This paper describes various sealing solutions for severe service conditions. The CAN2A and CAN8 rotary face seals use tungsten carbide against carbon-graphite. An integrated engineering approach to high performance sealing with O-rings is described.
This paper describes various sealing solutions for severe service conditions. The CAN2A and CAN8 rotary face seals use tungsten carbide against carbon-graphite. An integrated engineering approach to high performance sealing with O-rings is described.
This paper describes various sealing solutions for severe service conditions. The CAN2A and CAN8 rotary face seals use tungsten carbide against carbon-graphite. An integrated engineering approach to high performance sealing with O-rings is described.
This paper describes various sealing solutions for severe service conditions. The CAN2A and CAN8 rotary face seals use tungsten carbide against carbon-graphite. An integrated engineering approach to high performance sealing with O-rings is described.
SEVERE SERVICE SEALING SOLUTIONS AECL-11181 Presented at Seminar on Applied Tribology in Engineering Toronto, Ontario, September 1994 by R. Metcalfe and R. Wensel REACTOR DEVELOPMENT ENGINEERING TECHNOLOGIES DIVISION Chalk River Laboratories Chalk River, Ontario KOJ 1J 0 1994 September AECL- 11181 Severe Service Sealing Solutions R. Metcalfe and R. Wensel Fluid Sealing Technology Unit Atomic Energy of Canada Limited Chalk River Laboratories, Ontario Successful sealing usually requires much more than initial leak- tightness. Friction and wear must also be acceptable, requiring a good understanding oftribology at the sealing interface. This paper describes various sealing solutions for severe service conditions. The CAN2A and CAN8 rotary face seals use tungsten carbide against carbon-graphite to achieve low leakage and long lifetime in nuclear main coolant pumps. The smaller CAN6 seal successfully uses tungsten carbide against silicon carbide in reactor water cleanup pump service. Where friction in CANDU fuelling machine rams must be essentially zero, a hydrostatic seal using two silicon carbide faces is the solution. In the NRU reactor moderator pumps, where pressure is much lower, eccentric seals that prevent boiling at the seal faces are giving excellent service. All these rotary face seals rely on supplementary elastomer seals between their parts. An integrated engineering approach to high performance sealing with O-rings is described. This is epitomized in critical Space Shuttle applications, but is increasingly being applied in CANDU plants. It includes gland design, selection and qualification of material, quality assurance, detection of defects and the effects of lubrication, surface finish, squeeze, stretch and volume constraints. In conclusion, for the severe service applications described, customized solutions have more than paid for themselves by higher reliability, lower maintenance requirements and reduced outage time. Introduction Although high performance sealing is required in many places, two industries lead all others in terms of their demandsnuclear and aerospace. More than 25 years ago a group of specialists was formed at AECL's Chalk River Laboratories to pursue seal research, product development and field application, resulting in a vast improvement in the performance, safety, reliability and maintainability of a wide variety of fluid seals (Ross-Ross and Metcalfe, 1983). This was necessary to resolve major shortcomings of commercial seals, which were evident in early CANDU nuclear plants. The resulting technology has become widely used throughout the sealing industry. Rotary seals for main coolant pumps (MCPs) were the first focus of R&D effort because these pumps are the heart of any nuclear plant (Earl, 1983). Their size, pressure CANada Deuterium Uranium and speed are at the leading edge of face seal applications, and heavy water is neither the easiest nor cheapest fluid to seal. Further rotary seal applications followed for other nuclear pumps and fuelling machines, including pump seals for AECL's main research reactor, NRU. Most recently, a third generation seal design has been supplied for the Bruce MCPs. The benefits from these improvements are ongoing for the life of these plants. Elastomers, either supplementary or separate from rotary seals, have also been vastly improved in CANDU plants since their early days. Original work established the susceptibility of various commercially available elastomers to radiation, compression set and extrusion in hot water or humid air-ozone environments (Wensel, 1977; Wensel and Cotnam, 1978). Thus, preferred elastomers could be selected for various static applications. Later work concentrated on dynamic performance, where information on stiffness, damping, resilience, friction and fretting damage for various elastomers and conditions could then be applied to design and maintenance of rotary seals (Wensel, 1985). In an outgrowth of this technology, AECL made a major contribution towards improving O-ring seals for Space Shuttle boosters in the aftermath of the Challenger accident (Wensel et al., 1988). Following the successful re-design of the case segment "field joints, AECL became prime contractor to Lockheed-Aerojet and NASA for seal design in the new generation of "advanced" boosters, employing numerous O-ring-sealed joints. This included extensive testing of various elastomer formulations to optimize the recipe for these applications and to ensure consistent quality. Similar methodology is used for selection, specification and inspection of elastomer seals for severe nuclear service (Wensel, 1993). Face Seal Fundamentals Rotary end face seals for severe service are "pressure-balanced" to enhance lubrication. Balancing is accomplished by stepping the so- called "flexibly-mounted" seal ring to reduce the hydraulic closing force. In Figure 1, the flexibly-mounted "rotor" is sealed to the shaft with an O-ring and runs against a solidly- supported "stator." Its hydraulic balance ratio is the ratio of the rear area of the rotor to the seal face area, normally about 70%. Springs pushing against the rear of the flexibly- mounted ring are normally used to hold seal faces closed whenever pressure alone is not enough. I f the spring force is large this may substantially increase the effective balance ratio, especially at low operating pressures where hydraulic forces are relatively low (Mayer, 1977). Face lubrication is provided by the leaking fluid. The film between the faces is no more than a few micrometers, and viscous shearing of liquid can often generate sufficient heat for boiling. This can cause dry rubbing and wearout, unless the faces remain separated by a film of gas. The boiling regime is particularly difficult to design for because liquid seals are generally axisymmetric and relatively narrow, while gas seals have hydrodynamic features and wide faces to provide enough "lift" to avoid rubbing contact (Yasuna and Hughes, 1990). Large seals for high pressure water have been the focus in the nuclear industry, where the hydrostatic effects of seal face deflection govern their performance (Watson, 1963; 1965). Thus, liquid leaking between the seal faces causes a separating force dependent on the pressure gradient. When the faces are flat and parallel, the pressure gradient is almost linear (Curve 1, Figure 2) and the separating force, represented by the area under the curve, is independent of the face separation. Under these conditions, hydrostatic lubrication with a stable, "balanced" separation is not possible. When the faces deflect to form a diverging gap in the direction of leakage, the pressure gradient falls below Curve 1of Figure 2 and lubrication is reduced further, causing hard rubbing contact near the outside of the seal faces. However, when the seal faces deflect to form a converging gap in the direction of leakage, the pressure profile is represented by Curve 2 of Figure 2 and becomes stable. Smaller separation would move Curve 2 towards a greater separating force, and vice versa. Therefore, full film lubrication is achieved at a stable separation dependent on the amount of convergence and the balance ratio, whether the seal is rotating or not. Many further aspects of liquid and gas seal performance are explained in the literature, covering tilting (Metcalfe and Brown, 1984), eccentricity (Metcalfe et al., 1978), misalignment (Kittmer and Metcalfe, 1980), whirl (Etsion and Constantinescu, 1984), and the response to various environmental conditions and transients (Lebeck, 1991). Success is usually a matter of providing sufficient lubrication without too much leakage penalty. Full film lubrication is often impossible, and performance is then governed by boundary lubrication. For severe service, one or more limits must be pushed beyond its generally accepted norm (Nau, 1980). There are many different ways that rotary face seals can and do fail (Metcalfe, 1976). Bruce NGS Main Coolant Pump Seals Earlier CANDU plants were designed with smaller MCPs and at least one spare. With Bruce-A, the bold precedent of no spare MCPs was set. However, the pump manufacturer's (Byron J ackson Canada) "SU" seal design from Pickering, which was upscaled for Bruce, proved to be too unreliable (Figure 3, at right). This was when the earlier years of seal R&D at Chalk River began to pay big dividends. The seal's deflection characteristics were analyzed by the newly available finite element technique and found to be highly sensitive to pressure and temperature changes (Metcalfe, 1976; Metcalfe et al., 1982). With this ammunition, several innovative modifications were quickly designed and tested. The aim was to maintain a converging gap between the sealing faces over as much of the operating cycle as possible by re-shaping the parts and their means of support, by matching the stiffnesses and thermal expansions of the materials, and by improving the flow of heat away from the sealing interface. This became the "CAN1" seal (Figure 3, at left), whose parts were fully compatible with the existing seal cartridges for Bruce-A. It saw commercial service from 1976 until a few years ago, when it was finally phased out in favour of the CAN2 design (Inset, Figure 3), which has a slightly higher pressure rating (Metcalfe, 1979). CAN2 seals began serving 600 MW CANDU needs at Point Lepreau and Wolsong-1 after extensive rig testing, followed by in-pump testing at the pump manufacturer's Toronto plant. Bruce-B and later, Darlington, used this design from the start. Its reliability has been excellentless than 1/2 day/unit/year of forced outage at Bruce, and virtually none elsewhere (Metcalfe and Burchett, 1987). However, recent changes in service conditions have measurably reduced seal lifetime at Bruce-A (intermittent low pressure running, which was not an original requirement for the CAN2 seals). Therefore, further upgrading to the CAN8 seal has begun, as described later. CAN2A Seal for BWRs By the early eighties, performance of the CAN2 seals at Bruce was well established and noticeably better than the pump manufacturers' seals being used in US Boiling Water Reactors (BWRs). Nine Mile Point Unit One (NMP-1) was having particular difficulties because of seals that were causing an average of one forced outage per fuel cycle, with consequential bearing failures. They contracted AECL to develop the CAN2A seal (Figure 4)a CAN2 derivative that was optimized to withstand extensive running at reactor head pressure (<0.3 MPa) and to close off leakage if cooling to the seal cavity was reduced. This latter feature was firstly to protect the close- clearance carbon bearing, and secondly to withstand loss of cooling during emergency "station blackout" conditions (Metcalfe, 1991). The two "original" CAN2A seal cartridges were installed in two of the five MCPs (termed Reactor Recirculation Pumps in BWRs) at NMP-1 in 1986. One was removed for assessment after one fuel cycle and found to have an extrapolated lifetime of more than ten years. CAN2A seals were then installed in the remaining MCPsall have performed perfectly ever since. At the refuelling outage in 1993, the second of the "original" (1986 vintage) CAN2A seal cartridges was removed for assessment. It was in excellent condition and looked capable of 15 to 20 years of service (Figure 5). NMP-1 's sister plant, Oyster Creek, has also installed CAN2A seals, beginning in 1990. Instead of replacing seals every fuelling outage (and nevertheless suffering forced outages) these plants have now extended seal replacement plans to five fuel cyclesan outstanding improvement. The savings to date according to NMP-1: More than $35 million! Because of station blackout concerns in the US, CAN2A seals in a full-scale pump mock- up were extensively tested for response to loss of cooling while the pump slows to a stop, but remains hot and pressurized (Figure 6). The seal faces did not "pop-open" or give high leakage under any circumstances, unless already detectably deteriorated (Rhodes, 1992; Green and Inch, 1992). CAN8 Seal Development Background. The CAN8 seal was developed in 1990 for the Grand Gulf BWR as a scaled-up and improved CAN2A. It is shown in a seal cartridge for the Bruce plant in Figure 7. It was installed in both Grand Gulf pumps in 1991 and ran smoothly through the fuel cycle. Both were then assessed while the pumps were being disassembled for shaft inspections. Their extrapolated lifetime was estimated as four fuel cycles. They were re built with further minor improvements, and continue to perform reliably. Features of the CAN8 seal that made it suitable for Grand Gulf also make it suitable for CANDUs. Parts are fully compatible from Grand Gulf to Bruce, Darlington, Lepreau and Wolsong-1. They can be adapted to fit Sulzer-Bingham pumps at Embalse, Cemavoda, Wolsong-2, -3, -4 or future CANDUs. The basic requirement in CANDUs is for reliable lifetime exceeding five years. The CAN2 seal does not quite achieve this. Its three main drawbacks are addressed by the CAN8 sealdamage to the stator holder through spinning of the stator, higher wear rate when subjected to varying conditions with low pressures, and occasional displacement of its U-cup during rapid transients. The particular features that overcome these and similar drawbacks of the pump manufacturers' seals are described in detail as follows (see Figure 8). Reduced sensitivity to transients. A major improvement achieved with the CAN8 design is its reduced sensitivity to transients, shown schematically in Figure 8. This is primarily responsible for its stability and long lifetime under normal running, and its capability for long-term back-up operation with full pressure drop across a single stage. When pressure or temperature in the seal gland is changed, its seal faces remain relatively flat. If they twisted and deformed, leakage would change and, more importantly, the faces would rub and wear more rapidly. The result is seen in the minimal size of the hysteresis loop (Figure 8) compared with previous designs. On the stationary side of the seal assembly, the much stiffer holder of the CAN2 seal was a major improvement over the more flimsy stainless steel back-up ring of the SU seal (Metcalfe, 1985). It also allowed the stator to be much smaller than in the SU seal, with correspondingly less of the unpredictable deformation (swelling, warpage) that occurs with carbon-graphite. The CAN8 seal uses an extremely stiff tungsten carbide stator support in place of stainless steel. This isolates it from the seal cartridge flanges, which warp when service conditions change and severely affect the pump manufacturers' seals (Martinson, 1980). On the rotating side, the contact area between the rotor and rotor support of the CAN8 seal is roughly a factor of five less than for SU or CAN2 seals. Thus, the CAN8 rotor is supported mostly by water pressure. Being made of very stiff tungsten carbide, it is therefore relatively unaffected by twisting of the rotor support, which is much less stiff. Reduced wear at low pressure. The CAN8 seal is much better for running at low pressures than the CAN2 or pump manufacturers' seals because of improved cooling of the rotating parts. Its seal faces do not heat-check. When seals run at low pressure, less water leaks between the faces and they axe more inclined to rub against each other. More heat can be generated, which can cause all the water to vaporize, particularly in the upper stage which vents to atmosphere. In the CAN8 seal, the faces rub less because the faces remain flatter. Any heat is rapidly conducted to the back of the tungsten carbide rotor because of its higher conductivity. A secondary cooling flow behind the rotor removes the heat. This flow is centrifugally pumped through holes in the rotor support. No spinning of the stator. To prevent the CAN8 carbon-graphite stator from spinning in its holder, as happens frequently with CAN2 seals, it is held gently around its outer circumference by a composite elastomer- stainless steel key ring with sixteen soft lugs. This has been shown to be capable of torques many times higher than would occur in service, without causing damage to the seal. The shapes of the elastomer lugs and the mating slots in the stator have been carefully designed to avoid stress concentrations, since carbon- graphite is relatively weak and brittle. Refurbishment. Only the stator, O-rings and U-cups (Figure 7) must be replaced every time when servicing the CAN8 seal. The rotor may normally be used twice by reversing it. In contrast with the CAN2 seal, the CAN8 tungsten carbide stator support is re-usable without re-lapping, and will not scratch or warp. Re-lapping of the seal flange or rotor support faces is unnecessary for the CAN8 seal, unless to remove burrs caused by careless handling. This seal is much less dependent on their flatness than are other seals. U-cup retention. The CAN8 seal is not prone to its U-cups being displaced ("rolled" out of their original seated position and unable subsequently to function). This happens with the SU seal through reverse pressurization, (e.g., if the reactor system pressure drops rapidly, the lower stage seal in the cartridge may briefly be pressurized in reverse, which displaces the U-cup). This happened more than once with CAN2 seals during commissioning of the four Bruce-B units. Although BWRs were thought to be immune, this also happened once at Oyster Creek through a "not-to-be-repeated event." Verification tests have demonstrated that the CAN8 seal is not susceptible to this. Loss of cooling. Temperature and radiation-resistant, functionally qualified, elastomer parts are supplied with the CAN8 seal. The ethylene propylene (EPDM) compound that is used is uniquely formulated to AECL's specification. It was chosen through extensive testing to maximize performance in hot water and to minimize long term deterioration. The O-rings and U-cups are quality-assured and batch-tested. The material is qualified by demonstrating that (in the form of a 3.5 mm cross-section O-ring) it is capable of resisting extrusion through a 0.38 mm gap for 18 hours at 290C and 7.5 MPa. CAN8 elastomers, therefore, are qualified for the worst case of complete loss of cooling to a stationary pump, as could happen during a "loss of cooling" or station blackout scenario. CAN6 SealReactor Water Cleanup B ackground. In contrast to MCP applications, seals for Reactor Water Cleanup Pumps (RWCP) are required by their BWR users to have very low leakage as well as long, reliable lifetime. Size is only 65 mm diameter, compared with 100 to 240 mm for MCPs. Speed is 3600 rpm, there is no injection cooling, and a single seal takes the full pressure drop. MCPs are less than half this speed and use at least two seals in tandem. The CAN6 seal (Figure 9) was developed under contract to five US utilities with particular needs for improved lifetime and ease of maintenance. In some cases these pumps were the single greatest source of radiation dose at the plant. As an improvement over the conventional seal it replaced, the CAN6 seal is a cartridge design that is installed as a unit, rather than piece by piece. This not only reduces maintenance time, but ensures the cartridge is correctly assembled in clean conditions on the bench. Cooling of the RWCP seal gland is primarily by recirculation through an external cooler, forced by a pumping ring built into the seal. There is also a cooling water jacket, but this alone does not keep the gland below 100C. The seal faces are tungsten carbide against silicon carbidetwo hard faces for added abrasion resistance, since unlike CANDU MCPs, there is no injection of clean water into the seal gland. For integrity, the faces are shrink-fitted inside and out with high strength stainless steel. Unwanted deformations due to pressure or temperature are prevented by the symmetrical, reversible shape of the seal rings and the way they are supported hydraulically. The only deformations are due to thermal gradients, designed to be self-relieving through "twisting open" of the seal faces in response to frictional heating between them. Instead of the springs rotating, in this case they are stationary in order to isolate the seal from distortion or misalignment of the gland ring, which is not changed when the CAN6 seal is installed. This puts the sliding O-ring (0-4 in Figure 9) in the coolest possible location to accommodate the inevitable tilt, axial movement and wear. Details of O-ring design for this application are given in a later section. CAN6 seals are currently operating in ten pumps at five plants (see Figure 10). Of these, all except the pumps at Grand Gulf are "hot- leg" installations, where pumpage is at full reactor temperature of almost 300C. At Grand Gulf, the RWCPs are mounted in the "cool leg" of the system, making recirculation cooling superfluous. The first two CAN6 seal installations were at Hope Creek in mid-1990. Figure 10 summarizes the service record here and elsewhere, showing just one seal failure (after two years) due to normal operation. Grand Gulf, the "cool-leg" installation, has the best recordboth pumps have been trouble-free for almost three years since installation of CAN6 seals. Other plants have all had some "consequential seal failures" due to inadequate cooling, crud or bearing failures. It is revealing to study these in more detail, since there are many lessons to be learned about avoiding similar problems in the future. Cooling lessons learned. Cooling problems have been most prevalent at River Bend, where a cluster of seal failures occurred in the fall of 1993 because heat transfer surfaces had degraded through fouling. Cooling was marginal previous to this, and because there is no recirculation cooling whenever the pump is stopped, standby conditions caused steam-cutting erosion of the faces of several of these seals. The start-up procedures (venting, heat-up, timing of bearing oil changes, etc.) were revised, and clean coolers were installed. Subsequently, both CAN6 seals at River Bend ran normally for eight months, although their gland ring temperatures were still around 120C. The seals were replaced for preventive maintenance, both to install larger external coolers and to make piping changes to inject clean, cool water into the seal cavity from an external source. This cools the seal cavity regardless of whether the pump is running or not, and if it fails, recirculation cooling now takes over. There have been no further problems. The lesson for CAN6 seals is that to achieve their potential they must be kept from boiling across their faces at all times. This requires that the running temperature in the seal cavity be below 100C (i.e., gland ring temperature below about 120C). Because seal gland temperature will rise to essentially that of the gland ring when the pump is stopped, hot standby time must be minimized. Other lessons learned from the field. Bearing failures have impacted on the CAN6 seals at River Bend and Perry. Heat from a worn bearing boosts the temperature of the seal by conduction along the pump shaft. The increased gland ring temperature can be mistakenly interpreted as a seal problem, even before the higher temperature has damaged the seal. Any significant, relatively sudden and systematic increase of temperature should therefore be suspected as a bearing problem unless there is also noticeable seal leakage. Misalignment led to one aborted CAN6 seal installation at River Bend and rubbing-galling damage between the sleeve and spring holder (Figure 9). This was surprising, since the minimum clearance is elsewhere. However, it was discovered that this gland ring and some others have very loose spigoted fits into the pump cover. Eccentricity is now checked carefully after each gland ring has been bolted- up. I f the gland ring or bore of the seal gland is more than 0.1 mm eccentric to the pump shaft, centering is called for by loosening and re-tightening the bolts. Otherwise, there may be difficulty installing the CAN6 seal cartridge, and its internal parts may rub and gall. Crud (dirty water) appears in the CAN6 service record (Figure 10) as the reason for seals in both pumps at Hope Creek "failing" in late 1990. In fact they were preventively replaced following chemical cleaning of the system. Normal crud levels in the reactor water cleanup system do not seem to have caused any problems in CAN6 seal performance, even though none but River Bend have installed an injection system. At Hope Creek, custom handling jigs are used to facilitate maintenance. At Grand Gulf, Hope Creek and Limerick, a training pump helps installation to be practised, unhindered by space, protective clothing or other constraints. These have helped avoid installation snags. CAN6 service conclusions. The only failure mode in almost thirty pump-years of service of the CAN6 design has been inadequate cooling to the seal cavity, where boiling temperatures have led to steam-cutting erosion of the seal faces, particularly during standby conditions. Otherwise, there have been no failures in normal service and no wom-out or broken parts. It has been crucial to follow-up closely, and to ensure through good communication and field service that each user learns not to repeat another's problems. The CAN6 design has proven itself robust and durable, with service lifetime of two or more years under normal conditions. Fuelling Machine Ram Seals In order to refuel CANDUs on power, fuelling machines attach to each end of each hot, pressurized fuel channel in turn, remove a seal disc, then proceed to push fuel in one end and out the other. The two concentric rams doing this are driven through four ball screws, all within the ram housing pressure boundary. Their four drive shafts are each sealed by an end face seal where they pass through this pressure boundary. For the fuelling machines in Pickering and the 600 MW CANDUs, the severe requirement is for seal torque to be no more than 0.6 N.mlow enough to achieve accurate positioning of the rams. Seal gland conditions are: - 25 to 55C - 0, 3 or 10 MPa (gauge) -24, 36 or 246 rpm, reversible Reliability is essential, as fuelling proceeds round-the-clock, and the machines are needed almost 40% of the time and "visit" almost a thousand fuel channels per year (Ross-Ross et al., 1975). Many seal types were tested during early development. The most acceptable was a six- pocket-with-orifice hydrostatic design, similar to those used in the first CANDU MCPs at NPD (Nuclear Power Demonstration), then at Pickering (Billington and Fitzsimmons, 1966; Pothier and Rod, 1980). Its face materials were bronze vs. carbide-coated stainless steel. Leakage was about 2 L/min at full pressure, and its main failure mode was dirt or erosion affecting the orifice flow and de-stabilizing the seal, thus causing face rubbing, friction and wear. It was also difficult and expensive to manufacture, with quality assurance of the orifices, face coating, and the bellows for axial movement being particular problems Performance was tolerable throughout the seventies and early eighties because each plant kept a spare machine available, but the days of generous spares came to an end in the mid eightieshigher reliability was demanded. A different type of hydrostatic seal (Figure 11: CAN13 seal) was quickly developed using analysis techniques and materials not available to the early CANDU designers. The bellows was substituted by an O-ring of material with demonstrated capability for the service. Silicon carbide was chosen for the new seal faces based on extensive hydrostatic seal testing in the seventies, when it was found to be both resistant to erosion and tolerant of moderate rubbing contact. The need and means to hold it securely in compression (by shrink-fitting) to prevent breakage had also been understood. Requirements for low torque and low speed necessitated a hydrostatic seal; the extreme range of pressure required a seal face that would neither erode while on pressurized standby, nor wear when rubbing at pressures as low as atmospheric. The flat-conical seal face configuration was developed so that the flat region of the face would rub lightly and not wear out-of-flat while running at atmospheric pressure and 246 rpm. The conical region was optimized to meet the torque requirement yet, for three reasons, to have minimum leakage at the higher pressures: (1) to minimize the erosive flow, (2) to minimize the amount of dirt consequentially filtered out between the seal faces, (3) to reduce the 2 L/min leakage per seal suffered with the previous seal design. CAN 13 seals were first installed in Pickering in 1988 after extensive testing in laboratory rigs and fuelling machines. Full commitment to change to this design was made in 1989 and completed by 1992. There have since been no failures of the 64 seals running in these eight reactors, despite dirty operating conditions in Pickering-B that have caused many pump seals to fail. The 600 MW CANDUs have similarly changed to the new seals. Savings due to installation of CAN 13 seals at Pickering are estimated to be at least M$1 per year, with about a third coming from maintenance savings and two thirds from extra kW-h of production. Extrapolating over the expected lifetimes of the existing plants now using this seal, the savings are of the order of M$ 20. The economic viability of future plants has also been much enhancedall this coming from an original 1985 investment of $53,230 for design, development, rig-testing and supply of the first two seals! NRU Eccentric Seal The NRU research reactor at Chalk River Laboratories has been the workhorse of CANDU system development since it was built in the fifties. The moderator (at atmospheric pressure in its vessel) carries away the reactor heat, pumped by seven Main Heavy-Water Pumps. These operate at 1700 rpm and no more than 0.35 MPa, with frequent stop- starts. Requirements for the seals are less than 0.2 mL/min leakage, high integrity and a reliable lifetime of seven years. The seal used for these pumps until 1992 was difficult to install and often exceeded the desired leakage. Spare parts were becoming unobtainable, and its lack of a back-up seal compromised its integrity, as seen when 565 kg of tritiated heavy water, worth ~$250 000, spilled into the Ottawa River in 1988 following a pump bearing failure. Although the activity of this spill (4xl014Bq total) had been diluted to less than 2% of the maximum in Canadian Drinking Water Guidelines by the time it reached the next community downstream, public concerns gave further impetus to system improvements, including better seals (Champ et al., 1989). Because boiling at the seal faces is a severe problem at low pressure, AECL's patented eccentric concept was applied (Figure 12) (Metcalfe, 1993). This idea traces its origins to elliptical seals developed by AECL for use as back-up seals at NPD, Douglas Point, KANUPP, RAPP and Pickering (Vilim and Zeller, 1963). Later, the same sweeping action across the seal face was adapted into an eccentric seal by Hayward Tyler, who supplied thus-equipped MCPs for the Caorso BWR (Italy). Success came after contract assistance by AECL to control deformations, which had been a similar problem for elliptical seals at high pressures. Recent testing at Chalk River has demonstrated that eccentric seals are suitable for CANDU MCP service, with deformation no longer a problem. They are also simple to manufacture. The eccentric seeds for NRU are designed into a single-unit cartridge to facilitate installation (Figure 13). They are arranged to expose the outboard seal to full pressure initially, with the inboard seal providing complete back-up in the event of outboard seal failure. This outboard "main seal," works as the primary seal while the inboard "backup seal remains flooded with water at full pressure on both sides (Metcalfe et al. 1994). Material and geometric details of both seals in the cartridge are given in Table 1. Each stationary seal ring (stator) is axisymmetric and eccentric. It is shaped to give a geometric balance ratio of 0.75. Adding the spring load, the effective balance ratio exceeds unity for sealing pressures below 0.26 MPa. Without eccentricity, such seals in NRU would operate under boundary lubrication conditions with danger of boiling between the faces. With eccentricity, the faces are hydrodynamically lubricated and cooled under all operating conditions. Extra cooling caused by the eccentricity was calculated to be about five times the cooling from all other effects (i.e., the temperature of the seal faces above ambient is five times less than for an otherwise similar concentric seal). The seal cartridge was tested as shown in Figure 13. A short-term test evaluated its general suitability, and the leakage and friction characteristics of each seal stage in the cartridge in response to pressure and temperature changes, then a long-term test verified the reliability of the final design. The short-term tests included pressures from 0.04 to 0.4 MPa; rotational speeds of 500, 1000 and 1700 rpm; temperatures between 24 and 70C; and spring load between 85 and 135 N. Leakage was less than 0.1 mL/min for all cases, and power requirement variations were less than 0.2 kW over and above the drive power for fully lubricated conditions (~0.5 kW for two seals and bearings). The sealing faces after tests were seen to be in excellent shape, with barely measurable wear. The long-term test that followed was a 2300-hour test, including stop-starts and intermittent axial movements. Mean leak rate was less than 0.05 mL/min, and power remained low, as before. Post-test examination showed the faces of both seals to be in good condition. Carbon stator thicknesses were measured for overall wear0.025 mm for the main seal and 0.013 mm for the back-up, easily meeting the requirement for seven years of extrapolated seal lifetime. Carbide rotors were barely worn. The first eccentric seal cartridge was installed in the NRU pumps in November 1992 and continues to operate successfully. Others are being installed in the remaining pumps. Table 1: Material and Geometric Details of NRU Seal for Main Heavy-Water Pumps DETAILS OF NRU SEAL Seal Face Material Sealing Face Details Part Type Density (kg/m3) Thermal Conductivity (W/m.K) Specific Heat (J /kg.K) Outer dia. (mm) Inner dia. (mm) Balance dia. (mm) Stator Eccentricity (mm) Spring Force (N) Rotor Tungsten Carbide 14900 90 180 102 93 95. 3 2. 4 89 Stator Carbon Graphite 1400 20 750 O-Ring Seal Fundamentals There is much more to sealing than simply squeezing an O-ring according to handbook guidelines, as was dramatically pointed out to the world when the Challenger exploded in J anuary 1986 (Metcalfe et al., 1989). The design of O-ring sealed joints is always a compromise, but significant improvements are usually feasible if, from the outset, the seal design is integrated with the associated parts not added as an afterthought, transcribed or scaled from another application. For optimal performance, the priorities and trade-offs required for design decisions must be well understood. Fundamental understanding of the sealing mechanism is crucial (Metcalfe and Wensel, 1994). Sealing is achieved when the leakage paths remaining between an O-ring and the counterface against which it is pressed are small enough to allow insignificant leakage. There must therefore be enough force to cause the relatively soft O-ring material to conform to the topography of the counterface (i.e., to in fill the machining marks, scratches and other roughness). Initially, this depends on the amount by which the O-ring is squeezed from its original shape, which becomes flattened across each sealing "footprint," creating contact force (Kuran et al., 1994). O-rings are able to transmit hydrostatic pressure independently of their deformation, since the hydrostatic component of stress on an O-ring creates no deformation (elastomers are essentially incompressible). Typical deformed shapes are usually the result of pressure variations of about 0.7 to 1.4 MPa (100 to 200 psi). In higher pressure applications, therefore, O-rings act almost as fluid-filled bags. This emphasizes their difference from conventional gaskets (e.g., spiral-wound), which rely on large clamping forces and require heavy flanges. WTien hydraulic pressure is applied to the upstream side of an O-ring, this may either increase or reduce the contact force (contact pressure), depending on whether the arrangement promotes "pressure-assist" or not. This is a crucial consideration for soft seals in general. Too much pressure-assist can cause friction problems, for example during sliding of piston-type seals. On the other hand, negative pressure-assist inevitably leads to leakage at higher pressures and is generally undesirable unless the sealed pressure is significantly lower than the initial contact pressure. The wedge-shaped seal in Figure 14 illustrates pressure-assist behaviour. This will not seal well if installed as shown in Figure 14b, whereas when installed the opposite way, as in Figure 14a, the greater squeeze at the upstream end of the sealing footprint acts to reduce penetration of hydraulic pressure and thus increase the contact force and sealing effectiveness. Space Shuttle Booster O-Rings Elastomeric O-rings are suitable for most quasi-static joints at temperatures below about 150C. They continue to be the most suitable option for Space Shuttle boosters (SRMs, Solid Rocket Motors), provided the hot gas inside is kept away from the joints! The contrast between the field joints (those assembled at the launch site) of the "Re designed" SRM (RSRM) and those of the next generation ("Advanced") ASRM, now in development, illustrates how much improvement a new, integrated approach can give compared with even the most thorough "afterthought" (Metcalfe and Wensel, 1994): (1) The RSRM joint (Figure 15) required structural changethe addition of a "capture feature" to the upper half of the jointto reduce the pre-Challenger gap opening problem during ignition transients. Many new case sections had to be manufactured to implement this. (2) O-ring squeeze was increased for the RSRM by using a larger cross-section in the same depth, but wider, groove. This made the assembly procedures more problematic because of greater friction and the chance of cutting the O-rings, which then fuelled a thorough revamping of the post-assembly leak-checking procedures and their efficacy. (3) Various elastomers, manufacturing processes and lubricants were investigated for the RSRM in order to boost resilience and subjugate defects compared with the original SRM. However, the manufacturing process of splicing ground cord stock into finished O-rings presented such a restriction that only the defect detection and acceptance criteria were significantly changed. Heaters therefore became an RSRM requirement for cold launch conditions. By comparison, there are fewer field joints in each ASRM, and they have been designed (Figure 15) with the following sealing considerations in mind: (1)The ASRM case structure is designed for essentially zero gap opening at all the O-rings. (2) High squeeze is used without creating assembly problems because of the face seal arrangement. (3) The elastomer formulation is considerably improved and the O-rings are net-moulded at their full size (not spliced from smaller pieces). Another ASRM joint where vast improvement over the "handbook" design was possible is the igniter-to-case joint, shown in Figure 16. This is a static application. Since the only significant movement is during assembly, it is desirable to create high contact forces in the sealing footprints. It is also desirable that these be as wide as possible. High squeeze and large O-ring cross-section are therefore two important design goals. As in the field joints, the basic shape of this joint is essentially fixed by the structural requirement for zero gap opening. Positioning the seals in a conventional bore seal arrangement (Figure 16a) raises concerns for damage to a critical sealing surface or an O-ring during assembly. The sealing bore of the uppermost member could easily be scratched due to metal-to-metal contact as it slides across the upper lip of the lower member. This is unlikely to be noticed during assembly due to the large size and weight of the components. Such scratches in the cross-footprint direction could cause leakage. O-ring damage could also occur during assembly because of the sliding distance, and particularly when passing a leak check port. High squeeze exacerbates this. Considering the effects of machining tolerances, including out-of-roundness and eccentricity of these two large-diameter components, the squeeze range for the conventional bore seals will be about 15%. This means that if for assembly reasons 25% squeeze is not to be exceeded, then at the opposite extreme of tolerances the squeeze will only be 10%. This range is too wide. In considering potential accident conditions, a conventional design would incorporate two identical seals having critical sealing surfaces on the same member, directly in line with one another. These are prime candidates for common-mode failure. For example, should a leak path be established by erosion of the first seal by a jet of high temperature gas, erosion of the second seal could be quick to follow. Recognizing these problems of the bore seal design, and returning to the original goals of high squeeze and large footprint, it is clear that this conventional arrangement is marginal at best. Neither can the cross-sectional size of the O-rings simply be increased to improve the situation. Available axial space is already used up by: (1) lead-in chamfers for assembly, (2) groove width (to provide sufficient axial space to prevent overfill of the groove by the squeezed O-rings), (3) the lip on the uppermost edge of the uppermost groove (to ensure that it will not be damaged by bending or breaking if bumped). By moving the O-rings into the comers (Figure 16b), much more axial space becomes available for the sealsthe lead-in chamfers become part of the seal cavities, the lip above the uppermost seal no longer exists and the axial lengths of the grooves become less (relative to the O-ring sectional diameter). Much larger seals can thus be accommodated in the given spacein fact, in addition to the 30% increase in seal size incorporated in the alternative design shown, the axial length and weight of the joint is reduced. The comer seal arrangement allows much greater squeeze to be applied to the O-rings, since this comes from axial compression rather than radial interference. It is also much better controlled, being governed by short axial dimensions and tolerances rather than large diameters. The potential for common-mode failure has been reduced by the alternative design, which avoids an "in-line" arrangement. Damage to the lower seal due to "jetting" of hot gases past a leak in the first seal is much less likely because of the tortuous path. The potential for assembly damage due to sliding, or to the leak check port, is eliminated. From the perspective of transient response to sudden pressurization at SRM ignition, the comer seals have a number of additional advantages over the rectangular groove bore seal arrangement. The first is "diagonal sealing." The "inlet" to each seal cavity is diagonally opposite the "outlet." On sudden pressurization then, there is a larger pressure force urging the O-ring to move towards, and thus seal, the outlet. With a bore seal arrangement, such "pressure-assistance" can be delayed, particularly when the O-ring is pre-set to the upstream edge of its groove (as is the case in this application because a high pressure leak check is conducted prior to flight). A further advantage is that once pressure is established, the contact force in the footprint region is magnified due to the acute angle, over that for rectangular grooves. High contact force means better in-filling of asperities and flaws and better "bridging" of contaminants. Other benefits of the alternative design are: (1) It eliminates clearance at the lower of the two seals, thus minimizing any concerns over possible extrusion. (2) Critical sealing surfaces are more accessible, both for initial machining and for refurbishment (ASRM components are intended for multiple use). (3) Internal stresses in the O-ring are lessened; triangular confinement avoids the damaging stresses of high squeeze in an unconstrained rectangular groove. Looked at as a whole, many benefits accrue from the comer seal design. However, parts must be carefully toleranced to avoid damage by exceeding 100% fill. As stated previously, elastomers are essentially incompressible; however, they may swell, and their thermal expansion is -2x10"^/C (i.e., an order of magnitude greater than most metals). Pump Seal O-Rings Similar improvements are obtainable in many other sealing applications through open- minded exploration of the geometrical options, and adherence to basic seal design principles (Metcalfe et al., 1992). A good example is given by the CAN6 seal for reactor water cleanup pumps (Figure 9), whose service history was described earlier. These required less radical treatment than the Space Shuttle O-ring examples, but each O-ring is tailored to its specific function. They were designed for high reliability, not for particularly high leak-tightness. In the CAN6 seal, slight additional leakage from the O-rings is not significant compared with water leaking between the rotating seal faces. Design parameters for the seven O-rings that supplement the rotary face seal are shown in Figure 9. Note that a wide range of squeezes is used. For good sealing, the higher the squeeze the better. The trade-off, however, is friction, which is a prime consideration for the axially moving O-ring 0-4. By contrast, for static face-type O-rings such as O-l, where no sliding occurs either during assembly or in service, high squeeze can be used. The upper limit then depends on factors such as tear strength at the service temperature, since the O-ring will split apart if squeezed too highly in a wide, rectangular groove (Stevens, 1989). O-ring 0-1 has negative stretch (compression), which creates elastic interference at its outside diameter to hold it in place; otherwise, assembly would be very difficult. The principle of using stretch to locate an O-ring is enhanced for 0-6 and -7 by using a 10 degree slope (semi-dovetail). Only minimal squeeze is needed for these, since they provide only back-up sealing. O-ring 0-5 is stretched 10% and has zero squeeze. This is because the CAN6 seal cartridge is inserted as a unit. There must be minimal friction as 0-5 slides into place, and it must be stretched tightly or it could fall out of position. Sealing relies on the strong pressure- assist behaviour induced by the "diagonal sealing" arrangement, whereby any leakage must pass from one comer to the diagonally opposite comer of the space that 0-5 occupies. Optimum Elastomer Selection Elastomer Characteristics. Elastomer seal "compounds" are intermittently produced in relatively small batches, compared to most industrial products. They are made by adding a variety of ingredients to a base elastomer stock. The choice of ingredients and their proportions govern the physical, chemical, and functional properties of the finished product. Since there are many base elastomers and many additives, the variety of compounds having different properties is often overwhelming. Industry wide standardization by formula does not exist, nor is it feasible. Being organic, elastomers are subject to deterioration with time, temperature, fluid contact, and other environmental influences. To select the best elastomer compound for a particular set of service requirements, compound-specific testing is required, with careful choice of performance criteria and test methodology (Wensel, 1993). Readily measured physical properties, like hardness and tensile strength, have traditionally been favoured in the selection process, rather than functional performance like (for seals) leak-tightness and extrusion resistance in actual service conditions. There is often little correlation. Hence, functionally related testing procedures must be used if high performance is needed. They must be based on the particular conditions under which the O-ring will or could be required to serve. These "functional tests" must cover all relevant effects of the actual service conditions, including accelerated lifetime testing (Wensel, 1985). Each test should reproduce a type of failure encountered or expected in actual service. Although functional tests must provide the basis of the methodology for selection of compounds for severe service, readily measured properties can then help to "fingerprint" the specific compound, once selected, to ensure that subsequent batches are the same. Space Shuttle O-ring selection. As an example of an extremely comprehensive process to derive the best fluorocarbon compound for all O-rings of the ASRM, thirteen measurable, function-related properties and their corresponding test methods were devised that encompassed all the service requirements for these seals (see rows and columns of Figure 17). Next, weighting factors were estimated for each "box" of this matrix, based on the expected influences of each property on each sealing requirement. Trade-offs were appraised and quantified during this process. The thirteen properties of sixteen different candidate compounds were then measured. Each formulation and manufacturing process was strictly controlled. The quantifiable results, analyzed to ensure statistical significance, were then used with the pre- established weighting factors to select the optimum compound for ASRM service. They also demonstrated that most of the sixteen compounds could be considered "qualified" for the intended service, but with reduced margins. Next, this optimum compound was evaluated for variations, especially batch-to- batch, to establish rejection limits for quality assurance. Three functional properties (compression-recovery, hot jet resistance, high temperature extrusion resistance) and eight physical/chemical properties (specific gravity, tensile strength, elongation, modulus, hardness, compression set, rheometry, volumetric swell) were found sufficient for this purpose. Together, these properties and their respective rejection limits served to "fingerprint" the compound. Nuclear O-ring selection. For nuclear applications, ethylene propylene (EPDM) is often the preferred basic elastomer class due to its resistance to hot water and aging. In its formulation, there are trade-offs such as extrusion resistance gained at the expense of thermal aging. Selecting the optimum commercially available compound requires both testing and application-specific prioritizing of performance requirements (Wensel 1994). Figure 18 illustrates the wide range of performance that occurs. In this case, three EPDMs are compared on the basis of thermal aging resistance when used as static seals in hot water. The range of failure times, particularly at the higher temperature condition, is striking: 37 weeks for the best and only 2 weeks for the worst. Similarly, extrusion resistance tests in hot water for loss of cooling in a typical nuclear plant (Figure 19) give a wide range of performance between EPDMs. One compound resists extrusion at gaps four to five times those of another, although in common industrial practice such materials are often regarded as equivalent. There is clearly a strong need to be compound-specific. Specific testing to qualify elastomer seals in MCPs for station blackout conditions has been performed for several US PWRs (Pressurized Water Reactors). The problem is that because no external power is available for an extended period to drive pumps for cooling, the MCP seals can reach main coolant temperatures of >250C (Rhodes et al., 1987). Seal leakage is the safety concern, since this could uncover the reactor core. There are two possibilities, one is leakage directly past the elastomer seals, the other, through opening of the end face seals as a consequence of "binding" of the elastomer seals when the shaft moves axially. The qualification process defined potential worst case events, then tested to determine whether the elastomer (i) maintained a seal, and (ii) did not "bind" excessively to the shaft. This included accelerated aging of the elastomer seals. Figure 20 is an example of a test matrix to assess integrity of the elastomer seals in a particular MCP seal under station blackout conditions. Analysis (thermal-hydraulic, structural, etc.) provided predicted "best- estimate" pressure, temperature and gap conditions for each of the many O-ring seals in this assembly. From this, four possible "worst-case plus margin" combinations of pressure, temperature, gap and pre-history (thermal and radiation aging) were identified. Statistically significant numbers of tests were run to determine failure pressures at each of the gap-temperature conditions and thus to demonstrate that the seals would continue to function during and after a station blackout. To assess the possibility of "binding" of any axially moving elastomer seals, axial stroking tests were conducted at predicted worst-case conditions, and forces were compared to the balance of hydraulic forces that essentially maintain an equilibrium small separation between the rotary face seal rings (Rhodes and Metcalfe, 1987). Figure 21 shows schematics of some of the seals that have been tested, and Figure 22 shows the basic arrangement of the apparatus (a pair of seals back-to-back in a test cell connected to a pressurized water source with heat provided by a laboratory oven and stroking by an electromechanical device connected through a load cell outside the oven). From these tests it was found that axial friction forces are often two to three times greater at station blackout temperatures than at normal operating temperatures. This can be a relatively large de-stabilizing force, causing the seal rings to be dragged apart and leak excessively. Each seal design must therefore be assessed individually from this standpoint. Specifications, Inspection and Defects To ensure the correctly performing compound is received for critical applications, specifications must not unwittingly open the door to other compounds in the same class of elastomer. Otherwise, service may be unacceptablelow safety margins, unreliability and frequent replacement. I f alternative compounds are needed as back-up, then each must be separately qualified. As a minimum, purchase specifications should require that each elastomer seal be traceable to the particular "batch" of ingredients mixed and processed together to form the unvulcanized stock from which the seal was made, and that a manufacturer's certificate of conformance be provided confirming the seal's size, compound identification, batch number, date of cure, hardness, specific gravity and tensile strength relative to the manufacturer's expected values. In AECL-produced MCP seal assemblies for example, all elastomer seals are batch qualified by functional testing. In addition, the most critical elastomer seals in the assembly are individually serialized, and their moulds have cavities for simultaneous production of O-rings, which can then be functionally tested. This, and positive identification of the parts, serves to verify the moulding process in addition to verifying the batch of unvulcanized elastomer. Receiving inspectors at a plant, in this case, need only confirm the documentation. Defectsoverall nuclear approach. An oft-neglected area of quality assurance that impacts heavily on seal integrity and reliability is inspection methodology and acceptance criteria for defects. This includes defects in the seal gland as well as in the elastomer seal, since machining marks and other irregularities in the gland surfaces can disrupt sealing just as much as can isolated scratches, pits, abrasions, and cuts in the seal itself. Although defect acceptance criteria for seals and seal glands are best established by application-specific functional testing, some general guidelines apply. Defects like scratches, machining marks ("chatter marks" in a lathe-turned part) or cuts that extend across the "footprint" of the seal are a prime concern. Whether or not these are acceptable depends largely on their steepness, i.e., their depth to width ratio. This applies equally to defects in the surfaces of the seal gland. The deeper and narrower the scratch or groove, the more difficult for the elastomer to deform into it. Limits can be assigned based on test data and analysis (Kuran et al., 1994). For surface defects, examination by unaided eye is a satisfactory inspection method. This requires stretching of each region, since many defects such as cuts and tears are difficult to see in unstrained parts. Size can be compared to reference standards that simulate acceptance limits, and (if necessary) measured using optical and mechanical aids (e.g., calibrated magnifier, depth measuring microscope, stylus profilometer). For detection of internal defects such as inclusions, voids and regions of inhomogeneity in elastomer seals, a non-destructive tool called an Elastodynamic Tester has been found most useful. This measures reaction force resulting from an imposed deformation. Figure 23 shows an automated system for elastodynamic testing of O-ringsa 1994 R&D 100 Award winner (Anon, 1994). The reaction force on two pinch rollers is measured as the O-ring is driven and squeezed between them. Internal defects are signalled by spikes in reaction force. Any generally high or low force, or variation around the O-ring, signifies abnormal properties when compared with a known baseline. Space Shuttle O-ring defects. The approach followed in developing rejection criteria and defect inspection methods for Space Shuttle O-rings was first to develop functional sealing tests that subjected the O-ring to simulated conditions exceeding "worst-case," then to use these tests to evaluate intentional defects of all plausible and potentially dangerous types (Wensel et al., 1988). For each type of defect, the critical size for unacceptable leakage was generally found by bracketing a failure at one size with a pass at a smaller size. Supplementary tests with transparent fixtures allowed defect behaviour to be observed under the simulated service conditions, both statically and during ignition transient simulations. O-rings were viewed and photographed to measure the shape and width of the footprint (region of contact) under a range of squeeze, pressure and gap opening conditions, thus establishing the size of each type of defect at which bridging of the footprint (i.e., leakage) occurs. "Defect detection requirements" were established by applying a safety factor (i.e., a reduction of at least two in the largest defect that consistently passed the sealing tests and was also seen to be safe in the footprint observations). I f the O-rings could consistently and economically be manufactured to a more stringent requirement, and detection method sensitivity was sufficiently reliable at these smaller defect sizes, then a higher safety factor than two was applied. The detection capabilities of inspection techniques were assessed relative to the detection requirements. Rejection limits specific to each adopted detection technique were determined for each defect type. For visible, directly measurable surface defects (abrasions, grooves, voids, cuts), rejection limits were defined simply in terms of defect dimensions. For sub-surface defects (voids, inclusions, regions of inhomogeneity, sub standard material where depth and orientation within the cross section were important factors), rejection limits were defined in terms of elastodynamic test results. This measured the effect of defects on the static and dynamic contact (sealing) force response, and was therefore most closely related to sealing ability. In summary, inspection requirements and defect limits for severe service should be customized to functional, application-specific testing. This assures safe service without imposing overly stringent standards and wastefully high rejection rates. Elastomer Seal Storage and Usage Elastomers are subject to deterioration with time, temperature, and other environmental influences. Ideal storage conditions are cool, dark, and free from contaminants (such as ozone, solvent vapors, etc.). Elastomer seals should be stored in a relaxed state, free from strain (i.e., not folded, twisted, or hanging on a rack). Under such conditions, most elastomer compounds will remain serviceable for many years. Measurement of critical sealing properties (e.g., compression set, extrusion resistance, hardness) of O-rings of certain ethylene propylene and nitrile compounds stored under such conditions by AECL has shown them to be essentially unchanged after more than twenty years. Not all elastomer compounds are this stable, however, particularly not all nitrile compounds. Immediately prior to installation, after verifying that an elastomer seal taken from storage is of the required size and material, it should be thoroughly examined for defects that might previously have gone unnoticed, particularly for crazing or cracking that might have occurred during storage. All contacting surfaces of the seal gland should be examined for edge break at the comers of grooves, and smoothness of lead-in chamfers and countersurfaces over which the elastomer must slide during assembly. Rolling or twisting of an O-ring in its groove with bore-type assemblies can be avoided by ensuring smooth surfaces and correct lubrication. Only a thin film is needed, and once applied, care is necessary to avoid introducing contaminants, particularly hairs and fibres, which readily create leak paths. Excessive or inappropriate lubricant, however, can cause failures (e.g., by causing swell or by restricting small flow passages or contaminating the rotary face seals in MCPs). Conclusion The Canadian nuclear industry had special needs to develop greater fundamental understanding, improved products and better practice in the field of fluid sealing. Various solutions for severe service have been described, covering both rotary face seals and elastomer seals. For face seals, controlled lubrication is the key to long seal lifeachievable in several distinct ways, but generally by considering all possible operating conditions and ensuring through good design that a favourable alignment and lubricant film face is maintained between their faces. For elastomer seals, a thorough understanding of principles is needed, coupled with an open-minded, custom-design approach, and close attention to delivering consistent, well-qualified material. The economic benefits of better sealing given by just the examples described here are in file hundreds of millions of dollars to Canada a not-inconsiderable fraction of the total $1.3 billion annual savings estimated as feasible through improved tribological practices industry-wide (Anon, 1987). In addition, there has been immeasurable spill-over, with many industries now using and benefitting from nuclear-developed sealing technology and nuclear plants benefitting from the greater knowledge gained through Space Shuttle O-ring improvement programs. Acknowledgement The contributions of many colleagues towards the sealing solutions presented here is gratefully acknowledged. References Anon, 1987, "Enhancing Reliability and Efficiency Through the Reduction of Wear and Friction,National Research Council Canada, Ottawa. Anon, 1994, "Elastodynamic Inspection System," R&D Magazine, (a Cahners Publication), September. Billington, I.J., and Fitzsimmons, T.E., 1966, "Final Report on Shaft Seal Development," Dilworth, Secord, Meagher & Associates Limited, Toronto, Ontario, Report No. DSM-203-358 Revised, (AECL Report AECL-2549). Champ, D.R., Brown, R.M., Cooper, E.L., and Cornett, R.J., 1989, "Emergency Response to a Spill of Tritiated Heavy Water - The Interface Between Emergency Response, Routine Monitoring and Research," Proceedings of an International Symposium on Recovery Operations in the Event of a Nuclear Accident or Radiological Emergency organized by the International Atomic Energy Agency, Vienna, November (AECL Report AECL-10250). Earl, A.H., 1983, "Reliability of CANDU Heat Transport Pumps," Proceedings of International Symposium on Reliability of Reactor Pressure Components, Stuttgait, Federal Republic of Germany, March 21-25. Etsion, I., and Constantinescu, I., 1984, "Experimental Observation of the Dynamic Behavior of Noncontacting Coned-Face Mechanical Seals," ASLE Transactions, Vol. 27, 3, pp. 263-270, July, (AECL Report AECL-8604). Greene, T.B., and Inch, G.B., 1992, "Evaluation of Shaft-Seal Leakage Under Station-Blackout Conditions for the Reactor-Recirculation Pumps at Nine Mile Point Unit One, Proceedings of the Fifth International Workshop on Main Coolant Pumps, Electric Power Research Institute, Palo Alto, California. Kittmer, C.A., and Metcalfe, R., 1980, "An Inside View of Rotary Seal Dynamics," Proceedings of the Symposium on Engineering Applications of Mechanics, Ottawa, June, (AECL Report AECL-6947). Kuran, S., Grade, B.J., and Metcalfe, R., 1994, "Low Pressure Sealing Integrity of O-Rings Based on Initial Squeeze and Counterface Finish." Paper accepted by STLE for publication in Tribology transactions. Presented at 1994 STLE Annual Meeting, Pittsburgh, PA, (AECL Report AECL-11154). Lebeck, A.O., 1991, "Principles and Design of Mechanical Face Seals," John Wiley & Sons, New York. Martinson, A.R., 1980, "Design, Development and Testing of Large-Diameter, High-Pressure Seals for Nuclear-Reactor, Primary-Coolant Pumps-A Challenge to the Pump Manufacturer," Lubrication Engineering, Vol. 36, 6, pp. 325-340. Mayer, E., 1977, "Mechanical Seals," 3rd English Edition, Newnes-Butterworths, London, Boston. Metcalfe, R., 1976, "End Face Seals in High Pressure Water-Learning from Those Failures," Lubrication Engineering, Vol. 32, 12, ASLE, (AECL Report AECL-5607). Metcalfe, R., 1976, "The Use of Finite Element Deflection Analysis in Performance Predictions for End Face Seals," Proceedings of Third Symposium on Engineering Applications of Solid Mechanics, University of Toronto, Toronto, Ontario, June 7-8, (AECL Report AECL-5563). Metcalfe, R., Pothier, N.E., and Rod, B.H., 1978, "Diametral Tilt and Leakage of End Face Seals With Convergent Sealing Gaps," Proceedings of 8th International Conference of Fluid Sealing, Cranfield, England, (AECL Report AECL-6234). Metcalfe, R., 1979, "Development of a Better Seal for CANDU," Proceedings of Canadian Nuclear Association, 19th Annual International Conference, Toronto, June. Metcalfe, R., Kittmer, C.A., and Brown, G.W., 1982, "Effects of Pressure and Temperature Changes on End-Face Seal Performance," ASLE Transactions, Vol. 25, 3, pp. 361-371, July, (AECL Report AECL-7644). Metcalfe, R., and Brown, G.W., 1984, "Eccentricity of Balanced End Face Seals," Proceedings of 10th International Conference on Fluid Sealing, BHRA, Cranfield, England, (AECL Report AECL-8289). Metcalfe, R., 1985, "Sensitivity of a Reactor Coolant Pump Seal to Changes of Operating Conditions," Electric Power Research Institute Report, EPRI NP- 4244, Palo Alto, California, September, (AECL Report AECL-11184). Metcalfe, R., and Burchett, P.R., 1987, "Primary Heat Transport Pump Seal Reliability, Performance and Development," Proceedings of 14th Inter-Ram Conference for the Electric Power Industry, Toronto, May, (AECL Report AECL-9547). Metcalfe, R., Baset, S.B., Lesco, R., and Selander, W.N., 1989, "Modelling of Space Shuttle Solid Rocket O-Rings," Proceedings of 12th International Conference on Fluid Sealing, BHR Group, Cranfield, England, (AECL Report AECL-11167). Metcalfe, R., Rhodes, D.B., and Peterson, A.J., 1991, "Development of a Nuclear Pump Seal for BWR Application," Proceedings of the Fourth International Workshop on Main Coolant Pumps, Electric Power Research Institute , Palo Alto, California, (AECL Report AECL-11149). Metcalfe, R., Baset, S 3 . , and Kuran, S., 1992, "Contact hydraulics in the Sealing Footprint-Effects on Deformation, Leakage and Friction of Soft Seals," Proceedings of 13th International Conference on Fluid Sealing, BHR Group, Cranfield, England, (AECL Report AECL-11166). Metcalfe, R., 1993, "Eccentric Face Seal With Asymmetric Closing Force," United States Patent Number 5,180,172, January. Metcalfe, R., Graham, T.A., and Wong, W.C., 1994, "Eccentric Seals For Nuclear Pumps," Proceedings of 14th International Conference on Fluid Sealing, BHR Group, Cranfield, England, (AECL Report AECL- 11139). Metcalfe, R., and Wensel, R., 1994, "High Performance O-Ring Sealed Joints," Lubrication Engineering, Vol. 50, 2, STLE (AECL Report AECL- 10865). Nau, B.S., 1980, "Observations and Analysis of Mechanical Seal Film Characteristics," ASME Journal of Lubrication Technology, Vol. 102, July. Pothier, N.E., and Rod, B.H., 1980, "Development Testing of a Pocket-Type, Hydrostatic Rotary End Face Seal in High-Pressure Water," ASLE Transactions, Vol. 23, 1, pp. 77-85 January, (AECL Report AECL-6378). Rhodes, D.B., Hill, R.C., and Wensel, R.G., 1987, "Reactor Coolant Pump Shaft Seal Stability During Station Blackout," U.S. Nuclear Regulatory Commission, NUREG/CR-4821, EGG-2492, May, (AECL Report AECL-9342). Rhodes, D.B., and Metcalfe, R., 1987, "Preventing 'Dryout' and Popping-Open' Failures in End Face Seals," Proceedings of the 4th Acot Research Seminar, Tribology Research for Canadian Industry, National Research Council Canada, Ottawa, May. Rhodes, D.B., 1992, "Performance of the CAN2A Recirculation Pump Seal Cartridge During a Station Blackout," Proceedings of the Fifth International Workshop on Main Coolant Pumps, Electric Power Research Institute , Palo Alto, California. Ross-Ross, P.A., Adams, E.J., Dixon, D.F., and Metcalfe, R., 1976, "Performance and Reliability of Primary Circuit Components in CANDU Reactors," reprinted from Nuclear Energy Maturity, Proceedings in Nuclear Energy Series, Pergamon Press, Oxford and New York, (AECL Report AECL-5092). Ross-Ross, P.A., and Metcalfe, R., 1983, "Mechanical Development for Reliable Reactor Components," paper presented at the CSME Council and Annual General Meeting in Calgary, 1980 April, (AECL Report AECL-8186). Stevens, C.A., 1989, "Prediction of Fracture in Unconstrained Elastomeric O-Ring Seals," Proceedings of 12th International Conference on Fluid Sealing, BHRA, Cranfield, England. Vilim, P., and Zeller, L.A., 1965, "Shaft Seal for A Pump," Canadian Patent Number 716.850, August. Watson, R.D., 1963, "Effect of Seal Ring Deflection on the Characteristics of Face-Type Mechanical Shaft Seals in High Pressure Water," (AECL Report AECL- 2242). Watson, R.D., 1965, 'Terformance Testing of Conical-Face High Pressure Rotary Shaft Seals," (AECL Report AECL-2551). Wensel, R.G., 1977, "Resistance of O-Ring Seal Compounds to Heat and Ionizing Radiation in Air and in Water," (AECL Report AECL-5697). LEAKAGE ^ HOUSING \N PRESSURE STATIC O-RING STATOR ROTOR s AXIALLY MOVING O-RING SPRINGS AXI AL FORCES AND BALANCE PRESSURE PROFILE O-RING FRICTION CLOSING PRESSURE SPRING FORCE Figure 1. A Rotary End Face Seal with Flexibly-Mounted Rotor. The axial forces on the rotor must be in equilibium. This is possible without any contact between the seal faces if the hydraulic pressure profile has the shape shown. Wensel, R.G., and Cotnam, B.M., 1978, "Evaluation of O-Rings of Various Elastomer Compounds for Service in Hot Water," (AECL Report AECL-6214). Wensel, R.G., 1985, "Factors Affecting Wear Damage to Elastomer Seals in Main Coolant Pump Face Seals," Electric Power Research Institute, Report EPRI NP-4245, Palo Alto, California, September, (AECL Report AECL-11185). Wensel, R., Cotnam, B., Gentili, H., and Constantinescu, I., 1985, "Friction and Axial Force/Displacement Characteristics of Elastomer Seals in Water," Lubrication Engineering, Vol. 41, 9. Wensel, R.G., Metcalfe, R., Pothier, N.E., and Russell, B.G., 1988, "O-Ring Seal Studies for Space Shuttle Solid Rocket Booster Joints," Canadian Aeronautics and Space Journal, Vol. 34, No. 4,1988 December, (AECL Report AECL-9897). Wensel, R., 1993, "Using Improved Elastomers to Enhance CANDU Station Reliability," Proceedings of International Nuclear Congress, INC 93, Toronto, October, (AECL Report AECL-10912). Wensel, R.G., Metcalfe, R., and Rhodes, D.B., 1994, "Overcoming Problems with MCP Elastomer Seals," Proceedings of the Seventh International Workshop on Main Coolant Pumps, Electric Power Research Institute, Palo Alto, California, (AECL Report AECL-11182). Yasuna, J.A., and Hughes, W.F., 1990, "A Continuous Boiling Model for Face Seals, ASME Journal ofTribology, Vol. 112, April. Figure 2. Hydrostatic Pressure Profile Characteristics between End Faces of a Rotary Seal. LOCKING PLATE TERTI ARY OR BACK-UP SEAL ( CARBON SEGMENTED BUSHING) GLAND RETURN OR STAGI NG FLOW (NO. 2) PRI MARY OR / NO. 1 STAGE / SEAL / SHAFT SLEEVE Figure 3. Seal Cartridge for Bruce MCPs. The BJ -SU seal parts are shown at right; the AECL CAN1 parts at left; the AECL CAN2 parts are inset (No. 1stage only). Figure 4. CAN2A Seal for BWR Service. Two stages are shown, -140 and 150 mm balance diameters. Figure 5. Condition of No. 1Stage CAN2A Seal Faces after Three Fuel Cycles Service. Visually both seal faces looked perfect. They are shown with an optical flat to measure their lightband flatness. The centre of each seal face is almost original condition; edges are rounded by ~1fim. The No. 2 stage was very similar. C LC OUTLET (T10) CLC INLET (T 11) CONTROLLED - BLEED OFF INTEGRAL HEAT EXCHANGER - PUMP COVER - SEAL LEAKAGE COLLECTION CAN RECIRCULATION FLOW -RECIRCULATION FLOW ( T 6) FILLER HOT LOOP INLET * SEAL CARTRIDGE Figure 6. Nine Mile Point Reactor Recirculating Pump Mock-Up. Thermal mass and external piping were included for full simulation of station blackout behaviour. Figure 7. CAN8 Seal for BWR and CANDU Service. The CAN8 seal parts are shown Bruce seal cartridge. ENVELOPE OF POSSIBLE DEFLECTION FOR 6.9 MPa (1000psi) DEFLECTION HYSTERESIS LOOP FOR PRESSURE INCREASE THEN DECREASE SPAN OF POSSIBLE DEFLECTION FOR 6.9 MPa (1000 psi) (|iin, where 40 jxin = 1 ^m) TEMPERATURE SENSITIVITY Figure 8. Comparison Showing Improved Deflection Characteristics of CAN8 over CAN2 and SU Seals for Bruce No. 1 Stage. The separate plots for each stator face and rotor face show how they deflect in response to pressure changes. Scales are all equal, and the span of possible deflection (|iin for 1000 psi) is given by the lightly shaded regions. The direction of arrows shows deflection hysteresis when pressure is increased to 6.9 MPa (1000 psi) then decreased to zero (darkly shaded regions). Any environmental temperature variations change deflection within the lightly shaded region according to the sensitivities shown boxed. Assumed friction coefficients are: >0.1 for stator to holder; >0.3 for rotor to holder. Deflection cannot go beyond these regions unless actual friction is higher. QUENCH PUMP COVER / SPACE CONSTRAINT mm LABEL SIZE SECT. dia. INNER dia. SEAL TYPE INNER dia. OUTER dia. AXIAL SQU EEZE FILL STR ETCH LUBR ICANT 0-1 243 3.5 104.4 Face 85.7 108.0 2.5 29% -3% No 0-2 225 3.5 47.2 Bore 47.6 53.7 4.3 13% 74% 0.7% Yes 0-3 227 3.5 53.6 Bore 53.8 59.9 4.3 14% 74% 0.5% Yes 0-4 230 3.5 63.1 Bore 66. 1 72.4 4.3 10% 68% 4.7% Yes 0-5 230 3.5 63.1 Bore 69.8 76.5 4.6 0% 58% 10.6% Yes 0-6 230 3.5 63.1 Face 66.7 ~ 3.2 6.7% ~ 5.7% No 0-7 230 3.5 63.1 Face 66.7 ~ 3.2 6.7% ~ 5.7% No Figure 9. CAN6 Rotary Face Seal Assembly Showing Custom O-Ring Gland Parameters. This seal is for Reactor Water Clean-up Pump Service in BWRs. Figure 10. CAN6 Service Record, Showing All Replacements and Reasons. Figure 11. CAN13 Seal for AECL Fuelling Machine Ball Screw Rams. The rotating seal face is flat-conical to give hydrostatic lubrication when pressurized. I I S tator Eccentric housing O-Ring Springs Rotating seal face Stationary seal face SECTION XX eccentricity Figure 12. Tilt-Resistant Eccentric Seal Arrangement. The stator is mounted eccentrically, but because its shape and loading are axisymmetric, it has no tendency to tilt relative to the rotor which is fixed rigidly to the shaft. The rotating seal face has a velocity component, Vr, normal to the edge of the stationary seal face. Figure 13 NRU Main Heavy Water Pump Seal Cartridge in Seal Tester. SEALING FOOTPRINT SEEPAGE PRESSURE SEALING FOOTPRINT Figure 14. Wedge-Shaped SealEffects of Forward vs. Reverse Pressure. TOP WALL (MOVABLE) " ADVANCED" SOLID ROCKET MOTOR (ASRM1 FIELD JOINT -1.2 cm (0.5 in.) PRIMARY RING 2ND O-RING EXTRA O-RING CUTOUTS FOR -150 BOLTS EXTERIOR INTERIOR ' Zero gap opening ' High squeeze ' Potential for assembly damage greatly reduced CHALLENGER" SOUP ROCKER MOTOR (SRM) FIELD JOINT .TANG O-RING SEALED JOINTS IGNITER CHAMBER J OINT INITIATOR J OINT ///THROUGH-BULKHEAD INITIATOR / / / / PRESSURE TRANSDUCER 7 //^jLEAK-CHECK PLUGS jt / J p ' igniter to case joint -CASE TO CASE (FIELD J OINTS) NOZZLE (TO CASE) J OINT 1 LOCATIONS OF NOZZLE JOINTS 1. 2. 3. 4. 5 & 6 HOLES FOR177 PINS CLEVIS Initial gap still present Gap opening still present Axial movement still present Squeeze limited Assembly damage concerns Heaters necessary Figure 15. Space Shuttle Boosters and their O-Ring Sealed Joints. There are numerous such joints in each booster. Failure of a "field" joint caused the 1986 Challenger accident. The "re design" and "advanced" field joints are much more robust. (a) Conventional Bore Seals (b) Alternative Corner Seals GOOD SEALING =HIGH SQUEEZE +LARGE FOOTPRINT Figure 16. Comparison of Igniter to Case Conventional Bore Seal J oint with Improved Corner Sealing Arrangement. MEASURABLE PROPERTIES SEALING REQUIREMENTS* A B c D E F G TOTAL Compression Recovery 3 2 3 0 1 0 0 9 Age Resistance 3 3 2 0 1 0 0 9 Extrusion Resistance 0 0 3 3 2 0 0 8 Hot Gas J et Resistance 0 0 3 3 0 1 0 7 Compression Stress Resistance 0 2 1 2 1 0 0 6 Surface Toughness 0 0 0 0 3 1 0 4 Sealing Ability 0 0 2 0 0 3 0 5 Permeability 0 0 1 0 0 0 0 1 Abrasive-Erosion 0 0 0 0 1 1 0 2 Modulus 1 0 1 0 1 2 0 5 Elongation 0 0 0 0 1 2 0 3 Hardness 1 0 1 0 1 3 0 6 Swell 1 3 0 0 0 0 3 7 LEGEND* A - Follow gap opening at 0.5C (33F). B - Adequate dynamic response after 5-year assembly. C - Accept pressure without leakage. D - Resistant to heat and hot gases. E - Resistant to mechanical damage on assembly. F - Seal against a single-point machined finish of 1.6 }imRa (63 [iinch arithmetic average roughness height) G - Compatible with corrosion-inhibitor. 3 =High Relationship 2 =Moderate Relationship 1=Low Relationship 0 =No Relationship Figure 17: Example of Matrix Relating Sealing Requirements to Measurable Properties. EPDM A (177C) ...E3...EPDM B (177C) EPDM C {177C) EPDM A (232C) EPDM B (232C) EPDM C (232C) O-Rings sealing 6.9 MPa Hot Water Sectional Diameter 3.53 mm Squeezed 20% 0 10 20 30 40 50 60 Ti me (weeks) Figure 18. Thermal aging comparison of EPDM O-rings. The O-rings were inserted in a flange-type gland, heated and pressurized, held until end of test or excessive leakage. Every ten weeks each was temporarily disassembled to measure compression set (initial height-final height) / (initial height - squeezed height). P r e s s u r e
D i f f e r e n t i a l
( M P a ) 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 Ext rusi on Gap (mm) Figure 19. Extrusion resistance comparison of EPDM O-rings TEST CONDITIONS: WATER 288C, 18-HOUR HOLD AT NOTED BASE PRESSURE Figure 20. Extrusion testing of O-rings under four possible "worst-case" conditions for a particular station blackout event F A I L U R E
P R E S S U R E
O N
R A M P I N G
A F T E R
1 8 - H O U R
H O L D
( M P a ) Hi gh Pr e s s u r e Si de En er gi zi n g 0 - Ri n g Channel Seal Lo w Pr e s s u r e Si de Hi gh Pr e s s u r e Si de Lo w Pr e s s u r e Si de Hi gh Pr e s s u r e Si de O- Ri n g ^ B a c k u p Ri ng Lo w Pr e s s u r e Si de Figure 21. Typical Seals and Test Fixtures. Figure 22. Apparatus for Stroking of Axially Moving Elastomer Seals. A pair of seals back-to-back in a test ceil is connected to a pressurized water source with heat provided by laboratory oven. Stroking is by an electromechanical device outside the oven, with any "binding" measured by a load cell. Figure 23. Elastodynamic Inspection System for O-Rings. A Space Shuttle booster O-ring is being inspected. Anomalies are compared with calibration signals tor reference defects. Overall properties are compared with known baseline material.