Silicate- or epoxy zinc primers

The superior protection

April 2006 Page 1
Abstract
The application of zinc-rich primers on ferrous substrates is a very efficient method of
anticorrosion protection. It is a known fact that to achieve a long life coating system
you need a zinc primer as a first coat. Zinc offers threefold protection since it; seals
the underlying metal from contact with its corrosive environment, provides galvanic
protection and repairs minor damages in a coating forming a barrier to further
electrochemical action. A short description of these properties will be presented in
this paper. Compared to epoxy the silicates can be pigmented at extremely high levels
of zinc dust giving zinc to zinc metal contact and, consequently, excellent cathodic
protection properties like those obtained with galvanizing. There is a trend in new
international standards that the demand for zinc content is the same for zinc epoxy
and zinc silicate given weight by weight. If it is a wish to have the same zinc content
level for inorganic and organic coatings the values should be given volume by
volume. Calculation examples and figures will be presented.

The type of corrosion protection and the galvanic potential can easily be illustrated by
electrical impedance testing. The potential of bare steel in seawater is approximately
-650 mV
SCE
(Saturated Calomel Electrode) and zinc has a potential of approximately
-1050 mV
SCE
. As long as the potential is below -800 mV the primer still gives
cathodic protection. Above this level the primer will only give you a barrier effect.
For unexposed zinc primers the potential are usually between -900 mV and -1000 mV
depending on type of binder, zinc content and film thickness.

Earlier the type of zinc primer normally specified has been zinc silicate and most
typical zinc ethyl silicate. This is because within the parameters of zinc silicates the
solvent-borne ethyl silicates have been found to be generally more tolerant than the
water-borne alkali metal zinc silicates. The zinc silicates give the best corrosion
protection (especially alone), adhesion to Sa 2, chemical resistance, heat resistance,
abrasion resistance, welding and cutting properties. The water-borne silicates can be
made with zero VOC and is more environment friendly compared even to water-borne
epoxy. Zinc silicate is a typical new building coating. The zinc epoxy is easier to
apply in higher film thickness without mud cracking and can be applied with
conventional airless spray while alkali silicates normally need special equipment. Top
coating is also easier compared to silicate, which may give popping and adhesion
failure because of high alkalinity on alkali silicate paint. The curing of the zinc epoxy
is faster and is not depending on high humidity and the shelf life of a zinc epoxy is far
longer than ethyl silicate. Zinc epoxy is also more surface tolerant and is a typical
maintenance coating. Zinc epoxy was used in the shopprimer market for some years
but the consumption has decreased a lot. The reason is high zinc content and poor
weldability. The silicates are unbeatable on back burning, pore formation and welding
fumes.

Keywords: - Zinc primers
- Cathodic protection
- Zinc dust
Silicate- or epoxy zinc primers
The superior protection
April 2006 Page 2
1. Introduction
1.1 General background
The application of zinc-rich primers on ferrous substrates is a very efficient method of
anticorrosion protection. It is a common fact that to achieve a long life coating
system you need a zinc primer as a first coat. Zinc primer offers threefold protection
in that it:

1. Seals the underlying metal from contact with its corrosive environment,
barrier effect. Figure 1.

2. Provides galvanic protection. Figure 2.

3. Repairs minor damages in the coating to form a barrier to further
electrochemical action. Picture 1.

1.2. Zinc dust content
The anticorrosive and mechanical properties of zinc primers are highly dependent
upon the level of zinc dust present. Compared to epoxy the silicates can be pigmented
at extremely high levels of zinc dust giving zinc to zinc metal contact and,
consequently, excellent cathodic protection properties like those obtained from
galvanizing. The silicate will create a primary valency bonds with the substrate as
well as the zinc particles while the epoxy will create a secondary valency bonds. The
primary valency bonds are up to 6 times stronger than the secondary valency bonds.
There is a trend in new International standards that the demand for zinc content is the
same for zinc epoxy and zinc silicate given weight by weight. When standardizing the
level of the zinc content in inorganic and organic coatings the values should be given
volume by volume. It is clear from the tests in figure 3 that Zn-silicate will give much
lower potential compared to Zn-epoxy even if the weight% of Zn-dust is higher. By
comparing 86 weight% Zn-dust epoxy and silicate primers by volume instead, the
zinc epoxy will have about 55 vol% Zn-dust while the zinc silicate will have 70 vol%
Zn-dust.

Another topic that is more and more highlighted is the composition of zinc dust. Some
users of zinc primer specify metallic zinc content and other specify total zinc or zinc
dust content. The general rules are:

1. Total zinc is the sum of all the zinc compounds in the formulation including:
Zinc dust, zinc oxide, zinc phosphate etc.

2. The composition of the zinc dust is specified by ASTM D520 and ISO 3549.

3. Metallic zinc can be calculated from the zinc dust content. The zinc dust
should contain minimum 94% metallic zinc according to ISO 3549.

The standards also specify the content of impurities allowed in the zinc dust. A new
trend is the demand for low lead zinc according to ASTM D520 type II (max.
0.01%) or type III (max. 0.002%).

Silicate- or epoxy zinc primers
The superior protection
April 2006 Page 3
2. Inorganic or organic zinc primers
The zinc primers can be divided into different groups depending on the binder and
solvent. The main groups used by the industry today are:



The typical properties of common zinc primers are compared in table 1.

2.1 The cathodic properties of a zinc primer
The type of corrosion protection and the galvanic potential can easily be illustrated by
electrical impedance testing. The potential of bare steel in seawater is approximately
-650 mV
SCE
(Saturated Calomel Electrode) and zinc has a potential of approximately
-1050 mV
SCE
. As long as the potential is below -800 mV the primer still gives
cathodic protection. Above this level the primer will only give you a barrier effect.
For unexposed zinc primers the potential are usually between -900 mV and -1050 mV
depending on type of binder, zinc content and film thickness. These properties are
evaluated in figure 3. Three different formulations were tested on 4 test panels. 75
microns of zinc ethyl silicate with 86% zinc dust in dry film gave by far the lowest
electrical potential. The other panels are covered with zinc epoxy and in the beginning
the potential are the same independent of zinc content and film thickness. During the
exposure it is obvious that higher zinc content gives lower potential and is more
important than higher film thickness. The reason is that it is better conductivity when
the zinc content is higher, see figure 3. After a while the conductivity is dropping
when the Zn is sacrificing and creating Zn-salts instead. These salts will fill the
voids in the film and the primer will have higher and higher potential until the
protection is only by barrier effect. Higher film thickness will of course also
contribute to better corrosion protection even if it is less important compared to the
zinc content. The difference after outdoor exposure is clear in picture 2. A low zinc
content epoxy primer applied in different film thickness is exposed at seaside. The
area with only 15 m is full of rust all over the area while the area with 35m has
started to rust only in the scribe. The area with 80 m film thickness is still protecting
the scribe and looks perfect.

The electrical impedance testing is a well known test for zinc primers. Most of the
zinc primers will still have cathodic protection after 100 days and the primers with
high zinc content applied in high film thickness will last for more than 300 days.
Compared to real life testing of zinc primers this is not very long but still it is almost a
year. By making a scratch with a standardized size in the film the time for testing can
Inorganic Organic
Alkali silicate
Water-borne
Ethyl silicate
Solvent-borne
Solvent-borne Water-borne
Sodium Potassium Lithium 1-comp. 2-comp. Epoxy Polyure
thane
Epoxi
ester
Epoxy
1-comp. 2-comp. 2-comp. 3-comp.
Silicate- or epoxy zinc primers
The superior protection
April 2006 Page 4
be reduced dramatically. See figure 4. After 4 days the potential has increased by 123
mV. In the standardized test with panels without scratch it takes more than 100 days
to have the same increase in potential. By implementation of this test it is possible to
test and screen a lot of formulations after relatively short time with exposure.

It is also possible to test other types of primers and multiple layers by electrical
impedance. It is not only the benefit of the pure zinc primer that can be evaluated but
also the barrier effect of the total system. As long as the potential is higher or lower
compared to steel the corrosion has not started.

2.2. The curing mechanism
Even if the cured product based on ethyl silicate and alkali silicate is the same the
initial products is very different. The ethyl silicate is an organic binder before curing
while the alkali silicate is an inorganic binder. The ethyl silicate needs humidity to
cure while the alkali silicate needs to get ride of the water before it cures. The speed
of the curing of ethyl silicates compared to alkali silicates is faster and easier to
achieve. The curing process of an alkali silicate is complex and is depending on the
type of metal in the alkali silicate. The alkali silicates used are sodium, Na, potassium,
K, and lithium, Li, or a mixture of some of them. See table 2 for properties regarding
the different alkali silicates.

A short description of the curing is that the binder will react with metal, drop in pH or
heat in the beginning with further reaction with the CO
2
in the air. These reactions
will make acids that react with Zn-ions to form a zinc silicate polymer. Further
developments are the introduction of colloidal silica and styrene acryl in combination
with the alkali silicate. This is done to lower the pH of the paint which gives better
application- and top coating properties. Unfortunately this will create other
limitations. Ethyl silicates must be pre-hydrolyzed to achieve proper curing. The pre-
hydrolyzed binder will react with water and Zn-ions to create zinc silicate polymer
and ethanol. The ethanol will evaporate fast and contribute to the high VOC level.
The finished matrix will only contain inorganic material:

The water-borne silicates can be made with 0 VOC and is much more environment
friendly compared to even water-borne epoxy that needs co-solvents for film
formation.

Zinc epoxies are most used among organic zinc primers. The solvent-borne epoxies
are normally 2-components. The water-borne epoxies used to be 3-components
because a combination of zinc and water will react and create hydrogen gas. New
technology has resulted in 2-component water-borne epoxies. Epoxy is normally
cured with polyamides, amine adducts etc. Polyamides are used because of its reduced
tendency to react with the zinc powder.
- Si O Si O Si -
O O
O O
Zn Zn
Zn Zn
Silicate- or epoxy zinc primers
The superior protection
April 2006 Page 5
2.3. Mechanical resistance
The adhesion and cohesion strength of inorganic- and organic zinc primers are quite
different. As mentioned earlier the silicates will react by forming primary valancy
bonding with the steel and give excellent adhesion if the pretreatment is good enough.
Because of this reaction the silicate should only be applied on Sa 2 (Or concrete
which has a lot of metal ions accessible). On all other kind of surfaces like St 2 or old
paint the silicate will have poor adhesion. The alkali silicate are very sensitive to
impurities like oil and fat on the surface, since they do not contain any solvents for
secondary cleaning of residual oils and contaminations. Because of the chemical
reactions in the silicates the cohesion is also acceptable despite the extremely high
pigment volume concentration (PVC). The adhesion of silicate primers are very good
because of the primary valency bonding between the silicate and substrate. Zinc
epoxy primers have properties similar to other epoxy primers, with good adhesion and
mechanical strength because of the strong physical attraction in secondary valency
bonds. It is possible to have good adhesion to most surfaces depending on the
formulation. The adhesion and cohesion strength are strongly dependent of the ratio
between PVC and CPVC (critical pigment volume concentration), see figure 5.

Where will the break come in a system with a zinc primer as a first coat? It is of
course desirable to have a film that is impossible to break, but so far this is not
possible. By using zinc primer with good adhesion properties there is minimum risk
for under film corrosion. The paint system should have higher cohesion and adhesion
strength compared to the cohesion strength of the zinc primer. This will make the
cohesion in the zinc primer the weakest link so that if the paint system gets
mechanical damages down to the steel it will have as much zinc as possible accessible
to protect the "scribe". See figure 6.

The high PVC/CPVC ratio of the silicates gives also some limitations. First of all they
have a big risk for mud cracking if they are applied to thick. The ethyl silicates have
normally the highest PVC/CPVC ratio of the silicates and mud cracking will appear at
lower film thickness compared to the alkali silicates. One of the reasons for the higher
PVC/CPVC ratio of the ethyl silicates is the use of pigments and extenders in the
paint formulation. Zinc pigments need very little binder to be "wetted" compared to
normal extenders and the alkali silicates have normally higher zinc content than the
ethyl silicates. But the most important issue with regard to mud cracking is the speed
of curing. Ethyl silicates cure much faster than alkali silicates. Mud cracking appears
when the silicate matrix cannot take the internal stresses that develop during the
curing of the primer. At too high thicknesses, the upper layer of the inorganic zinc
will cure faster than the layer underneath, causing excessive stresses which the
inorganic silicate matrix cannot take.

Another benefit by using inorganic zinc silicates are that when applied it does not
shrink. Together with the surface tension of the coating this property makes these
kinds of primers very good in covering of edges, corners and bolts etc. The organic
zinc primers are not as good because they will always have some shrinkage.

2.4 Chemical and heat resistance
When it comes to chemical resistance the silicate matrix is very inert and, with the
exception of strong acid and alkalis, does not degrade in most industrial and marine
environments. The film is inert to crude and refined oils, greases, solvents, chlorine,
Silicate- or epoxy zinc primers
The superior protection
April 2006 Page 6
CO
2
and industrial gases. In general it is resistant to most chemicals within the pH
range 6-10 depending on the temperature. The corrosion resistance of zinc to the
chemical is usually the primary consideration, but in some cases, the effect of zinc
corrosion on a consumer product or chemical is of greater concern than the actual
corrosion rate of zinc. One example is the formation of zinc salts that is not acceptable
for cargoes like J et-fuel. Zinc epoxy is normally not used for chemical protection
because the epoxy used is not optimized for this purpose and the product will at the
same time have limitations because of the zinc.

Inorganic zinc silicate will have high heat-resistance and is excellent against radiation
including nuclear radiation. The heat resistance is limited by the zinc to maximum
400C since the melting point of zinc is 419.5C. Above this temperature it is a
possibility of zinc to react with the oxygen in the air or with the silicate, rendering the
zinc inert and leaving it as a simple barrier coating. The zinc epoxy primers are
limited by the type of epoxy and will normally resist temperatures up to 120C.
Another limitation for zinc primers is in contact with hot water. The galvanic effect
will start to decrease at 60C and with further increase in temperature the potential
difference will be zero or may actually be reversed at 70C. This effect will only
happened when the water is "soft" or distilled. When the "water" temperature is above
120C there are normally not any problems regarding the reversed potential.

2.5 Top coating of zinc primers
All inorganic zinc silicates are formulated with PVC above CPVC. As mentioned
earlier the film will be porous and let liquid and air come into the film. This will give
problems with popping in the next coat and in the end create pinholes. This can be
avoided by using a mist coat technique or by using a tie-coat. The zinc epoxy will
normally not have this problem but since many of the formulations have PVC/CPVC
ratio close to 1 it could happen.

The alkali silicates are binders with high pH. This high pH will give adhesion failures
of the next coat if precautions are not taken. Usually products based on lithium
silicate and with more than 90% zinc dust by weight can be top coated quite fast. By
using slower curing alkali silicates and/or lower content of zinc the time to over
coating will increase. The paint will be like fresh concrete and the pH will be reduced
during the curing process. By applying water to the surface it is possible to reduce the
pH. Ethyl silicates will not have the same problem and can easily be formulated down
to 30% zinc dust by weight and still have good top coating properties.

When it comes to ethyl silicates and organic zinc epoxy the pH on the surface is not
any topic but the products needs to be cured before they are top coated. Insufficient
curing of the primer before top coating is the main cause of failure of coating systems
based on ethyl silicates. If the primer is top coated before it is cured the film will not
develop the necessary physical and corrosion protection properties. This can however
easily be avoided by determining the degree of cure before top coating through tests
for hardness and/or solvent sensibility of the primer. A solvent-borne zinc epoxy
primer is more tolerant to be top coated but to develop the best mechanical properties
and avoid solvent entrapment it is better to have it fully cured. The water-borne zinc
epoxy can be top coated very early and almost as fast as the solvent-borne.

Silicate- or epoxy zinc primers
The superior protection
April 2006 Page 7
2.6 Cutting and welding
The high performance shopprimers used today are based on zinc ethyl silicate. These
shopprimers are very good for the welding and cutting process because they do not
contain any organic materials when cured. The silicates are unbeatable on back
burning, pore formation and welding fumes as soon as it is cured. Uncured ethyl
silicate has poor welding and cutting properties because it still contains some organic
material. Any organic material will contribute to gas formation and then increased
content of pores. The fastest shopprimers to weld in has also very low content of zinc.
High content of zinc will give problems with zinc fever for the welders and pores in
the welding seem. Picture 3 shows the pore formation when inorganic- and organic
shopprimer is used. Zinc epoxy was used in the shopprimer market for some years but
the consumption has decreased a lot. The reason is high zinc content and the organic
vehicle that creates pores in the welding seems.

3. Discussion
Both inorganic and organic zinc primers have a lot of benefits but some properties are
better for one type of primer. The different properties of alkali silicate, ethyl silicate,
solvent-borne and water-borne epoxy zinc primers are compared in table 1. Because
of these properties the area of use are different for the 2 type of primers and some
typical are listed below.

Inorganic zinc silicate:
- Barge decks because of the extremely good abrasion resistance
- High strength bolted steel because of high friction (slip) coefficient
- Pipelines, power plants and power transmission lines
- Bridges, ships and tankers (interior and exterior surfaces including storage
tanks
- Oil rigs and offshore drilling platforms
- Rocket launch gantries
- Water tanks
- Construction materials operating over 100C like: chimneys, kilns,
incinerators, furnaces, ductwork and piping
- Coal washeries
- Wharf facilities
- Mineral processing plants
- As shopprimer
- Inside the Statue of Liberty

Organic Zinc epoxy:
- "Bad" pre-treatment steel
- Maintenance project
- Touch-up of zinc silicate shopprimed steel
- High performance coatings with good flexibility
- Steel that is impossible or hard to blast to Sa 2 because of cost or
accessibility

The type of primer normally specified for new building has been zinc silicate and then
typical zinc ethyl silicate. This is because within the parameters of zinc silicates the
solvent-borne ethyl silicates have been found to be more generally tolerant than the
water-borne alkali metal zinc silicates. The zinc silicates give the best corrosion
Silicate- or epoxy zinc primers
The superior protection
April 2006 Page 8
protection (especially alone), adhesion to Sa 2, chemical resistance, heat resistance,
abrasion resistance, welding and cutting properties. The corrosion protection
properties of inorganic zinc primers and organic zinc primers are compared in figure
3. Even if the zinc epoxy primer with higher zinc content is compared to the zinc
ethyl silicate the electrical potential of the zinc epoxy is higher.

While zinc silicate is a typical new building coating the zinc epoxy is more a
maintenance primer. The epoxy is easier to apply in higher film thickness without
cracking and can be applied with conventional airless spray while alkali silicates
normally need special equipment. Top coating is also easier compared to a silicate
witch may create popping and also adhesion failure because of high alkalinity on
alkali silicate paint. Shelf life of a zinc epoxy is far better than ethyl silicate. Zinc
epoxy is also more surfaces tolerant.

The development of zinc silicate shopprimers made a revolution for the welders and
cutters in the steel business. After years with slow welding with a lot of pores in the
welding seem and slow cutting with large damages of the shopprimer, it is now
possible to do this with minimal problems. A total inorganic film with a low content
of zinc will give very good properties. The difference in welding properties is obvious
in picture 3. The next generation of shopprimers will be inorganic- and organic water-
borne products. Today these kinds of products still have some challenges that need to
be solved.

4. Conclusion
It is no doubt that zinc-rich primers a very efficient method of anticorrosion
protection. Zinc offers threefold protection since it; seals the underlying metal from
contact with its corrosive environment, provides galvanic protection and repairs
minor damages in a coating forming a barrier to further electrochemical action. In
Picture 1 is the formation of zinc salts and how the zinc protects the scribe on a test
panel during exposure obvious.

Compared to epoxy the silicates can be pigmented at extremely high levels of zinc
dust giving zinc to zinc metal contact and, consequently, excellent cathodic protection
properties like those obtained with galvanizing. There is a trend in new international
standards that the demand for zinc content is the same for zinc epoxy and zinc silicate
given weight by weight. If it is a wish to have the same zinc content level for
inorganic and organic coatings the values should be given volume by volume.

The type of corrosion protection and the galvanic potential can easily be illustrated by
electrical impedance testing. The potential of bare steel in seawater is approximately
-650 mV
SCE
(Saturated Calomel Electrode) and zinc has a potential of approximately
-1050 mV
SCE
. As long as the potential is below -800 mV the primer still gives
cathodic protection. Above this level the primer will only give you a barrier effect.
For unexposed zinc primers the potential are usually between -900 mV and -1000 mV
depending on type of binder, zinc content and film thickness.

Earlier the type of zinc primer normally specified has been zinc silicate and most
typical zinc ethyl silicate. This is because within the parameters of zinc silicates the
solvent-borne ethyl silicates have been found to be generally more tolerant than the
water-borne alkali metal zinc silicates. The zinc silicates give the best corrosion
Silicate- or epoxy zinc primers
The superior protection
April 2006 Page 9
protection (especially alone), adhesion to Sa 2, chemical resistance, heat resistance,
abrasion resistance, welding and cutting properties. The water-borne silicates can be
made with zero VOC and is more environment friendly compared even to water-borne
epoxy.

The zinc epoxy is easier to apply in higher film thickness without mud cracking and
can be applied with conventional airless spray while alkali silicates normally need
special equipment. Top coating is also easier compared to silicate, which may give
popping and adhesion failure because of high alkalinity on alkali silicate paint. The
curing of the zinc epoxy is faster and is not depending on high humidity and the shelf
life of a zinc epoxy is far longer than ethyl silicate. Zinc epoxy is also more surface
tolerant and is a typical maintenance coating.

Zinc epoxy was used in the shopprimer market for some years but the consumption
has decreased a lot. The reason is high zinc content and poor weldability. The silicates
are unbeatable on back burning, pore formation and welding fumes.

Inorganic zinc should be used where high performance is necessary. In less severe
environments, organic zincs may be used to provide good protection with better
physical properties.
Silicate- or epoxy zinc primers
The superior protection
April 2006 Page 10

References

1. Charles G. Munger, "Zinc silicate Coatings" 40 years experience, J ournal of
Protective Coatings & Linings, p.34 44, March 1985.
2. Clive H. Hare, "Protective Coatings Fundamentals of chemistry and
composition, SSPC 94-17
3. Clive H. Hare, Matthew Steele and Steven P. Collins, "Zinc loadings, cathodic
protection, and post-cathodic protective mechanisms in organic zinc-rich
metal primers" J PCL September 2001 p.54 72
4. Mike Mitchell and Mark Summers, "How to select zinc silicate primers", PCE
J uly 2001 p.12 15.
5. B. del Amo and C.A Giudice, "Influence of some variables of zinc-rich paints
based on ethyl silicate and epoxy binders, American Paint & Coatings J ournal
September 23, 1991 p. 36 43.
6. D. Pereira, J . D. Scantlebury, M. G. S. Ferreira and M. E. Almeida, "The
application of electrochemical measurements to the study and behavior of
zinc-rich coatings", Corrosion Science, vol. 30, No. 11, pp. 1135-1147, 1990.
7. Ray Mudd, "organic zinc-rich coatings" J ournal of Protective Coatings &
Linings October 1995, p. 51 63.

Silicate- or epoxy zinc primers
The superior protection
April 2006 Page 11
Substrate
Air +water
Binder
Pigments
Fillers
60-70 microns

Figure 1. Sealing the underlying metal from contact with its corrosive environment,
the barrier effect stops oxygen and water from penetrating down to the steel to create
corrosion.






Figure 2. The presence of strongly electronegative zinc-pigmented coating short-
circuits all local cell activity on steel. The steel becomes totally cathodic to the zinc
anode. The zinc corrodes, but the steel will not corrode even at bare spots. It is
mandatory that the zinc coating be in electrical contact with the steel surface;
therefore, the steel must be stripped of all contamination.
Electrolyte

Zinc primer


Steel substrate
Silicate- or epoxy zinc primers
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April 2006 Page 12
Figure 3. Development of the electrical potential in mV up to 100 days for zinc
primers with different zinc content, film thickness and binders

















Figure 4. Testing of electrical potential on a panel with scratch
-1100
-1050
-1000
-950
-900
-850
-800
0 20 40 60 80 100 120
80%Zn epoxy, 80 micron 80%Zn epoxy, 50 micron
90%Zn epoxy, 40 micron 86%Zn silicate, 75 micron
Corrosion potential
700
750
800
850
900
950
1000
1050
1100
1 2 3 4
Days
-
m
V
80% Zn epoxy,
45 microns with
scratch
Silicate- or epoxy zinc primers
The superior protection
April 2006 Page 13

Figure 5. Effect of PVC/CPVC ratio on electrical properties of organic zinc rich primers

1 mm
scribe
Zinc epoxy primer with better
adhesion properties than cohesion
properties
More steel to protect
because adhesion failure
between steel and
zincprimer.
More zinc available to
protect scribe because of
cohesion failure in zinc
primer
Zinc epoxy primer with
better cohesion properties
than adhesion properties
1 mm
scribe
Zinc epoxy primer with better
adhesion properties than cohesion
properties
More steel to protect
because adhesion failure
between steel and
zincprimer.
More zinc available to
protect scribe because of
cohesion failure in zinc
primer
Zinc epoxy primer with
better cohesion properties
than adhesion properties


Figure 6. Schematic illustration of a scribe in a steel panel. Mechanical damages
down to the steel will be created differently depending on the "weakest link" in the
paint system. The upper part of the scribe is protected with a zinc primer with better
adhesion than cohesion properties. The lower part has better cohesion than adhesion
properties.
Pigment is totally
encapsulated.

Excess resin separates
pigment particles and
pigment from substrate.

Film is strong, adhesive
and impermeable.

High electrical resistance
prevents transfer of
electrical current.

No cathodic protection
provided
Pigment is just encapsulated.

Sufficient resin to cover all
pigment particles in resin
sheath and to fill inter-
pigmentary interstiches and
achieve adhesion to
substrate.

Film is adhesive and
cohesive but will conduct
electrical current.

Cathodic protection occurs
and anode consumption is
controlled
Insufficient resin to fill all inter-
pigmentary interstiches.

Film becomes porous with poor
physical properties and reduced
cohesion and adhesion.

Lateral cohesive failure (zinc
splitting) in top coated films is
possible.

Electrolyte will penetrate the film.

Electrical conductivity is possible
between pigment particles and
electrolyte porosities.

Cathodic protection occurs, and
anode consumption is rapid.
PVC less than CPVC PVC=CPVC PVC greater than CPVC
Silicate- or epoxy zinc primers
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April 2006 Page 14


Picture 1. Ethyl silicate exposed for high humidity and salt spray for 10000 hours.
The scribes are soon "repaired" and closed by zinc salt.


Picture 2. Testing of a low zinc dust content epoxy primer applied in 80 m, 60m,
35 m and 15 m and exposed at seaside.


Picture 3. Seem after welding in inorganic shopprimer to the left and organic
shopprimer to the right. The organic material forms gasses that create pores in the
welding seem.
Silicate- or epoxy zinc primers
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April 2006 Page 15
Table 1. Typical properties of common zinc primers

Property Alkali silicate Ethyl silicate Solvent epoxy Water epoxy
Corrosion protection Excellent Excellent Very good Very good
Top coating Fair good Very good Very good
Adhesion Very good Very good Good good
Cohesion Fair Fair Good Good
Surface tolerant Fair Good Very good Good
Mud cracking Good Not so good Very good Very good
Welding Excellent Excellent Fair Bad
Cutting Excellent Excellent Fair Bad
Abrasion Excellent Excellent Very good Very good
Flexibility Limited Limited Good Fair
Shelf life, months 9 6 12 12
Curing 5 Days 12 hours 7 Days 7 Days
Pot life, hours 5 8-12 24-48 6
Flash point >100C <23C 25-35C >100C
Over-coating
interval 23C/10C:
2h / 8h 12 h / 24h 1.5h / 2h 2h / 3h
Chemical resistance Excellent within
pH 6-10
Excellent within
pH 6-10
Not used Not used
Heat resistance 400C 400C 120C 120C
VOC g/l 0 470 420 140
Vol% solid 75 60 60 55
Tolerance of high
humidity
Very good Excellent Fair Very good
Water resistance Very good Very good Excellent Very good
Solvent resistance Excellent Excellent Very good Very good
User-friendly Fair. Need special
equipment and
water must be
removed for drying
Good. Needs
humidity to
cure.
Very good Good. Water
must be
removed for
drying.

Silicate- or epoxy zinc primers
The superior protection
April 2006 Page 16
Table 2. The effect of ratio of silica to alkali metal oxide on coating characteristics:

Ratio of silica to alkali metal oxide Effect on coating characteristics
Higher Higher the viscosity of the solution
Higher the drying speed of the film
Higher the curing speed of the film
Higher the susceptibility to low temperature
Higher the chemical resistance of coating films
Lower Higher the specific gravity of the solution
Higher the solubility in water
Higher the pH value of the solution
Lower water resistance
Higher the adhesion and binding power

Silicate Chemical composition Ratio of silica to alkali metal oxide
Sodium silicate SiO
2
:N
2
O 2.4:1 to 4.5:1
Potassium silicate SiO
2
:K
2
O 2:1 to 5.3:1
Lithium silicate SiO
2
:Li
2
O 2:1 to 8.5:1







Hvard Undrum
Jotun AS, Jotun Coatings Marine and Protective Coatings Laboratory
Hystadveien 167, P.O. Box 2021,
N-3248 Sandefjord, Norway
Fax: +47 33 46 59 01
E-mail: [email protected]