PROBLEMAS DEL CAPTULO IV
Lupis, C. H. P.: Chemical Thermodynamics of Materials
Solucin:
eug 5
4. Co{..r\. ul eo .4","^L
d.r.rra^I :
h)
Vt--t,o I
: ta
1o
o.rr) =- -,i^,|^?
e Jo
\o 4pt6vn dr--',v.tA ^ l*
4t't *tk*cro
dac-aaaJ-
B ?orq r4^^ Upo)fi .o
r )q
*"'*- ,) lrrtLr
..^r_rrl*rco.
^ *r-o
*LKl,.*
S*-r.
par^
<{(r)
,tn*a^
\z-.*.*os +4-
{s'r?-{
'
ll_
i"
l)lt
; _Io,LTrr
b,
."d1
!AL
r)
v? eir
-, I
f*
oo
= Aloaorr
3rq
.{,,\
31,
=AloEY
ft
,JZ z
L
3
qro,tt,
0
\r'.
-o/yr
- ,
( ?'r1
( + 4{rI t.;{;i
J*/
=[eqTt;"cl r
J-
G"
ruo
l _Jr.rr^L vtrrr.l
BL
go
". d^ *g*rou
r {.4
a(el problema:
Otra forma de resolver
Su,
(d- o)
* , .uJ**,*ro
d- AboJ*,tto
$L
Solucin:
6ot
14B 'h
3-88
c,$,.,oJ. r,r,,*\ bo. ,r. 273'k Z
&
P"trtdoal
P: looo "*tt^.
Otra\"'
forma
de resolver ela.problema:
Q*t,
ok
Z \.r
.ro.torro Curt;tLo
&lgov
L73"V
1 18 ol.
d^ t
:)
B*= (o.B) ( r*)t
Br: p
cs
",
t)( b.baAyAJ.
g2
Br=
U9
-Al 6"73 A'r No
At
A'cetAqclnh U,-r,ol pr, T:_ ?-73-kd"*.^ A),, ."a A rn,-..o",, l)
tl^ vo.A^Jrro
Itroo"k
T:
kt
'tr fr
t?oo "L
*"
\,'tvo.t-r-c*[
d^
\5.15
\\g "'1.
\* 1,rr.Q.* cr.. t- {,b. L
I
tQ-r--rrt.o>
q-*
0.
No ( r*)*
l^--)
o.b
B.= (o'r ) (a'86\3'\)o
0*
= 4rr,?g t .xJo
bL
q.
2.34
AA51a k-
eo"8t
0I a*a"
tf o o
0"1,.^,rr- C.\.4a. ) o\
'T-z-
\oo':r.
cr",r.r-Gndg cr.
*L* $.*j*
fioo* t,rn'*-
f.;O,'ac +^-^-
NL
to*".d* Iu:
a; i
nq-r,
&/v:
t**n
re
l*rp,r* d^" C,z Q
c,p : -hp
t""r
Af'-
f\tc*
T;* S 13* 3r' f : l$0o ,t[*
.
qrd;wtrw
f3 (lrso) p
$.a
(tao*\A,
(&t'osr
(r{isd###i#}*sJHd:?
)Ltntlr"
(sL
IG
a-2gf4\
TG (tclc".r)
.dA
q.
0 q. ??3*k ) lwJ***.
T--- lFOo "V*. b & [*e]e o$-^-.
| 7
t;
looc &
cffi::lMen*ut_-*__
--*'t?.")
(taocr\( /.uoqq )
Fo'6,u*.Jq#
'ttoo r?^)
C,AT
[.o^d* t*
t#lr) ;
')
A
L3 Y +ilo-
44, #g 6r l&orh H lrnpo*[,^"'
"
I o^^^ \^^-o,t
,T
I
I
Chapter
IV.
Chemical Potentials, Fugacities, and Activities
-0.8
i
i
icn
,*
:\
:\/
:
:<
:Q
1.5
.o
t
-3.0
-4.5
kru.
,,.,
Figure 2. Reduced second virial coefficient, B2lNe(r*)r as a function of the
perature, kTlu*. Curve C is calculated from equations (19) and (20). The
points on C are a mixture of data for Ar. Ne. N2, and CH. Curves A and
quantum ef[ects for I{e and H. respectivel'. (.Ajier Hli lll.',
Solucin:
\r5
\l
(-
>-.=,
il* Li
z-:
-l lo
p trs
!1
\hs#/
\_
ab
,fu\
H
b
r\t
c-
'_)
s-d
.rD
Lr*
yt
F)t
\
1_
,"-t
1-,-
01"l
<
f$
|
rl<_\
-llA
L---C
F \>s
1l
-O
rJ
*\k
\_
\q-
\------,
o
11"
- )-.s
--
<_
?*f \<
ll
L*c{
\'q'
1-P
\--c
ale
o
lN)
qq
rl
q\
t'
-9
-t
1-
nl<
-\
-T5
$*
L;-t
-\'i"|s
%l
,^\
<l
1!
e"1)
.-^)
1 J)
1l
-O
1-
tl'
='-
+r-
s-^
y'
Irs
l
b
g.
?
r
.-l
{-A
"{
\*-/
+=
7
e_
t.
8I
{s^n
eh
L\\
?
l.
'F
r\
p3
tr*
F
F\
9=.
FrA
oFi
x1l
f:
x.,-
f3
iF
9"
T
flI
:-
V<''--rfl
o,e
-1.,
ch f
T
30
q.,J
-f
c)-tE-*
t-J-
dh
oJ 2
i
e -F"
i's,
Otra forma de resolver el problema:
*yu
E !.'h n.
#'H*.:f#iff-t) r
aSrAJ t
't
:.
A}q*"#} z,[
{. l$-'p*t'$
\,
(*9,,
tbh'l>) (Et 'lrust'rtJ
i***'*.-*'@
(st'r)T
-s
ob
tl *
(q,ca
| ',
'"+
) (sr'?',8$ o'l
?blr{rq'o
r,"'r'ryrufsrl,r71*o
o*
7h
lrlr
*1*
q'.,l
I ? bhh s'
lb-ut
{,,
ql0o "l
+r
G,qt f
*l$,f,
(:r
) CIecr
t? tf ^ o,
lv
1r'T wU,$f
I
q \/\t'!' $${s\
l-
l.
,1-ol
'
*(il*t
tl *fl tt ?
T*
-**o'*h
*r ,*
',vap 4'r l)u 'i*fl
"I
Y'vwfl **L
{p)r"
ar"rrtpl"rt
*l*n
**'
":
$tl
"ra'''a^'nr,l*r\
"""\'?
*{ )
51d -tNd
a r\
It,b:qr+ *tN ' 7 Sa'c) *,A
'lbhftg"o t'A
'[**/
*tt *3t x "!\ 't i-q l
t"Yr".^tr oltt t'\ avl
:il1 l*
In Fs/*1, or* *rtl?&$"
tl o
'i,-r\.f rr
o^luJffi?ft.--.
r.r'rant"ltl*rrr
(:
+rnd)(q*n) (':
J?Jr.ft :' (u
$'?P
t
^ l{:ra',rr
.)
(,:
t.uu{\
n #f
(-* +d)to-
J,^#:
**ru $} "J;a
d q *"*f
"
'i4 *p rrnrulf
}r
e{ryry
*u"r?
lf "*?O
rfi + ffi{rffi]ru''fldY
**,
,d
$ og-*, J
q* A
s)'r")*v.,"'rv?
Ar-a
*_.--.- +
'l
l-/, T,(E*
AP L'uW;f-J I*AtL;;*
*.y?
;
"#*.-h)
d-
ili-
6A
'*l
1tu
btiJ
'l
(-'
,J 'dlt-{
^d\
"L-*,
F
'btr
I
T*A
zA
dp
a
\l!fi\ tdttp rnrro
'61
J7)
i'a
r'ilD '
lt
"\
dP
of tltnxzp
*L',u
tio-l,qp y
t,
,l
I
J
'\
bt)
tt/
*Y
,r*p y^w-t Jp
?3 or
\)
Solucin:
4, Lr' -o0"," !,, &
Vq, v/.o|.
l[rt^L[t) y b (e^^ Lts/,-.r)
^(..^
fturq "l wtl-rr orA-o N. sor,r q = l. t l O b t:o"o51 l, P*o J\^^[.r,rr.gtll
e"It^ .lo \* vato-'- e,: 2,2Sg
b: o,o{g. 1,* \o, $u*.,4qdro d^
)
eolo>
3cl% C Ll.l 10 7.4J" dt l*\, a*n*lrro. d,.^^br^V
A^"> erv r-u-ror rr,r-Lt"L
,
(rr^a
d- \OoO,,nL
e-r.t.n
b Otra forma
de resolver el problema:
.
(v+) (p *
h): *t
5"<^
:-)
(V-b) (P V"+ar) =
p\"* ov -
Pb{
t-
.,.
Va- dr-r Waob
2rV"
L
\o .".,o".*i"' aL
rT
r,
v==o
o\1 (tb+a-t)vt*av- 'f =-<>
Sn frne ?*1- tI '
(Zes,'lv, .^"(o \t.,
"cc>qcufu
\oe.,
\3-
Lt
toooXo,os'tt) +
,-^*
'
V (r'qo\(o'o:ar) = o
lo. oaaos)telu) tJt* \'31? -
'\a. (-t*,,o *t, '"^L =s'c )
V T; 118
=> log)o\*- 63.,t-Vt+t,31oV- o.oS43 =o
\, =' o' os6o5 \\t ?
J d'Ft.,ro !^'a-- o. oeob -^
r{-o.^"
p-
o.
ogos
\}s - oI'-' f *.-l
---"-'ogoqi.
;) II ur-- o' .
o3ot t
t" r
\
"L
i o
ra-nc'
-oo
Q*ol v'*t,lo
l*
e.r)o-ca.l'
faJta d
.tlq
looc,us-f Crooo)[o.o'{?-s) + Lo.oaeos)tzq$] N"*
tooo
t'-
61.l3vt+ l.2s3V
o' o46\ = o
-- o -ou13 \ls )
.
o. o^rolz i. ( ooo qo.Vr=
'L
J
l v,
l u.= o,otto?1 L )
l.2s3V - (l..ztr[oo{1*8):6
CH'
*rre {ou^= o' o5?3o
Jf
C-^ I, .ra.
4'
----ta
v."\{'
P*, o{-o lodo
cl,-\
oha.c.,
eJo a, to-
'e&p.n*n.J*^
J.#n-
'(or:a
e'."bL"*ot-
lr*orc*'f ( t)
.,i
l^{ $r
a*s
r'
p**rl&
I
"J
(t,)
s3q I
0'.0f 6o,f -_ ggq I
1,"
(r\ = - !-^U.ensz) +^
Cf*
2.ozrud
+ 2.3oB: o. (41?
o .c.l17
S*=
= 0ooo )U, QD 55)
,h,,n-t A*{,r${ flu,o
J Cf*.f
| u se
,r-,^( o\ ? s ^[
tqo
e)-r ot-^
p*;ro.
(n -Off?3
A"oqef
{o. oszcrs*}L e*f
2 Le- as*})
J
(o *taoSl{,Zqt)(o .os?8}
" ${{f;f
0- os?-)- - o-ot{? F
l*(+/r) : -!^(o.r1so) -B.216a+ a*,rf,r+: o.7s8r
r= ?n : (rood[1.e9*q1)
. ?C8l
{=
x,f,*
ct"o-*
-1,* fJ
.*
*^t{^" f. :
't
6r
L,:
4',o
P'lo)Lllcrr.r)
legg.
b*n
.frO**l .o J *,Lr.'**o
"tq l* ."*rrp*(a-
"
&.uot 388 '72*"#^
Solucin:
Otra forma de resolver el problema:
?Jtr.fr U sotu \^^(rr. J r qcrs ,
Doo.e.re$Jo
*[ H*b[-^^^ .{
\* cr*..-.l^
d^*
efi"r^" ' "(l
t^*--\^,,t
.,) &*
oL* /^-'f
fu,2 2. ?.3 Llst
b -- o .o4 qB Ll, /*--; t
ee
aatt^^Jr qt*
- d^
, ,.l ^
\. = 3tr )
vL
o,a*
L.;\,r ?6,c
4A,- Vo, t+^ W"Ls
f4;ra.
?.--
n/*V )
T.=
o. 1rs'l
L'l/.^^.\
J-
\*
\*r^go*^l*^,
cor-r,rgo-.ri|"^,"^,
P.:41
6'6 ^\*
T*
( f+q)
"L \rr.-.'.Io^-* C
o,oa-clr
r.? lo " otlzE)z
\e8.q *t/'^^-r\
T.z
(c^J1o^
2.2'r
o=4
\a
*lc..,L
o.r
d,* \o
so/r+Vo (9t rs e.r I)
*r?
\o
Vo^r, dLr fn/*n-b
Solucin:
),
'1*"7
t"oo\
Jd-
= ':*
eF"\*4 :',*',t "l
v"{a
xT|d a
w
tr(Jbft
"v-{rt
' 'i,' ,it
*va
t*A
( -9-* se,.t -!, r ) (
$l ) =,h
qtf-,
s tr 9j
1c/ \rL
J
.'t
**h
,w'\
***\
=-a
hl s lix
o r tf1'tr
tobo
:d":
,:d'
]fut
\r3
rwra f f1
tW
Tdiil
?
-d
tw
( ut
(:
'o/'* stY :
","*@
\ ef2
?
ryyr'tlg6}w-*rril
I
=-2y
wr:'o*
I"f
l\^/a*)-J*T
'|.lcrr..lou
o\
Erolkf.tr\v^r-co
T-|"'tfl
= \v
^/'O
---'+
""'o1"arrr
i^ofartcypo^y\ ?,F"-\ot-anb V
":-:-:J:-'
-\ *
*1"i
' Tt.6/\ g ,oFlas or?
Otra forma de resolver el problema:
,a.coJr.-,o
?9 S -*,lc crwral,nr
' b rorcrr. .^-"t \r\rns5^
".Sp
t\"'o $
11YTf* "un oppe lrr ro& 1p ioreal"t '\ 1-\"0 ' vnt'cs)rxs'tr
u 1'onl1 rro&r. .,'P Ypr-r,ltw.?rr"\ S otro or".h,1
f 'bFht!ols.A/,'?t(|Fh
w v ' ?roozr --r \o ob'o :b trarssrvf fr" v-v bprloE D*-lxo wyn v\a)
Answers to Problems
Solucin:
ies
7.
ap"rlaxz
02 p.zl
EXT
0;
dln^yz__ I
8.
aXl> 0. These conditions yield
I
aX3 X7'
o2ln"!z_
Xz'
LXz
a3 p'rl
a: plP: jX and pllpr:
From
,,
rAg
'-
d3ln^yz=_2
aX32 Xl
YtlY2, we deduce
\t'gXs(P e'glPsu
^Ycuxcu
* 16gXae(PelPc")
Using L'Hospital's rule,
(ffi)
.,rg+o
(ft),^"-o
:' "' ffi
13
Similarly,
_ (d(t - Y1.1J\ _ (dYc"\
\x*- xg-r - \tt - xo)/ *Ae+r \dx..,,/r."-o
/ dYo,
:et'to9i"Jo-l
9. AtP:1atm,
ln^y"
:0.075
- -1.8, "ye:0.165, aB:0.041.InPs -
(A.FI,,"'/R) x
(llTb- llT) and Pe : 6.1 x l0-8 atm. Consequently, at P: I
Ps: asPs:0.41 x 6.1 x 10-E :2.5 x l0-e atm.
At p : g000 atm, ( ln a"lap)r: (vn - vi)/R? and
x 7999 x 0.0242 :
_ [t* v" _ _vi vr
dp : -2.25
(s)r",- Jt
RT
1.987 x 1000
Thus (a)sooo atm : 0.803 x 0.041 : 0.033.
(cn)sooo",-
,n
r
atm,
_0.219
With no information on the fugacity of B in the gas phase, we may assume
It follows then that ps:0.033 x 6.1
that it behaves as a perfect gas.
x l0-E - 2.0 x l0-e atm.
Chapter V
l.
2.
22.9% CHo, 77.1%
3.
2037'K.
4.
AGo
5.
The reaction taking place may be written SO2 + 2H2S
the basis of I mol SOz and 1.5 mol H2S we obtain
417"K.
LH"
K:
5.5
}l2.
fAS" :29,900
103
ph,o
21.46T cal.
4\2(2.5
Z}IzO + 3S(l). On
- r)
Pso,Ph,s (l - fX1.5 -
2L)
which yields tr, : 0.725. The composition of the flue gases is 15.5% SOr,
2.8% HrS, and 81 .7% H2O. The production rate is 31.2 tonnes/hr and the
heat generated is 9.6 x 10 kcal/hr (exothermic reaction).
I
"L
rrr-courr.crtt< r,r.rt-:rr,rlau.cc cr* zt^ - f.oarr,bo. \o. cooot,.ror-r^ {q.r,r.uo.lrr,
rstca5 q.*- b< c*b^ *l,t$o-..o
<.-rrll"o r,\ .|e,-,r.r.,.,.,.,o d^ Lr.
A p"*lo
I
"u,
ov.,.goatcr.
d^fa^A"lrr-[
Otra forma de
resolver el problema:
d^ -gr^ yo
&***"r6frr c)- \o
trc{*? t'"{*d"'t
=)
K,rz Xt T;
&a=
y- n,
)* a d'n.J'-"u'^lto'*fo""^it
&l
acltu'd^'l
Var.,.> $^,- \.^
y-"
*\
\hc-'tt\'it^l'a.'"
lo^^)o
lt
e\'
NL U fo''r
p,logo,rraroJ
a-t'{tyt'A# d"z '
,^r'**,o^r.....n 1o -t< \\'\c'tt*^*-o\*t"t- '\^-
fl** *f*o \oJo
,!
.&t-,ra{y'
,, *"ld*#' *
s)
*)
&4*
rz
reTA*rQt
r-d,o**n-.*("*-,
r ''f-;A d z
*,r*# d retrrf,-'- htKu
ffr'*,4.-.,
^*.[.,*-r,
*^,
&t"c'q" '*{ ftr',,--'$q qJl {l**o
;
Ut
d
?f,e
-)
"{ S"u.t*{*-'\u/t.*} h
,,
Ceil &
du
{.q"'l*
&u* F*^/*
d'uu,
ffiffi:;.
*r J*,, L,fl.*(h'* v
ffi
r o,
*l 3,r*
*,ru
L *.(
't^
b'*
+-fi*'\%-q
sm
J-0* f*,
*f*
Jffim',wmrsE,wb
r\
dta
J,[*y
dY*
1du
4
Cltlh'
.al'#tts
*,
<
{tJ,r
cr \q
Vt
= tr-r*
Y,F
wrrrl?rrfo. hTF * -'b
,t
4ttf
*d;F
aac"\vriyo,,F*Ft
!'
'
-.&Tlr'r_*_-rr-"-dd
*ilr
*?.clcv*\".:i
"X"
flo
(+)'$:ft)"l'
[""i
tJ rC
af l._
^Y,
--/
(=
l'
iffiwP,a \-
-T'*l-*f
=<1
,1."-m\"*
3
('+
\"tg
l,r
;dP
r 3,lwfrt
**
P
)J"
.{%e
,&I- (Y,F
?
\"d*dt-'-'rrrdt'
7a
r;t!
JzF ra
'I
"(*{
l',
Answers to Problems
ies
7.
ap"rlaxz
02 p.zl
EXT
0;
dln^yz__ I
8.
aXl> 0. These conditions yield
I
d3ln^yz=_2
aX3 X7'
aX32 Xl
o2ln"!z_
Xz'
Solucin: LXz
a3 p'rl
a: plP: jX and pllpr:
From
,,
rAg
'-
YtlY2, we deduce
\t'gXs(P e'glPsu
^Ycuxcu
* 16gXae(PelPc")
Using L'Hospital's rule,
(ffi)
.,rg+o
(ft),^"-o
:' "' ffi
13
Similarly,
_ (d(t - Y1.1J\ _ (dYc"\
\x*- xg-r - \tt - xo)/ *Ae+r \dx..,,/r."-o
/ dYo,
:et'to9i"Jo-l
9. AtP:1atm,
ln^y"
:0.075
-1.8, "ye:0.165, aB:0.041.InPs
(A.FI,,"'/R) x
atm,
(llTb- llT) and Pe : 6.1 x l0-8 atm. Consequently, at P: I
Ps: asPs:0.41 x 6.1 x 10-E :2.5 x l0-e atm.
At p : g000 atm, ( ln a"lap)r: (vn - vi)/R? and
x 7999 x 0.0242 :
_ [t* v" _ _vi vr
dp : -2.25
(s)r",- Jt
RT
1.987 x 1000
Thus (a)sooo atm : 0.803 x 0.041 : 0.033.
(cn)sooo",-
,n
r
_0.219
With no information on the fugacity of B in the gas phase, we may assume
It follows then that ps:0.033 x 6.1
that it behaves as a perfect gas.
x l0-E - 2.0 x l0-e atm.
Chapter V
l.
2.
22.9% CHo, 77.1%
3.
2037'K.
4.
AGo
5.
The reaction taking place may be written SO2 + 2H2S
the basis of I mol SOz and 1.5 mol H2S we obtain
417"K.
LH"
K:
5.5
}l2.
fAS" :29,900
103
21.46T cal.
Z}IzO + 3S(l). On
- r)
Pso,Ph,s (l - fX1.5 - 2L)
ph,o
4\2(2.5
which yields tr, : 0.725. The composition of the flue gases is 15.5% SOr,
2.8% HrS, and 81 .7% H2O. The production rate is 31.2 tonnes/hr and the
heat generated is 9.6 x 10 kcal/hr (exothermic reaction).
I
f1*,,^L. aY,r/dttn; 4h= ; **=n
bo*: \soook L g.rr-rt- d.. vsgrrr ; \.. (t b -\ &t cqrror oo
3,G, xrr
b g.Gyt66 ok- --geu^-^^^*., l co.u6a'rl-.^,.i-^^L o^ [ .\.hs
laa r..sec&r-,'. Ur^V^r)/{;.t$^V-) I=,(..,ir,|.
gw.d^t<n
Otra forma
de resolver6*r
el problema:
trroxtr<4os
d-: Pi
k-a.
:)
&.r*n g?
,l.ou.&- ( >
lpt
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P,
ti
'T *) f, a /'F;
F.
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fo, + fu
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m.)
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lo d^ Ln !l *t'[*[
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l=1'J"ti
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af,T*u'rr\r'\rr\5 rny
o=*'riq
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1-
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b9,^g'g =qh
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t-
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lu-l'P \
LF/
z'nbl'|-
^y hrl'I
?xnT
r q_{
7 *']u'r(
(=
y-/(ro,( y)
y't-
hv'b a
Y) :
*f'l .rr1" t-J
tr,
-/
0,9
0,9
4.7
t--
0.6
Yg
0.5
0.4
0.3
0,2
0.1
0
0.1
0.2
0.3
0.4
0.5
0.5
0.7
0.8
0,9
Xs
@t
q b fe
grrl,q.rc b pt@ @rt
wMa
q, k @ rhr.t&.k k
tu a at wda
&
Ag4t. l
sf{"lI,,
fe
ut
xt
,,
rAg
'-
9.
\t'gXs(P e'glPsu
^Ycuxcu
* 16gXae(PelPc")
Using L'Hospital's rule,
Element B boils at 25)'K with a standard enthalpy of vaporization equal to 55,0(X
liquid
solution characterized
caUmol. At l0)'K and I atm it forms with component A a 13
I
:7X+
by the following
ln
and
VlXs-4XXs cm3t
'y":
irroperties:
-3.2X2^
.,rg+o
mol. The liquid solution is equilibrated with a gaseous phase containing A, B, and
Similarly,
argon.
It may be assumed that the gases behave ideally and that argon has no solubilit
in the liquid
the activity of(dYc"\
(d(t - Y1.1J\
/ dYo, solution._Determine
_ B in the solution and its partial pressurt
in the gas phase at T:
lO(X)oK,xo)/
Xs = 0.25, and
P = I atm as well as at P = 80) atm
\dx..,,/r."-o
\x*- xg-r \tt - you
*Ae+r
Soecify any other assumption
find it necessary to make.
(ffi)
(ft),^"-o
:' "' ffi
:et'to9i"Jo-l
Solucin:
9. AtP:1atm,
ln^y"
:0.075
-1.8, "ye:0.165, aB:0.041.InPs
(A.FI,,"'/R) x
atm,
(llTb- llT) and Pe : 6.1 x l0-8 atm. Consequently, at P: I
Ps: asPs:0.41 x 6.1 x 10-E :2.5 x l0-e atm.
At p : g000 atm, ( ln a"lap)r: (vn - vi)/R? and
x 7999 x 0.0242 :
_ [t* v" _ _vi vr
dp : -2.25
(s)r",- Jt
RT
1.987 x 1000
Thus (a)sooo atm : 0.803 x 0.041 : 0.033.
(cn)sooo",-
,n
r
_0.219
With no information on the fugacity of B in the gas phase, we may assume
It follows then that ps:0.033 x 6.1
that it behaves as a perfect gas.
x l0-E - 2.0 x l0-e atm.
Chapter V
l.
2.
22.9% CHo, 77.1%
3.
2037'K.
4.
AGo
5.
The reaction taking place may be written SO2 + 2H2S
the basis of I mol SOz and 1.5 mol H2S we obtain
417"K.
LH"
K:
5.5
}l2.
fAS" :29,900
103
21.46T cal.
Z}IzO + 3S(l). On
- r)
Pso,Ph,s (l - fX1.5 - 2L)
ph,o
4\2(2.5
which yields tr, : 0.725. The composition of the flue gases is 15.5% SOr,
2.8% HrS, and 81 .7% H2O. The production rate is 31.2 tonnes/hr and the
heat generated is 9.6 x 10 kcal/hr (exothermic reaction).
I
