Berthelot SF 98 99 175 181 PDF
Berthelot SF 98 99 175 181 PDF
Berthelot SF 98 99 175 181 PDF
The objective of this part is to emphasize the context in which the problem of the mechanical analysis of laminate or sandwich structures is stated. Chapter 1 is an introduction which gives general features on composite materials. The constituents (matrix and fibres) are analysed in Chapter 2. The general architecture of laminate and sandwich materials is next considered in Chapter 3.
CHAPTER 1
Civil engineering Aviation, space, sports, biomedecine, etc. Thermomechanical applications Space
Peaux Ames
Metals, laminates, etc. Foams, honeycombs, balsa, reinforced plastics, etc. Multiple areas
matrix reinforcement
Thus, for the characterisation of a composite material, it will be necessary to consider: the nature of the constituent materials and their properties, the reinforcement geometry, its repartition, the nature of the interface between the reinforcement and the matrix. The reinforcement geometry will be described by the reinforcement shape, its size, the reinforcement concentration, its orientation, etc. If all of these parameters combine to determine the resultant properties of the composite material, the decriptive models will consider only some of these parameters because of the complexity of the mechanical phenomena which are involved. For example, the shape of the reinforcement will be approximated as either spheres or cylinders. The concentration of the reinforcement is usually measured by the volume fraction or the weight fraction. The development of the models considered in this book will show that the volume fraction of reinforcement is a determining parameter for the mechanical properties of composite materials. For a given reinforcement concentration, the reinforcement distribution through the volume of composite materials is also an important feature. A uniform distribution will lead to the homogeneity of materials: the mechanical properties of materials will be independent of the measurement point. In the case of nonuniform distributions of the reinforcements, material fracture will be initiated in the areas of low reinforcement concentrations, which leads to a decrease in the fracture properties of composites. For composite materials in which the reinforcement is constituted of fibres, the fibre orientation is a determinant factor for the anisotropy of materials. This aspect constitutes one of the fundamental properties of composite materials: the ability to tailor the composite structure according to a conception and fabrication of the structure in such a way to obtain the structure properties wished.
arrangement of fibres and their orientations allow us to modify the mechanical properties of composite materials, in such a way to obtain materials ranging from strongly anisotropic materials to transverse isotropic materials. Designers thus have in composite material a material the properties of which can be modified by adjusting: the nature of the constituents, the proportion of the constituents, the orientation of the reinforcement, according to the performances required. Fibre composite materials lead to high mechanical properties and justify to develop an extensive study of their mechanical behaviours. So, this type of composite materials will be considered essentially in the present textbook.
Among these various composites, we can cite: 1. Composites with organic matrix (resin, fillers), with: mineral fibres: glass, carbon, etc. organic fibres: Kevlar, polyamides, etc. metallic fibres: boron, aluminium, etc. 2. Composites with metallic matrix (light and ultra-light alloys of aluminium, magnesium, titanium), with : mineral fibres: carbon, silicon carbide (SiC), metallic fibres: boron, metallo-mineral fibres: boron fibres coated with silicon carbide (BorSiC). 3. Composites with mineral matrix (ceramic), with: metallic fibres: boron, metallic particles: cermets, mineral particles: carbides, nitrides, etc. Composite materials with an organic matrix can be used only for temperatures which do not exceed 200 to 300 C. For higher temperatures, composite materials with a metallic matrix are used up to 600 C and composites with a metallic matrix up to 1,000 C.
F=
ES l , l
(1.1)
where E is the Youngs modulus of the beam material, S the cross-sectional area of the beam and l the length of the beam. The beam stiffness K = ES l caracterizes the mechanical performances of the beam in the elastic domain. In the case of two materials 1 and 2, the ratio of the
beam stiffnesses is: K1 E1S1 l2 = , K 2 E2 S2 l1 and the ratio of the weights of the beams is: m1 S1l1 1 = , m2 S2l2 2 (1.3) (1.2)
introducing the specific weights (weights per unit of volume) of the beams. The combination of Relations (1.2) and (1.3) leads to : K1 E1 1 m1 l2 = . K 2 E2 2 m2 l1
2
(1.4)
For a structure, the dimensions of the elements are given, and the comparison of the beam stiffnesses must be considered for identical lengths. Therefore, for l1 = l2 : K1 E1 1 m1 = . (1.5) K 2 E2 2 m2
Lastly, the use of materials in the space and aviation areas, and further in the areas of sports, building, etc., has led to compare the mechanical properties of structures with equal weights. For m1 = m2 , the stiffness ratio is: K1 E1 1 = . K 2 E2 2 (1.6)
Thus, it appears that the best material is that which has the highest value of E , leading to the highest value of the stiffness of the beam. The term E is called the specific Youngs modulus of the material. A similar investigation can be implemented in the case of a three-point bending beam where the beam is subjected to a load F (Figure 1.3). The relation between
the load and the transverse deflection at the beam centre is given by : (1.7) f = Kf , l3 where f is the deflection at the beam centre, I the inertia moment of the cross section and l the span length distance between the supports. The coefficient K is the bending stiffness of the beam. In the case of a cylindrical beam section of radius r, the moment is given by
and the weight is I=
F = 48 EI
r4,
m = r 2l.
It follows that in the case of two materials 1 and 2, the bending stiffness ratio is given by:
K1 E1 12 m1 l2 = . 2 K 2 E2 2 m2 l1
2 5
(1.8)
So, for bending beam, it results that the best material is that which has the highest value of E 2 . Similar developments can be considered in different shapes of the structures: plates, shells, complex structures. The conclusion is always of the same nature: for identical weights and dimensions, the most rigid structures are obtained by using materials that have the smallest specific weight. Similarly, the comparison of the structure strengths lead to similar conclusions for the fracture stresses of materials. Thus, it has become usual to compare the mechanical properties of materials by considering the specific values (with respect to the weight per unit of volume) of the moduli and fracture stresses of materials.
l
FIGURE 1.3. Three-point bending beam.
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performances can not be achieved to the detriment of the cost of the finished product. In this area, the impact of the cost of the material and its elaboration is very high. Table 1.2 gives the specific mechanical characteristics of usual materials elaborated in bulk form. The traditional materials such as steel, aluminium alloys, wood and glass have comparable specific moduli. In contrast, it is observed that the specific fracture stress of glass is clearly higher than that of steel and of aluminium alloys. Furthermore, it is an established fact that the fracture stresses measured for the materials are notably smaller that the theoretical values. This difference is attributed to the presence of defects, as microcracks, in the materials. To increase the values of the fracture stresses, it is then necessary to seek for processes of material elaboration which lead to a decrease of the defects inside the materials. This objective is achieved by elaborating the materials in the form of fibres of very small diameters of some tens of microns. It is clear that it is necessary to proceed from materials which already have high specific properties in the bulk form. The mechanical properties of materials elaborated in the form of fibres are reported in Table 1.3. The values reported clearly show the interest in elaborating materials in fibre form to achieve higher values of the fracture stresses. Owing to their low cost, glass fibres are used most where the low cost of the products is a determinant factor. However, glass fibres have a limited value of the modulus. Other fibres, as carbon fibres, Kevlar fibres and boron fibres have a high specific modulus, hence the interest of these fibres in space and aviation areas.
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TABLE 1.3. Specific mechanical properties of materials, elaborated in the form of fibres.
Modulus Fibres E (GPa) 72.4 85.5 390 240 130 385 Fracture Stress Density (kg/m3) 2,540 2,480 1,900 1,850 1,500 2,630 Specific Modulus E / (MN m/kg) 28.5 34.5 205 130 87 146 Specific Stress
E-Glass S-Glass Carbon with high modulus high stress Kevlar (aramid) Boron
composite materials are elaborated. Moreover, the analysis of the mechanical properties which will be developed in this book will show that the volume fractions are the factors which it is necessary to introduce in the theoretical models for describing the mechanical properties of composites. It is therefore necessary to derive the relations which relate one fraction to the other. These relations will be established for a two-phase material and then extended to a material with multiple phases.
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respective indices for the composite material, the fibres and the matrix. The volume fraction of fibres is: v Vf = f . (1.9) vc The volume fraction of the matrix is:
Vm =
with
vm , vc
(1.10) (1.11)
Vm = 1 Vf ,
since
vc = vf + v m .
(1.12)
with
Pm = 1 Pf .
or
cvc = f vf + mv m .
The specific weight of the composite material is thus written as a function of the volume fractions as:
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c = f Vf + m (1 Vf ) .
Similarly, considering the total volume of the composite:
vc = vf + v m ,
(1.19)
(1.20) . (1.21)
we obtain:
pc
pf
pm
c =
Pf
Pm
(1.22)
The relations between the weight fractions and volume fractions can now be established considering the relations:
Pf = pf f vf f = = Vf , pc cvc c Pm =
(1.23)
and
m Vm , c
(1.24)
where the specific weight of composite material is deduced from Relation (1.19). The inverse relations are obtained in a similar way. We have:
Vf = Vm =
c Pf , f c Pm , m
(1.25) (1.26)
where the specific weight of composite material is deduced from Relation (1.22). Equations (1.19) to (1.26) can be extended to the case of an arbitrary number of constituents. The genaral expressions for n constituents are:
Pi =
i Vi , c
n
(1.27)
with
c =
and
iVi ,
i =1
(1.28)
Vi =
c Pi , i
(1.29)
with
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c =
i =1 i
n
Pi
(1.30)
ct
The presence of porosities in a composite may involve a significant decrease of the mechanical properties of the composite. Porosity also increases the sensitivity of the composite material to the external environment: increase of the humidity absorption, decrease of the resistance to chemical products, etc. So, it is important to have an evaluation of the porosity proportion as a means to estimate the quality of a composite. A high-quality composite material will contain less than 1 % by volume of porosities, when a mediocre-quality composite could be reached as much as 5 %.
EXERCISES
1.1 Express the volume fraction Vf of fibres in a composite as a function of the weight fraction, introducing the ratio f /m of the specific weights and the ratio (1 Pf) / Pf of the weight fractions of matrix and fibres. 1.2 Plot the curve for the volume fraction of fibres as a function of the weight fraction of fibres in the case of glass fibre (f = 2500 kg/m3) composites, of carbon fibres (f = 1900 kg/m3), of Kevlar fibres (f = 1500 kg/m3), for the same matrix m = 1200 kg/m3. 1.3 A composite structure is designed as made of a composite containing a volume fraction Vf of fibres. The volume of the structure is vc. Calculate the fibre and matrix weights which are necessary. Application : Vf = 50%, vc = 0,01 m3. Calculate the weights in the case of the composite materials considered in Exercise 1.2.
CHAPTER 2
2.1 INTRODUCTION
As considered in this book, a composite material is constituted of a matrix with fibre reinforcement embedded in the matrix The matrix is a resin, such as polyester, epoxide, etc., in which fillers are incorporated, in such a way to reduce the production cost while improving the properties of the resin. From a mechanical point of view, the filler-resin system behaves as a homogeneous material. So, the composite material is considered as being constituted of a matrix and a fibre reinforcement. The reinforcement brings to the composite material its high mechanical properties, when the role of the matrix is to transfer to the reinforcement the external mechanical loading and to protect the reinforcement against external aggressions. The type of reinforcement-matrix association depends on the constraints imposed by the designer: high mechanical properties of composite, good thermal stability, low cost, resistance to corrosion, etc. The purpose of this chapter is to give a general view of the various constituents which are used. The synthesis is given from the viewpoint of the mechanical engineering. For a more extensive analysis, the reader should refer to specialized books.
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According to these considerations, the resins used for composite materials are polymers modified by fillers and additives, such as mould release agents, stabilizers, pigments, etc. Resins are delivered in solution in the form of polymers in suspension in solvents that prevent linking between the prepolymerized macromolecule. When heated, links are developed between the chains of the prepolymer so as to constitute a cross-linked polymer with a three-dimensional structure. Two large families of polymer resins exist: thermoplastic resins and thermosetting resins. These two types of resin have the property of being able to be moulded or manufactured in order to obtain either a finished product or a semifinished product the form of which can be next modified. The thermoplastic resins, the production of which reaches the highest tonnage because of their low cost, have the property of being able to be processed several times by successive heating and recooling. These resins can thus be salvaged and easily recycled. However, the mechanical and thermal properties are low. In contrast, the thermosetting resins can be processed only once. After polymerization by heat applying in the presence of a catalyst, these resins lead to a structure that can be destroyed only by an application of high thermal energy. Thus, thermosetting resins have mechanical properties and especially thermomechanical properties which are much higher that those of thermoplastic resins. As a result of these higher properties, thermosetting resins are extensively used in the manufacture of composite materials. However, improvement of the properties of thermoplastic resins leads to their increasing use. Two other classes of resins with specific uses are also used in the elaboration of composite materials. They are: thermostable resins which in continuous service can support temperatures of the order of 200 C and higher, elastomers, the reinforcement of which using different fibres leads to various applications in the automotive industry.
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low production cost, a wide diversity that offers many possibilities, their adaptation to different fabrication processes that are easy to carry out and to automatize. Hence the industrial development of polyester resins is continually increasing. According to their Youngs modulus, polyesters resins are classified into flexible resins, semirigid resins or rigid resins. The resins usually used in manufacturing composite materials are of rigid type. These cured polyester resins have the following properties: Density Tensile modulus Bending modulus Tensile fracture stress Bending fracture stress Tensile fracture strain Bending fracture strain Compressive fracture stress Shear fracture stress Deflection temperature under a load 1,200 kg/m3 2.83.5 GPa 34.5 GPa 5080 MPa 90130 MPa 25 % 79 % 90200 MPa 1020 MPa 60100 C
Among the advantages of the unsatured polyester resins are the following : a good rigidity, resulting from a fairly high Youngs modulus, a good dimensional stability, a good wettability of reinforcements, the ability to be manufactured, a good chemical behaviour, a low cost of production, a good chemical resistance to hydrocarbons (petrol, fuel, etc.) at room temperatures, etc. Among the disadvantages, it can be reported: a mediocre behaviour with temperature, which is less than 120 C in continuous use, a sensitivity to cracking, especially under shocks, an inportant shrinkage, of the order of 8 to 10 %, a poor behaviour in steam environment, with the risk of hydrolysis, hence the necessity of covering polyester resin composites with a gel-coat layer to protect them, a degradation in ultraviolet environment, a flammability.
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1. Phenolic resins are the oldest of the thermosetting resins, the best known of which is the bakelite. The characteristics of these resins are the following ones: Density Bending modulus Tensile fracture stress Tensile fracture strain Bending fracture stress Compressive strength Deflection temperature under a load Among the advantages, we have: an excellent dimensional stability, a good temperature stability, a good chemical resistance, a low shrinkage, good mechanical properties, a low cost. Among the disadvantages, we report: an elaboration using moulding processes with pressure, hence low production rate, dark colors of resins, the resins can not be used for food applications. Phenolic resins will therefore used for applications that require a high temperature behaviour or good chemical resistance. 2. The properties of aminoplast resins are close to those of phenolic resins. To the advantages of these resins, it can be added: the ability to use in food applications, the possibilty of colouring the resins. 3. Furane resins provide probably the best chemical resistance of any thermosetting resin. Hardening is faster than for phenolic resins. However the cost of furane resins is high, about three times higher than the cost of phenolic resins, hence the use of the furane resins is limited. Their good chemical resistance leads to use the furane resins for tanks, pipes, containers of chemical agents. 1,200 kg/m3 3 GPa 40 MPa 2.5 % 90 MPa 250 MPa 120 C
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performances which are used in the areas of aeronautical construction, space, missiles, etc. The general mechanical characteristics of epoxide resins are the following ones: Density Tensile modulus Tensile fracture stress Bending fracture stress Tensile fracture strain Shear fracture stress Deflection temperature under a load 1,1001,500 kg/m3 35 GPa 6080 MPa 100150 MPa 25 % 3050 MPa 290 C
Epoxide resins thus lead to high mechanical properties. However, to benefit of these high performances, it is necessary to have long cycles of transformation and long cure times, from several hours to several tens of hours, at relatively high temperatures from about 50 to 100 C. Among the advantages of epoxide resins, we have: good mechanical properties in tension, compression, bending, shock, etc. superior to those of polyester resins, a good behaviour at high temperatures: up to 150 C190 C in continuous use; an excellent chemical resistance, a low shrinkage in moulding processes and during cure (about 0,51 %), a very good wettability of reinforcements, an excellent adhesion to metallic and mineral materials. Among the disadvantages, it can be reported: a long time of polymerization, a high cost, the need to take precautions in the manufacture processes, a sensitivity to cracking.
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the polypropylene, the polystyrene, the polyamide, the polycarbonate, etc. The interest of thermoplastics lies in their low cost, resulting from the initial materials as well as the fabrication processes (injection, extrusion, pultrusion, etc.). Nevertheless, this low cost is associated with mechanical and thermo-mechanical properties which are low. We report hereafter some characteristics for Polypropylene and polyamide. Polypropylene Density (kg/m3) Fracture stress (MPa) Tensile modulus (GPa) Deflection temperature under a load (C) 900 2035 1.11.4 5060 Polyamide 1,140 6085 1.22.5 65100
The various thermoplastics can be reinforced by fibres to obtain composite materials. However, the use of thermoplastics in the domain of composites have a limited development on account of the low properties of thermoplastic resins and the need to use high temperatures to process the transformations from initial solid products.
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systems or to reduce the final costs of the composite matrices. The quantity of the added products can vary from some tens of percent in the case of fillers to a few percent or less in the case of additives. The addition of these products has the function of improving the mechanical and physical properties of the finished products as well as making easier their manufacture processes. Some example of fillers and additives are given hereafter in this section.
2.3.2 Fillers
2.3.2.1 Reinforcing Fillers
The object of incorporating reinforcing fillers in resins is to improve the initial mechanical properties of resins. These fillers can be classified according to their geometric forms, as spherical fillers or non-spherical fillers. 2.3.2.1.1. Spherical Fillers The basic interest in these fillers lies in their spherical forms which avoid stress concentrations and, as a consequence, decrease the cracking susceptibility of the matrix compared with the use of non-spherical fillers. Spherical fillers, usually called microspheres, are elaborated in the forms of solid spheres or hollow spheres. The solid or hollow microspheres have diameters usually ranging from 10 to 150 m. They can be elaborated from glass, carbon or organic component as epoxide, phenolic, polystyrene, etc. Hollow glass microspheres represent more than 90 % of the spherical fillers used for composite matrices. Hollow Glass Microspheres The main advantage of hollow glass microspheres lies in their low density, from 100 to 400 kg/m3, yielding an increase in the specific modulus of the filled resins and their behaviour under compression. The fabrication of hollow glass microspheres is carried out by flowing, in a high temperature area, fine particles of glass containing an expansion gas, usually a mixture of nitrogene and carbon dioxide. When the particles are submitted to the high temperatures, the gas expands inside the melted glass particles. Next, the particles are rapidly cooled inducing the solidification of the walls of the microspheres before the decrease of the gas pressure. The hollow spheres so obtained has diameters of the order of 20 to 130 m, with wall thicknesses of about 0.5 to 2 m. The microspheres can next be selected according to their sizes. Lastly, the spheres are submitted to surface treatments, leading to the improvement of bonding between resin and spheres. Hollow glass microspheres are most frequently incorporated in epoxide or polyester resins. Their use is restricted to low pressure manufacturing processes because of the weak resistance of the hollow spheres to crushing.
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The essential advantages of incorporating hollow glass spheres in resins are: the decrease of the matrix density, an increase of the Youngs modulus of the resin, the improvement in the behaviour of matrix under compression. Other microspheres Other hollow microspheres are elaborated as: Carbon microspheres: density 120 kg/m3, diameter 5 to150 m. Organic microspheres (epoxide, phnolic, etc.) : density 100 to 500 kg/m3, diameter 10 to 800 m. These microspheres are usally more expensive (up to five times more for carbon microspheres) than glass spheres. Among other microspheres used are solid glass spheres. Compared to hollow glass spheres, the characteristics of solid glass spheres are: a high density: 2,500 kg/m3, a lower cost, the ability of manufacturing the products at high pressures. 2.3.2.1.2. Non-spherical Fillers Among the non-spherical fillers, mica is the material which is the most used. It is then incorporated in the forms of flakes of transverse dimensions from 100 to 500 m and thicknesses of 1 to 20 m. Mica is usually added to thermoplastic or thermosetting resins for electrical and electronical applications.
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The principal fillers which are used are: carbonates: chalks or calcites (CaCO3), which are the most used, silicates: talc, kaolin, feldspar, wollastonite, silicas, obtained by crushing and sifting of quartz sand. 2.3.2.2.2. Fire Retardant Fillers These fillers are incorporated in resins for reducing or impeding the combustion processes. Among the solid fillers introduced in thermosetting resins are: the aluminium hydrate, the most used, the antimony oxide. 2.3.2.2.3. Conductive and Anti-Static Fillers Organic resins are thermal and electrical insulators. For specific applications, it is therefore to incorporate in resins conducting fillers. The usual fillers are: metallic powders or flakes of copper, aluminium, iron, etc., glass spheres metallized with copper, silver, etc., carbon particles, as carbon black, metallic filaments.
2.3.3 Additives
Additives are incorporated in small quantities (a few percent or less) and processed as: mould release agents, pigments and dyes, anti-shrinkage agents, light stabilizers.
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are gathered together into a bundle called a strand. The usual nomenclature of the various fibre forms is still not well established, and is generally derived from the nomenclature used for glass fibres. A single continuous fibre is usually called an elementary filament or monofilament. Monofilaments are next gathered into strands or yarns. Continuous or discontinuous yarns are characterised by their linear density, which is the weight per unit length. This linear density is a measure of the fineness of the strands or yarns, and depends on the diameter and number of monofilaments. The linear density is given by the tex number, which is the weight of a strand or yarn of length 1,000 m. Hence: 1 tex = 1 g/km. In fact, it would be better to write: 1 tex = 10-6 kg/m. according to SI system of units. The first definition is best adapted to a practical use.
2.4.3.1. Mats
Mats are layers of continuous or discontinuous strands or yarns randomly distributed in a plane without preferential orientation. Fibres are bounded together with either a high or low solubility binder. The absence of preferential orientation of fibres leads to mechanical properties of layers which are isotropic in the plane of the mat. The difference between chopped strand mats and continuous strand mats lies essentially at the level of their deformability properties. The first ones are not very deformable, whereas the second ones can be processed to obtain complex shapes by a regular stretching of the mat in all the directions. Continuous strand mats are particularly suitable for matched-die moulding with deep moulds to process complex shapes of structures by pressure, injection or vacuum moulding.
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weft
Woven fabrics differ by the type of fibres (strands, yarns, rovings, etc.) and thus by the linear density of warp, as well as by the type of weave. Different types of weaves can be identified according to the repeating pattern of warp and fill interlacing. Figure 2.2 gives some examples of usual weave styles: plain weave or taffeta, twill or serge weave, satin weave, cross-ply weave, unidirectional weave. Plain Weave In plain weave, also known as taffeta, each warp and fill thread passes over one thread and under the next, leading to a cloth which is plane and stable, but not very deformable. This weave fabric leads to mechanical properties fairly identical in the two warp and weft directions, when the weaving threads are the same. However, the plain weave fabrics induce a high degree of crimp to the fibres, leading to a decrease of some mechanical performances of composite materials. Twill Weave In twill weave, known as serge, the number of warp threads and weft threads which interlace with each other can be varied. In a 2 1 serge, weft threads pass over one and under two warp threads, and in a 2 2 serge, the weft threads pass over two and under two warp threads. This type of weave fabric leads to a diagonal pattern of the weave (Figure 2.16). Serge cloth allows slippage to occur between warp and weft and has a good adaptability to moulding processes in the case of complex shapes. Satin Weave Satin weave is quite similar as serge, but the number of warp threads and weft threads that pass over each other before interlacing is greater. Each satin weave is characterised by a number, usually 4 or 8, indicating that the warp threads pass over 4 or 8 weft threads. This results in one face of the satin cloth which contains mostly of warp threads, and the other face of weft threads. Satin weave shows excellent ability for moulding complex shapes.
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8 satin weave
Cross-ply weave
Unidirectional cloth
Cross-ply Weave In cross-ply weave, two layers of cross threads are superposed without interlacing and held together by fine warp and weft threads. The absence of interlacing suppresses the shear effects and leads high performances of cloth, but with a high cost. Unidirectional Cloth In unidirectional cloth, the threads are aligned in the warp direction, and held together by fine weft threads. So, the fabric is unidirectional with high performances in the warp direction. The mechanical properties of the various cloths depend on: the type of threads used to manufacture the cloth: their nature (glass, carbon, etc.), the type of assemblage (with or without twisting), etc.; the type of weave: unidirectional weaves lead to the best mechanical properties of composite materials along a given direction; satin weaves and, to a lesser degree, twill weaves lead to mechanical properties which are greater than the ones of plain weaves; the linear density of the warp and weft threads of the cloth.
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1 2
diameters (some tens microns), the glass loses this character and then has good mechanical properties. Glass fibres are manufactured from special mineral glasses, composed of silica alumina, lime, magnesia, etc. These low cost materials, associated to quite simple production processes, give glass fibres an excellent price/performances ratio, which put glass fibres in the first rank of reinforcements actually used in composite materials. According to their compositions, different types of spinning glasses can be used to product glass fibres (Table 2.1). In practice, glasses of type E constitute almost all the production of glass fibres which are actually produced. The other types of glasses are used for specific applications as: D-glass, with high dielectric properties, used for the construction of electronic equipments for telecommunications, in particular for radoms; C-glass, resistant to chemical agents, used for the superficial processing of structures exposed to chemical environment;
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TABLE 2.1. Different types of spinning glasses. Type E D A C R, S General characteristics General use in mechanical engineering High dielectric properties High alkali content Good chemical resistance High mechanical properties
R- and S-glasses, with high mechanical properties, used for manufacturing composite structures with high mechanical performances. Only glass fibres of types E and R are used for mechanical applications, the compositions of which are reported in Table 2.2. It can be noted the very small proportion or the absence of akaline oxide in contrast of glasses used currently. This fact leads to production processes of glass fibres with high temperatures.
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Alumina
Bushing
Monofilament
Sizing Strand
the cooling conditions and speed of drawing, glass filaments with different diameters can be obtained. The monofilaments are then gathered together without twisting into a bundle called a strand, which is wound into a spool or onto a tube. These basis strands are mostly used for produce glass reinforcements incorporated in composite materials. Discontinuous glass fibres can also be obtained and next assembled into a yarn called verranne. The verranne yarns are distinguished from the continuous fibres by a cotton wool appearance.
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absence of cohesion between the fibres of a strand; sensitivity of the glass to abrasion, leading to a deterioration when the fibres are handled after drawing; sensitivity to attack by humidity and water; creation of electrostatic charges resulting from frictions between fibres, etc. To overcome these defects, an operation called sizing is carried out at the exit of the bushing, which consists in depositing on the glass fibres a sizing product the composition of which depends on the further use. Considering the defects reported, the functions of sizing process are: to establish some cohesion between the filaments; to give a greater or lesser stiffness to the strands according to strand use: strands used for moulding or weaving must be flexible, strands to be cut must be stiffer; to protect the filaments against abrasion; to avoid the generation of electrostatic charges; to make easier the impregnation of the filaments by the resins: good superficial wetting of fibres and good penetration inside the fibre strands; to promote bonding between the resin matrix and the fibres upon which the mechanical properties of composite materials are depending, but also to increase the aging behaviour of composites, to decrease the sensitivity to humidity and corrosion, etc.
Ef
fu fu
vf
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TABLE 2.4. Tensile fracture stresses measured on monofilaments and industrial strands. (in MPa). Characteristics Monofilament drawn at the exit of bushing Monofilament drawn from industrial strand Industrial strand constituted of a large number of filaments E-glass 3,400 2,0002,400 1,2001,550 R-glass 4,400 3,600 1,7002,000
TABLE 2.5. Fracture characteristics of industrial glass strands, deduced from the characteristics measured on unidirectional fibre composites. Characteristics Tensile fracture stress Ultimate strain (MPa) (%) Verre E 2,4002,600 3.4 Verre R 3,0003,600 4
obtain a simultaneous and uniform loading of all the filaments which constitute the strands. When strands are incorporated in composite materials, the fibrematrix bonding induced by the sizing process ensures a fairly homogeneous distribution of the loading on the strand filaments. The values of fracture characteristics, deduced from the fracture properties of unidirectional composites are reported in Table 2.5. These values are quite close to those measured on monofilaments obtained from industrial strands (Table 2.4), and usually these values may be considered as being representative of the fracture properties of glass fibres. It has to be noted that glass fibres keep their mechanical properties up to quite high temperatures, of the order of 200 C for E-glass and 250 C for R-glass. These fibres are thus well adapted to reinforcing matrices that have high thermal properties.
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For example, the strand might be referred as EC 9 34: continuous strand of Eglass fibre, with filament diameter of 9 m and strand linear density of 34 tex. This designation conforms to the ISO 2078 standard. 2.5.1.5.2. Milled Threads Milled fibres are produced by milling continuous strands. Fibre lengths are of the order of a few tenths of a millimetre, with a length-to-diameter ratio of about 10 to 40. Milled fibres are generally used as fillers for resin systems used in casting, encapsulating and tooling applications. Fibre loading of up to 40 % weight can be obtained. 2.5.1.5.3. Chopped Strands Chopped strands are obtained by cutting continuous strands. They are usually supplied in lengths of 3, 4.5, 5, 13, 25 and 50 mm. The chopped strands are used in the manufacture of dough moulding compounds and as reinforcement of thermoplastic resins. 2.5.1.5.4. Rovings and Yarns Continuous rovings are obtained by assembling parallel strands, without twisting, and winding into a spool or onto a tube to form a cheese (or cake) (Figure2.7). The designation of the roving indicates either the linear density or the number of basic strands. For example, for roving EC 10 2,400 (global designation) or roving EC 10 4060 (complete designation), EC 10 40 denotes the basic strands, 60 gives the number of basic strands assembled without twisting, 2,400 indicates the global linear density in tex of the roving. The different types of rovings are produced to meet the needs of the different processes of composite moulding. Rovings differ by: the number of basic strands: 2, 8, 15, 30, 60 for example; the global linear density: 600, 1,200, 2,400, 4,800, 9,600 tex.
FIGURE 2.7. Different forms of roving supplies: (1) Spools, (2) Roving Cheeses or Cakes wound on tubes (Vetrotex documentation).
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Applications of rovings are varied: chopping for fabrication of mats, for spray layup; weaving for making surfacing cloths or preforms; continuous impregnation, as filament winding, pultrusion; etc. To obtain rovings, the strands are assembled without twisting. The strands can also be twisted into yarns and next woven into weave fabrics. The twist may be of about 20 to 40 turns per metre and leads to a uniform cloth to be woven. 2.5.1.5.5. Curly Rovings Curly rovings (Figures 2.8 and 2.9) are made by assembling curly glass strands. The structure of curly rovings provides the ability to have some reinforcement in the direction transverse (or close to transverse) to the direction of strands. Curly rovings are used essentially in weaving heavy cloth. Such cloth allows an improvement in the behaviour of composite materials subjected to interlamina shear between composite layers. 2.5.1.5.6. Chopped Fibre Mat Chopped fibre mats are constituted of chopped strands or rovings randomly distributed in a plane. A typical construction is shown in Figures 2.10 et 2.11. Chopped fibre mats differ by the characteristics of the chopped strands or rovings (type of glass, fibre diameter, linear density, etc.) and by the characteristics of the binder used to hold the fibres together. Usually the binders are chemical ones, in the forms of liquids or powders. A liquid binder generally imparts greater drapability of the mat than a solid binder. High binder contents are used to prevent the fibres to flow with the resin during moulding processes. Mechanical bonding is also used with lightweight roving. The chopped strands or rovings are needled into the others. Such mats show a good drapability and fast wet out. The length of fibres is usually 50 mm. The weight per unit area is currently 300, 450 and 600 g/m2. However, for particular uses it is possible to obtain products with weights less than 300 g/m2 or greater than 600 g/m2, for example 900, 1,200 g/m2. 2.5.1.5.7. Continuous Fibre Mat Continuous fibre mats (Figures 2.12 et 2.13) are rather similar to chopped fibre mats. They have a better deformability and thus improved drapability in the composite processes. Usually, continuous fibre mats are made from strands having a low linear density of the order of 25 tex. 2.5.1.5.8. Woven Glass Fabrics (Figures 2.14 to 2.18) The different types of woven fabrics have been presented (Subsection 2.4.3) in the general case. Woven glass fabrics are supplied in the forms of rolls of two sizes: large width (Figures 2.14 to 2.16), close to a metre for strand cloths, or up to about 3 m in the case of roving or yarn cloths; small width in the form of ribbons (Figure 2.17).
36
37
38
39
FIGURE 2.14. Examples of three glass plain weaves, processes from rovings of different linear density: 2,400, 1,200 and 320 tex (Documentation Vetrotex).
FIGURE 2.15. Plain weave fabric, made with glass strands (Documentation Vetrotex).
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FIGURE 2.17. Unidirectional roving weave fabrics: (1) unidirectional cloth in the weft direction, (2) unidirectional cloths in the warp direction (Documentation Vetrotex).
FIGURE 2.18. Complex constituted of unidirectional roving cloth and mat, with chemical bonding (Documentation Vetrotex).
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The weights of glass cloths are functions of the characteristics of threads and weaving parameters. They are currently in the ranges: from 50 to 500 g/m2 for strand cloths, from 150 to 1,000 g/m2 for roving cloths and yarns cloths.. Moreover, there exists complex arrangements (Figure 2.18) which combine mat with weave cloth. The principal application of these products is the reinforcement of structures of plane forms or low curvature. When such structures are subjected to bending loading, the unidirectional cloth is put in the tensile area and the mat in the compressive area, according to their respective properties suited to the two types of loading.
layer 3
layer 2 3.35
layer 1
1.42
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to remarkably high theoretical specific mechanical properties. These considerations explain the extensive developments of fabrication processes for elaborating carbon fibres with directions of the crystallographic planes which is as parallel as possible to the fibre axes. Industrial fibres do not reach the theoretical mechanical values because imperfections in the crystalline structure. However, mechanical characteristics in fibre direction remain high and can reach the order of 700 GPa for the Youngs modulus and 4,000 MPa for the tensile fracture stress. Mechanical properties in the transverse direction of fibres are lower.
inert gas
GRAPHITIZATION HNO3 OXIDATION 300 C CARBONIZATION 2,600 C 2 possible routes OXIDATION HM or UHM fibres
HS fibres
inert gas
HNO3
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300 C
Carbonization. The second stage consists of progressively heating the crosslinked fibres from 300 C to about 1,100 C in a furnace with inert atmosphere. Water and cyanhydric acid are then eliminated, and only the carbon atoms are preserved in the chain:
CN CH CH O CH CH CN CH O CH CH CN CN CH CH O C CH C C C C C C C C + H20 + 4HCN
1,100 C
The fibres obtained after this stage have good mechanical properties and can be used after surface treatment (Figure 2.20). The fibres are then called HS carbon fibres (high-strength carbon fibres). Graphitization. The graphitization process is used for obtaining fibres which have a high Youngs modulus. This process consists of carrying out after carbonization a pyrolysis of the fibres in an inert atmosphere at temperatures up to 2,600 C. The graphitization stage causes a high degree of orientation of the hexagonal structure of carbon atoms along the axis of the fibres, which leads to an increase in the Youngs modulus. However, simultaneously with this orientation, defects are induced in the carbon structures, implying a decrease in the fibre strength. According to the level of graphitization, the high strength fibres are converted into HM (high modulus) fibres or UHM (ultra high modulus) fibres. Surface treatment. The last stage of fibre elaboration consists of a surface treatment by oxidation in an acid atmosphere (nitric or sulfuric). The object of this treatment is to increase the roughness of the filament surface and to improve bonding between the matrix resin and the fibres.
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2.5.2.2.2. From Pitch Precursor Since the mid 1970s, processes of carbon fibre elaboration were developed from pitch as precursor. Pitch is a residue of oil refining. In these processes, the pitch precursor is first converted into a mesophase (intermediate between liquid and crystal phase) by heating the pitch to about 350 C to 450 C. Then, the mesophase is transformed into a filamentary form by spinning or extrusion, which improves the molecular orientation. As in the case of PAN process, the filaments obtained are oxidized and carbonized, and next pyrolized above 2,000 C to obtain high modulus fibres. Carbon fibres produced by this process have significant production advantages: a high weight efficiency: a fibre/precursor ratio of about 75 to 90 % (50 % for the PAN process, a faster speed of graphitization, a cheaper precursor material. The development of this technique would allow carbon fibres to reach the commercial markets, such as the automobile market, with a significant decrease in fibre cost price compared with fibres obtained from the PAN Precursor.
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TABLE 2.6. Properties of carbon fibres, compared with those of E-glass fibres. Properties Density (kg/m3) Diameter (m) Youngs modulus Ef (GPa) Specific modulus Ef / (MNm/kg) Tensile fracture stress fu (MPa) Specific fracture stress fu/ (kNm/kg) Cost price referred to E-glass fibres E-glass HS Carbon 1,750 57 230 130 3,000 4,000 1,710 2,290 1015 HM Carbon 1,810 57 400 210 2,800 1,550 3050 UHM Carbon 1,950 57 600 310 2,000 1,030 200400 HM Carbon (pitch) 2,000 12 280 140 2,000 2,400 1,000 1, 200 50100
1* 4 $/kg en 2006.
Fibres are produced by extrusion and spinning processes. A solution of the polyamide polymer is held at low temperatures (between 50 C and 80 C and then extruded at a temperature of about 200 C. Aramid fibres are then drawn and conditioned to improve their mechanical properties.
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2.5.3.2 Properties
Typical mechanical properties of aramid fibres are reported in Table 2.7 for different types of monofilaments. For multifilament strands, the mechanical characteristics are usually lower. The table shows a high specific tensile fracture stress, of the same order of height as the HR carbon fibres (Table 2.6), at a cost price 4 to 6 times less. Nevertheless, their use is limited by some weaknesses of composite materials with aramid fibres, as: low resistances to compression, bending, buckling; sensitivity to interlaminar shear. These weaknesses are usually associated to a poor interfacial bonding between fibres and matrix. Different fibre treatments have been developed for improving the interfacial bonding and the delamination resistance of the aramid fibre composites. However, the poor interlaminar bond between fibres and matrix leads to high impact resistance and damage tolerance of composites. This results from the absorption of energy by widespread delamination and splitting of fibres.
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(kg/m3)
(m) Ef (GPa) Ef / (MNm/kg)
fu (MPa) fu / (kNm/kg)
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Boron fibres and boron-silicon carbide fibres are available in the form of: continuous strands made of parallel filaments, peimpregnated fibrous yarns or coated filaments in spools for filament windding and pultrusion, woven fabrics and preforms. These fibres associated to epoxide matrices, with which adhesion is very good, or with other thermoplastic or themosetting matrices, are used in the sport and leisure domains.
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TABLE 2.9. Mechanical properties of fibres of SiC, SiNC and SiCTi. Characteristics Density Youngs modulus Specific modulus Tensile fracture stress Specific fracture stress SiC (kg/m3) (GPa) (MNm/kg) (MPa) 2,550 180200 7080 3,000 1,200 SiNC 2,350 170 70 2,400 1,000 SiCTi 2,400 200 85 3,000 1,250
Ef E f /
fu
fu / (kNm/kg)
TABLEAU 2.10. Mechanical properties of ceramic fibres with an alumina base. Alumina Al2O3 (kg/m3) (GPa) 3,400 3,950 300390 90100 1,500 2,000 440500 Aluminosilicate Al2O3, SiO2 3,100 3,200 190250 6080 2,100 2,200 685 Borosilicoaluminate Al2O3, SiO2, B2O3 2,700 3,100 150200 5565 1,700 1,800 580630
Characteristics
Density Youngs modulus Specific modulus Tensile fracture stress Specific fracture stress
Ef
Ef / (MNm/kg)
fu
(MPa)
fu / (kNm/kg)
Among these fibres are: 1. Fibres of vegetable origin, as sisal, jute, or flax, used as woven cloths, in yarn form for filament winding or in dough moulding compounds. 2. Synthetic fibres, as polyester (tergal, dacron, etc.) fibres, polyamide fibres, polyethylene fibres, polypropylene fibres, etc. 3. Metal fibres, as steel fibres, copper fibres, aluminium fibres, used with metal matrices for thermal, electrical or thermomechanical applications.
CHAPTER 3
3.1 INTRODUCTION
Usually, the elaboration of structure of composite materials is carried out by moulding processes in which the structures are moulded by successive layers constituted of matrix and reinforcement. This general technique, usually called lamination, leads to forming laminated materials or laminates. Furthermore, laminates can be associated with light materials to obtain sandwich materials. Moulding processes are considered in References 6 and 7. Only, the architecture of composite materials deduced from the considerations of the moulding processes will be developed hereafter in this chapter. Architecture of composite materials constitutes an introduction to the study of the mechanical behaviour of composite materials which will be developed next along this book. So, the various moulding processes show the general feature of composite structures to be designed in the form of plates and shells by lamination of successsive layers. This design justifies the importance that will, hereafter, be placed in the analysis of composite materials in the form of plates of one single layer or of several distinct layers. Next, shells can be modelled as a set of plates, and their study derived from the analysis of plates.
3.2 Laminates
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layers
laminate
laminate: 45 0 45 90 90 30 designation: x 30 90 90 45 0 45 z
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The identification of a laminate can be obtained by using the following orientation code: 1. Each layer is identified by the orientation in degrees between the fibre direction and the x reference axis (Figure 3.2). 2. Successive layers are separated by /, if the layers orientations are different. 3. Successive layers with the same orientation are indicated by using a numerical index. 4. The layers are successively designed going from one face to the other. Brackets indicate the beginning and the end of the code. The designation depends on the axis system chosen. An example is reported in Figure 3.2.
30
90
45
45
y x 30 90 45 0 45 y x z
3.2 Laminates
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3.2.2.3 Examples
Some examples of laminates and designations are given hereafter. Laminate 0 30 30 45 45 Designation
[ 45 / 30 / 0 ]
30 60 60 0 45
0 45 45 45 45
[452 / 452 / 0]
0 45 45 45 45 45 45
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If a symmetric laminate has an even number of layers, its designation starts from a face and finishes at the midplane. An index S indicates that the laminate is symmetric. For example: 90 45 45 0 0 45 45 90 If the laminate has an odd number of layers, the designation is similar to the preceeding one, but the central layer is overlined. For example: 90 45 45
[90 / 452 / 0 ]S
0 45 45 90
3.2 Laminates
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0 45 90 0 45 90 60 30 60 30 60 30
0 0 45 90 45 0 0
K K G G G C C
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mat
unidirectional
FIGURE 3.4. Beam bending.
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laminates
foam core
balsa core
grain of balsa
laminate
58
honeycomb core
corrugated core
The sandwich skins are most frequently constituted of laminates with glass fibres, carbon fibres or Kevlar fibres. Light alloy sheets are also used. In order that sandwich constructions are efficiency, it is necessary to have a good bonding between the core and the skins so that the mechanical loading can be transmitted between core and skins. The bonding is obtained by using resin systems for skins compatible with the core materials or by interleaving particular interface layer between core and skins.
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These reinforcements usually increase the elasticity modulus by a factor of about two to five. The mechanical behaviour of these materials can be homogenized and the mechanical behaviour analysis is then reduced to that of a usual isotropic material.
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F3
F1
F2
F1 F2 F3 loads imposed
For describing the mechanical behaviour of composite structure it is necessary to know the stress field and displacement field at every point of the structure
Study Process Analysis at Constituent Level of a Layer Laminate or Sandwich Behaviour Analysis of the Composite Structure
Analysis at Constituent Level Analysis of the elastic properties and fracture behaviour of layer as function of constituents
Laminate or Sandwich Behaviour Study of the elastic properties and fracture behaviour of a laminate or sandwich material as function of layers
Part II
To develop the concepts of the mechanical analysis of composite materials and structures, it is necessary to be familiar with the basic theory of the mechanics of deformable structures. A synthesis of the basic elements is presented in this part, considering the classical concepts: stresses (Chapter 5), strains (Chapter 6), the elastic behaviour of materials (Chapter 7) and the fundamental elements of the mechanical analysis of deformable structures (Chapter 8).
CHAPTER 4
Mathematical Basics
The strain state and stress state at a point of a deformable solid submitted to a mechanical loading are characterised by 3 3 square matrices which depend on the orientation of reference system. In this chapter, basic properties on matrices and transformations are recalled.
functions of the previous ones as: ' = a11e1 + a12e2 + a13 e3 , e1 ' = a21e1 + a22e2 + a23e3 , e2 ' = a31e1 + a32e2 + a33e3. e3 This relation can be expressed in the matrix form:
(4.1)