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This document provides 16 chemistry problems involving deriving expressions for mole fractions of components in terms of the extent of reaction (ξ) for various chemical reactions. The problems cover both single and multiple reactions involving gases, liquids, solids and heterogeneous catalysis. Expressions are to be developed for mole fractions of reactants and products in each chemical reaction given the initial number of moles for each component.

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Niraj Thakre
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82 views

Assignment

This document provides 16 chemistry problems involving deriving expressions for mole fractions of components in terms of the extent of reaction (ξ) for various chemical reactions. The problems cover both single and multiple reactions involving gases, liquids, solids and heterogeneous catalysis. Expressions are to be developed for mole fractions of reactants and products in each chemical reaction given the initial number of moles for each component.

Uploaded by

Niraj Thakre
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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CT Time Table 03-02 IPC CAD 04-02 CET PDC 05-02 CFD

ASSIGNMENT NO- 01

FORMULA FOR MOLE FRACTION IN TERM OF EXTENT OF REACTION yi=(nio+ i ) / (no + i ) =

where nio = initial mole of ith component, no = total mole initially, extent of reaction = stiochiometric coefficient FOR MULTPLE REACTION yi=(nio+
i,j
j) /

(no +

j)

QUESTIONS
1) The saponification for the formation of soap from aqueous caustic soda and glyceryl steriate is 3NaOH(aq) + (C17 H35 COO) 3C3H5 3C17 H35 COONa + C3 H5 (OH)3 Where initial moles of NaOH is 10, (C17 H35 COO) 3C3 H5 is 3 and C17 H35 COONa is 2 mole. Now derive the expression for mole fraction of various component in term of extent of reaction. yNaOH=(10-3 )/15 , y(C17 H35 COO) 3C3 H5 =(3- )/15, yC17 H35 COONa =2+3 /15 y C3H5(OH)3= /15 2) Initially there are 10 mole each of the reactant with no product S02 + 1/2O2 S03 Now derive the expression for mole fraction of various component in term of extent of reaction. YSO2=(10- )/ (20-1/2 )/ , yO2 =(10-1/2 )/(20-1/2 ), ySO3 = /( 20-1/2 ),
I_

3) For the solid catalyzed reaction , having initial moles of A as 2, B as 5 and C is 3 respectively 4A + 5B , 4C + 6D derive the expression for mole fraction of various component in term of extent of reaction. yA=(2-4 )/(10+ ) , y B =(5-5 )/(10+ ), yC=(3+4 )/(10+ ), y D=6 /(10+ ),

4) Develop an expression for each of the following components for mole fraction in term of extent of reaction for the liquid-phase reaction having initial moles of each component as 1 mole.

y (CH)2O=(1- )/(4- )

y H2O =(3- )/(4- ), y (CH2OH)2= /(4- ),

Where initial moles of ethylene oxide and water is 1 and 3 moles respectively. 5) Methanol can be produced according to the reaction CO+2H2 CH3OH having equimolar mixture of CO and H2. Express mole fraction of various component in term of extent of reaction. y CO=(1- )/(2-2 ) , y H2 =(1- )/(2-2 ), y CH3OH= /(2-2 ),

6) In the homogeneous gas-phase reaction CH4+ 3/2O2 HCOOH + H2O Containing 10 moles of CH4, 5 moles of O2 , 5 moles of HCOOH and 1 mole of H2O respectively. Express mole fraction of component in term of extent of reaction. y CH4=(10- )/(21-1/2 ) , y O2 =(5-3/2 )/(21-1/2 ), y HCOOH=(5+ )/(21-1/2 ),

7) Consider the reaction CO + H2 O CO2 + H2. Having initial moles of CO and H2O as 1 and 1 mole respectively. Calculate mole fraction in terms of extent of reaction. yCO=yH2O = (1-)/2 yCO2=yH2 = /2

8)

Given the following two reactions N2O4 2NO2 2NO2 2NO(g) + O2 Having initial moles of N2O4 , NO2 and O2 as 10, 5and 1 mole respectively. Calculate mole fraction in terms of extent of reaction. y N2O4=(10- 1)/(16+ 1+ 2 ) , y NO2 =(1+2 1-2 2)/(16+ 1+ 2), y NO=(2 2)/(16+ + 2 ) , y O2=(1- 2)/(16++ 1+ 2),

9)

Consider reaction as given below 2HI(g) H2(g) + I2(g) 0.50 mol HI and 0.30 mol H2. Calculate mole fraction in terms of extent of reaction. y HI=(0.5-2 )/(0.7) , y H2 =(0.3+ )/0.7), y I2=( )/(0.7),

10) Consider reaction as given below

With 2 moles of methane and 3 moles of water. Express mole fraction of various component in term of extent of reaction. y CH4=(2- 1)/(5+2 1) , y H2O =(3- 1- 2)/(5+2 1), y H2=(3 1+ 2)/(5+2 1), y CO=( 1- 2)/(5+2 1), 11) Consider the reaction of phosphene(50 moles) with oxygen(50 moles)

Express mole fraction of various component in term of extent of reaction. y PH3=(50-4 )/(100-5 ) , y O2 =(50-8 )/(100-5 1), y P4O10=( )/(100-5 ), y CO=( )/(100-5 ),

12) Consider the reaction with 50 gm oh H2O2 and 25 gm of O2 Express mole fraction of various component in term of extent of reaction. y H2O2=(1.47- )/(2.25+ ) , y O3 =(0.78- )/(2.25+ ), y H2O=( )/(2.25+ ), y O2=(2 )/(2.25+ ),

13)

Consider a reactions having initially 100 mole of methane 200 moles of oxygen. Express mole fraction of various component in term of extent of reaction CH4 + O2 HCHO +H2O CH4 + 2O2 CO2 + H2O y CH4=(100- 1- 2)/(300- 2) , y O2 =(200- 1-2 2)/(300-2 2), y H2O=( 1+ 2)/(300- 2), y CO=( 1)/(300- 2), For the gas phase reaction, 2A + B = R + S seven moles of A are reacted with four moles of B in a batch reactor. Express mole fraction of various component in term of extent of reaction

14)

15)

For the gas phase reaction, C2 H4 + 1/2 O2 C2H4O C2H4 + 3 O2 2 CO2 + 2 H2O Initially, one mole of C2H4 and three moles of air (~21% O2) react. Derive an expression relating the mole fractions of each of the components

y C2H4=(1- 1 - 2)/(4-1/2 1) , y O2 =(0.63-1/2 1-3 2)/(4-1/2 1), y C2H4O=( 1)/(4-1/2 1) , y CO2=( 2)/(4-1/2 1), y N2=(2.37)/(4-1/2 1),

16) 1mole of steam undergoes the water gas shift reaction and CO is supplied in excess of stiochiometric requirement. CO + H2 O CO2 + H2. Derive an expression relating the mole fractions of each of the components. y CO=(2- )/3 yH2O=(1- )/3 yCO2= /3 yH2= /3

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