Chapter II
Chapter II
encountered in quantum physics, for example due to the electron-lectron interactions or due to an external field. The solution of these problems can be solved using the theory of perturbation. In the theory of disorder, the Hamiltonian system has been broken down into two main parts and the parts without disturbance or nuisance tribe. At the tribal bullies are decomposed into a stationary perturbation (perturbation theory of free time) and the theory of time-dependent problems. Time independent perturbation theory (Stationary) No case of degenerate Review the Hamiltonian of a system with a form
H gH H 0 1
1 H gH 0
(1.1)
with a Hamiltonian without interruption and disruption is Hamiltonian. The perturbation, the energy eigen values and functions will have a small correction,
(0) En En E n
(1.2)
(1.3) Furthermore, the energy eigen values and functions can be written in the form of a convergent (1.4) (1.5) It Energy (1.6) with the exact solution is known. Substitution of (1.2) and (1.3) to (1.4) yields: (1.7) or (1.8) is (1.9) true if and only if can be written in the form is clear eigenvalue that equation the for g the case of 0 this applies disorder and are: series,
Of (1.10) (1.12)
the
equation
is
obtained (1.11)
and
so
on
...
Note that also the solution to equation (1.11). Thus, these equations and solutions as well as and. Thus dperlukan constraints (constraint) to create a unique solution. This constraint is taken as follows: all the corrections of the equation (1.3) is considered for s> 0 normal and all to, n. ie (1.13)
In the Hilbert space H, the relationship hormalisasi above shows that (and also) is normal (orthogonal) to. This relationship will be used to build.
Correction
Order
From equation (1.11) above, it appears that proposes that the solution is a linear combination of, namely so that equations can be written in the form (1.14) Multiplication (1.15) With At (1.16) And (1.17) Furthermore, the value obtained from the normalization constraint on the s = 1, (1.18) So, (1.19) At (1.20) j = n, apply j n, obtained of the equation with the right result
Thus, the wave functions and energy eigenvalues of particles in the correction of order (1.21) (1.22) In and Correction Order order expansion converges, it must be true, or (1.23) 2 1 due to the disturbance Hamiltonian
As the first order correction, the wave function for the second order correction is taken (1.24) so (1.25) Multiplying (1.26) the last equation from the left produces that equation (1.12) can be written into as a linear combination wave function undisturbed,
at
j,
equation
(1:26)
written
as
the
normalization
condition,
obtained
So that the wave function and total energy of particles after the second order
correction
can
be
written
as,
(1.31) (1.32) Degeneration Note (1.33) In the case of folding with a generation-q (q-fold degeneracy), i = 1, 2, ... q, means that even though so for i q. Cases that
So the solution is to build a new basis functions from the set that diagonalizes the (n, i q), which means building the off-diagonal elements are zero, so. Think of the fruit consists of a function q which diagonalizes the (n, i q), (1.34) So (1.35) Furthermore, the shape can be expressed as a diagonal matrix size. Given that the basis for the Hilbert space and is that
the
matrix
to
be
written
as
Similar as in the case did not degenerate, the energy correction of order 1 for the degenerate (1.37) Consider the Schr odinger equation. By taking and with n q, then the Schr odinger (1.38) above result due). This means that the (n q). So that the diagonal elements of submatrices * with (n q) is the first order correction of the Hamiltonian. (1.39) equation is written into case can be written as
the
last
equation
to
yield
Above equation can be written in matrix form. For example, for n = 1, and obtained (1.42) Basis for the above matrix is. For n = 2, then the equation obtained for fruit and q. And so on. Then, for n q, then For there each will n = be 1, pieces 2, ... of q, the so matrix that the equation solution q as exists, above. then the equation for the following:
(1.43) Each with n = 1, 2, ..., q meemberikan and solutions on these coefficients will provide a new basis on the basis of this degeneration is not removed and become degenerate. So, in the end obtained the functions and energy eigenvalues as follows: (1.44) (1.45) (1.46) (1.47) (1.48) (1.49) Time Suppose (1.50) with a solution of the form (which is a stationary solution and obtained through separation of variables) is known exactly. Disturbance applied to the Hamiltonian assume t 0. After the disturbance is applied, Schr odinger equation solution is not to be stationary. No stationary solution can be obtained from a linear combination (1.51) of stationary solutions, there Dependent is a Hamiltonian Disorders form
with a coefficient of linear combinations of the (only) depend on time. Physical meaning of the relations obtained by applying the completeness,
(1.52) Thus, it can be interpreted as a possibility to find the particle / system is in state n at Substitution of (1:51) time into equation t. Schrdinger,
(1.53)
Multiply (1.54)
the
last
equation
then
integralkan
on
the
whole
space,
Seen that the g 0 (no perturbation), the Cm constant (independent of time). Can then (1.55) Substitution (1.56) By collecting each tribe according to the rank of g, obtained of these series into equation (1:54), be written
(1.60) Eg disturbance applied at t = 0, so that before the disturbance (and take the system state before the disturbance is expressed as) applies
(1.61) Thus, it is certainly valid and applicable for all t (for constant), (1.62) Substitution (1.63) Substitution of these results to the following equations will give the results (1.64) of these results to (1:58) to give
(1.65)
by
(chronological
time).
On
quantum
mechanics,