Acetylene

001001
Synthetic/Analytical chemistry.
4/7/2014.
Material Safety Data Sheet
Product name
AIRGAS INC., on behalf of its subsidiaries
259 North Radnor-Chester Road
Suite 100
Radnor, PA 19087-5283
1-610-687-5253
Product use
MSDS #
Date of Preparation/
Revision
In case of emergency
Section 1. Chemical product and company identification
Acetylene
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Supplier
1-866-734-3438
Synonym : Ethyne; Ethine; Narcylen; C2H2; Acetylen; UN 1001; Vinylene
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Inhalation
Emergency overview
Section 2. Hazards identification
Routes of entry
Potential acute health effects
Acts as a simple asphyxiant.
Contact with rapidly expanding gas may cause burns or frostbite.
Ingestion is not a normal route of exposure for gases
Contact with rapidly expanding gas may cause burns or frostbite.
Eyes
Skin
Inhalation
Ingestion
Physical state Gas.
See toxicological information (Section 11)
WARNING!
FLAMMABLE GAS.
MAY CAUSE FLASH FIRE.
MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.
CONTENTS UNDER PRESSURE.
Keep away from heat, sparks and flame. Do not puncture or incinerate container. May
cause target organ damage, based on animal data. Use only with adequate ventilation.
Keep container closed.
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Medical conditions
aggravated by over-
exposure
Pre-existing disorders involving any target organs mentioned in this MSDS as being at
risk may be aggravated by over-exposure to this product.
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Contact with rapidly expanding gases can cause frostbite.
Target organs : May cause damage to the following organs: lungs, upper respiratory tract, central
nervous system (CNS).
Potential chronic health effects
Chronic effects : May cause target organ damage, based on animal data.
Target organs : May cause damage to the following organs: lungs, upper respiratory tract, central
nervous system (CNS).
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Acetylene
Acetylene 74-86-2 100 NIOSH REL (United States, 1/2013).
CEIL: 2662 mg/m
CEIL: 2500 ppm
Section 3. Composition, Information on Ingredients
Name % Volume Exposure limits CAS number
As this product is a gas, refer to the inhalation section.
Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. To avoid the risk of static discharges
and gas ignition, soak contaminated clothing thoroughly with water before removing it.
Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical
attention immediately.
Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
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No action shall be taken involving any personal risk or without suitable training.If it is suspected that fumes are still present,
the rescuer should wear an appropriate mask or self-contained breathing apparatus.It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation.
Frostbite : Try to warm up the frozen tissues and seek medical attention.
305C (581F)
Flammable.
Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
Closed cup: -18.15C (-0.7F).
Lower: 2.5% Upper: 100%
In case of fire, use water spray (fog), foam or dry chemical.
Extremely flammable in the presence of the following materials or conditions: open
flames, sparks and static discharge, heat and oxidizing materials.
Section 5. Fire-fighting measures
Flammability of the product
Auto-ignition temperature
Flash point
Flammable limits
Products of combustion
Fire hazards in the
presence of various
substances
Fire-fighting media and
instructions
In case of fire, allow gas to burn if flow cannot be shut off immediately. Apply water
from a safe distance to cool container and protect surrounding area. If involved in fire,
shut off flow immediately if it can be done without risk.
Contains gas under pressure. Flammable gas. In a fire or if heated, a pressure
increase will occur and the container may burst, with the risk of a subsequent explosion.
Special protective
equipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
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Immediately contact emergency personnel. Keep unnecessary personnel away. Use
suitable protective equipment (section 8). Shut off gas supply if this can be done safely.
Isolate area until gas has dispersed.
Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof
tools and explosion-proof equipment. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
Environmental precautions
Section 6. Accidental release measures
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Personal precautions :
Methods for cleaning up :
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Acetylene
Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed
until ready for use. Avoid all possible sources of ignition (spark or flame). Segregate
from oxidizing materials. Cylinders should be stored upright, with valve protection cap in
place, and firmly secured to prevent falling or being knocked over. Cylinder
temperatures should not exceed 52 C (125 F).
Use only with adequate ventilation. Use explosion-proof electrical (ventilating, lighting
and material handling) equipment. High pressure gas. Do not puncture or incinerate
container. Use equipment rated for cylinder pressure. Close valve after each use and
when empty. Keep container closed. Keep away from heat, sparks and flame. To avoid
fire, eliminate ignition sources. Protect cylinders from physical damage; do not drag, roll,
slide, or drop. Use a suitable hand truck for cylinder movement.
Section 7. Handling and storage
Handling
Storage
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Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
acetylene NIOSH REL (United States, 1/2013).
CEIL: 2662 mg/m
CEIL: 2500 ppm
Section 8. Exposure controls/personal protection
Engineering controls
Product name
Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts. If contact is possible, the following protection should be worn, unless the
assessment indicates a higher degree of protection: safety glasses with side-shields.
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
When there is a risk of ignition from static electricity, wear anti-static protective clothing.
For the greatest protection from static discharges, clothing should include anti-static
overalls, boots and gloves.
Personal protection
Eyes
Skin
Respiratory
Consult local authorities for acceptable exposure limits.
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Personal protection in case
of a large spill
: Self-contained breathing apparatus (SCBA) should be used to avoid inhalation of the
product.
Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Hands :
The applicable standards are (US) 29 CFR 1910.134 and (Canada) Z94.4-93
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Acetylene
-81C (-113.8F)
0.907 (Air = 1)
635 (psig)
35.25C (95.5F)
26.04 g/mole
Melting/freezing point
Section 9. Physical and chemical properties
Molecular weight
Critical temperature
Vapor pressure
Vapor density
C2-H2 Molecular formula
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Specific Volume (ft
3
/lb) : 14.7058
Gas Density (lb/ft
3
) : 0.0691
The product is stable.
Extremely reactive or incompatible with the following materials: oxidizing materials.
Under normal conditions of storage and use, hazardous polymerization will not occur.
Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
Section 10. Stability and reactivity
Stability and reactivity
Incompatibility with various
substances
Hazardous decomposition
products
Hazardous polymerization
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Section 11. Toxicological information
Specific effects
Carcinogenic effects No known significant effects or critical hazards.
Mutagenic effects No known significant effects or critical hazards.
Reproduction toxicity No known significant effects or critical hazards.
No specific information is available in our database regarding the other toxic effects of
this material to humans.
May cause damage to the following organs: lungs, upper respiratory tract, central
nervous system (CNS).
Chronic effects on humans
Other toxic effects on
humans
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Toxicity data
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Section 12. Ecological information
Environmental fate : Not available.
Environmental hazards : This product shows a low bioaccumulation potential.
Toxicity to the environment : Not available.
Aquatic ecotoxicity
Not available.
Products of degradation: carbon oxides (CO,
CO)
and water. : Products of degradation
Section 13. Disposal considerations
Product removed from the cylinder must be disposed of in accordance with appropriate Federal, State, local
regulation.Return cylinders with residual product to Airgas, Inc.Do not dispose of locally.
Section 14. Transport information
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Acetylene
2.1 Limited
quantity
Yes.
Packaging
instruction
Passenger
aircraft
Quantity
limitation:
Forbidden.
Cargo aircraft
Quantity
limitation: 15
kg
DOT Classification
TDG Classification 2.1
ACETYLENE,
DISSOLVED
UN1001 ACETYLENE,
DISSOLVED
Regulatory
information
UN number Proper shipping
name
Class Packing group Label Additional
information
UN1001
Explosive
Limit and
Limited
Quantity
Index
0
Passenger
Carrying Ship
Index
75
Passenger
Carrying
Road or Rail
Index
Forbidden
Special
provisions
38, 42
Mexico
Classification
UN1001 ACETYLENE,
DISSOLVED
2.1 -
Not applicable (gas).
Not applicable (gas).
Not applicable (gas).
Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the
product.
Section 15. Regulatory information
U.S. Federal regulations TSCA 8(a) CDR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): This material is listed or exempted.
SARA 302/304: No products were found.
SARA 311/312 Hazards identification: Fire hazard, Sudden release of pressure,
Delayed (chronic) health hazard
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United States
Acetylene
Clean Air Act (CAA) 112 accidental release prevention - Flammable Substances:
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Acetylene
Connecticut Carcinogen Reporting: This material is not listed.
Connecticut Hazardous Material Survey: This material is not listed.
Florida substances: This material is not listed.
Illinois Chemical Safety Act: This material is not listed.
Illinois Toxic Substances Disclosure to Employee Act: This material is not listed.
Louisiana Reporting: This material is not listed.
Louisiana Spill: This material is not listed.
Massachusetts Spill: This material is not listed.
Massachusetts Substances: This material is listed.
Michigan Critical Material: This material is not listed.
Minnesota Hazardous Substances: This material is not listed.
New Jersey Hazardous Substances: This material is listed.
New Jersey Spill: This material is not listed.
New Jersey Toxic Catastrophe Prevention Act: This material is not listed.
New York Acutely Hazardous Substances: This material is not listed.
New York Toxic Chemical Release Reporting: This material is not listed.
Pennsylvania RTK Hazardous Substances: This material is listed.
Rhode Island Hazardous Substances: This material is not listed.
Clean Air Act (CAA) 112 regulated flammable substances: acetylene
State regulations
CEPA Toxic substances: This material is not listed.
Canadian ARET: This material is not listed.
Canadian NPRI: This material is listed.
Alberta Designated Substances: This material is not listed.
Ontario Designated Substances: This material is not listed.
Quebec Designated Substances: This material is not listed.
WHMIS (Canada) Class A: Compressed gas.
Class B-1: Flammable gas.
Class F: Dangerously reactive material.
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Canada
Section 16. Other information
FLAMMABLE GAS.
MAY CAUSE FLASH FIRE.
MAY CAUSE TARGET ORGAN DAMAGE, BASED ON ANIMAL DATA.
CONTENTS UNDER PRESSURE.
Label requirements :
Notice to reader
Label requirements : Class A: Compressed gas.
Class B-1: Flammable gas.
Class F: Dangerously reactive material.
United States
Canada
3
4
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National Fire Protection
Association (U.S.A.)
Health
Special
Instability
Flammability
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Hazardous Material
Information System (U.S.A.)
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2
Health
Flammability
Physical hazards
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Acetylene
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
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