Electron-Positron Bremsstrahlung and Pair Creation in Very High Magnetic Fields
Electron-Positron Bremsstrahlung and Pair Creation in Very High Magnetic Fields
Electron-Positron Bremsstrahlung and Pair Creation in Very High Magnetic Fields
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Mon. Not. R. Astron. Soc. 000, () Printed 5 August 2010 (MN L
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Electron-positron bremsstrahlung and pair creation in very
high magnetic elds
P. B. Jones
E-mail: [email protected]
the shower and diuse to the surface. It is likely that the
temporal behaviour of these dierent components does lead
to instabilities that are the basis of observable phenomena
(Jones 2010). In general, there appears to be no reason a
priori why both B cases should not be present in the
neutron-star population and it is of interest to understand
how each might be observed in the electromagnetic spec-
trum. Estimates of shower development in previous work
relied on the correspondence principle, that for large values
of the Landau quantum number the zero-eld cross-sections
are valid, but this is unlikely to be satisfactory at B Bc
where the number of contributing Landau states can be
small. The present paper attempts to give cross-sections that
are rather better than order-of-magnitude estimates but are
not of high accuracy owing to the discrete nature of the
Landau spectrum and to truncations that are made in per-
forming the calculations. Its purpose is to see whether and
in what way the cross-sections dier qualitatively from those
at zero eld. Nucleon production in electromagnetic showers
occurs almost entirely through formation and decay of the
giant dipole resonance. Thus the paper is concerned, par-
ticularly, with factors that inuence the low-energy photon
track length and its depth distribution.
With neglect of radiative corrections and of the anoma-
lous magnetic moment, the energy states of an electron in a
uniform magnetic eld are
E =
_
p
2
+ 1 + 2nB (1)
in which p is the longitudinal momentum component, paral-
lel with B, and n = 0, 1, 2, ... is the Landau quantum num-
ber. Apart from the Appendix and where explicitly stated
otherwise, momentum and energy are here expressed in units
of mc and mc
2
; the magnetic ux density B is in units of
Bc. In electron-photon interactions, the conserved quanti-
ties are energy and the longitudinal momentum component.
Thus the kinematic behaviour of an electron is that of a par-
2 P. B. Jones
ticle conned to one dimension and of mass m
_
1 + p
2
in
which we have dened, purely for ease of notation, a notional
transverse momentum component p
2nB.
We have adopted the solutions of the Dirac equation
found by Johnson & Lippmann (1949) and give a summary
of calculational details in the Appendix. These are unre-
markable except that owing to the one-dimensional kine-
matics of electrons and the small number of Landau states
that contribute signicantly at B Bc, we have found it
convenient, given that numerical computation must be in-
volved, not to proceed with the usual approach of covariant
formalism and Green functions but instead to write down
the transition matrix to second order directly in terms of
time-ordered matrix elements calculated using an explicit
representation of the Dirac matrices. It is also appropriate
to mention here that the states given by equation (1) are
two-fold degenerate for n > 0 only if radiative level shifts,
natural widths, and the anomalous magnetic moment of the
electron are neglected. But for the high-energy spin-averaged
or summed processes considered here, the ne structure is
of no consequence and we use only the completeness of the
Johnson-Lippmann eigenfunctions. References and some fur-
ther details are given in the Appendix.
The most simple problem here is that of nding the re-
placement for Rutherfords scattering formula. Small-angle
Coulomb scattering in the zero-eld case is replaced at
B Bc by the Coulomb excitation of Landau states. This
has been treated by Bussard (1980) and Langer (1981)
but only in the non-relativistic limit. The relativistic cross-
sections that we require appear not to have been published
previously and are given in Section 2. There have been many
calculations of transition rates for cyclotron emission, and
a summary is contained in the review of Harding & Lai
(2006). New transition rates are given in Section 3 to al-
low comparison with previous work and, more specically,
to obtain the distribution of photon transverse momentum
k
with longitudinal
moment transfer q. Free atoms in high magnetic elds have
an axially symmetric but complex electron density distribu-
tion. But the departures from uniform electron density in
condensed matter are not large except for a small number
of inner orbitals and we therefore adopt the potential Ze
V
of a point charge within a spherical Wigner-Seitz unit cell
of uniform electron density. Its radius is
rWS = 2.15 10
10
Z
0.23
B
0.40
cm, (2)
obtained from the ion number density calculated by Medin
& Lai (2006) for atomic number Z. Calculational details are
summarized in the Appendix. The symmetry of
V indicates
that Landau functions in cylindrical polar coordinates are
the appropriate choice. The quantum number l denotes the
spatial degeneracy of these states and the procedure is to
average the transition rate over all l in the range 0 l lm.
Each state has a guiding centre radius
2l + 1rB, where rB
is the cyclotron radius. The incident ux is then c divided by
(2lm + 1)r
2
B
, and the cross-section at incident momentum
p 1, with no spin-ip, is the limit lm of,
nn
= r
2
B
_
Ze
2
hc
_
2 _
2lm + 1
lm + 1
_
lm
l=0
p + q, n
, l
V |p, n, l
2
. (3)
This expression is greatly simplied by the selection rule
(n l) = 0 arising from equation (A3) and from the ax-
ial symmetry of
V . Spin-ip cross-sections are smaller by a
factor of the order of (p
)
2
/4E
2
relative to unity and
as our interest is primarily in electrons with p mc they
have not been calculated. The range of initial-state quan-
tum numbers l should be so large that the cross-section is
independent of lm in the case of an isolated atom. We have
conrmed that, for B = Bc, this condition is satised ad-
equately for lm 30 at which value guiding centres are
at radii approaching the Wigner-Seitz cell radius. Numeri-
cal cross-sections
nn
are given in Table 1, for n, n
4.
They are in units of 1bn = 10
24
cm
2
and are for Z = 26
and longitudinal momentum p = 20, but are almost exactly
independent of p. Calculation to the lowest order in
V is
satisfactory here, as for the zero-eld small-angle Ruther-
ford formula, owing to the pole in the amplitude at zero
momentum transfer. Thus the cross-sections are linear in
Z
2
.
The cross-sections of Table 1 are valid in the relativistic
limit of p 1 so that comparison with the near-threshold
cross-sections found by Bussard (1980) and Langer (1981)
is not possible. But the standard Rutherford cross-section
at small angles can be expressed in terms of a continu-
ous variable n through the correspondence principle relation
p
, with n, n
4, are almost
exactly independent of longitudinal momentum at p mc but
have been calculated for electrons of p = 20 mc incident on an
isolated neutral atom of atomic number Z = 26. The magnetic
ux density in the rst column is in units of Bc = 4.41 10
13
G. The signicance of the n n transitions is considered in the
text and later in Section 6.
B n n
= 0 1 2 3 4
0.3 4 91 271 1132 6128 20886
3 182 841 5454 23132 6146
2 525 4483 25901 5467 1138
1 3032 29470 4491 843 272
0 34574 3036 526 182 91
1.0 4 27 80 334 2056 8729
3 54 248 1804 9543 2063
2 156 1460 10521 1810 336
1 968 11746 1463 249 80
0 13439 970 156 54 27
3.0 4 9 25 102 713 3862
3 17 77 621 4179 716
2 49 498 4554 623 103
1 328 5012 500 78 25
0 5628 329 49 17 9
values and dependences on n and B are quite close to those
given in the Table for an initial state with n = 0. The n n
cross-sections are well-dened by equation (3) even though
they are to an evanescent state whose asymptotic nal
form with q = 0 is indistinguishable from the unscattered.
These n = 0 transitions to virtual states of nite q ap-
pear in the calculation of second-order processes, in partic-
ular bremsstrahlung and pair creation cross-sections, and in
condensed matter are relevant to the Landau-Pomeranchuk-
Migdal eect considered in Section 6.
The cross-sections in Table 1 are typically two orders
of magnitude larger than those we obtain for Coulomb
bremsstrahlung in Section 5. Thus Rutherford scattering
excites higher Landau states whose decay is an important
source of photons, particularly in the later stages of shower
development. We shall refer to this in greater detail in Sec-
tion 7.
3 CYCLOTRON EMISSION
Transition rates for relativistic cyclotron emission are obvi-
ously relevant to the low-altitude plasma above polar caps
at B Bc and therefore have been calculated by a number
of authors (Herold, Ruder & Wunner 1982, Latal 1986, Bar-
ing, Gonthier & Harding 2005; see also the review of Harding
& Lai 2006). The principal reason for our calculation here,
which is limited to unpolarized electrons, is to investigate
the sequence of partial transition rates by which an electron
in Landau state n decays to n = 0. These determine the dis-
tribution of the transverse photon momentum k
= k sin ,
where is the photon angle with respect to B, and hence
electromagnetic shower development at B Bc.
In the rest frame of the initial electron, the relation
between momentum k and is,
k sin
2
= E0
_
E
2
0
sin
2
(p
2
p
2
)
_
1/2
, (4)
in which E0 =
_
1 + p
2
nn
=
1
h
_
1
1
d(cos )
k
2
2h
3
c
E
+ ck cos
2
1
2(lm + 1)
s,s
lm,l
l,l
=0
, n
, s
, k, |e
A|n, l, s
2
, (5)
summed over photon polarization states
and
, respec-
tively parallel with and perpendicular to k B, and over
nal electron spins. The radiation eld vector potential is
A
given by equation (A6) and the nal-state electron energy is
E
m
= 12.
The computed values, in units of 10
3
B, where B is the
cyclotron angular frequency, are given in Table 2 for n 4.
The summed transition rates given in the nal row of each
section are the sole results of this paper that can be com-
pared directly with previously published work. Agreement
with the rates shown in Fig. 3 of Harding & Lai (2006) is
satisfactory insofar as accurate comparison is possible. It is
interesting to see that there is eectively no selection rule
on n and that the partial rates display the n-dependence
noted by these authors in that, with increasing magnetic ux
density, there appears an enhanced rate for direct transitions
to the n = 0 ground state. The dependence on photon po-
larization is not given here. It is unremarkable: transitions
to
.
Photon angular distributions vary with n but are also un-
remarkable and are not given here. For n = 4 they have
a maximum at = /2; for n = 1 the maxima are near
= 0, .
The maximum photon transverse momentum occurs at
= /2 and is,
k
,max
=
_
1 + p
2
_
1 + p
2
. (6)
It is not possible to make a compact statement about the dis-
tributions of k
= 2 for electron-positron
Landau numbers n = n = 0 and k
= 1 +
1 + 2B
for n = 0 with n = 1. Rates immediately above the lower
threshold are partially inhibited by a selection rule but above
the higher threshold, transition rates for magnetic pair cre-
ation are so high that photon mean free paths are small
compared with the radiation length, which is the basic unit
of length for shower development. But Table 2 shows that,
except for the highest magnetic eld, the majority of tran-
sitions from n 4 have k
B
for unpolarized elec-
trons. The sums of the partial transition rates for n 4 are in
the nal row of each section.
B n
n = 1 2 3 4
0.3 3 1.33
2 1.33 0.68
1 1.24 0.59 0.38
0 0.76 0.39 0.26 0.20
sum 0.76 1.63 2.18 2.59
1.0 3 0.97
2 1.05 0.59
1 1.14 0.61 0.42
0 1.06 0.67 0.52 0.45
sum 1.06 1.81 2.18 2.43
3.0 3 0.61
2 0.68 0.39
1 0.79 0.43 0.30
0 0.94 0.62 0.50 0.44
sum 0.94 1.41 1.61 1.74
10.0 3 0.35
2 0.39 0.22
1 0.46 0.25 0.17
0 0.62 0.41 0.34 0.29
sum 0.62 0.87 0.98 1.03
4 PAIR CREATION
Coulomb pair creation in a uniform magnetic eld requires
a longitudinal momentum transfer q from the nucleus,
q = k(1 cos )
1
2p+
_
1 + p
2
+
_
1
2p
_
1 + p
2
_
, (7)
an expression valid for nal-state electron and positron mo-
menta p 1, and therefore diers from the zero-eld case
in being a function of both k and k
= 0 for which
conditions it falls to zero at k
V |p q, n, l, s
(E(p) E(p q) + i)
1
p q, n, l, s|e
A| p+, n+, l+, s+
+p+, n+, l+, s+|Ze
2
P
,
= Z
2
_
e
2
hc
_
3 _
h
mc
_
2
_
k
_
1+p
2
+
_
1+p
2
dE
2
EE+
pp+
nm
=0
lm
=0
M
P
,
2
(9)
for pair creation by a photon of momentum k, transverse
momentum k
, and of polarization
or . In this expres-
sion, the charges have been factored out from the matrix
element (8). There are a number of approximations here
that merit some consideration. Firstly, truncation of the
Landau quantum numbers to n 4 has been tested by
examination of the computed cross-section as a function of
nm for 0 nm 4. The basis for this truncation is that,
for xed k, the amplitude given by equation (8) is approx-
imately p
1
= 0
for photons polarized parallel with kB. This is consistent
with the fact that for this polarization, the matrix element
(A7) should be exactly zero for n+ = n = 0 (see Semionova
& Leahy 2001).
The cross-sections in Table 3 are quite slowly varying
functions of k and can be compared with the asymptotic
k 1 Bethe-Heitler value of
P
= 5.0 bn for unpolar-
ized photons incident on a screened Z = 26 nucleus in zero
magnetic eld. The correspondence principle indicates that
the Bethe-Heitler expression with modied screening should
be a fair approximation at moderate elds, of the order of
10
12
G, for which the Landau quantum number associated
with p
,
P
approaches the n-
dependent thresholds for magnetic pair production at which
q and hence the energy denominators in equation (8) be-
come zero; and (ii), the rapid decrease of cross-sections at
B > Bc.
5 BREMSSTRAHLUNG
The emission of a photon of momentum k at an angle
with B, and a change of Landau quantum number n n
,
requires a longitudinal momentum transfer from the atom
of
q = k(1 cos ) +
1 + p
2
2p
1 + p
2
2p
, (10)
where the initial electron longitudinal momentum is p mc
and the nal momentum is p
= p + q k cos .
The transition matrix element, to second order for an
isolated atom, is
M
B
,
= p
, k, n
, l
, s
|e
A|p + q, n, l, s
(E(p) E(p + q) + i)
1
p + q, n, l, s| Ze
2
V |p, n, l, s +
p
, n
, l
, s
| Ze
2
V |p
q, n
, l
, s
(E(p
) E(p
q) + i)
1
p
q, k, n
, l
, s
|e
A|p, n, l, s, (11)
in which the subscripts and again refer to the pho-
ton polarization with respect to k B. As in the previous
Section, and for the same reason, we have neglected two
time-ordered terms in the amplitude that involve virtual
pair creation in the Coulomb eld. The existence of single-
photon magnetic pair creation thresholds implies that the
bremsstrahlung cross-section in a high magnetic eld is best
expressed in terms of the independent variables k and k
.
The cross-section dened by the energy-loss rate (equivalent
to the radiation length) is then given by an integration over
photon energy,
Rad
=
_
km
0
dk
k
p
d
B
dk
, (12)
in which the dierential bremsstrahlung cross section for
an electron in Landau state n, summed over both photon
polarization states, is,
d
B
dk
= (2lm + 1)r
2
B
Z
2
_
e
2
hc
_
3 _
1 + n0
4
_
_
k
k
dk
lm
l,l
=0
s,s
nm
=0
M
B
2
, (13)
The summations have been truncated to nm = 4 and
lm = 12, as in the case of pair creation, but this approxi-
mation is much less satisfactory for bremsstrahlung and has
lead us to omit values for B < Bc. Bearing in mind the
importance of the variable k
, the cross-section
Rad
given
by equations (12) and (13) has been divided into two com-
ponents:
Rad
1
is for the interval 0 < k
>0
n(r
n
(r
)e
ip
(zz
)iE
(tt
)
, (16)
constructed from the Landau functions given by equation
(A3). The truncation to n = 0 is possible because, as we
found in Section 2, the n = 0 transition rates are at least
an order of magnitude smaller. It also excludes spin-ip and
back-scattering (p
dt
G(r, t; r
, t
)U
i
n(r
)e
ipz
iEt
=
_
dq
2
U
i
q
q + i
e
iq(zz
i
)
_
n(r
)e
ipziEt
_
, (17)
in which U
i
q
is the matrix element of U
i
between states p and
p
and t
du
2
_
dq
2
e
iu(zz
j
)
u + i
U
j
u
e
iq
(zz
i
)
q
+ i
U
i
q
=
i
_
dq
2
U
j
q
U
i
0
e
iq(zz
j
)
q + i
, (18)
in which u = q q
. It is given by,
j
_
z
j
dze
iK
z
_
dq
2
U
j
q
q + i
e
ipz+iq(zz
j
)(zz
j
)/2
=
j
_
1
p K
+ i/2
_
U
j
0
e
i(pK
)z
j
, (19)
in which = a/|U0|
2
, where a is the mean interatomic
separation zj zj1 and we have integrated rst over z and
then over q by completion of the contour in the semi-innite
upper half of the complex q-plane. The right-hand side of
equation (19) contains, within brackets, the momentum-
space Green function for an electron propagating without
back-scattering, spin-ip or n = 0 transitions. Forming the
square modulus of the remaining term (and neglecting any
inhomogeneity in the U
j
0
) yields the (one-dimensional) static
structure function for a linear chain of Na atoms,
S(q) =
1
Na
Na
j=1
e
iqz
j
, (20)
which contains, as a function of q = K
p, the dependence
of the transition rate on the condensed-matter structure.
Allowance for transitions with change of Landau quantum
number should not be dicult but is not essential because,
as can be seen from the Table 1 cross-sections, their mean
free path is considerably longer than .
Pair production and bremsstrahlung cross-sections in-
cluding the LPM eect are obtained immediately, assuming
a random distribution of atoms dened by a structure func-
tion S(q) = 1, simply by substituting this Green function
for the energy denominators contained in equations (8) or
(11). We have done so and have repeated the calculations
by which the Table 3 and 4 cross-sections were obtained.
The revised cross-sections given in the lower sectors of these
Tables are for Z = 26 and require some comment.
In the case of pair production, the re-calculated cross-
sections are given in Table 3 just for B = Bc and show
that, owing to the very high matter density ( 2 10
5
g
cm
3
) the LPM eect becomes noticeable at k = 4000 and
reduces cross-sections by more than an order of magnitude
at k = 40000. However, its eect on bremsstrahlung is less
simple. The re-calculated cross-sections in Table 4 show that
there is an initial increase at low values of p. The explanation
for this is as follows. For xed values of the kinematic vari-
ables and quantum numbers, there is a partial cancellation
of the two terms in equation (11) which arises because the
energy denominators are almost exactly equal in magnitude
( q) but have opposite signs. The presence of
1
in the
modied Green function creates a further amplitude term
in which this cancellation is not present, so producing the
cross-section increase. But with increasing p, values of q de-
cline and eventually the
1
component of the denominator
becomes dominant. Its eect becomes marked for p > 20000
mc.
The presence of the LPM eect removes the simple Z
2
scaling of cross-sections, but equations (14) and (15) allow
us to see that Z
S
=
_
S(q)
d
dq
dq, (22)
taken over the complete interval of q for the process, and
that this diers from the S = 1 cross-section by a factor of
order unity, not Na.
7 CONCLUSIONS
The cross-sections obtained here are those that, with Comp-
ton scattering, determine electromagnetic shower develop-
ment. For magnetic ux densities of the order of 10
12
G,
Landau quantum numbers n 10
2
are associated with
transverse momenta p
=0
nn
. (23)
From the transition rates given in Table 2 and the values
of
Rad
given in Table 4, we can see that its value is not
strongly B-dependent. Specically, for B = Bc, Z = 26,
Rad
= 22 bn and l
Rad
= 1.8 10
5
cm with inclusion
of the LPM eect, so that for n = 4, the inequality (23)
becomes p < 1100 mc. At lower momenta, the process of
bremsstrahlung becomes simply a sequence of excitation
(or de-excitation) of higher-n Landau states by Ruther-
ford scattering and de-excitation by cyclotron emission. At
even lower momenta, the balance between excitation and
de-excitation changes and the typical values of the Landau
quantum number decrease until for lRu lce, that is, for
p
mc
lRu
c
10 (24)
they are n = 1. With the cross-section 01 from Table 1,
we nd lRu = 4.0 10
7
cm. The transition rate 10 =
1.06 10
3
B gives p 11 mc.
The above summary of the properties of the
bremsstrahlung and pair creation processes at high magnetic
elds serves to show qualitatively how the characteristics of
electromagnetic showers dier from the zero-eld case. In
the initial stages of an electron-initiated shower of about
10
3
GeV, the Landau-Pomeranchuk-Migdal (LPM) eect is
far more eective in reducing cross-sections owing to the
very high density of the condensed matter at the neutron
star surface. Therefore, shower development is displaced in-
ward until typical electron or photon energies are reduced
to the extent that the eect becomes unimportant. At this
stage, electron energy loss becomes rapid, occurring within
lengths much shorter than l
Rad
. Photon mean free paths are
dependent on k
= 1 +
1 + 2B for n = 0 with n = 1.
It is signicant that cyclotron decay, which is dominant
in the later stages of shower development, always leads to a
decrease in Landau quantum number, so bringing about a
convergence of the shower toward small k
_
0
(m + E)n
p
n1
pn
_
_
1,n1 =
_
_
(m + E)n1
0
pn1
p
n
_
_
each multiplied by the common normalization factor G =
1/
_
2E(E + m). The longitudinal momentum component
is p. These solutions have eigenvalues given by equation (1)
and are two-fold degenerate for n > 0, but they are not
identical with the true physical states owing to radiative cor-
rections that have been neglected. Natural line-widths, and
level shifts arising from the electron anomalous magnetic
moment and from radiative corrections, are all of similar
magnitude and give physical states that are quite dierent
from the above solutions (see Herold, Ruder & Wunner 1982;
also Baring, Gonthier & Harding 2005). The distinction
would be important if spin-polarized electron or positron
states were being considered. However, for the cross-sections
obtained here, which are for relativistic energies, lepton spin-
polarization is not of interest and the ne-structure in energy
levels can be safely neglected. In this paper, we always aver-
age or sum over lepton spin states so that we require only the
completeness of the Johnson-Lippmann states. These, with
the negative energy solutions given by the transformation
E E, have been used explicitly in Sections 2 - 5. The
corresponding representation of the Dirac matrices is easily
found from equations (47)-(54) of Johnson & Lippmann and
is
=
_
0
0
_
=
_
I 0
0 I
_
.
The subscript s = 1 labelling the spinors indicates that
for the case n = 0, or in the limit B 0, they are also
eigenstates of z with eigenvalues as indicated. The func-
tions n are a complete orthonormal set of eigenfunctions
of
2
labelled by the Landau quantum number n. Their rel-
ative phases are not arbitrary because they are required to
satisfy the conditions,
(x + iy)n1 = p
(n)n,
(x iy)n = p
(n)n1, (A2)
where p
(n) =
, , z,
with B parallel with the z axis appear to be the optimum.
The functions are then,
nl
=
(i)
n
rB
n!l!
(ln)/2
e
/2
fn(l, )
e
i(ln)
2
e
ipz
, (A3)
conveniently expressed in terms of the variable = r
2
/2r
2
B
,
where rB = mc
2
3
f4 = l(l 1)(l 2)(l 3) 4l(l 1)(l 2)
+ 6l(l 1)
2
4l
3
+
4
(A4)
in obvious sequence and they satisfy,
fn(l, ) = ()
nl
f
l
(n, ), (A5)
which is worth noting in relation to states with l < n.
We adopt gaussian cgs units so that the ne struc-
ture constant is e
2
/hc. Perturbations of the correct sign
are introduced into equation (A1) by modifying the energy-
momentum four-vector, A A+
A and E EZe
2
V , to
include the radiation eld
A and the atomic Coulomb po-
tential for nuclear charge Z. Thus the absorption of a photon
with wave-vector k and angular frequency is represented
by the matrix element of
e
A =
_
2hc
2
_
1/2
e e
ikr
, (A6)
in which is the polarization vector either parallel with, or
perpendicular to, the vector k B.
The creation of a pair in states specied by
|p, n, l, s, as in lines three and six of equation (8),
is given by the matrix element
_
r
dr
ddz
,n
(p, E, l)e
A
s
+
,n
+
(p+, E+, l+), (A7)
in which the positron energy is E+ > 0. Evaluation of this
proceeds by matrix multiplication and immediately yields,
for each set of values of s and of photon polarization, a
linear combination of terms each of which, apart from kine-
matic factors, contains an integral of the form,
I(k
, n, l, n+, l+) =
_
r
dr
de
ik
cos
,l
(r
)
n
+
,l
+
(r
).
These expressions, and the integrals contained in them, have
all been evaluated numerically. Therefore, we are unable
to give useful analytical expressions for any of the cross-
sections calculated in this work. Evaluation is the more te-
dious because the transverse dipole approximation is not ad-
equate so that there is no radiative transition selection rule
that is eective for physically signicant values of k
. But
10 P. B. Jones
matrix elements of the Coulomb potential satisfy (nl) = 0
strictly for isolated atoms; also in condensed matter to the
extent that components with the symmetry of the crystalline
eld are small.
This paper has been typeset from a T
E
X/ L
A
T
E
X le prepared
by the author.