GEOSYNTHETICS RESEARCH AND APPLICATIONS IN THE

MINING AND MINERAL PROCESSING ENVIRONMENT

K. Renken
1
, D.M. Mchaina
2
, E.K. Yanful
3

1,3
Civil & Environmental Engineering, University of Western Ontario, London, ON, Canada N6A 5B9
1
Tel: (519) 850-3437, Fax: (519) 850-3439, krdesign@sympatico.ca
3
Tel: (519) 661-4069, Fax: (519) 661-3942, eyanful@eng.uwo.ca
2
53 Hillside Avenue, RR#2, Cambridge, ON, Canada N1R 5F3
Tel: (519) 624-3126, Fax: (519) 624-2111, dmchaina@hotmail.com


ABSTRACT

This paper presents research conducted under the 2003 North American Geosynthetics
Society Award of Excellence. The objective of the research was to investigate the use of
geosynthetics in the mining and processing sector and to summarize field performance results
related to geomembrane (GM), geosynthetic clay liners (GCLs) and geogrid applications. The
paper commences with a summary of challenges in environmental mine management and
formulates key questions for determining the suitability of geosynthetics for a particular
application. Examples of case studies are then reviewed, including: 1) GCLs covered with
shallow soil covers to limit infiltration and possibly acid rock drainage (ARD); 2) GCLs installed
below GMs; 3) estimation of the longevity of high density polyethylene (HDPE) exposed to
ARD; 4) use of geogrid to cover a ponded area on a tailings impoundment; and 5) use of HDPE
to cover tailings. Technical considerations for GCL and GM installations are presented and
polymer degradation mechanisms are summarized to put current practice in the mining industry
in perspective. Areas requiring further research are identified.

It was found that the mining and mineral processing industry is moving more and more
towards the use of geosynthetics for civil, geotechnical and environmental engineering
applications. Geosynthetic liners and collection pipes for heap leach operations are widely used
and ever higher target heap heights are fostering the development of new design, laboratory
testing, and construction methods. The duration of the service life of geosynthetics and their
cost-effectiveness compared to other available alternatives are the main concerns facing the
mining and mineral processing industry, especially for their use in long-term geotechnical and
environmental control.

Keywords: geomembrane, GM, GCL, mining, waste containment


1. INTRODUCTION

The geosynthetics industry has been growing rapidly in the past 25 years and
geosynthetic materials have become common features in many modern civil, geotechnical and
environmental engineering applications. At mine sites, geomembranes (GMs) have been
primarily used for liquid containment (drainage waters, process solutions, treatment ponds), as
basal liners for heap leach facilities or other solid waste facilities, and to some extent, for tailings


impoundments. Reclaimed fill structures may also include relatively impervious GM liner caps
to prevent precipitation from infiltrating into the underlying fill materials to achieve full
containment or diversion of liquids. Geogrids have been used to stabilize soft soils for road
construction and mine tailings for soil cover placement. Geopipes are used for conveyance of
runoff, drainage, process waters, or for leak detection around mine sites. Table 1 summarizes
common types of geosynthetics and their application in the mining industry.

Table 1. Common Geosynthetic Materials and Applications in the Mining Industry















The suitability of geosynthetics for long-term applications for waste containment in the
mining industry is still being scructinized. Although laboratory tests predict lifespans of up to
several hundred years for materials such as HDPE (Koerner, 2004), manufacturers are willing to
warranty their products (materials and their replacement) for up to 20-30 years (e.g. Colorado
Lining International, 2005). While short and medium term (up to ~ 30 years) geosynthetics
performance data is available, long-term field performance data is non-existent and available
predictions have been based on a variety of laboratory tests and modeling to date. In addition,
unsatisfactory field performance results have been reported and have prompted the geosynthetics
industry to improve their products and respective user guidelines (Melchior, 2002; Rollin, 2004;
Koerner, 2004; Koerner and Koerner, 2005). These factors may be contributing reasons for the
limited use of geosynthetics to address long-term issues such as the control of Metal Leaching
(ML) and acid rock drainage (ARD).

1.1 Objectives and Scope

This paper presents research conducted under the 2003 North American Geosynthetics
Award of Excellence awarded by The North American Geosynthetics Society (NAGS). The
objective of the research was to investigate the use of geosynthetics in the mining and processing
sector and to summarize field performance results and technical considerations related to
geomembranes (GMs), geosynthetic clay liners (GCLs) and geogrid applications. The study
methodology included but was not limited to a questionnaire sent to the mining industry,
individual industry contacts, personal communication with consultants and colleagues, and
literature review. To meet the objectives, challenges in environmental mine management were
reviewed, pertinent case studies of geosynthetic use were identified, technical considerations
Geosynthetic
Material
Polymer Type Principal Application
Geomembranes HDPE, LLDPE, Plasticized PVC, PP heap leach liner, surge pond containment, settling ponds
waste containment, water and solutions impoundments,
engineered covers
Geonets HDPE drainage
Geogrids HDPE, Polyesters (PET), PP stabilization of soft soils, base for road construction
Geopipes HDPE, LLDPE, PVC conveyance of clean, drainage and process waters
Geotextiles PP, PET cushion layers, filter cloths
Note: HDPE = high density polyethylene PVC = polyvinyl chloride
LLDPE = linear low density polyethylene PP = polypropylene


were summarized, and key issues regarding the use of geosythetics to meet those challenges
were raised.

1.2 Challenges in Environmental Mine Management

Environmental protection challenges in the mineral sector include:

1) Mines, unlike other facilities such as dedicated landfill sites, usually have a much larger
footprint (typically hundreds of hectares). Therefore, environmental protection measures
have to be practical, robust, economical, acceptable to regulatory bodies, sustainable and
environmentally sound.
2) Duration of responsibility and/or the post closure period for the site may extend over several
decades and even centuries especially for sites with acid generating or radioactive wastes;
hence waste containment and environmental control systems need to be functioning in the
long-term and be economically feasible. Most ML/ARD mitigation and control measures
must be designed, constructed, and operated in a manner that allows them to perform
indefinitely under normal and extreme climatic conditions.
3) Management of mine waste does not generate revenue for environmental controls - no
tipping fees can be charged as in the case of dedicated landfill sites, because mine waste is
generated and remains on site, to a large extent. Thus, engineering controls for waste
management have to be technically and economically feasible.
4) Waste management is normally considered a major liability to the industry. However, the
industry recognizes the extent of this liability and diligent control measures are implemented
such aspects as design for closure to minimize long-term liabilities. Small studies have been
carried out to investigate possible recycling of mine waste, but no favourable, economically
viable results have been reported.
5) Mines are often located in remote areas, which might make transportation of construction
materials to the site difficult and expensive. In most cases, local materials are preferably
used for construction and remediation purposes if available and suitable.
6) The environment is often harsh, especially for those sites with ML/ARD or that are located at
high elevations. Therefore, measures to mitigate and control ML/ARD or other problems
must be compatible with site-specific conditions and implemented according to defined
specifications required to meet performance objectives.
7) For logistical reasons, most existing mine and mineral processing waste storage facilities are
located in topographic depressions or at the bottom of slopes. These areas are often zones of
ground water discharge with high rates of flow during some periods of the year. Under such
conditions, leaching will continue even if an engineered cover effectively limits surface
infiltration.
8) Limited resources tend to be dedicated for maintenance, inspection, monitoring and
surveillance programs during closure and long-term care and maintenance. Therefore, control
systems have to be robust and relatively maintenance free.
9) During the post closure stage, major inspections of waste containment systems by qualified
personnel are typically only done on bi-annual or annual basis in Canada or even less
frequent in other parts of the world. Infrequent inspections by a competent person may lead
to structural failure that could have been prevented through a more frequent structured
monitoring program.


10) Suitable, local materials to serve as geosynthetic interface materials, such as clay, gravel,
sand and silt, may be lacking at some sites, especially those located in northern climes.

Since mine site management concerns, such as dam and slope stability and ML/ARD
mitigation and control, are long-term, it is critical to ensure that materials used for environmental
and geotechnical controls require minimal maintenance and monitoring, perform as designed,
have a long service life, and are economically feasible. For the benefit of readers unfamiliar with
ARD, pertinent aspects are briefly reviewed in the next paragraph.

ARD is a serious environmental and economic concern facing the mining industry today.
ARD, characterized by low pH levels, high acidity, and high sulphate and metal concentrations
and can contaminate receiving environs, if not properly managed. ARD forms naturally in three
stages, if sulphidic materials are insufficiently buffered with alkaline minerals such as calcite.
As ARD develops, the pH drops progressively from near neutral to slightly acidic levels and then
to very low pH levels (< 3.0). Sulphide oxidation reactions in the first stage are primarily abiotic
and relatively slow, reactions in the third stage are primarily biotic (biologically mediated) and
rapid, and reactions in the second stage (transition stage) are both abiotic and slow and biotic and
fast. Bacteria most commonly isolated from ARD generating environments include Thiobacillus
ferrooxidans, Leptospirillum ferrooxidans, and T. thiooxidans (Rawlings, 1997). T.
ferrooxidans are purely autotrophic and grow optimally at pH levels of 1.8 to 2.5 at a
temperature ranging from 30 to 35
o
C, but some strains of T. ferrooxidans are also adapted to
growth in lower temperatures (Rawlings, 1997). L. ferrooxidans are able to grow at pH levels as
low as 1.2 at a temperature ranging from 20 to 45
o
C. T. thiooxidans grow in association with T.
ferrooxidans and L. ferrooxidans are able to grow at pH levels as low as 0.8 at a temperature
ranging from 30 to 35
o
C (Rawlings, 1997). To mitigate ARD, physical barriers have been used
to minimize infiltration of precipitation, oxygen diffusion, and oxygen flux to the sulphidic
material.

Key questions in the assessment of the suitability of geosynthetics for a particular
application include:

1) Do they work to address the challenge (e.g. compatibility with the mine and environment,
containment, collection, conveyance, isolation, etc.) in the mining environment?
2) What is the projected service life and how does that service life compare to the required
service life of the facility?
3) What are the costs and requirements for initial geosynthetic installation, subsequent
maintenance, and eventual replacement, recycling or abandonment?
4) What are the competing alternatives to geosynthetics and is the use of geosynthetics cost-
effective compared to other options (e.g. natural soils, engineered soil-based systems for
containment, pump and treat)?

This paper addresses the first two questions for GCL and polyethylene (PE) and
polypropylene (PP) products. Answers to the third question may vary greatly depending on the
required products (type, polymer formulation, thickness or weight, etc.), the manufacturer,
shipping, installation environment, and therefore, are site- and/or waste-type specific. Budget
estimates for material costs may be in the range of US$0.34 to US$0.60/ft
2
(CDN$5-10/m
2
) for
GCLs, US$0.22 toUS$0.60/ft
2
(CDN$3.50-8.00/m
2
) for linear low density polyethylene


(LLDPE) GMs, US$0.22 to US$0.60/ft
2
(CDN$4-8/m
2
) for HDPE GMs, and approximately
US$0.16/ft
2
(CDN$1.70/m
2
) for heavy (e.g. 16 oz) geotextile cushion layers.

Answers to the fourth question will also be site-, ore-, and/or waste-specific. The use of
geosynthetics to mitigate and control ARD from tailings and waste rock competes with methods
such as the use of natural soils or modified soils, collection and treatment (with or without any
cover), water covers, store and release covers, rigid covers (e.g. shotcrete), conventional and
paste backfill (reduces the quantity of tailings impounded), and desulphurization of tailings. For
example, depending on the site-specific factors, the overall cost of material procurement,
engineering and installation may be upward of $250,000 per hectare or $25 per square meter for
an engineered cover to mitigate ARD while a store and release cover has been estimated to cost
$84,000 per hectare (Mchaina, 1995, 2003). Depending on site and waste characteristics, options
such as collection and treatment have proven to be the economical and practical approach to
dealing with ARD problems. Whatever cover or capping option is selected, there is typically
some requirement to collect and treat drainage waters. As such, regulators in some countries and
jurisdictions (for example, Canada) require financial security to cover unexpected poor cover
performance and replacement costs. For example in Canada, ML/ARD sites are required to be
kept under long-term care and maintenance for at least 100 years. As discussed earlier, suppliers
of geosynthetics warranty their products for up to 20-30 years, consequently, regulatory
authorities tend to regard the use of geosynthetics as a temporary measure to mitigate and control
ML/ARD.


2. GEOSYNTHETICS

The review of key technical considerations and examples of case studies for the use of
geosynthetics in the mining and mineral processing industries commences with GCLs, followed
by polyethylene (PE) and polypropylene (PP) products. GCLs have been used extensively in
landfill design and construction as hydraulic barriers and secondary hydraulic barriers below
GMs. GCLs have been used by the mining industry for capping and waste containment
(Ecosystem Restoration, 1995; Crouse et al., 1999 and 2000), but not as widely used as in the
municipal waste management industry. Presented case studies include GCLs covered with
shallow soil covers to limit infiltration and possibly acid rock drainage, and GCLs installed
below GMs.

2.1 Geosynthetic Clay Liners (GCLs)

Geosynthetic clay liners (GCLs) have become popular as hydraulic barriers in composite
soil/geosynthetic cover and liner systems for landfills or as replacements for compacted clay
liners. Compared to natural clay liners, GCLs are quicker to install, require less on-site QC/QA,
occupy less volume, and use lighter weight construction equipment (Stewart and von Maubeuge,
1997).

GCLs consist of a layer of bentonite clay supported by geotextiles and/or GMs and held
together by needling, stitching, or chemical adhesion. Most currently manufactured GCLs are
needle-punched. GCLs are usually classified based on their bentonite content, the type and


weight class of top and bottom geotextiles (such as woven (W), nonwoven (NW), or scrim-
reinforced), type of internal support (e.g. needle-punched or stitch-bonded), and extra features
(manufacturer specific). In scrim-reinforced geotextiles, a woven geotextile and a non-woven
geotextile are needle-punched together. The hydraulic conductivity of most sodium bentonite
GCLs ranges from 1.010
-11
to 5.010
-11
m/s at the factory (Koerner and Daniel, 1997; Petrov
and Rowe, 1997). GCLs are generally more resistant to cracking due to freeze-thaw cycles and
desiccation than compacted clay liners (Koerner and Daniel, 1997).

2.1.1 Technical Considerations for Design and Construction with GCLs

Key considerations for design and construction with GCLs are listed below prior to
detailing case studies to emphasize some of the technical considerations and to present recent
research.

1) Shipping, handling, and storage practices need to address the fragileness of the GCLs to
prevent damage, punctures and/or premature hydration. If a GCL hydrates prematurely
and is subsequently loaded, for example by walking or placing soil on it, the hydrated
bentonite may be squeezed out from underneath the confined area towards the less confined
GCL resulting in high hydraulic conductivity zones.

2) Proper construction techniques need to be followed. Basic installation guidelines are
typically provided by GCL manufacturers. Additional, more stringent guidelines may have
to be adopted to address site-specific or waste-specific issues. In all installations, it is crucial
1) to prevent premature hydration of GCLs, 2) to prevent puncturing or ripping of the GCL,
3) to apply a confining pressure equivalent to at least 300 mm of soil cover on top of the
GCLs as soon as possible after placement (at least on the same day and prior to any
precipitation on that day), 4) to provide adequate seam overlap (25 to 45 cm) to
accommodate GCL shrinkage due to temperature changes, 5) to add sufficient bentonite in
the seam areas, and 6) to prevent wrinkles during GCL installation. Improper installation can
result in significant decreases in performance. Unsatisfactory performance is often due to
improper site preparation, for example, by placing GCLs on top of or below soils that are so
coarse or angular that the GCL is punctured. Wrinkles may result in localized redistribution
of hydrated bentonite (squeezing of bentonite to less confined zones) in the GCL resulting in
higher hydraulic conductivity in affected areas. Insufficient bentonite in seam areas may
lead to significant leakage, especially when GCL is installed to contain liquids (Chamberlain
et al., 1997).

3) GCL liquid permeability and flux vary with confining stress. For low confining stresses
(< 420 kPa), the higher the confining stress, the lower the permeability and the flux (Trauger,
2005).

4) The GCL (bentonite and geotextiles) needs to be chemically compatible with the liquid
or gas that it will come in contact with (e.g. regarding pH levels, acidity, chemical
compound(s)). For example, bentonite tends to maintain its swelling capacity in the pH
range of 2 to 13 (Olsta, 2005). Therefore, GCLs are not compatible with strong acids (pH <
2) nor with strong bases (pH >13).

5) Need to consider internal shear strength of hydrated GCL (ASTM D 6496) and
interface shear strength of GCL with the materials above and below it (ASTM D 6243).


GCLs are typically internally reinforced with needle-punching or other methods, because the
angle of internal friction for unreinforced bentonite is low (approximately 4-9
o
corresponding
to a slope of 14H:1V to 6H:1V) (Thiel, 2005). Interface strength of GCLs is material
specific and depends on the geotextile (woven or nonwoven) and whether hydrated bentonite
extruded through the fabric. Slope stability should be evaluated on a case by case basis for in
situ soils and the combinations of geosynthetics and other materials added to the slope
assuming average and worst-case conditions. Long-term reinforced GCLs on 3H:1V slopes
(33% or 18.3
o
) should be no problem for soil cover systems (Thiel, 2005). However,
Bonaparte et al. (2002) cited numerous 2H:1V cover systems containing GCLs that failed.
On slopes steeper than 3H:1V, it is recommended to use needle-punched GCLs with a non-
woven geotextile on top and a scrim-reinforced non-woven geotextile on the bottom.

6) Need to minimize ion exchange of monovalent Na
+
for divalent cations such as Ca
2+
or
Mg
2+
. The exchange of monovalent Na
+
for divalent cations such as Ca
2+
or Mg
2+
, can lead
to significant increases in GCL hydraulic conductivity, because the divalent ion decreases the
swelling capacity of the bentonite which in turn results in higher porosity (Melchior, 1997;
James et al., 1997). It is important to note that ML/ARD phenomena are in part
characterized by the release of divalent cations even before acid is generated. Sometimes
this is due to liming during milling. To illustrate increased hydraulic conductivity after ion
exchange, Lin and Benson (2000) conducted a series of swell test on GCL specimens using
deionized water (DI) and 0.0125 M CaCl
2
. The hydraulic conductivity of samples subjected
to four wet-dry cycles using 0.0125 M CaCl
2
was 4,000 times as high as the hydraulic
conductivity of samples subjected to wet-dry cycles using distilled water.

To prevent exchange of monovalent Na
+
for divalent cations, GCLs have been placed
directly beneath GMs (Benson, 1999). However, although placement of GCLs below GMs
may address the problem of ion exchange, it might create a GCL desiccation problem (see
GCL case studies by Southen (2005), Koerner and Koerner (2005)).

7) Need to protect GCLs from tearing and cracking due to differential settlement. This
requirement can be achieved by good site preparation and following appropriate QA/QC
protocols during construction/installation.

2.1.2 GCL Case Studies

2.1.2.1 Field performance of 45 cm soil cover systems containing GCLs in
temperateclimate (Melchoir, 2002)

The following case study demonstrates the importance of safeguarding GCLs in shallow
soil cover systems (0.4 - 1.0 m) against desiccation and ion exchange.

In 1994, a large lysimeter study commenced on the Hamburg-Georgswerder landfill to
test the field performance of GCLs. The landfill is located near Hamburg in northern Germany
(~ 53
o
20N, 10
o
20E; mean annual precipitation of 750-1,000 mm). Two 100 m
2
lysimeters
were integrated into the landfill cover to measure the percolation rate through a needle-punched
and a stitch-bounded GCLs under a cover consisting of 30 cm topsoil (sandy loam) and 15 cm
drainage layer (gravel) (Melchior, 2002). Three other products, including a Grundseal GM,
were tested under similar conditions in smaller control plots. Grundseal is a composite product


consisting of the thin HDPE liner with granular bentonite adhesively glued to one side. The
following key results were reported (Melchior, 2002):

The needle-punched and stitch-bonded GCLs, except for the GM-bentonite GCL, were
penetrated by fine roots starting in 1994. Only a few roots grew in the overlaps of the GM-
bentonite GCL.
A network of cracks, up to 2 mm wide, that did not heal after rewetting of the GCLs
developed during the summer of 1995.
In the needle-punched and stitch-bounded GCLs, sodium bentonite had become calcium
bentonite within two years after installation due to ion exchange with the cover soils. As a
result, the swelling capacity of the bentonite in the needle-punched and stitch-bounded GCLs
was less than half of its original capacity in 1996 and 1998.
In the composite GM/GCL, the calcium content of the bentonite increased as well (from 20
to 28%), but not as dramatically as for the other GCLs. (Ion exchange in the composite
GM/GCL may have occurred with the subsoil.) The swelling capacity of the composite
GM/GCL decreased from 20 mL/2g to 12 mL/2g from 1994 to 1999.
The estimated percolation through the needle-punched and stitch-bounded GCLs was
1.710
-7
m
3
/m
2
/s, or approximately 3,400 times the original permeability.
By 1998 (after 4 years), all needle-punched and stitch-bounded GCLs had hydraulic
conductivities several magnitudes larger compared to their initial values based on fixed wall
hydraulic conductivity tests.

In summary, Melchior (2002) found that desiccation, cation exchange, plant root
penetration and shrinkage increased the hydraulic conductivity of needle-punched and stitch-
bonded GCLs significantly under a shallow 45 cm soil cover. The estimated percolation through
the needle-punched and stitch-bounded GCLs was 1.710
-7
m
3
/m
2
/s, or approximately 3400
times the original permeability. The composite GM/GCL performed better than the needle-
punched and stitch-bonded GCL. During the performance evaluation, the GCLs were not
exposed to freeze-thaw episodes, the pH was neutral, and soil and soil water were free of
aggressive contaminants (Melchior, 2002).

2.1.2.2 Field performance of 45 cm soil cover systems containing GCLs in humid climate
(Renken et al., 2003a, 2003b, 2003c, 2005)

The authors of this paper conducted a field performance evaluation of a GCL soil cover
system at the Premier Gold Project (PGP) located near Stewart, BC, Canada (~ 56
o
05N,
130
o
00W; Elevation 335 m; mean annual precipitation > 2,200 mm). The field performance
evaluation commenced in 2002 for a GCL Plot, a Control Plot and two other treatment plots.
The cover systems were evaluated for their ability to reduce infiltration and oxygen flux into
underlying, potentially acid generating tailings. The GCL cover system (~11.5 x 15 m) consisted
of (bottom to top) 0.75 m potential acid generating tailings, 0.1-0.15 m fine sand, a needle-
punched GCL (Bentomat ST), 0.1-0.15 m fine sand, 0.25-0.35 m of coarse sand and gravel,
and 0.05-0.10 m top soil seeded with a grass and legume mixture.

Renken et al. (2005) inferred that the GCL below the 45 cm soil cover in the humid
climate appears to have, at least partially, desiccated during the second summer, because: 1)


higher oxygen concentrations were observed in two out of three soil profiles in 2004 in the
tailings; 2) GCL Plot runoff and interflow results were intermittent; and 3) some GCL
specimens, exhumed in 2004, had air entry values (AEVs) of less than 10 kPa. These low AEVs
would render the GCL susceptible to desiccation. The AEV is defined as the matric suction
(sometimes also called soil suction) at which the first water filled soil pores drain. The GCL
reduced oxygen concentrations in the covered tailings, but measured oxygen concentrations were
still high enough to support sulphide oxidation (at least in the second summer), which was to be
inhibited by the candidate cover system for the tailings. The inferred field hydraulic
conductivity was 110
-10
to 210
-10
m/s in 2004.

2.1.2.3 Laboratory Study: GCL desiccation below a geomembrane

Southen (2005) found that GCL desiccation occurs under certain initial and boundary
conditions when placed below a GM. Desiccation is primarily dependent on the initial water
content of the subsoil beneath the GCL and the temperature gradient (Southen, 2005). GCLs
placed below a GM and on top of silty sand subsoil with an initial gravimetric water content
ranging from 12.1 to 13% resulted in increased final water contents in all four GCL specimens
tested (increase from initial water content of 70 to 82% to final water content of 90 to 112%)
under a temperature gradient of 25.5 to 29 (
o
C/m). In contrast, GCLs placed below a GM and on
top of silty sand subsoil with an initial gravimetric water content ranging from 4.2 to 6.6%
resulted in decreased final water contents in all four GCL specimens tested (decrease from initial
water content of 72 to 110% to final water content of 9.5 to 28.6%) under essentially the same
temperature gradient of 24.8 to 27 (
o
C/m) (Southen, 2005). Desiccation cracks were numerous
and relatively uniformly spaced in a honeycomb pattern. Based on Southens (2005) results, one
may conclude that GCLs placed below a GM and on top of a drainage layer (which typically has
a low gravimetric water content) are likely to desiccate unless they are recharged due to leaks in
the GM.

2.1.2.4 Panel Separation of GCLs below textured Geomembranes that were left uncovered
(Koerner and Koerner, 2005)

Koerner and Koerner (2005) investigated GCL panel separations that occurred in landfill
cover systems at five locations. Separation of the adjacent GCL panel edges ranged from 0 to
300 mm for most cases and up to 1,200 mm in the worst case. At one landfill, just about every
adjacent GCL panel along the upper southerly facing slope separated. Koerner and Koerner
(2005) investigated the effects of longitudinal steep slope tensioning of the GCL, GCL shrinkage
(e.g. due to cyclic wetting and drying), and GCL contraction on relatively flat slopes for these
cases. In all five cases, the GCLs had been installed below textured GMs (with the textured side
facing the GCL) that had been left exposed from two months to five years with no covering of
any type. GCLs with non-woven geotextiles on both sides with no internal scrim reinforcement
were found to be a major cause for GCL panel separations (Koerner and Koerner, 2005). It
should be noted that Koerner and Koerner (2005) did not investigate the effect of ion exchange
on the shrinkage behavior of the GCLs. Ion exchange could have occurred with the subsoil as
was reported by Melchior (2002).



To prevent similar problems with GM/GCL cover systems, Koerner and Koerner (2005)
recommended the following:

To cover GM/GCL composite liners in a timely manner (site specific) to minimize exposure
to cyclic temperature extremes;
To only use scrim reinforced GCLs (at least one of the geotextiles in the GCL should be
scrim-reinforced);
To have a minimum GCL overlap of 25 to 45 cm (10 to 18 in);
To use GCLs with a low as-manufactured moisture content to minimize shrinkage;
To protect GM/GCL composite liners or covers from thermal stress when left exposed by
using thermal blankets, geofoam, or other insulation techniques.

2.1.3 Potential for GCL use in ML/ARD Mitigation

GCLs, and especially GCLs installed below GMs, have been used extensively as hydraulic
barriers in the municipal waste industry (Koerner, 1998). Based on this extensive use, GCLs
installed below GMs used as hydraulic barrier in cover systems to mitigate and control ARD
are expected to perform well. Longevity of the GCL/GM system would be limited by the
longevity of the GMs and the geotextiles of the GCLs, and the quality of installation.

The performance of GCLs in liner systems (GCLs alone or below GMs) would depend on
the pH and acidity/alkalinity and the cation concentrations in the contained liquids. Since
bentonite looses its swelling capacity below pH 2 (Olsta, 2005), a GCL liner may fail when it is
needed most to contain highly acidic solutions with a pH lower than 2. Ion exchange may also
be an issue, because typical ARD has high concentrations of Cu
2+
, Zn
2+
, and Pb
2+
. Thus, the
performance of GCLs as hydraulic barriers in liner systems to mitigate ARD appears
questionable, because if the GM would leak, the GCL would be exposed to a host of divalent
cations at high concentrations which, in turn, would increase the hydraulic conductivity of the
GCL (potentially beyond the liner performance specifications).

The GCLs suitability to act as a oxygen diffusion barrier to mitigate ARD seems
questionable based on the case studies reviewed. The main shortcomings of a GCL are its short
oxygen diffusion path length and its susceptibility to desiccation. The likelihood of temporary
partial or complete desiccation of GCLs under field conditions appears high due to the following
factors:

1) GCLs under shallow soil covers are prone to desiccation and ion exchange;
2) GCLs under thick soil covers are also prone to ion exchange (which could increase the
porosity and probably the effective oxygen diffusion coefficient) and, potentially desiccation;
3) GCLs below GMs are prone to desiccation if installed above drainage layers (which is
typical); and
4) GCLs installed between two GMs would remain dry unless the GMs leak.

Future field performance research focused on the oxygen diffusion aspects of GM/GCL
and GM/GCL/GM cover systems would be needed to assess the utility of cover systems
containing GCLs to mitigate ARD. Further laboratory and field performance research of
GM/GCL, GM/clay, GM/GCL/GM, GM/clay/GM liner systems would be essential to assess the


utility of liner systems containing geosynthetics to mitigate and control ARD/ML problems.
Field performance should also be investigated at subzero climes that are typical in the mining
industry.

2.2 Other Geosynthetics

The summary of other geosynthetics commences with a description of common
formulations and mechanisms of degradation. This is followed by technical considerations for
GM installations and examples of case studies. Presented case studies include: 1) estimation of
longevity of HDPE (high density polyethylene) coupons after exposure to synthetic ARD; 2)
considerations for heap leaching; 3) soft tailings stabilization; and 4) use of a HDPE cover
system for tailings.

2.2.1 Common formulations of geosynthetics and mechanisms of degradation

Polymers in geosynthetics are subject to degradation and, therefore, their service life
depends on their constituent resins and additives and the environmental conditions they come in
contact with. Polymers are long-chain molecules built through addition (polymerization) of
small repetitive molecules called monomers. Polymer chains are linked together by weak inter-
chain interaction and stay intact as long as the applied chemical or physical stresses are lower
than the inter-chain interaction. The chemistry of polymers is governed by the laws of organic
chemistry and is directly related to the types of molecular groups along its chains (Kay et al.,
2004). Common formulations of geosynthetics are presented in Table 2. Polymer degradation is
caused by mechanisms such as oxidation, temperature and temperature stresses, UV radiation,
chemical attack, mechanical stress, and microbiological activity (Kay et al., 2004). In general,
the service life becomes shorter the higher the exposure of oxidizing agents, the higher the
temperature, and the higher the exposure to UV radiation. The service life due to chemical
solvent attack depends on the type of solvent (GSE, 2002). The service life of geosynthetics is
usually extended by adding antioxidants, UV stabilizers, or pigments to the polymer
formulations.

Table 2. Approximate Formulations of Common Geosynthetics (Koerner, 2004)








The long-term oxidation-induced aging of geosynthetics occurs in three discrete stages:
Stage A) antioxidant depletion time, Stage B) induction time, and Stage C) time to reach
reduction in the desired engineering property (Bonaparte et al., 2002). Typically, Stage A is the
longest and is projected to range from several to hundreds of years (e.g. for HDPE; Koerner,
2004) during which the desired engineering properties remain essentially the same. Stage B is a
transition stage that is much shorter than Stage A. In Stage B, a measurable amount of oxidation
Polymer Type Resin
Various
Additives
Carbon Black /
Pigment
Filler Plasticizer
Polyethylene / Polyester / Polystyrene 97% 0.5-1.0% 2-3% 0 0
Polypropylene 96% 1-2% 2-3% 0 0
Polyvinyl Chloride (unplasticed) 80% 2-3% 5-10% 10% 0
Polyvinyl Chloride (plasticed) 35% 2-3% 5-10% 25% 30%


induced chain scission (breaking C-C bonds in polymer chain) occurs. The time to reach
reduction in the desired engineering property in Stage C varies, but may be quite brief.
Embrittlement is a physical manifestation of the degradation process. Oxidation is accelerated
by the catalytic effects of transition metal ions in a chemically activated state. Of these, ferric
iron (Fe
3+
) is the most common but copper and manganese have also been shown to be important
(Rollin, 2004). High ferric iron concentrations are associated with ARD generation.

When exposed to heat, internally stressed polymer chain segments tend to reorganize
themselves to achieve a more stable, crystalline state. Increased crystallinity affects the material
properties and results in increased stiffness and reduction of the geosynthetics permeability and
elasticity (Kay et al., 2004). In HDPE geosynthetics, a higher crystallinity increases its
susceptibility to stress-cracking (environmental stress cracking or ESC) which is a serious
concern. ESC refers to the brittle failure of a stressed sample in the presence of a sensitizing
agent. The ESC deformation tends to occur within thin sections even if the stress is applied over
a relatively large area and ultimately leads to a complete rupture of the material. Studies have
shown that the stress level involved in ESC failure is typically less than one half of the short-
term yield stress (Kay et al., 2004). A notch, a scratch, or some other type of stress concentrator
accelerates the stress-cracking process.

Polymers can resist deterioration upon exposure to solvents, if the inter-chains links are
stronger than the interaction of the solvent with the polymer. Amorphous phases are typically
more vulnerable to solvent penetration than crystalline phases and therefore resistance of a
particular polymer increases with its crystallinity (Kay et al., 2004). Due to this fact, HDPEs are
more resistant to solvent attack than LLDPEs (linear low density polyethylenes). For PE
(polyethylene) and PP (polypropylene), swelling of the amorphous phase due to solvent
penetrations can create a stressed zone at the interface between amorphous and crystalline
phases, resulting in chain ruptures (Kay et al., 2004).

2.2.1.1 Characteristics of Polyethylene and Polypropylene Geosynthetics

PE geosynthetics are very resistant to chemical substances and do not easily deteriorate
when exposed to alkaline and acid agents (except oxidizing acids), salt solutions, or microbes,
because they are non-polar in nature (Kay et al., 2004). Due to their resistance to chemical
attack and low glass transition temperature of 50
o
C, PE geosynthetics have been the most
widely used in the mining and mineral processing industries. Since a polymer becomes brittle
and loses its impact resistance when the temperature is below its glass transition, PE may be
more appropriate in cold climates than PP (Kay et al., 2004). The glass transition temperature of
PPs is typically around 10
o
C. A drawback of HDPE is that it is sensitive to environmental
stress cracking in the presence of a sensitizing agent. Compared to HDPE, LLDPE is less
susceptible to stress cracking and has higher interface friction values, is easier to install in cold
climates, and is able to sustain more strain (Lupo and Morrison, 2005). PPs are generally more
resistant to creep and relaxation, fatigue at higher temperatures than PEs. Chemical resistance of
PPs is similar to or higher than that of PEs (Kay et al., 2004). However, PPs are more sensitive
to oxidation than PEs (Kay et al., 2004).



2.2.2 Technical Considerations for Design and Construction with GMs

Key technical considerations for the successful installation of GMs follow.

1) Need to consider the environmental stress cracking or ESC degradation process when
HDPE geosynthetics are exposed to chemical substances and mechanical stresses.
Material specifications including a resistance to stress cracking higher or equal that proposed
in the GRI GM13 (2003) specification for GMs (based on ASTM D5397) should be
considered. Stress on PE materials should be minimized (Kay et al., 2004).

2) Need to ensure that candidate geosynthetics meet appropriate tensile strength, puncture
resistance, and tear strength requirements for the desired application. Typical protocols
to assess material properties are ASTM D 4885 for tensile strength, ASTM D 4833 for
puncture resistance, and ASTM D 1004 and D5884 for tear strength.

3) Need to ensure that interface properties are compatible with adjacent materials and
anticipated loadings. The interface of any two materials can cause problems (e.g. old / new
GM or prefabricated penetration structure / GM; GCL / GM; GM / geotextile). Thermally
induced failures need to be considered, especially if the materials will be directly exposed to
thermal fluctuations on a long-term basis (e.g. in cover systems). One of the key items to be
considered is the coefficient of thermal expansion of adjacent materials (Kay et al., 2004).
Load testing and interface shear testing (ASTM D5321) and slope stability analysis should be
conducted based on anticipated field conditions and candidate liner/cover materials. Field
test pads are also recommended by some practitioners to confirm modeling results.

Analyses of past slope failures on GM lined fill structures, such as solid waste landfills and
heap leach pads, have shown that liner induced failures tended to occur at the planar GM
liner interface with weaker under- or overlying materials (Breitenbach, 2004). Slope failures
from weak foundation conditions were found to be due to one or more of the following:
reactivation of a previous landslide, thawing of frozen subgrade soils, overly wet subgrade,
subgrade subsidence (e.g. due to compressible soils), and excavations into toe areas of the fill
(Breitenbach, 2004).

4) Shipping, handling, and storage practices need to prevent damage of GMs.
Geosynthetics delivered to an installation site need to be inspected for damages. Damaged
goods should be discarded.

5) The geosynthetic has to be chemically compatible with the liquid or gas that it will come
in contact with (e.g. ASTM D 5322, D 5747). The response to solvent exposure(s) and
other chemical or mechanical stresses should be evaluated for candidate materials, especially
if exposure is frequent and if no relevant performance data exists (for example, if
geosynthetics will be exposed to a cocktail of chemical compounds). General information
and guideline tables regarding the chemical compatibility of geosynthetics are available from
geosynthetic manufacturers or in the literature. For example, HDPE usually performs
satisfactorily up to 60
o
C when exposed to 10% HCl, 35% HCl, 10% H
2
SO
4
, 50% H
2
SO
4,
and
sodium cyanide (GSE, 2002). However, halogen hydrocarbons can severely affect the
properties of PE.

6) Proper construction techniques need to be followed. Geomembranes are typically
installed by specialized firms. The site has to be prepared to prevent punctures or other


damage to the GM and it has to be protected from natural hazards. The intactness of installed
GMs can be checked by pressure testing the seams and with electrical methods on the width
of the panels. Wrinkles in installed GMs have to be minimized (best prevented), because
wrinkles induce internal stresses that can reduce the GMs service life. Wrinkles in GMs
located above a GCL may induce a vertical stress on the GCL, which tends to cause
redistribution of hydrated bentonite inside the GCL (Dickinson and Brachman, 2003).
Nonuniform distribution of bentonite may lower the overall hydraulic performance of the
GCL by creating hydraulic holes (i.e. zones with higher hydraulic conductivity). To avoid
waves or wrinkles in GMs, light-colored (e.g. white) GMs could be used, GMs could be
deployed and seamed without intentional slack, GMs could be covered with an overlying
light colored temporary geotextile until backfilling with cover soils occurs, and backfilling
could be performed only in the coolest part of the day or even at night (Bonaparte at al.,
2002).

7) Need to protect GMs from tearing and cracking due to differential settlement. This may
be achieved by ensuring firm and uniformly graded foundations for the GMs.

2.2.3 Polyethylene and Polypropylene Case Studies

2.2.3.1 Laboratory Study: Exposure of geosynthetics to synthetic ARD (Gulec et al., 2004,
2005)

Gulec et al. (2004, 2005) estimated the antioxidant depletion rates in 1.5 mm thick HDPE
GM coupons after their immersion in synthetic ARD at various temperatures. HDPE coupons,
which met the GRI GM13 (2003) standard, were kept in the ARD solutions at 20
o
C, 40
o
C, and
60
o
C for 21 months and several others were immersed in synthetic ARD for 10 weeks at 80
o
C.
Gulec et al. (2004, 2005) also evaluated mechanical and hydraulic properties of HDPE coupons
and of a needle-punched, non-woven PP geotextile (200 g/m
2
), and a drainage composite
consisting of a HDPE geonet with a needle-punched, non-woven PP geotextile (200 g/m
2
) heat
bonded to each side. The synthetic ARD was prepared with deionized water (DI) using
FeSO
4
H
2
O, ZnSO
4
7H
2
O, CuSO
4
, CaSO
4
, and H
2
SO
4
and had an average pH of 2.4. It
contained approximately 1,500 mg/L Fe, 350 mg/L Zn, 35 mg/L Cu, 4,500 mg/L SO
4
2-
, and 200
mg/L Ca (Gulec et al., 2005).

Estimates of the antioxidant depletion rates in the HDPE material were based on the first-
order (exponential) degradation equation for the Oxidation Induction Time (OIT). Based on the
antioxidant depletion rates, S, listed in Table 3 for synthetic ARD with an average pH of 2.4, the
corresponding half-lives of the antioxidant depletion for the HDPE coupons were 135.9 months
(11.3 years) at 20
o
C, 14.4 months (1.2 years) at 40
o
C, 7.65 months (0.63 years) at 60
o
C, and 0.57
months (0.05 years) at 80
o
C. The estimated lifetime of the HDPE depended primarily on
temperature, the type of liquid, and the initial OIT. At 20
o
C, the HDPE lifetime (for immersed
specimens) ranged from 67.3 to 83.3 years for synthetic ARD (Table 3). At 40
o
C, the HDPE
lifetime ranged from 14.3 to 17.7 years for synthetic ARD (Table 3). At 60
o
C, the lifetime
ranged from 3.7 to 4.5 years for synthetic ARD and from 7.8 to 9.7 years for deionized water
(Table 3).



Table 3. Estimated Lifetime for a 1.5 mm GRI MR13 HDPE geomembrane immersed in
synthetic Acid Rock Drainage and Deionized Water




















Gulec et al. (2005) did not observe any statistically significant changes in the hydraulic
and mechanical properties of the tested materials, based on an analysis of variance (ANOVA)
and linear regression. In the opinion of the authors of the present paper, no significant
deterioration of engineering properties should be expected within 21 or 22 months, because 22
months corresponds to approximately 2.9 half-lives of the anti-oxidation depletion measured for
HDPE at 60
o
C; i.e. the duration of the test period chosen by Gulec at al. (2004, 2005) was well
within the expected safe timeframe in which deterioration of engineering properties would not
be expected. Also, based on previously reported research (Kay et al., 2004), PP was expected to
show similar chemical resistance compared to PE, at least, in the temperature range of 20-60
o
C.

2.2.3.2 Case Study: Considerations for Heap Leaching

The use of heap leach pads started in the 1980s with gold recovery operations. The heap
leaching process may be used to extract gold and/or silver or copper from low grade deposits.
For example, copper may be extracted with the SX-EW (oxide leaching and solvent extraction-
electrowinning) process. In the heap leach process, the ore is piled onto a liner, typically a 1.5
mm or 2.0 mm HDPE or LLDPE liner, and an extractant solution is applied to the surface, which
dissolved the metal in the ore. The metal bearing leachate (pregnant solution) is collected above
the liner and pumped to a solvent extraction plant to remove and concentrate the metal. Gold is
typically extracted with an alkaline extractant and copper with a weak acid solution. Most of the
current heap leach facilities are single-lined (Thiel and Smith, 2004).

Heap leaching presents several engineering challenges for the construction, operation and
the decommissioning. A typical ultimate target height for current heap leach facilities is 50 m,
but some operations have target heights of 150-200 m. In addition, GMs are typically not
Immersion Temperature
Measured Anti-
Oxidant Depletion
Anti-oxidant
Half-life based
Anti-Oxidant
Depletion
Estimated Lifetime (years) based on
S values and Arrhenius Plot
2
Medium Rate S on measured S Rate S based on Initial OIT Initial OIT Initial OIT
(Gulec et al., 2004) (= ln(2)/S) regression
1
80.5 min 100 min 270 min
(1/month) (year) (1/month)
Synthetic 20
o
C (293
o
K) 0.0051 11.3 years 0.0063 67.3 70.2 83.3
Acid 40
o
C (313
o
K) 0.0480 1.2 years 0.0296 14.3 14.9 17.7
Rock 60
o
C (333
o
K) 0.0906 7.65 months 0.1155 3.7 3.8 4.5
Drainage 80
o
C (353
o
K) 1.2056 0.58 months 1.1 1.1 1.4
DI Water 60
o
C (333
o
K) 0.0514 13.48 months 0.0543 7.8 8.1 9.7
Notes: 1 a) The regression equation 'ln S = 19.16 - 7099(1/T)' for synthetic acid rock drainage was based on an
Arrhenius plot obtained for T = 293
o
K, 313
o
K, and 333
o
K (Gulec et al., 2004).
b) The regression equation 'ln S = 15.79 - 6228(1/T)' for deionized water (DI) was based on an
Arrhenius plot obtained for T = 333
o
K and data presented by others (Gulec et al., 2004).
2 The estimated lifetime was calculated by assuming a final OIT of 0.5 min and an initial OIT as indicated.
S
OIT final OIT inital
Lifetime Estimated
) _ ln( ) _ ln(
_

=


protected from overlying coarse granular soils with heavy geotextile cushion layers to save costs
and to increase slope stability. Thus, the exerted pressure on the basal liner and leachate
collection system of a typical heap leach facility is or will be very high, because ore density
ranges from 1,500 to 1,800 kg/m
3
(Thiel and Smith, 2004; Lupo and Morrison, 2005). Detailed
laboratory testing is required to evaluate whether potential liners are physically and chemically
compatible with the high anticipated loading and the environmental and operating conditions.

A potential problem with the use of polyethylene (PE) GMs as heap leach liners is that
irrigation with extractant solutions may induce exothermic reactions and the growth of meso-
and thermophilic bacteria in the ore. Elevated temperatures in the heap would result in earlier
degradation of the PE membrane. Soil temperatures of up to 50
o
C have been observed in field
heap leach operations (Thiel and Smith, 2004). Thiel and Smith (2004) also reported the use of
concentrated sulphuric acid (H
2
SO
4
) at some operations to extract copper from leach piles. This
practice led to compatibility problems with the GM liner; one installation in Chile experienced
significant softening of the HDPE GM (Thiel and Smith, 2004). HDPE has been found to be
incompatible with concentrated H
2
SO
4
at high temperature (GSE, 2002; Smith, 2003).

The design, construction, and continued operation of leachate collection systems under
high loading are challenging. Promotion of arching of the gravel or ore placed above leachate
collection pipes is considered to be critical for distributing the load. Lupo and Morrison (2005)
presented some design guidelines for those pipes. Advanced Drainage Systems (ADS, 2002)
also presented a case study for a 60.96 mm (24) HDPE pipe (N12) installed at the Morenci
Mine, Arizona, USA. This pipe, joined by split couplers, was installed with loose backfill in a
narrow trench carved in bedrock.

2.2.3.3 Case Study: Soft Tailings Stabilization (Neukirchner and Lord, 1998)

Neukirchner and Lord (1998) reported that a biaxial PP geogrid (Tensar BX-2000) was
successfully used to cover a historically ponded (HP) area of the Consolidated Tailings Pile at
the Eagle Mine Superfund site, located near Minturn, Colorado. The covered tailings and
wastewater treatment sludge had extremely high moisture contents (41-737%) and low shear
strengths (undrained shear strength 1.4 kPa 8.6 kPa).

To cover the ponded area, two causeways were first constructed across the soft HP area
using large rock (up to 1.8 m in diameter) available from an onsite borrow area. The causeways
facilitated the movement of materials during construction and provided a firm starting base for
the geogrid (Neukirchner and Lord, 1998).

The geogrid material and a 45 cm (18 in) drainage layer were successfully placed on the
HP area in the winter using the frozen surface as support. The drainage layer consisted of pit run
(< 15 cm (6) cobbles and sandy gravel). Neukirchner and Lord (1998) found that the placement
of the drainage layer was necessary (1) to drain water from the consolidation of the underlying
materials, (2) to prevent the overlying fill from becoming saturated, and (3) to provide a solid
base for the fill on top. A drainage water collection system was installed and was essential in
removing spring snowmelt and water of consolidation. Operation of the system during freezing
days and/or night presented a significant challenge (Neukirchner and Lord, 1998). Placement of


the drainage layer occasionally caused large upward movement of the material being covered.
Formation of these waves was addressed by moving to other work areas until some of the rise
dissipated, by approaching the soft area from a different direction and by pushing material
slowly onto the rise.

2.2.3.4 Case Study Poirier Mine: HDPE Cover System over Tailings (Maurice and Wiber,
2004)

One of the most notable geosynthetic installations in Canada was done at the Poirier
Mine located in northwestern Quebec, some 150 kilometers northeast of Rouyn-Noranda. The
mine operated from 1965 to 1975 and rehabilitation works started in 1998 to 2000. The
remediation work involved installation of a HDPE GM cover system over approximately
5,000,000 tons of tailings (Maurice and Wiber, 2004). The rehabilitated tailings area was 46 ha.
The cost-effectiveness of a very low permeability HDPE cover system consisting of a HDPE GM
and a protective soil layer was evaluated against a compacted clay cover. The HDPE GM was
deemed to be better suited than the compacted clay to maintain structural integrity when
subjected to abnormal differential settlement. The HDPE cover system also proved to be
cheaper than compacted clay because the latter required a much thicker frost-protection soil
layer.

Some of the challenges experienced during construction included the following: tailings
were flowing up to the surface after placement of the protective soil layer; the HDPE GM was
punctured by a tree stump and underlying liquefied tailings escaped to the surface through the
puncture; and liquefaction of tailings caused a significant subsidence (Maurice and Wiber, 2004).
The HDPE cover system was evaluated four years after installation and it was concluded that the
facility performed as intended. As this is one of the major liner installations, it will be critical to
monitor its performance in the long-term over and beyond the GM manufacturers guaranteed
service life.


3. SUMMARY

This paper summarized key considerations for the use of geosynthetics in mining related
applications. Pertinent case studies were presented. It was found that the mining and mineral
processing industry is moving more and more towards the use of geosynthetics for civil,
geotechnical and environmental engineering applications. Geosynthetic liners and collection
pipes for heap leach operations are widely used and ever higher target heap heights are fostering
the development of new design, laboratory testing, and construction methods. The duration of the
service life of geosynthetics and their cost-effectiveness compared to other alternatives are
currently the main concerns in the mining industry, especially for their use in long-term
geotechnical and environmental controls.

Due to their resistance to chemical attack and the low glass transition temperature of
50
o
C, polyethylene (PE) geosynthetics have been the most widely used in the mining and
mineral processing industries. Primary concerns of their use are physical, mechanical, and
chemical compatibility with site conditions and adjacent materials. Subjecting the materials to


less stress, lower temperatures, and less oxidizing agents increases their service life and vice
versa. The service life is very temperature dependent. For example, it was found that the HDPE
lifetime ranged from 67.3 to 83.3 years for synthetic ARD at 20
o
C, compared to 3.7 to 4.5 years
for synthetic ARD at 60
o
C (for fully immersed coupons) in one of the reviewed case studies.
The technique of heap leaching with concentrated sulphuric acid has led to chemical
compatibility problems with a GM liner in the field. The use of geogrids to stabilize soft soils
has been well demonstrated.

Future field performance research focused on the oxygen diffusion aspects of GM,
GM/GCL and GM/GCL/GM cover systems would be needed to assess the effectiveness of these
systems to mitigate and control ARD. Further laboratory and field performance research for
GM, GM/GCL, GM/clay, GM/GCL/GM, GM/clay/GM liner systems would be essential to
assess the effectiveness of liner systems containing geosynthetics to mitigate and control
ARD/ML problems.


ACKNOWLEDGEMENTS

The research for this paper was conducted under the 2003 North American Geosynthetics
Society (NAGS) Grand Award of excellence. The NAGS Awards of Excellence Program was
initiated in 1989 as an industry sponsored program to recognize excellence in the state-of-art and
state-of-practice of geosynthetics in North America. The authors appreciate and thank all
supporters and contributors to this study. Thank you for responding to our questionnaire.
Special thanks go to Bruno Herlin of Terrafix Geosynthetics Inc., Dr. Tony Sperling of Sperling
Hansen Associates, and Western Tank and Lining for sharing detailed factory, field and design
information.


REFERENCES


ADS (Advanced Drainage Systems) 2002. ADS Case study Underground Revolution. http://www.ads-
pipe.com/us/en/customer/news/caseundgrndrevolution.shtml; accessed Aug. 15, 2005.
ASTM (American Society for Testing and Materials). D 1004 Standard Test Method for Initial Tear Resistance of
Plastic Film and Sheeting.
ASTM D 4833. Standard test method for index puncture resistance of geotextiles, geomembranes and related
products.
ASTM D 4885. Standard test method for determining performance strength of geomembranes by the wide strip
tensile method.
ASTM D 5321. Standard test method for determining the coefficient of soil and geosynthetic or geosynthetic and
geosynthetic friction by direct shear method.
ASTM D 5322. Standard test method for immersion procedures for evaluating the chemical resistance of
geosynthetics to liquids.
ASTM D 5747. Standard test method for tests to evaluate the chemical resistance of geomembranes to liquids.
ASTM D 5397. Standard test method for evaluation of stress crack resistance of polyolefin geomembranes using
notched constant tensile load test.
ASTM D 5884. Standard Test Method for Determining Tearing Strength of Internally Reinforced Geomembranes.
ASTM D 5885. Standard test method for oxidation-induction time of polyolefin geosynthetics by high-pressure
differential scanning calorimetry.
ASTM D 6243. Standard test method for determining the internal and interface shear resistance of geosynthetic clay
liner by the direct shear method.


ASTM D 6496. Standard test method for determining average bonding peel strength between top and bottom layers
of needle-punched Geosynthetic Clay Liners.
Benson, C.H. 1999. Final Coves For Waste Containment Systems: A North American Perspective. Xvii Conference
Of Geotechnics Of Torino, Torino, Italy. Nov. 23-25, 1999.
Bonaparte, R., D.E. Daniel, and R.M. Koerner. 2002. Assessment and Recommendations for Improving the
Performance of Waste Containment Systems. GeoSyntec Consultants University of Illinois Drexel University.
Atlanta, GA 30342 Urbana, IL 61801 Philadelphia, PA 19104 performed under EPA Cooperative Agreement
Number CR-821448-01-0. http://www.epa.gov.ORD/NRMRL/pubs/600r02099/600R02099.pdf accessed Aug.
9, 2005.
Breitenbach, A.J. 2004. Improvement in Slope Stability Performance of Lined Heap Leach Pads from Design to
Operation and Closure. GFR Engineering Solutions. Vol. 22. No. 1.
Cetco 2002. BentomatST Certified Properties.
Chamberlain, E.J., A.E. Erickson, C.H. Benson. 1997. Frost Resistance and Liner Materials for Landfills and
Hazardous Waste Sites. Cold regions Research and Engineering Laboratory Special Report 97-29. US Army
Corps of Engineers. 23p.
Colorado Lining International. 2005. Products and Services Information Booklet.
Crouse, P.E., B.S. Jacobs, P.G. Corser, and J.V. Redmond. 1999. Geomembrane and GCL mining usage tests. Geotechnical
Fabrics Report. October/November 1999.
Crouse, P.E., B.S. Jacobs, P.G. Corser, and J.V. Redmond. 2000. Field Performance of a Geomembrane and Geosynthetic Clay
Liner (GCL) at Two Mine Sites. In Geotechnical Special Publication No. 103. Advances in Transportation and
Geoenvironmental Systems using Geosynthetics. Eds. J.G. Zornberg and B.R. Christopher. Proc. Of Geo-Denver 2000. Aug.
5-8, 2000. 94-105p.
Dickinson, S. and R.W.I. Brachman. 2003. Thickness of a GCL beneath a Geomembrane Wrinkle and Coarse
Gravel Backfill Under Large pressure. 56th Canadian Geotechnical Conference /3rd Joint IAH-CNC/CGS
Conference, Winnipeg, Man., Sept. 29-Oct. 1, 2003.
Ecosystem Restoration. 1995. Brooklynn Mine Reclamation Project.
http://www.ecorestoration.montana.edu/mineland/histories/metal/brooklyn/default.htm; accessed Oct. 3, 2004.
GRI (Geosynthetic Research Institute Test Method) GM13. 2003. Standard specification for test properties, testing
frequency and recommended warranty for high density polyethylene (HDPE) smooth and textured
geomembranes. http://www.geosynthetic-institute .org/grispecs/gm13.pdf. accessed Aug. 23, 2005.
GSE. 2002. Chemical Resistance Chart.
http://www.gseworld.com/Literature/TechnicalNotes/PDF/TN032ResistChart.pdf. Accessed: Aug. 23, 2005.
Gulec, S.B., T.B. Edil, and C.H. Benson. 2004. Effect of acidic mine drainage on the polymer properties of an
HDPE geomembrane. Geosynthetics International. Vol. 11( 2): 60-72.
Gulec, S.B., C.H. Benson, and T.B. Edil. 2005?. Effect of acidic mine drainage on the mechanical and hydraulic
properties of geosynthetics. Report GT-04-023738.
http://www.uwgeotech.org/pdf/14%20Gulec%20et%20al%2005%2on%20AMD.pdf . accessed: Aug. 12, 2005.
36p.
James, A., Fullerton, D., and Drake, R. 1997. Field Performance of GCL Under Ion Exchange Conditions. J. of
Geotechnical and Geoenvironmental Engineering, ASCE, 123(10): 897-901.
Kay, D., E. Blond, J. Mlynarek. 2004. Geosynthetics Durability: A Polymer Chemistry Issue. 57th Canadian
Geotechnical Conference/5th Joint CGS/IAH Conference, Quebec City, Quebec, Oct. 24-27, 2004. Session 4D.
pp. 1-14.
Koerner, R.M. 1998. Designing with Geosynthetics. Fourth Edition. Prentice Hall, Upper Saddle Rover, NJ.
Koerner, R.M. 2004. Geosynthetic Seminar. Geosynthetics Institute. Host: Terrafix. Hosting Facility: Pearson
Convention Centre, Brampton, ON. April 5, 2004.
Koerner, R.M., and D.E. Daniel. 1997. Final covers for solid waste landfills and abandoned dumps. Thomas Telford,
London, U.K.
Koerner, R.M. and G.R. Koerner. 2005. In-Situ Separation of GCL Panels Beneath Exposed Geomembranes. GRI
White Paper #5. Geosynthetic Institute, Folsom, PA 19033 USA.
Lin, L. and C. Benson. 2000. Effect of wet-dry cycling on swelling and hydraulic conductivity of geosynthetic clay
liners. Journal of Geotechnical and Geoenvironmental Engineering, 126, No. 1: 40-49.
Lupo, J.F. and K.F. Morrison. 2005. Innovative Geosynthetic Liner Design Approaches and Construction in the
Mining Industry. 2005 GeoFrontiers Conference. Austin, Texas. January 24-26, 2005.
Maurice, R. and M. Wiber, 2004. Performance of Dry Covers, Proceedings of the 11
th
Annual British Columbia
MEND ML/ARD Workshop , Vancouver., British Columbia, December 1-2, 2004-: Released March 2005


Mchaina, D.M. 1995. Conceptual Decommissioning Plan, Myra Falls Operations, Westmin Resources Limited.
Report Submitted to the British Columbia Ministry of Mines, December 20, 1995.
Mchaina, D.M. 2003. Deccommissioning and Closure Plan, Myra Falls Operations, Boliden Westmin Canada
Limited. Submitted to the British Columbia Ministry of Energy and Mines, December 22, 2003.
Melchior, S. 1997. In Situ Studies on the Performance of Landfills Caps. Proceedings International Containment
Technology Conference, US Dept. of Energy, Germantown, MD 365-373.
Melchior, S. 2002. Field studies and excavations of geosynthetic clay liners in landfill covers. In Clay Geosynthetic
Barriers. Zanzinger, Koerner and Gartung (Eds.). A.A. Balkema Publishers. Lisse. ISBN 90 5809 380 8. pp.
321-330.
Neukirchner, R.J. and G.G Lord. 1998. Covering of Soft Mine Tailings. Tensar Earth Technologies. Inc. Spring
Lake, NJ 07762.
Olsta, J. 2005. Chemical Compatibility and Installation of GCLs. In GCL University (Course Notes for one day
course on GCLs) prepared by Cetco Lining Technologies. May 10, 2005.
Petrov, R.J., and R.K. Rowe. 1997. Geosynthetic clay liner (GCL) chemical compatibility by hydraulic
conductivity testing and factors impacting its performance. Can. Geotech. J. 34: 863-885.
Rawlings, D.E. (Ed.). 1997. Biomining. Theory, Microbes, and Industrial Processes. Springer Verlag. 297p.
Renken, K., Yanful, E.K., and Mchaina, D.M. 2003a. Experimental Soil-Based Cover System to Mitigate ARD in
Potentially Acid-Generating Tailings: Pre-Construction Design and Modeling. 56th Canadian Geotechnical
Conference /3rd Joint IAH-CNC/CGS Conference, Winnipeg, Man., Sept. 29-Oct. 1, 2003.
Renken, K., Yanful, E.K., and Mchaina, D.M. 2003b. Soil-Based Cover System Field Trials to Mitigate ARD in
Potentially Acid-Generating Tailings: Construction and Preliminary Results. 56th Canadian Geotechnical
Conference /3rd Joint IAH-CNC/CGS Conference, Winnipeg, Man., Sept. 29-Oct. 1, 2003.
Renken, K., Yanful, E.K., and Mchaina, D.M. 2003c. Pilot Study of Cover Systems to Mitigate ARD in Combined
Wet and Dry Closure of a Potentially Acid-Generating Tailings Storage Facility. British Columbia Reclamation
Symposium. Kamloops, BC. Sept. 15-18, 2003.Renken, K., Yanful, E.K., and Mchaina, D.M. 2004.
Temperature Dependent Behaviour of Low Percentage Bentonite Granular Soil Mixtures: Remarkable Results.
57th Canadian Geotechnical Conference/5th Joint CGS/IAH Conference, Quebec City, Quebec, Oct. 24-27,
2004.
Renken, K., Yanful, E.K., and Mchaina, D.M. 2005. Field Performance Evaluation of Soil-based Cover Systems To
Mitigate ARD For The Closure Of A Potentially Acid-Generating Tailings Storage Facility. British Columbia
Reclamation Symposium. Abbotsford, BC. Sept. 19-22, 2005 (in Press).
Rollin, A. 2004. Long term performance of Polymeric Geomembranes. 57th Canadian Geotechnical Conference/5th
Joint CGS/IAH Conference, Quebec City, Quebec, Oct. 24-27, 2004. Session 5D. pp. 20-24.
Smith, M.E. 2003. HDPE Leach Pad Liners and Pre-Curing of Copper Ores.
http://www.technology.infomine.com/leachmine/PapersEnglish/HDPE.pdf. accessed Aug. 23, 2005.
Southen, J. M. 2005. Thermally Driven Movement Within and Beneath Geosynthetic Clay Liners. Ph.D. Thesis.
University of Western Ontario, London, Ont. 320p.
Stewart, D. and K. von Maubeuge. 1997. Cost effective and efficient solutions with geosynthetic clay liners for
sealing applications in the mining industry. In Tailings and Mine Waste 97. Balkema, Rotterdam.
Thiel, R. and M.E. Smith. 2004. State of Practice Review of Heap Leach Pad Design Issues. Geotextiles and
Geomembranes. Elsevier Publisher. Vol. 22(6). 555-568.
Thiel, R. 2005. Shear Strength and Slope Stability. In GCL University (Course Notes for one day course on GCLs)
prepared by Cetco Lining Technologies. May 10, 2005.
Trauger, B. 2005. Introduction and Hydraulic Properties. In GCL University (Course Notes for one day course on
GCLs) prepared by Cetco Lining Technologies. May 10, 2005.