Method Carbon
Method Carbon
Method Carbon
ZET
Bu almada Au (CN)7 kompleksinin sourulmas iin aktif karbon
kullanlmtr.
Al ayn aktif karbon numunesi kullanlarak bunlarn sourma
performanslar tespit edilmi, sourma kapasitesi ve kinetii her nu
munenin fiziksel ve kimyasal zellikleriyle karlatrlmtr.
ABSTRACT
This work presents a study of characterization of activated carbons
for the adsorption of Au (CN^ complex.
A comparative study of six samples of activated carbons, three
Brazilian and three produced out of Brazil was made in order to determine
their qualification for a performance in adsorption circuits in the extractive
metallurgy of gold. The adsorptive capacity and the kinetics of adsorption
were compared to the physical and chemical properties of each one. The
influence of poluant ions on the kinetics and loading capacity of
aurocyanide anion was also determined.
TRKYE X M L M A D E N C L K K O N G R E S , 1 9 9 3
427
1.
INTRODUCTION
EXPERIMENTAL PROCEDURE
2.1
2.1.1
Materials
Samples of Activated Carbon
428
Reagents
Methodology
429
VM
%
ASH MOIST.
X
X
5,79
6,34
1,72
3,26
4,02
2,83
0,50
0,50
91,70
98,00
91,88 6,36
82,99 10,55
86,48 7,86
88,21 9,64
1,76
6,46
5,66
2,15
3,65
4,29
8,55
6,74
0,47
0,50
0,50
0,45
98,00
98,00
92,49
90,40
95,00
97,00
2,43
1,88
1,60
2,65
3,80
2,82
pH VALUE
suspension filtrate
1110
1200
1230
850
1000
881
9,50
9,60
9,50
9,00
9,30
9,00
6,50
9,30
8,40
6,40
8,90
9,10
Loading Capacity
Table II.
pH
10
100,00
0,90
3,62
14,20
45,00
10,000
0,090
0,362
1,420
4,500
9,910
9,638
8,580
5,500
Carbon
Loading
X/M
24,78
32,13
42,90
54,8
430
Tabela I I I .
Activated
Carbon
Isotherm Coordinates P l o t t e d in F i g . 1
[Au]eq.
C
mg Au a d s . / g a. c .
X/M e x p .
X/M c a l c .
0,90
3,62
14,20
45,00
24,78
32,13
42,90
54,84
24,60
32,49
42,70
53,78
0,999
0,006
1,40
4,52
16,00
43,00
24,65
31,83
42,00
56,38
24,27
32,15
43,55
55,21
0,995
0,014
2,30
7,00
23,50
51,00
24,43
31,00
38,25
49,00
24,52
31,33
40,89
48,49
0,987
0,018
3,20
11,20
29,00
65,50
24,20
29,60
35,50
34,50
24,87
29,27
33,12
36,82
0,893
0,031
9,00
16,20
34,50
67,00
22,75
27,93
32,75
33,00
24,06
26,90
31,06
35,23
0,876
0,033
9,50
21,00
37,50
69,00
22,63
26,33
31,25
31,00
22,71
25,99
28,68
31,81
0,901
0,026
Table IV.
Activated
Carbon
1/n
Maximum Capacity
of the Adsorbent
(X/M) co
0,20
0,24
0,22
0,13
0,19
0,17
63
68
56
39
38
34
KgAu/t
A
B
C
D
E
F
R
Standard e r r o r
Squared
e s t . de X/M
25
22
20
21
16
15
431
3.3
Kinetics of Adsorption
Carvo Ativado
A
B
C
D
E
F
432
Cte.
Cinttica
h-1
590
828
776
200
147
212
K-value
kgAu/t
25
22
20
21
16
15
1/n
0.20
0.24
0.22
0.13
0.19
0.17
433
CONCLUSIONS
434
435
436
437
438