Solar Hydrogen Fuel Cell
Solar Hydrogen Fuel Cell
Solar Hydrogen Fuel Cell
Aim: To find the faradays efficiency of the given prototype solar hydrogen fuel cell system
Apparatus:
Solar module
Electrolyser
Fuel cell
Load module
Demonstration Ammeter/Voltmeter
Lamp 100-150 watts
9 hook-up cables
2 long tubes
2 short tubes
2 tube clips
Distilled water
Principle: Working of solar hydrogen fuel cell system consist of following steps
1. The solar module converts light into current.
2. This current splits water into hydrogen and oxygen in the electrolyser.
3. The gases generated can be stored in the storage cylinders of the electrolyser.
4. The hydrogen and oxygen are fed into the fuel cell, where they are converted directly into
current.
5. The current drives the electric motor, which activates the propeller
Theory: Refer operating instruction manual of Heliocentris Hydro genius professional
Experimental Setup:
Procedure:
1. Set up the apparatus as shown in Fig. b2a. As an alternative to the solar module, you can also use a
DC power supply if you want the electrolyser to fill up more quickly. NB: the voltage across the DC
power supply must not exceed 1.8 volts, the current must not exceed 3 amps. Check the
polarity of the electrolyser!
2. Check that the gas tubes between the electrolyser and the fuel cell are correctly connected. Adjust
the rotary switch on the load module to "OPEN".
3. Make sure that both of the electrolyser's gas storage cylinders are filled with distilled water up to the 0
ml mark. Use the illuminated solar module to set a constant current (between 700 and 900 mA). The
solar module must be aligned toward the light source in such a way that gas production can be clearly
observed (see Experiment e1).
4. Purge the entire system for 5 minutes with the gases produced. Then set the rotary switch on the load
module to 2 for 3 minutes. The ammeter should now show a current of about 400 mA and the
voltmeter a voltage of about 0.75 volts. Now turn the rotary switch on the load module back to
"OPEN".
5. Use the clips to close the two short tubes at the gas outlets of the fuel cell (see Fig. b2b).
6. Interrupt the connection between the solar module and the electrolyser when the 60 ml mark is
reached on the hydrogen side of the electrolyser.
7. Since the system always has a certain leakage rate because of its tubes and seals, an idle
measurement must be made first. Record the loss of hydrogen from the hydrogen storage cylinder
without load (position "OPEN") over a period of 3 minutes and determine the leakage rate in ml of
hydrogen per minute.
8. Reconnect the electrolyser to the solar module and refill the hydrogen storage cylinder up to the 60
ml mark. Then interrupt the power supply to the electrolyser again.
9. Adjust the resistance to 0.3 . Record the volume of hydrogen consumed by the fuel cell in 180
seconds. Also measure and note the voltage and current at the fuel cell. Switch back to "OPEN" after
180 seconds.
10. Repeat steps 8 and 9 twice and calculate the average values for the amount of hydrogen consumed
by the fuel cell. After making the measurements, switch to "OPEN" and remove the clips from the
tubes of the fuel cell.
Observations:
interpretation.
Fuel cell without load determination of the
leakage rate: t = 3 min
Volume loss of hydrogen from
storage
ml
Leakage rate of system ml/min
Table of measurements: R = 0.3 time = s V1 = ml Vaverage= ml
voltage = V V2 = ml Vcorr = ml
current = A V3 = ml
Calculations:
Determination of the Faraday efficiency of the fuel cell:
The Faraday efficiency
F
is the
ratio between the experimentally determined volume of hydrogen and the volume of
hydrogen to be expected theoretically:
F
= V
H2experimetal
/ V
H2theoretical
The Faraday efficiency of the electrolyser should be close to 1(100%). Faradays 2
nd
Law makes it possible to
calculate the volume of hydrogen to be expected theoretically
I.t = n. z. F
V
H2theoretical
= (I. t. V
m
)/(z. F)
Result/Graphs: