Unit 1: Structure, Bonding and Main Group Chemistry

Unit 1.
Unit 1: Structure, bonding and main group

chemistry
Topic 1.1: Atomic structure
Definitions (easy marks in the examso must learn!):
Atomic number (Z) of an element is the number of protons in the
nucleus of its atom.
Mass number of an isotope is the number of protons + the number of
neutrons in the nucleus.
Isotopes are atoms of the SAME element which have the SAME number
of protons but different number of neutrons. (I.e. they have the same
atomic number but different mass number)
Relative atomic mass (Ar) of an element is the average mass (taking
into account the relative abundance of each isotope) of the atoms of that
element relative to 1/12th the mass of a carbon-12 atom.
Relative isotopic mass is the mass of one isotope relative to 1/12th the
mass of a carbon-12 atom.
Relative molecular mass (Mr) of a substance is the sum of all the
relative atomic masses of its constituent atoms.
Molar mass is the mass of one mole of the substance. Units are grams
per mole and it is numerically equal to the relative molecular mass
1st ionisation energy is the amount of energy required per mole to
REMOVE one electron from each gaseous atom to form a singly
positive ion: E(g) --- E+(g) + e** Ionisation energies are always endothermic and relate to the formation
of a positive ion**
1st electron affinity is the energy change per mole for the ADDITION of
one electron to a gaseous atom to form a singly negative ion: E(g) + e- --- E-(g)
S block are elements in which the highest occupied energy level is an

s orbital. They are in groups 1 and 2.
Unit 1.1
**similar definition applies to p block (groups 3 to 7 and 0) and d block (Sc
to Zn) elements**
Youll learn more about the d block in unit 5.
Mass spectrometer: The basic principle: If something is moving and you subject it to a sideways force, instead of
moving in a straight line, it will move in a curve - deflected out of its
original path by the sideways force.
Suppose you had a cannonball travelling past you and you wanted to
deflect it as it went by you. All you've got is a jet of water from a hose-pipe
that you can squirt at it. Frankly, its not going to make a lot of difference!
Because the cannonball is so heavy, it will hardly be deflected at all from
its original course.
But suppose instead, you tried to deflect a table tennis ball travelling at
the same speed as the cannonball using the same jet of water. Because
this ball is so light, you will get a huge deflection.
The amount of deflection you will get for a given sideways force depends
on the mass of the ball. If you knew the speed of the ball and the size of
the force, you could calculate the mass of the ball if you knew what sort of
curved path it was deflected through. The less the deflection, the heavier
the ball.
Formula: r = mv/Bq
Where:
R = radius of deflection
m = mass of the ion being deflected
B = magnetic field strength
q = charge on the ion
**this formula isnt needed for EDEXCEL chemistry, but it helps

understanding the concept(physics people may come across this in their
course)**
Diagram: -
Unit 1.1
Ionisation
The vaporised sample passes into the ionisation chamber. The electrically
heated metal coil gives off electrons which are attracted to the electron
trap which is a positively charged plate.
The particles in the sample (atoms or molecules) are therefore bombarded
with a stream of electrons, and some of the collisions are energetic
enough to knock one or more electrons out of the sample particles to
make positive ions.
Most of the positive ions formed will carry a charge of +1 because it is
much more difficult to remove further electrons from an already positive
ion.
These positive ions are persuaded out into the rest of the machine by the
ion repeller which is another metal plate carrying a slight positive charge.
Unit 1.1
Acceleration
The positive ions are repelled away from the very positive ionisation
chamber and pass through three slits, the final one of which is at 0 volts.
The middle slit carries some intermediate voltage. All the ions are
accelerated into a finely focused beam.
Basically, the electrons are accelerated by an electric field.
Deflection
Different ions are deflected by the magnetic field by different amounts.
Detection
Only ion stream B makes it right through the machine to the ion detector.
The other ions collide with the walls where they will pick up electrons and
be neutralised. Eventually, they get removed from the mass spectrometer
by the vacuum pump.
Unit 1.1
When an ion hits the metal box, its charge is neutralised by an electron
jumping from the metal on to the ion (right hand diagram). That leaves a
space amongst the electrons in the metal, and the electrons in the wire
shuffle along to fill it.
A flow of electrons in the wire is detected as an electric current which can
be amplified and recorded. The more ions arriving, the greater the current.
In short:
The spectrum is given by positive ions!

Metals and the noble gasses form singly positively charged ions in
the ratio of the abundance of their isotopes.
The relative atomic mass of an element can be calculated from
mass spectra data: -
Ar = the sum of (mass of each isotope x percentage of that isotope)/100

Example:Boron was analysed in a mass spectrometer. Calculate the relative atomic
mass of boron using the results below:
Peaks at m/e of
10.0
11.0
Abundance (%)
18.7
81.3
Answer: Ar = (10.0 x 18.7 + 11.0 x 81.3) / 100 = 10.8

**you can apply this to any question of this type**
Electron structure (facts!)
The first shell only has an s orbital

The second shell has one s and three p orbitals
The third and subsequent shells have one s, three p and 5 d orbitals
Each orbital can hold a max. of 2 electrons
Unit 1.1
So the order of filling is: -
1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6
etc
Electronic Configuration can be predicted. If the following rules are

followed:
1.
Electrons go into lower energy levels before higher ones.
2.
Electrons go into lower subshells before higher ones.
3.
Electrons occupy orbitals with 1 electron rather than 2 if possible.
Sizes of atoms and ions
The atoms become smaller going across a period from left to right,
because the nuclear charge increases, pulling the electrons in
closer, though the number of shells is the same.
The atoms get bigger going down a group because there are
more shells of electrons.
A positive ion is smaller than the neutral atom from which it
was made, because the ion has one shell fewer than the atom.
A negative ion is bigger than the neutral atom, because the
extra repulsion between electrons causes them to spread out.
***In an atom, the outer electrons are shielded from the pull of the nucleus
by the electrons in shells nearer to the nucleus***
1st ionisation energy
This is a general increase going from left to right across a period. Its
caused mainly by the increased nuclear charge (atomic number)
without an increase in the number of inner shielding electrons.
Unit 1.1
There are slight decreases after group 2 (this is because, for group
3, it is easier to remove an electron from the higher energy p
orbital), and after group 5 (because for group 6, the repulsion of the
two electrons in the p orbital makes it easier to remove one of
them).
There is a decrease going down a group. This is caused by the

outer electron being further away from the nucleus. (The extra
nuclear charge is balanced by the same extra number of inner
shielding electrons).
Successive ionisation energies
The 2nd ionisation energy of an element is always bigger than the

first, because the 2nd electron is removed from a positive electron.
When there is a very big jump in the value of successive ionisation
energies, an electron is being removed from a lower shell, e.g. if this
jump happens from the 4th to the 5th ionisation energy, four
electrons have been removed from the outer shell during the first
four ionisations, and so the element is in Group 4.
Electron affinity
1st electron affinity values are always negative (exothermic), as a

negative electron is being brought towards the positive nucleus in a
neutral atom.
***They are most exothermic for the halogens***
The 2nd electron affinity values are often positive (endothermic),

because a negative electron is being added to a negative ion, so
extra energy is needed to overcome the effect.
Wellthat does it for Unit 1.1.I will post the rest of them also (when I
get time). The key to this unit is good memory! Most of the model
answers can be viewed above.
If you find memorizing the definitions difficult, write them each out 10
times and it will hopefully stick in your head!
Thanks for reading it .
- Mathemagician

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Unit 1: Structure, Bonding and Main Group Chemistry

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Unit 1.

Unit 1: Structure, bonding and main group

S block are elements in which the highest occupied energy level is an

**this formula isnt needed for EDEXCEL chemistry, but it helps

Different ions are deflected by the magnetic field by different amounts.

The spectrum is given by positive ions!

Ar = the sum of (mass of each isotope x percentage of that isotope)/100

Answer: Ar = (10.0 x 18.7 + 11.0 x 81.3) / 100 = 10.8

Electron structure (facts!)

The first shell only has an s orbital

So the order of filling is: -

1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6

Electronic Configuration can be predicted. If the following rules are

Sizes of atoms and ions

1st ionisation energy

There is a decrease going down a group. This is caused by the

Successive ionisation energies

The 2nd ionisation energy of an element is always bigger than the

1st electron affinity values are always negative (exothermic), as a

The 2nd electron affinity values are often positive (endothermic),

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