Chemistry Test

CHEMISTRY TEST
Max.Marks:
Q1.Classify the following as ionic, metallic, molecular, covalent, or amorphous.
a) P4O10 b) (NH4)3PO4 c) I2 d) Plastic e) graphite f) Brass g) Rb h) LiBr i) Si
Q2.A Solid AB has NaCl structure. If the radius of cation A
+
is 100 pm, what is the possible maximum and minimum
radius of anion B
-

Q3. If the radius of Mg
2+
, Cs
+
, O
2-
,S
2-
and Cl- ion are 0.65 A
0
, 1.69 A
0
, 1.40 A
0
, 1.84 A
0
and 1.81 A
0
respectively.
Find the coordination number of MgO, MgS and CsCl.
Q4.In corundum, oxide ions are in hcp and aluminium ion occupies 2/3 of the octahedral void. What is the formula of
aluminium oxide?
Q5.Classify as being either a p-type or n-type semiconductor
a) Ge doped with In
b) B doped with Si
Q6.Explain the type of deviation exhibited by a mixture of
a) ethanol and acetone
b) acetone and chloroform.
c) phenol and aniline. Draw a graph of vapor pressure vs mole fraction in each case.
Q7.Derive the mathematical expression to show that the relative lowering of vapor
pressure of a solution containing a nonvolatile solute and a volatile solvent is equal to
the mole fraction of the solute.
Q8. What will happen when
a) Eext =1.10V
b) Eext <1.10V
c) Eext > 1.10 V is applied on the cell Zn
+2
/ Zn || Cu
2+
/ Cu ? (E
0
Zn
2+
/ Zn = - 0.76 V and E
0
Cu
2+
/ Cu = + 0.34 V
Q9.Resistance of a conductivity cell filled with 0.1M KCl is 100 ohm. If the resistance of the same cell filled with 0.02
M KCl is 520 ohm, calculate the conductivity and molar conductivity of 0.02 M KCl. Conductivity of the 0.1M KCl is
1.29 s/m.
Q10. 2NO2+F2 _2NO2F
Experiment (NO2)M (F2)M Rate(M/S)
1 0.2 0.05 0.006
2 0.4 0.05 0.012
3. 0.8 0.10 0.048 Find the order with respect to NO2 and F2.Also find the overall
order of the reaction. Deduce the mechanism of the reaction.

Q11. The rate constant for the first order decomposition of H2O2 is given by following equation:
Log K = 14.34 1.25 X 104 K/T. Calculate Ea for this reaction and at what temperature will its half-life be 256
minutes.
Q12.A colloidal solution of AgI is prepared by two different methods shown below:-

(i) What is the charge of AgI colloidal particles in the two test tubes (A) and (B)?
(ii) Give reasons for the origin of charge.
Q13.Outer electronic configuration of elements a) X= 4f
1
5d
1
6s
2
b) Y=4f
7
5d
0
6s
2
Determine the
a) atomic numbers of X and Y b) Stable oxidation states of X and Y
c) Which is an oxidizing agent and which is a reducing agent? Why?
Q14. Account for the following:
a) KMnO4 titration is not carried out using HCl as acid medium
b) Highest fluoride of Mn is MnF4 while highest oxide is Mn2O7.
Q15. Write the IUPAC name and indicate the oxidation state, electronic configuration and coordination number of the
central metal in the complex [Co (NH
3
)
5
Cl ] Cl
2.
Also give the primary and secondary valences of the metal. Give
the stereochemistry and magnetic moment of this complex.

Q16.Write the reactions involved in the extraction of
a) Fe from hematite ore b) Cu from copper pyrite ore
c) Zn from zinc blend ore d) Al from alumina
Q17.Draw the graphs
a) Concentration Vs time for reactant.
b) Concentration Vs time for product.
c) Concentration Vs time for a zero order reaction.
d) ln[R] Vs time for a first order reaction.
e) potential energy diagram of a catalyzed reaction.

Q18.Concentrated sulphuric acid is added followed by heating to each of the following test tubes
labeled (i) to (v)

Identify in which of the above test tube the following change will be observed. Support your answer with the help of a
chemical equation.
(a) Formation of black substance
(b) Evolution of brown gas
(c) Evolution of colorless gas
(d) Formation of brown substance which on dilution becomes blue.
(e) Disappearance of yellow powder along with evolution of colorless gas.
Q19.Give one application each of coordination compounds in
a) Analytical chemistry
b) Biological system
c) Medicine
d) Extraction of metal/metallurgy
e) Estimation of hardness of water.
Q20. A metal ion Mn+ having d4 configuration combine with three didentate ligand to form a complex compound.
Assuming D0>P
i) Draw the diagram showing d orbital splitting during this complex formation.
ii) Write the electronic configuration of the valence electron of the metal Mn+ ion in terms of t2g and eg.
iii) What type of hybridization will Mn+ ion have?
iv) Draw the structure of isomers exhibited by this complex.

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CHEMISTRY TEST

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