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Third Semester Examination April-2009 Chemistry-Xi: Questions From Section "C"

This document contains a chemistry examination from April 2009 for class 11 pre-engineering students. It consists of 13 short answer questions and 4 long answer questions. The short questions cover topics like significant figures, stoichiometry, gas laws, atomic structure, chemical bonding, and acid-base reactions. The long questions require explaining concepts such as the rate of reaction, shapes of molecules based on valence shell electron pair repulsion theory and hybrid orbital theory, gas laws, electrode potentials and short notes on various chemistry topics. Students have 2 hours and 40 minutes to complete the exam which is out of a total of 69 marks.

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Zia Rathore
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41 views3 pages

Third Semester Examination April-2009 Chemistry-Xi: Questions From Section "C"

This document contains a chemistry examination from April 2009 for class 11 pre-engineering students. It consists of 13 short answer questions and 4 long answer questions. The short questions cover topics like significant figures, stoichiometry, gas laws, atomic structure, chemical bonding, and acid-base reactions. The long questions require explaining concepts such as the rate of reaction, shapes of molecules based on valence shell electron pair repulsion theory and hybrid orbital theory, gas laws, electrode potentials and short notes on various chemistry topics. Students have 2 hours and 40 minutes to complete the exam which is out of a total of 69 marks.

Uploaded by

Zia Rathore
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOC, PDF, TXT or read online on Scribd
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THIRD SEMESTER EXAMINATION APRIL- 2009

CHEMISTRY-XI
Class: XI (Pre-Engineering)
Time Allowed: 2.40 hours

Dated: 07-04-2009
Total Marks: 69

Note: Answer 09 questions from Section B and attempt any 02


questions from Section C.
Section-B (Short Questions)
Note: Attempt any 09 of the following Questions. The answer of each part of a
question should not exceed
5 to 6 lines.
Atomic Masses in a.m.u: C=12,O=16,Cl=35.5,H=1,Na=23,N=14
Q#1

Q#2

Q#3

Q#4

(a) What are Significant Figures ? Write down its any three rules.
(03)
(b) Determine the significant figures in the following.
(02)
(i) 0.0020 (ii) 9000 (iii) 2.300 (iv) 94.21
(a) Define any ONE of the following terms:
(01)
(i) Stoichiometry
(ii) Mole & Avogadros Number
(iii) Molecular Formula
(b) Acetic acid contains, carbon, hydrogen and oxygen.
(04)
4.2gm of sample of acetic acid on complete combustion gave 6.21gm of CO 2 and 2.54gm of water. The
molecular weight of acetic acid is 60. Find Molecular formula.
(a) Write down any three postulates of Kinetic Molecular Theory Of Gases.
(02)
3
0
(b) 1.40dm volume of a gas measured at a temperature of 27 C and a pressure of 900 torr . Calculate the
number of moles.
(02)
(c ) Why a falling drop of liquid is spherical ?
(01)
(a) What informations are obtained about the structure of an atom from Rutherfords Experiment by
bombardment with alpha particles ?
(03)
(b) Write down the properties of Cathode Rays.
(02)

Q#5

(b) What is radioactivity ? write down the properties of alpha rays.


(c) Write down the electronic configuration. Calculate the number of electron, protons and
neutrons in any TWO of the following.
80
31
40
35Br , 15P , 20Ca

(02)
(03)

Q#6

(a) Define Principal Quantum Number.


(b) Explain any FOUR of the following reasons.
(i)
Why ionic compounds are soluble in water ?
(ii)
Why bond energy of HCl is greater than H2 ?
(iii)
What is the effect of molecular weight on viscosity ?
(iv)
Why metallic crystals are good conductor of electricity ?

(01)
(04)

(v)
(vi)

Why an anion has less Electronegativity than its parent atom ?


Why 4s orbital is filled first than 3d orbital ?

Q#7

(a) What is chemical bond ? Why elements combine and form chemical bond ?
(b) Define Ionic bond. Explain the formation of Sodium Chloride - NaCl.

(02)
(03)

Q#8

(a) Define Pi bond and Sigma bond.


(b) Define and Explain Polar and Non-Polar bonds.
(c ) What is Dipole moment ? What is the effect of polarity on Dipole moment ?
(b) State and explain First Law of thermodynamics.
(a) Calculate the heat formation of acetic acid at 25 0C from the following data.
(i) 2C + 2H2 + O2 ------------------- > CH3COOH
Hf ?
(ii) C + O2
------------------- > CO 2
H = -394 kj / mole
(iii) H2 + O2
------------------- > H 2O
H = -286 kj / mole
(iv) CH3COOH + 2O2 ------------------ > 2CO2 + 2H2O H = -870.8 kj / mole

(01)
(02)
(02)
(02)
(03)

(a) State Le-Chateliers Principle. Describe the effect of change of temperature,


concentration and pressure on any ONE of the following reactions at equilibrium.
(i) N2 + 3H2 ========= 2 NH3 H = -22 kj / mole
(ii) 2SO2 + O2 ========= 2SO3
H = -395 kj / mol
(b) Define any ONE of the following.
(i) Common Ion Effect
(ii) Solubility Product

(04)

Q#11

(a) Define Molarity and Molality.


(b) Define and explain Hydration. What is the effect of nuclear charge on hydration?
(c ) What is the difference between saturated solution and super saturated solution ?

(01)
(03)
(01)

Q#12

(a) What Oxidation is Number ? Write any two rules of oxidation number.
(b) Determine the oxidation number of any Three of the following:
(i) C in HCOOH
(ii) Mn in MnO-4
(iii) Cl in HClO
(iv) Cr in K2Cr2O7
(iv)S in H2SO4
(v) N in HNO3

(02)
(03)

Q#13

(a) What is Buffer Solution ? How it opposes any change in its pH ?


(b) Define and explain PH. Calculate the PH of 0.004 mol dm-3 HCl at 250C

(03)
(02)

Q#9

Q#10

(01)

Section-c (Long questions)


Attempt any two questions:
Q#1

Q#2

Q#3

Q#4

(a) Define Rate of reaction. What are the effects of Concentration, Temperature, Catalyst, Nature of
reactant, Surface Area of reactant and Radiations on rate of reaction ?
(06)
(b ) Balance the equation by Ion-Electron Method.
(06)
MnO4- + Fe2+ ------------------------- > Mn2+ + Fe3+
(a) Predict the shapes of the following molecules on the basis of Electron-Pair Repulsion Theory
(i) BeCl2 (ii) BF3 (iii) CH4
(06)
(b) Predict the shapes of the following molecules on the basis of Hybrid Orbital Theory.
(i) H2O (ii) NH3 (iii) CCl4
(06)
(a) Sate and explain Boyles Law
(06)
(b) What is electrode potential ? What is Standard Electrode Potential ? Determine the electrode
potential of Zinc metal.
(06)
Write down short note on any TWO of the following.
(i)
Covalent Bond and Co-ordinate Covalent Bond
(ii)
Spectrum

(06+06)

(iii)
(iv)

Crystalline Solids and Amorphous Solids.


Postulates of Bohars Atomic Theory.

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