/or explosion do not breathe fumes. Use water spray to cool unopened
containers.

Hazardous combustion
products

Carbon monoxide. Carbon Dioxide. Hydrocarbons.

6. Accidental Release Measures

Personal precautions

Iso-Octenes
902748
Prepared by 3E Company

Keep unnecessary personnel away. Local authorities should be advised if significant spills cannot
be contained. Keep upwind. Keep out of low areas. Ventilate closed spaces before entering. Do
not touch damaged containers or spilled material unless wearing appropriate protective clothing.
See Section 8 of the MSDS for Personal Protective Equipment.

CPH MSDS NA

Version #: 01

Revison date: 04-27-2011

Print date: 04-27-2011

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Environmental precautions

If facility or operation has an "oil or hazardous substance contingency plan", activate its
procedures. Stay upwind and away from spill. Wear appropriate protective equipment including
respiratory protection as conditions warrant. Do not enter or stay in area unless monitoring
indicates that it is safe to do so. Isolate hazard area and restrict entry to emergency crew.
Flammable. Review Fire Fighting Measures, Section 5, before proceeding with clean up. Keep all
sources of ignition (flames , smoking, flares, etc.) and hot surfaces away from release. Contain
spill in smallest possible area. Recover as much product as possible (e.g. by vacuuming). Stop
leak if it can be done without risk. Use water spray to disperse vapors. Spilled material may be
absorbed by an appropriate absorbent, and then handled in accordance with environmental
regulations. Prevent spilled material from entering sewers, storm drains, other unauthorized
treatment or drainage systems and natural waterways. Contact fire authorities and appropriate
federal, state and local agencies. If spill of any amount is made into or upon navigable waters, the
contiguous zone, or adjoining shorelines, contact the National Response Center at
1-800-424-8802. For highway or railways spills, contact Chemtrec at 1-800-424-9300.

Methods for containment

Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak
if you can do so without risk. This material is a water pollutant and should be prevented from
contaminating soil or from entering sewage and drainage systems and bodies of water. Dike the
spilled material, where this is possible. Prevent entry into waterways, sewers, basements or
confined areas.

Methods for cleaning up

Use non-sparking tools and explosion-proof equipment.

Small Spills: Absorb spill with vermiculite or other inert material, then place in a container for
chemical waste. Clean surface thoroughly to remove residual contamination. This material and its
container must be disposed of as hazardous waste.
Large Spills: Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal. Prevent product from entering drains. Do not allow
material to contaminate ground water system. Should not be released into the environment.

Other information

Clean up in accordance with all applicable regulations.

7. Handling and Storage

Handling

Wear personal protective equipment. Do not breathe gas/fumes/vapor/spray. Avoid contact with
eyes, skin, and clothing. Do not taste or swallow. Avoid prolonged exposure. Use only with
adequate ventilation. Wash thoroughly after handling. The product is extremely flammable, and
explosive vapor/air mixtures may be formed even at normal room temperatures. DO NOT handle,
store or open near an open flame, sources of heat or sources of ignition. Protect material from
direct sunlight. Take precautionary measures against static discharges. All equipment used when
handling the product must be grounded. Use non-sparking tools and explosion-proof equipment.
When using, do not eat, drink or smoke. Avoid release to the environment.

Storage

Flammable liquid storage. Do not handle or store near an open flame, heat or other sources of
ignition. This material can accumulate static charge which may cause spark and become an
ignition source. The pressure in sealed containers can increase under the influence of heat. Keep
container tightly closed in a cool, well-ventilated place. Keep away from food, drink and animal
feedingstuffs. Keep out of the reach of children.

8. Exposure Controls / Personal Protection

Occupational exposure limits
US. ACGIH Threshold Limit Values
Material

Type

Value

Iso-Octenes (Mixture)

STEL
TWA

2.5 ppm
0.5 ppm

Material

Type

Value

Iso-Octenes (Mixture)

Ceiling
STEL
TWA

25 ppm
5 ppm
1 ppm

US. OSHA Table Z-2 (29 CFR 1910.1000)

Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)
Material

Type

Value

Iso-Octenes (Mixture)

STEL

8 mg/m3
2.5 ppm
1.6 mg/m3
0.5 ppm

TWA
Iso-Octenes
902748
Prepared by 3E Company

CPH MSDS NA

Version #: 01

Revison date: 04-27-2011

Print date: 04-27-2011

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Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and
Safety Regulation 296/97, as amended)
Material

Type

Value

Iso-Octenes (Mixture)

STEL
TWA

2.5 ppm
0.5 ppm

Canada. Ontario OELs. (Ministry of Labor - Control of Exposure to Biological or Chemical Agents)
Material

Type

Value

Iso-Octenes (Mixture)

STEL
TWA

2.5 ppm
0.5 ppm

Canada. Quebec OELS. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)
Material

Type

Value

Iso-Octenes (Mixture)

STEL

15.5 mg/m3
5 ppm
3 mg/m3
1 ppm

TWA
Mexico. Occupational Exposure Limit Values
Material

Type

Value

Iso-Octenes (Mixture)

STEL

16 mg/m3
5 ppm
3.2 mg/m3
1 ppm

TWA
Engineering controls

Provide adequate general and local exhaust ventilation. Use process enclosures, local exhaust
ventilation, or other engineering controls to control airborne levels below recommended exposure
limits. Use explosion-proof equipment.

Personal protective equipment

Eye / face protection

Wear safety glasses. If splash potential exists, wear full face shield or chemical goggles.

Skin protection

Wear chemical-resistant, impervious gloves. Full body suit and boots are recommended when
handling large volumes or in emergency situations. Flame retardant protective clothing is
recommended.

Respiratory protection

Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a
risk assessment indicates this is necessary. Respirator selection must be based on known or
anticipated exposure levels, the hazards of the product and the safe working limits of the selected
respirator. If workplace exposure limits for product or components are exceeded, NIOSH
approved equipment should be worn. Proper respirator selection should be determined by
adequately trained personnel, based on the contaminants, the degree of potential exposure and
published respiratory protection factors. This equipment should be available for nonroutine and
emergency use.

General hygiene
considerations

Consult supervisor for special handling instructions. Avoid contact with eyes. Avoid contact with
skin. Keep away from food and drink. Wash hands before breaks and immediately after handling
the product. Provide eyewash station and safety shower. Handle in accordance with good
industrial hygiene and safety practice.

9. Physical & Chemical Properties

Appearance

Colorless liquid.

Color

Colorless.

Odor

Gasoline

Odor threshold

Not available.

Physical state

Liquid.

Form

Liquid.

pH

Not available.

Melting point

-135.4 F (-93 C)

Freezing point

Not available.

Boiling point

214.5 F (101.4 C)

Flash point

31.7 F (-0.15 C) Closed Cup

Evaporation rate

Not available.

Iso-Octenes
902748
Prepared by 3E Company

CPH MSDS NA

Version #: 01

Revison date: 04-27-2011

Print date: 04-27-2011

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Flammability limits in air, upper, Not available.

% by volume
Flammability limits in air, lower, Not available.
% by volume
Vapor pressure

Not available.

Vapor density

3.8

Specific gravity

0.7

Solubility (water)

Very slightly soluble.

Partition coefficient
(n-octanol/water)

Not available.

Auto-ignition temperature

736 F (391.11 C) (2,4,4-Trimethyl-1-pentene)

Decomposition temperature

Not available.

Percent volatile

100 %

10. Chemical Stability & Reactivity Information

Chemical stability

Stable under normal temperature conditions and recommended use.

Conditions to avoid

Heat, flames and sparks. Ignition sources. Contact with incompatible materials. Do not pressurize,
cut, weld, braze, solder, drill, grind or expose empty containers to heat, flame, sparks, static
electricity, or other sources of ignition; they may explode and cause injury or death.

Incompatible materials

Strong oxidizing agents. Reducing agents. Acids. Alkalis.

Hazardous decomposition
products

Carbon oxides. Sulfur oxides. Nitrogen oxides (NOx). Hydrocarbons.

Possibility of hazardous
reactions

Hazardous polymerization does not occur.

11. Toxicological Information

Acute effects

Harmful: may cause lung damage if swallowed. May cause skin and eye irritation. Mist or vapor
may be irritating to eyes and respiratory tract. In high concentrations, vapors and spray mists are
narcotic and may cause headache, fatigue, dizziness and nausea.

Sensitization

This substance may have a potential for sensitization which may provoke an allergic reaction
among sensitive individuals.

Chronic effects

Danger of serious damage to health by prolonged exposure. Prolonged or repeated overexposure

may cause central nervous system, kidney, liver, and lung damage.

Subchronic effects

Liver and kidney damage may occur after prolonged and repeated exposure.

Neurological effects

May cause central nervous system disorder (e.g., narcosis involving a loss of coordination,
weakness, fatigue) and/or damage.

Further information

Symptoms may be delayed.

12. Ecological Information

Aquatic toxicity

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Persistence and
degradability

Not available.

Bioaccumulation /
Accumulation

No data available.

Partition coefficient
(n-octanol/water)

Not available.

Mobility in environmental
media

No data available.

13. Disposal Considerations

Waste codes

D001: Waste Flammable material with a flash point <140 F

Disposal instructions

Dispose in accordance with all applicable regulations. Dispose of this material and its container to
hazardous or special waste collection point. Incinerate the material under controlled conditions in
an approved incinerator. Do not allow this material to drain into sewers/water supplies. Do not
contaminate ponds, waterways or ditches with chemical or used container.

Iso-Octenes
902748
Prepared by 3E Company

CPH MSDS NA

Version #: 01

Revison date: 04-27-2011

Print date: 04-27-2011

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14. Transport Information

DOT
Basic shipping requirements:
UN1216
UN number
Isooctenes
Proper shipping name
3
Hazard class
II
Packing group
3
Labels required
Additional information:
IB2, T4, TP1
Special provisions
150
Packaging exceptions
202
Packaging non bulk
242
Packaging bulk
128
ERG number
IATA
Basic shipping requirements:
1216
UN number
Isooctene
Proper shipping name
3
Hazard class
II
Packing group
Additional information:
3H
ERG code
IMDG
Basic shipping requirements:
1216
UN number
ISOOCTENES
Proper shipping name
3
Hazard class
II
Packing group
F-E, S-D
EmS No.
TDG
Basic shipping requirements:
ISOOCTENE
Proper shipping name
3
Hazard class
UN1216
UN number
II
Packing group

15. Regulatory Information

US federal regulations

This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication

Standard 29 CFR 1910.1200 (OSHA) and 8 CCR 5194 (Cal/OSHA).
All components are on the U.S. EPA TSCA Inventory List.

TSCA Section 12(b) Export Notification(40 CFR 707, Subpt. D)

Not regulated.
CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)
None
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
Section 302 extremely
hazardous substance (40
CRF 355, Appendix A)

No

Section 311/312 (40 CFR

370)

Yes

Clean Air Act (CAA)

Iso-Octenes
902748
Prepared by 3E Company

HAPS list
Urban HAPS list
CPH MSDS NA

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Revison date: 04-27-2011

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Clean Water Act (CWA) Section

112(r) (40 CRF 68.130)

Hazardous substance
Priority pollutant
Toxic pollutant

Safe Drinking Water Act

(SDWA)

MCLG
MCL

Drug Enforcement
Administration (DEA) (21 CFR
1308.11-15)

Not controlled

WHMIS status

Controlled

WHMIS classification

B2 - Flammable/Combustible

WHMIS labeling

Inventory status
Country(s) or region
Australia

Inventory name
Australian Inventory of Chemical Substances (AICS)

On inventory (yes/no)*
Yes

Canada

Domestic Substances List (DSL)

Canada

Non-Domestic Substances List (NDSL)

China

Inventory of Existing Chemical Substances in China (IECSC)

Yes

Europe

European Inventory of Existing Commercial Chemical

Substances (EINECS)

Yes

Europe

European List of Notified Chemical Substances (ELINCS)

Japan

Inventory of Existing and New Chemical Substances (ENCS)

Yes

Korea

Existing Chemicals List (ECL)

Yes

New Zealand

New Zealand Inventory

Yes

Philippines

Philippine Inventory of Chemicals and Chemical Substances

(PICCS)

United States & Puerto Rico

Toxic Substances Control Act (TSCA) Inventory

Yes
No

No

No
Yes

*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

State regulations

WARNING: This product contains chemical(s) known to the State of California to cause cancer
and birth defects or other reproductive harm.

16. Other Information

Other information

Note: This Material Safety Data Sheet applies to the listed products and synonym descriptions for
Hazard Communication purposes only. Technical Specifications vary greatly depending on the
products and are not reflected in this document. Consult specification sheets for technical
information.

HMIS ratings

Health: 1
Flammability: 3
Physical hazard: 0

NFPA ratings

Health: 1
Flammability: 3
Instability: 0

Disclaimer

This Material Safety Data Sheet (MSDS) was prepared in accordance with 29 CFR 1910.1200 by
Valero Marketing & Supply Co., ("VALERO"). VALERO does not assume any liability arising out of
product use by others. The information, recommendations, and suggestions presented in this
MSDS are based upon test results and data believed to be reliable. The end user of the product
has the responsibility for evaluating the adequacy of the data under the conditions of use,
determining the safety, toxicity and suitability of the product under these conditions, and obtaining
additional or clarifying information where uncertainty exists. No guarantee expressed or implied is
made as to the effects of such use , the results to be obtained, or the safety and toxicity of the
product in any specific application. Furthermore, the information herein is not represented as
absolutely complete, since it is not practicable to provide all the scientific and study information in
the format of this document, plus additional information may be necessary under exceptional
conditions of use, or because of applicable laws or government regulations.

Issue date

04-27-2011

Iso-Octenes
902748
Prepared by 3E Company

CPH MSDS NA

Version #: 01

Revison date: 04-27-2011

Print date: 04-27-2011

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