Materials. The Constituent Materials of A Composite Have Significantly Different Properties. Further, It
Materials. The Constituent Materials of A Composite Have Significantly Different Properties. Further, It
Materials. The Constituent Materials of A Composite Have Significantly Different Properties. Further, It
There is an unabated quest for new materials which will satisfy the specific requirements for various
applications like structural, medical, house-hold, industrial, construction, transportation, electrical;
electronics, etc. Metals are the most commonly used materials in these applications. In the yore of time,
there have been specific requirements on the properties of these materials. It is impossible of any
material to fulfill all these properties. Hence, newer materials are developed. In the course, we are going
to learn more about composite materials. First, we will deal with primary understanding of these
materials
and
then
we
will
learn
the
mechanics
of
these
materials.
Definition of a Composite Material
A composite material is defined as a material which is composed of two or more materials at a
microscopic scale and has chemically distinct phases.
Thus, a composite material is heterogeneous at a microscopic scale but statistically homogeneous at
macroscopic scale. The materials which form the composite are also called as constituents orconstituent
materials. The constituent materials of a composite have significantly different properties. Further, it
should be noted that the properties of the composite formed may not be obtained from these constituents.
However, a combination of two or more materials with significant properties will not suffice to be called
as a composite material. In general, the following conditions must be satisfied to be called a composite
material:
1. The combination of materials should result in significant property changes. One can see
significant changes when one of the constituent material is in platelet or fibrous from.
2. The content of the constituents is generally more than 10% (by volume).
3. In general, property of one constituent is much greater
than the corresponding
property of the other constituent.
The composite materials can be natural or artificially made materials. In the following section we will
see the examples of these materials.
Why we need these materials?
There is unabated thirst for new materials with improved desired properties. All the desired properties are
difficult to find in a single material. For example, a material which needs high fatigue life may not be
cost effective. The list of the desired properties, depending upon the requirement of the application, is
given below.
1. Strength
2. Stiffness
3. Toughness
4. High corrosion resistance
5. High wear resistance
6. High chemical resistance
7. High environmental degradation resistance
8. Reduced weight
9. High fatigue life
10. Thermal insulation or conductivity
of their planes. Thus, these are very effective reinforcement components. The flakes can be
packed more densely when they are laid parallel, even denser than unidirectional fibres and
spheres. For example, aluminum flakes are used in paints. They align themselves parallel to the
surface of the coating which imparts the good properties.
4. Whiskers: These are nearly perfect single crystal fibres. These are short, discontinuous and
polygonal in cross-section.
5. The classification of composites based on the form of reinforcement is shown in Figure 1.2. The
detailed classification further is given in Figure 1.3. The classification of particulate composites is
depicted further in Figure 1.4. Some of the terms used in these classifications will be explained in
the following paragraphs/lectures.
b) The quality of load transfer between fibre and matrix depends upon the surface area between fibre and
matrix. If the surface area between fibre and matrix is more, better is the load transfer. It can be shown
that for given volume of fibres in a composite, the surface area between fibre and matrix increases if the
fibre diameter decreases.
Let
be the average diameter of the fibres, be the length of the fibres and be the number of fibres
for a given volume of fibres in a composite. Then the surface area available for load transfer is
(1.1)
The volume of these fibres in a composite is
(1.2)
Now, let us replace the fibres with a smaller average diameter of such that the volume of the fibres is
unchanged. Then the number of fibres required to maintain the same fibre volume is
(1.3)
The new surface area between fibre and matrix is
(1.4)
Thus, for a given volume of fibres in a composite, the area between fibre and matrix is inversely
proportional to the average diameter of the fibres.
c) The fibres should be flexible so that they can be bent easily without breaking. This property of the
fibres is very important for woven composites. In woven composites the flexibility of fibres plays an
important role. Ultra thin composites are used in deployable structures.
The flexibility is simply the inverse of the bending stiffness. From mechanics of solids study the bending
stiffness is EI, where is Youngs modulus of the material and is the second moment of area of the
cross section of the fibre. For a cylindrical fibre, the second moment of area is
(1.5)
A. Natural fibres and
Thus,
B. Advanced fibres
(1.6)
A. Natural fibres Flexibility
The
fibres
are equation
divided into
sub is
categories.
Thus,natural
from the
above
it isfollowing
clear that three
if a fibre
thin, i.e. small in diameter, it is more flexible.
o Animal fibers: silk, wool, spider silk, sinew, camel hair, etc.
o Materials
Plant/vegetable
fibers: cotton (seed), jute (stem), hemp (stem), sisal (leaf), ramie,
Reinforcement:
and Forms
bamboo, maze, sugarcane, banana, kapok, coir, abaca, kenaf, flax, raffia palm, etc.
o Mineral fibers: asbestos, basalt, mineral wool, glass wool.
What
the types
of fibres? fibers:
B. are
Natural
fibresAdvanced
Theadvanced
fibres thatfibre
are used
in theas
fabrication
of a has
composite
can be divided
two
categories
An
is defined
a fibre which
a high specific
stiffnessinto
(that
is,broad
ratio of
Youngsas
follows:
modulus to the density of the material,
) and a high specific strength (that is the ratio of ultimate
strength to the density of the material,
).
3.
4.
5.
6.
Alumina
Aramid
Silicon carbide
Sapphire
Matrix Materials
Introduction
In the previous lecture we have introduced various advanced fibres along with their fabrication
processes, precursor materials and key features. In the present lecture we will introduce some matrix
materials, their key features and applications.
What are the matrix materials used in composites?
The matrix materials used in composites can be broadly categorized as: Polymers, Metals, Ceramics
and Carbon and Graphite.
The polymeric matrix materials are further divided into:
1. Thermoplastic which soften upon heating and can be reshaped with heat and pressure.
2. Thermoset which become cross linked during fabrication and does not soften upon
reheating.
The metal matrix materials are: Aluminum, Copper and Titanium.
The ceramic materials are: Carbon, Silicon carbide, Silicon nitride.
The classification of matrix materials is shown in Figure 1.11.
Thermosets
Difficult to repair
Can be re-processed
What are the common metals used as matrix materials? What are their advantages and
disadvantages?
The common metals used as matrix materials are aluminum, titanium and copper.
Advantages:
1. Higher transfer strength,
2. High toughness (in contrast with brittle behavior of polymers and ceramics)
3. The absence of moisture and
4. High thermal conductivity (copper and aluminum).
Dis-advantages:
1. Heavier
2. More susceptible to interface degradation at the fiber/matrix interface and
3. Corrosion is a major problem for the metals
The attractive feature of the metal matrix composites is the higher temperature use. The aluminum
matrix composite can be used in the temperature range upward of 300C while the titanium matrix
composites can be used above 800 .
What are the ceramic matrix materials? What are their advantages and disadvantages?
The carbon, silicon carbide and silicon nitride are ceramics and used as matrix materials.
Ceramic:
The advantages of the ceramic matrix materials are:
1. The ceramic composites have very high temperature range of above 2000
.
2. High elastic modulus
3. Low density
The disadvantages of the ceramic matrix materials are:
1. The ceramics are very brittle in nature.
2. Hence, they are susceptible to flows.
Carbon
The advantages of the carbon matrix materials are:
1. High temperature at 2200 .
25.
26.
27.
28.
29.
30.
31.
32.
33.
34.
35.
36.
37.
38.
like handle and dense construction. They find applications in stretch fabrics, lingerie, rain wear,
etc.
Monofilament: A large diameter continuous fiber, generally, with a diameter greater than 100
m.
Nonwovens: Randomly arranged fibers without making fiber yarns. Nonwovens can be formed
by spunbonding, resinbonding, or needle punching. A planar sheet-like fabric is produced from
fibers without going through the yarns spinning step. Chemical bonding and/or mechanical
interlocking is achieved. Fibers (continuous or staple) are dispersed in a fluid (i.e. a liquid or air)
and laid in a sheet-like planar form on a support and then chemically bonded or mechanically
interlocked. Paper is perhaps the best example of a wet laid nonwoven fabric where we generally
use wood or cellulosic fibers. In spunbonded nonwovens, continuous fibers are extruded and
collected in random planar network and bonded.
Particle: Extreme case of a fibrous form: it has a more or less equiaxial form, i.e. the aspect ratio
is about 1.
Plaiting: see Braiding.
Rayon: Term use to designate any of the regenerated fibers made by the viscose,
cuprammonium, or acetate processes. They are considered to be natural fibers because they are
made from regenerated, natural cellulose.
Retting: A biological process of degrading pectin and lignin associated with vegetable fibers,
loosening the stem and fibers, followed by their separation.
Ribbon: Fiber of rectangular cross-section with width to thickness ratio greater than 4.
Rope: Linear flexible structure with a minimum diameter of 4mm. it generally has three strands
twisted together in a helix. The rope characteristics are defined by two parameters, unit mass and
break length. Unit mass is simply g/m or ktex, while breaking length is the length of rope that will
break under the force of its own weight when freely suspended. Thus, break length equals mass at
break/unit mass.
Roving: A bundle of yarns or tows of continuous filaments (twisted or untwisted).
Spinneret: A vessel with numerous shaped holes at the bottom through which a material in
molten state is forced out in the form of fine filaments or threads.
Spunbonding: Process of producing a bond between nonwoven fibers by heating the fibers to
near their melting point.
Staple fiber: Fibers having short, discrete lengths (10-400 mm long) that can be spun into a yarn
are called staple fibers. This spinning quality can be improved if the fiber is imparted a waviness
or crimp. Staple fibers are excellent for providing bulkiness for filling, filtration, etc. Frequently,
staple natural fibers, e.g. cotton or wool, are blended with staple synthetic fibers, e.g. nylon or
polyester, to obtain the best of both types.
Tenacity: A measure of fiber strength that is commonly used in the textile industry. Commonly,
the units are gram-force per denier, gram-force per tex, or Newton per tex. It is a specific strength
unit, i.e. there is a factor of density involved. Thus, although the tensile strength of glass fiber is
more than double that of nylon fiber, both glass and nylon fiber have a tenacity of about 6g/den.
This is because the density of glass is about twice that of nylon.
Tex: A unit of linear density. It is the weight in grams of 1000m of yarn. Tex is commonly used
in Europe.
39. Tow: Bundle of twisted or untwisted continuous fibers. A tow may contain tens or hundreds of
thousands of individual filaments.
40. Twist: the angle of twist that individual filaments may have about the yarn axis. Most yarns have
filaments twisted because it is easier to handle a twisted yarn then an untwisted one.
41. Wire: Metallic filament.
42. Warp: Lengthwise yarn in a woven fabric.
43. Weft: Transverse yarn in a woven fabric. Also called fill.
44. Whisker: Tiny, whisker-like fiber (a few mm long, a few m in diameter) that is a single crystal
and almost free of dislocations. Note that this term involves a material requirement. The small
size and crystalline perfection make whiskers extremely strong, approaching the theoretical
strength.
45. Woven fabric: Flat, drapeable sheet made by interlacing yarns or tows.
46. Woven roving: Heavy, drapeable fabric woven from continuous rovings.
47. Yarn: A generic term for a bundle of untwisted or twisted fibers (short or continuous). A yarn can
be produced from staple fibers by yarn spinning. The yarn spinning process consists of some fiber
alignment, followed by locking together by twisting. Continuous synthetic fibers are also used to
make yarns. Continuous fibers are easy to align parallel to the yarn axis. Generally, the degree of
twist is low, just enough to give some interfilament cohesion.
What are the advantages of the composite materials?
The following are the advantages of composites:
1. Specific stiffness and specific strength:
The composite materials have high specific stiffness and strengths. Thus, these material offer
better properties at lesser weight as compared to conventional materials. Due to this, one gets
improved performance at reduced energy consumption.
2. Tailorable design:
A large set of design parameters are available to choose from. Thus, making the design
procedure more versatile. The available design parameters are:
1. Choice of materials (fiber/matrix), volume fraction of fiber and matrix, fabrication
method, layer orientation, no. of layer/laminae in a given direction, thickness of
individual layers, type of layers (fabric/unidirectional) stacking sequence.
2. A component can be designed to have desired properties in specific directions.
3. Fatigue Life:
The composites can with stand more number of fatigue cycles than that of aluminum. The
critical structural components in aircraft require high fatigue life. The use of composites in
fabrication of such structural components is thus justified.
4. Dimensional Stability:
Strain due to temperature can change shape, size, increase friction, wear and thermal stresses.
The dimensional stability is very important in application like space antenna. For composites,
with proper design it is possible to achieve almost zero coefficient of thermal expansion.
5. Corrosion Resistance:
Polymer and ceramic matrix material used to make composites have high resistance to
corrosion from moisture, chemicals.
6. Cost Effective Fabrication:
The components fabricated from composite are cost effective with automated methods like
filament winding, pultrusion and tape laying. There is a lesser wastage of the raw materials as
the product is fabricated to the final product size unlike in metals.
7. Conductivity:
The conductivity of the composites can be achieved to make it a insulator or a highly
conducting material. For example, Glass/polyesters are non conducting materials. These
materials can be used in space ladders, booms etc. where one needs higher dimensional
stability, whereas copper matrix material gives a high thermal conductivity.
The list of advantages of composite is quite long. One can find more on advantages of composite in
reference books and open literature.
What are the disadvantages of Composites?
1. Some fabrics are very hard on tooling.
2. Hidden defects are difficult to locate.
3. Inspection may require special tools and processes.
4. Filament-wound parts may not be repairable. Repairing may introduce new problems.
What are the applications of the composite materials?
The applications of the composites are given in the following as per the area of application.
Aerospace:
Aircraft, spacecraft, satellites, space telescopes, space shuttle, space station, missiles, boosters
rockets, helicopters (due to high specific strength and stiffness) fatigue life, dimensional stability.
All composite voyager aircraft flew nonstop around the world with refueling.
Carbon/carbon composite is used on the leading edges nose cone of the shuttle.
B2 bomber - both fiber glass and graphite fibers are used with epoxy matrix and polyimide
matrix.
The indigenous Light Combat Aircraft (LCA - Tejas) has Kevlar composite in nose cone, Glass
composites in tail fin and carbon composites form almost all part of the fuselage and wings,
except the control surfaces of the wing.
Further, the indigenous Light Combat Helicopter (LCH Dhruvh) has carbon composites for its
main rotor blades. The other composites are used in tail rotor, vertical fin, stabilizer, cowling,
radome, doors, cockpit, side shells, etc.
Missile:
Rocket motor cases
Nozzles
Igniter
Inter stage structure
Equipment section
Aerodynamic fairings
Launch Vehicle:
Rocket motor case
Interstage structure
Payload fairings and dispensers
High temperature Nozzle
Nose cone
Control surfaces
Composite Railway Carrier:
Composite railway auto carrier
Bodies of Railway Bogeys
Seats
Drivers Cabin
Stabilization of Ballasted Rail Tracks
Doors
Sleepers for Railway Girder Bridges
Gear Case
Pantographs
Sports Equipments
Tennis rockets, golf clubs, base-ball bats, helmets, skis, hockey sticks, fishing rods, boat hulls,
wind surfing boards, water skis, sails, canoes and racing shells, paddles, yachting rope, speed
boat, scuba diving tanks, race cars reduced weight, maintenance, corrosion resistance.
Automotive
Lower weight and greater durability, corrosion resistance, fatigue life, wear and impact resistance.
Drive shafts, fan blades and shrouds, springs, bumpers, interior panels, tires, brake shoes, clutch
plates, gaskets, hoses, belts and engine parts.
Carbon and glass fiber composites pultruted over on aluminum cylinder to create drive shaft.
Fuel saving braking energy can be stored in to a carbon fiber super flywheels.
Other applications include: mirror housings, radiator end caps, air filter housing, accelerating
pedals, rear view mirrors, head-lamp housings, and intake manifolds, fuel tanks.
Infrastructure Structures:
Corrosion is a major design consideration such as in the chemical and on off- shore oil plate
forms
Skeletal Structures
Walls and Panels
Mechanical Properties
Compressive strength : stress a material can withstand before compressive failure (MPa)
Creep : the slow and gradual deformation of an object with respect to time
Fatigue limit : Maximum stress a material can withstand under repeated loading (MPa)
Flexural modulus : is the ratio of stress to strain in flexural deformation, or the tendency for a material
to bend. It is determined from the slope of a stress-strain curve produced by a flexural test and uses units
of force per area. It is an intensive property.
Flexural strength : also known as modulus of rupture, bend strength, or fracture strength, a mechanical
parameter for brittle material, is defined as a material's ability to resist deformation under load.
Fracture toughness : Energy absorbed by unit area before the fracture of material (J/m^2)
Shear strain :in the angle between two perpendicular lines in a plane
Tensile strength : Maximum tensile stress a material can withstand before failure (MPa)
Coefficient of restitution :