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PHYSICS MT-4 Q.1 1.02MeV positron collides with 1.02 MeV electron and they are annihilated giving rise to two y-photons, The total energy of y-photons is (A) 1.02 MeV ( ) 2.0! MeV (") #,0$ MeV (%) !.0& MeV '2 The activity of a radioactive s()stance at ti*e t1 is A1 and at ti*e t2 is A2, +f the *ean life of the s()stance is T * then the n(*)er of ato*s decayed d(ring ti*e interval (t2 , t 1 ) will )e (A) A1t1 - A2 t2 ( ) (A1 ,A2) (") (A1-A2)- T* (%) (A1-A2) T* '#. , , radiations co*e, )(t of a radioactive s()stance (A) .hen it is heated ( ) .hen p(t in ato*ic reactor (") /pontaneo(sly (%) 0nder press(re '.! A radioactive ele*ent has (ndecayed (1-$!) part in 11 hr. +ts half 2ife in hrs will )e (A) 2,1 ( ) #,1 (") 3.1 (%) 11 '.1. The fraction of a radioactive *aterial which re*ains active after ti*e t is 4-1$, The fraction which re*ains active after ti*e t-2 will )e (A) !-1 ( ) 3-& (") #-1 (%) # - ! ' $ .The half life of a radioactive *aterial is #!.$1 seconds. +f at any ti*e 1022 ato*s are active, then the activity of that *aterial is (A) 1 5 1020 disintegration-s ( ) 2 5 1020 disintegration-s (") # 5 1020 disintegration-s (0) ! 5 1020 disintegration-s Q.7 "(rie is a (nit of (A) length (") *ass ( ) its is not any (nit (%) ato*i" n(*)er '.4 The relation )etvveen the *ean life () and half life (T1/2) of a radioactive *aterial is (A) 6 T1-2 - 0.$4# ( ) 6 0.$4# - T1-2 (") 6 T1/2 5 0.$4# (%) none of these '10 .hich of the following n(clear reaction is not possi)le (a) 371! 8 2 9e! - &:13 8 19 1 ()) 1 10 8 on; $"4 8 , 92 (c) #92 29e! 8 , 91 8 on ; 8 21.$ MeV 0 ! 1# 1 (d) 1 e 8 29e 37 8 , 9 (A) ),d ( ) a, ) (") ),c (%) a,d '.10 <or n(clear fission *ost s(ita)le ele*ent is that whose ato*ic n(*)er is (A) 1& ( )42 (")21 (%)11 '.11 The ato*ic *ass of 29e! is !.002$ a.*.(. The *ass e5cess of heli(* is (A) 1.2! MeV ( ) #.1! MeV (") 2.!2 MeV (%) !.!1 MeV '.12 +f real ato*ic *ass of a n(cle(s is M a*( and its *ass n(*)er is A, then its pac2ing fraction will )e (A) f 6 A-(M8A)= (") f6 >M , A?- A ( ) f 6 A- >M-A? (%) f6 (M 8 A)- A '.1# 200 MeV of energy *ay )e o)tained per fission of 0 2#1. A reactor is generating 1000 2. of power. The rate of n(clear fission in the reactor is (A)1000 (B)2x108 (C)3.125x106 (%)4#1 = '.1! A ne(tron ca(ses fission in 92U235 prod(cing !0@r43 and Te1#! and so*e ne(trons. The n(*)er of ne(trons released will )e (A) 1 ( )2 (") # (D)4 '.11 %(ring the process of n(clear f(sion (A) a heavy n(cle(s )rea2s a(to*atically into two frag*ents ( ) a heavy n(cle(s )rea2s )y the )o*)ard*ent of ther*al ne(trons (") a light n(cle(s )rea2s )y the )o*)ard*ent of ther*al ne(trons (%) two light n(clei co*)ine to for* a heavy n(cle(s and so*e other particles are e*itted . '.1$ The half-life of the isotope
11

7a2! is 11 hrs. 9ow *(ch ti*e does it ta2e for 3-& th of the sa*ple of this

isotope to decay (A) 31 hrs ( ) $1 hrs (") 11 hrs (%) !1 hrs '.13 +n a n(clear reactor cad*i(* rods are (sed for (A) ne(tron e*ission ( ) a)sorption of (nnecessary ne(trons (") a)sorption of heat (%) red(cing the velocity of ne(trons '.1& The intensity of A-rays *ainly depends (pon (A) The nat(re of *aterial of the target ( ) The nat(re of gas filled in the t()e (") The c(rrent flowing thro(gh the fila*ent.(%) The potential difference applied )etween the anode and the cathode '.14 A-rays of wavelength 0.1 A are allowed to fall on a *etal scatterer. The wavelength of scattered radiation is 0.111 A. +f h 6 6.624 X 10-#! B-s and *o 6 4 5 10-#1 2g, then the direction of the scattered photons will )e

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(A) cos-1 (0.1!3) ( ) cos-1 (0.4484) (") cos-1 (0.1) (%) cos-1 (0.3) Q.20 The fig(re represents the A-rays e*itted )y an A-ray t()e as a f(nction of wavelength. The sharp pea2s A and denote (A) and spectr(* ( ) "ontin(o(s spectr(* (") "haracteristic radiations (%) .hite radiations '.21 The wavelength of Ca line of a hydrogen li2e ele*ent is 0.#2 A. The wavelength of C line of that ele*ent will )e (A) 0.$! A (") 0.#2 A ( ) 0.1! A (%) 0.23 A '.22 The wavelength of Ca -line o)tained fro* an ele*ent with charge n(*)er @ will )e (A) #Dc (@ - 1)2 -! ( ) !- #Dc (@ - 1)2 (") (A) #D (@ - 1)2 -! (%) (A) !- #D (@ - 1)2 '.2# A potential difference of 20 2V is applied across an A-ray t()e. The *ini*(* wavelength of A-rays generated is (A) 0.$2 A ( ) 0.0$2 A (") $2.0 A (%) 7one of these '.2! An A-ray t()e operating at 10 2V converts 1 E energy in the for* of A-ray. +f the a*o(nt bf heat prod(ced is !41 watt, then the n(*)er of electrons colliding with the target per second is (A) $.21 5 101$ (") #.2 A 101$ ( ) !.11 5 101$ (%) 1.2 A 101$ '.21 An electron of $eV collides with a hydrogen ato* in the gro(nd state. This collision *(st )e (A) Ferfectly inelastic ( ) Ferfectly elastic (") Fartially elastic (%) Fartially inelastic %.26 T&' ratio of periods of electron in second and first or)its of hydrogen ato* is (A) ;+ G 1 ( ) & G 1 (") 2 G 1 (%) 1 G ! '.23 .hich of the following transitions in a hydrogen ato* e*its photon of the highest freH(ency (A) n 66 1 to n 66 2 ( ) n 66 2 to n 6 1 (") n 6 2 to n 6 $ (%) n 6 $ to n 6 2 '.2& The wave n(*)er of first line of al*er series io hydrogen ato* is 1.12 5 10 $ *-1 . The wave n(*)er of first line of Iy*an series in e#8 will )e (A) 2.!# 5 10$ *-1 ( ) 1.#1 5 10$ *-1 (") 1.!! 5 10$ *-1 (%) $.&# 5 10$ *-1 '.24 The ratio of wavelengths of first line of Iy*an series in Ii; and first line of Iy*an series in de(teri(* ( 192) () * . (A)1G4 ( )4G1 (")1G! (%)!G1 '.#0 +n ter*s of Dyd)erg;s constant D, the wave n(*)er of the first al*er line is (A)D ( ) #D- ! (")1D -#$ (%) &D-4 '.#1 Jnergy reH(ired to e5cite a hydrogen li2e ion is 4 Dyd)erg. The radi(s of first ohr or)it of this ion will )e (A) 0,529 A (")0.13$A ( ) 0,265 A (%) 0.032 A . '#2 Iinear *o*ent(* of an electron in first ohr or)it of hydrogen ato* will )e (A)hr-2 ( ) h-2 (") h-2r (%) h-!r '.## The %e- roglie wavelength associated with a nitrogen *olec(le at at*ospheric press(re and te*perat(re 2$+C will )e -.'(A) 23$ A ( ) 0.23$# A (") 23$.# A (%) 0 H.#! +f a-particles of *ass M are accelerated )y a potential difference of V volt, then their wavelength will )e (A) h- (MeV)1-2 ( ) h- (2MeV)1-2 (C) h- (&MeV)1-2 (D) h- 2(MeV)1-2 ,.35 I- .&' ionisation potential of heli(* ato* is 2!.$ volt, ehergy reH(ired to ionise it will )e (A) 2!.$ electron volt ( ) 2!.$ volt (") 1#.$ volt (0) 1#.$ electron volt '.#$ The energy of a photon of wavelength 1&00 A in eV, will )e (A)$.4 ( )1#.& (") #.!1 @ero

(%)

'.#3 Cinetic energies of an electron and a,proton are eH(al. The ratio of their wavelength will )e (A) (1&#$) 2G 1 ( ) 1G (1&#$)2 (")1&#$G1 ( %) (1&#$)1-2G1 '.#& +oniKation potential of hydrogen ato* is 1#.$ ev. 9ydrogen ato*s in the gro(nd state are e5cited )y *onochro*atic radiation of photon energy 12.1 ev. The spectral lines e*itted )y hydrogen ato*s according to ohr;s theory will )e - , (A) :ne ( ) Two (") Three (%) <o(r '.#4 The *o*ent(* of a ne(tron of wavelength 0.1 A will )e (A) @ero ( ) $.$2 5 10-2# Cg-*-s (") $.$2 5 10-2! Cg-*-s (0) $.$2 5 10-2! gm-cm/s

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'.!0 +f the velocity of all the particles is sa*e then which of the following particles will have associated *atter waves of *ini*(* wavelengthL (A) a-particles ( ) Frotons (") 7e(trons (%) Jlectrons '.!1 The difference of 2inetic energies of photo electrons e*itted fro* a s(rface )y light of wavelengths 2500 A and 5000 A will )e (A)10-14Bo(le ( )10-14erg (") 10-14 eV (0) #.4$ 5 10-14 Bo(le '.!2 .hen the photons of energy ho fall on a photosensitive s(rface (wor2 f(nction )y h0) electrons are e*itted fro* the *etallic s(rface. This is 2nown as photoelectric effect. The electron co*ing o(t of the s(rface have a 2inetic energy. Then it is possi)le to state that (A) All eMected electrons have the sa*e C.J. eH(al to h - h () ( ) The eMected electrons have a distri)(tion of 2inetic energy, the *ost energetic one have 2inetic energy eH(al to h( h(o (") The *ost energetic eMected electrons have 2inetic energy eH(al to h( (%) The 2inetic energy of the *ost energetic eMected electrons is h(o '.!# Threshold freH(ency of potassi(* is # 5 1014 9K. +ts wor2 f(nction will )e - . (A) 1 5 10*22 B ( ) 1 5 10*19 B (") 2 A 10-22 B (0) 2 A 10-14 B '.!! A radio station is trans*itting waves of wavelength #00*. +f the radiating power of the trans*itter is 10C., then the n(*)er of photons e*itted per second will )e (A) 1.1 5 10#1 (")1.151024 ( )1.1510#1 ## (0)1.1510 . '.!1 The 2inetic energy of photo-electrons depends (pon the (A) +ntensity of incident light ( ) The difference )etween the freH(ency of the incident light and the threshold freH(ency (") The s(* of the freH(ency of incident light and threshold freH(ency (%) The ratio of the freH(ency of light (sed and the threshold freH(ency '.!$ Iight of two different freH(encies whose photons have energies of 1 eV and 2.1 eV are incident one )y one on a *etal s(rface of wor2 f(nction 0.1 ev. The ratio of *a5i*(* energies of e*itted electrons will )e (A) 1 G ! ( ) ! G 1 (") 1 G 2 (0) 2 G 1 '.!3 The wor2 f(nction for.a *etal is ! ev. To eMect the pnoto-electrons with Kero velocity, the wavelength of the incident light sho(ld )e - (A) 2$00 A ( ) 1$00 A (C) 5900 A (0) 3125A Q.48 Dadiations of freH(ency ( are incident on a photosensitive *aterial. The *a5i*(* 2inetic energy of e*itted photons is J. .hen the freH(ency of radiation is do()led, the *a5i*(* 2inetic energy of photoelectrons will )e (A) 2J ( ) J -2 (") J , h( (%) J 8 h( Q.49 The plate resistance and a*plification factor of a triode are 1 :Cn GGMnB 20 respectively. The val(e of its *(t(al cond(ctance will )e (A) 2 *illi *ho ( ) 2 *ho (") 0.1 *ho (%) 0.1 2 *ho '.10 The pro)a)ility of electrons to )e fo(nd in the cond(ction )and of an intrinsic se*icond(ctor at a finite te*perat(re (A) %ecreases e5ponentially with increasing )and gap ( ) +ncreases e5ponentially with increasing )and gap (") %ecreases with increasing te*perat(re (%) +s independent of the te*perat(re and the )and gap '.11 The plate resistance and load resistance for a triode are sa*e and each is eH(al to 10 Cn. +f its a*plification factor is 20 the* its voltage a*plification will )e (A) 10 (&) 20 (") 11 (%) 1 Q.52 Vac((* diode is a non-lin9ar device, )eca(se(A) "athode and plate are not in sa*e straight line ( ) :n red(cing plate potential to Kero, the plate c(rrent )eco*es Kero (") The plate c(rrent is not proportional to plate potential (%) All of the a)ove Q.53 +n a vac((* t()e o5ide coated e*itters are (sed )eca(se (A) Their wor2 f(nction is *ore ( ) They e*it *ore electrons at lower te*perat(res (") They are cheaper (%) They are d(a)le Q .54 +n an e5peri*ent of triode it is fo(nd that at a constant plate potential of 200V the val(e plate c(rrent )eco*es fro* $.1*A to 11.1*A and the grid potential )eco*es fro* -2V and -1v. The *(t(al cond(ctance of triode will )e .

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(A) 1 oh* ( ) 0.1 *ho (")11*ho (%)1510-#*ho Q.55 The plate resistance and voltage gain of a triode are 110 and 10 respectively. +f the load resistance is 1 ::Cn then its a*plification factor will )e (A) 1 ( ) 10 (") 13.1 (%) $1.1 %.56 In the plate circ(it of triode a load is connected. +f a positive voltage is applied to the grid, then (A) The plate c(rrent and the plate voltage will increase (B) The plate c(rrent and the plate voltage will decrease . (") The plate c(rrent will increase and the plate voltage will decrease (%) The plate c(rrent will decrease and the plate voltage will increase '.13 r he correct state*ent o(t of following is (A) %iode valve can )e (sed as rectifier ( ) %iode valve can not )e (sed as a rectifier (") %iode is an o;h*ic device (%) The c(rrent flow in a diode is not (nidirectional '1& The phase difference; )etween the o(tp(t and the +np(t signal voltage in a triode a*plifier is (A) - ! ( ) (") - 2 (%) Kero %.59 The plate resistance of triode is 10C' and its a*plification factor is 2!. +f the inp(t singnal voltage is 0.! volt (r,*,s.) then the val(e of o(tp(t power will )e if DI 6 1C' (A) 10-2 watt (") !510-2watt -2 -2 ( ) 0.20! x 10 watt (%) & 5 10 watt ',$0 The voltage gain of a triode a*plifier is 10. +f inp(t potential is eg 6 sin wt then the val(e of o(tp(t potential across DI will )e (A) -10sinwt ( )10sint (")sin10t (%) -sin10t '.$1 The slopes of plate characteristics and *(t(al characteristics of a triode valve are 0.02 *7V and 1.00rnAB; V respectively. The a*plification of the valve will )e (A) 21 ( ) 10 (") 100 (%) 12.1 '.$2 The region in the characteristic c(rve of a diode where the plate c(rrent depends only on the plate voltage is called (A) /at(ration region ( ) Te*perat(re controlled region (") /pace charge li*ited region (%) 7one of a)ove '.$# The *ini*(* wor2ing voltage of a triode valve () 100/ 012'3 )40056 () 250/. +f the plate c(rrent at 100 V is 1*A, then the val(e of load resistance will )e (A) # 5 10! (") #0 ( ) #0 (%) 0.# '.$! +n a co**on )ase config(ration transistor a*plifies (A) Voltage only ( ) "(rrent and voltage (") Voltage and power (%) Voltage, c(rrent and power Q.65 %ifferent voltages are applied across a p-n M(nction and the c(rrents are *eas(red for each val(e. .hich of the following graphs is o)tained )etween voltage and c(rrent (A) (B)

'.$$ +f the forward )ias on F-7 M(nction is increased fro* Kero to 0.01V, then no c(rrent in the circ(it flows. The contact potential of M(nction plane is (A) @ero ( ) 0.01V (") More than 0.01V (%) Iess than 0.01 V '.$3 +np(t resistance of a co**on e*itter transistor a*plifier is !00 oh* and load resistance is &00 2ilo-oh*. +f the c(rrent gain a is 0.41 then the power gain will )e (A) 3.22 5 101 (") 1.23 A 10# ( ) $.3& 5 10! (%) !.#& 5 102 ' 68 Transistor is a (A) Voltage operated device ( ) Te*perat(re operated device (") "(rrent operated device (%) 7one of a)ove

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'.$4 F-7 M(nction has

(A) :h*ic resistance (") 7egative resistance ( ) 7on-oh*ic resistance (%) Fositive resistance '.30 +n a forvvard )iased F-7 diode, the inMected hole c(rrent in 7- region is proportional to the total charge ' of the inMected *inority carrier holesN This state*ent is (A) Tr(e ( ) <alse (") Tr(e at law voltage and false at high voltage (%) Tr(e at high voltage and false at low voltage '.31 To which of the following gates does the tr(th ta)le given )elow, )elongL A O 1 1 0 1 0 1 0 1 1 0 0 1 (A) 7A7% ( ) A7% (") A:D (%) 7:T '.32 %epletion layer is . (A) A region )etween charged layers of positive and negative ions on either side of the M(nction ( ) co*pletely (ncharged (") Fositively charged(%) 7egatively charged '.3# 9oles in a se*i-cond(ctor )ehave as they have(A) 7egative charge (A) ,vely charge ( ) Fositive charge (") 7o charge (%) +nitially positive and finally negative '.3! An A7% gate is followed )y a 7:T gate. .ith two inp(ts A and , the oolean e5pression of the o(tp(t " will )e (A)A ( )A8 (")A 8 (%) A. '.31 The energy gap in an intrinsic se*icond(ctor is of the order of (A):.1eV ( )1eV (")1eV (%)10eV CHEMISTRY MT4 Q.1 The cathodic reaction in electrolysis of dil(te 92/:! with Ft electrode is (a) o5idation ()) red(ction (c) )oth o5idation and red(ction (d) ne(traliKation Q.2 The specific cond(ctance of a 0.20 *ol I-1 sol(tion of an electrolyte at 20P" is 2.!&A10 -! oh*-+ c*-+. The *olar cond(ctivity of the sol(tion is (a) 1.2! oh*-+ 782 *ol-+ ()) !.4$ oh*-1c*2 *ol-+ (c) 1.2! oh*-+ c*2 (d) !.4$ oh*-1 c*2 Q3 Two Ft electrodes fitted in a cond(ctivity cell are 2.0 c* apartQ while the cross-sectional area of each electrode is 0.&0 c*2 ..hat is cell constantL (a) 1.21 c*-1 ()) 2.1c*-1 (c) 2.2#c*-1 (d) 2.1 c*-1

'!. .hen /:2 gas is passed thro(gh an acidified sol(tion of C2"r2:3 (A) The sol(tion )eco*es )l(e (") /02 is red(ced '1. /apphire is a *ineral ofG (a) "( ( ) The sol(tion )eco*es colo(rless (%) Rreen "r2 (/0!)# is for*ed. ()) @n (c) A+ (d) 9g (d) 7one

%6.:n adding a**oni(* hydro5ide sol(tion to aH(eo(s A+2(/0!)# (A) A precipitate is for*ed which does not dissolve in e5cess of a**oni(* hydro5ide ( ) A precipitate is for*ed which dissolves in e5cess of a**onia sol(tion (c) 7o precipitate is for*ed %6.The correct order of decreasing hardness of the following co*po(nds is G (A) %ia*ondS oraKon S car)or(nd(*S cor(nd(* ( ) oraKon S %ia*ondS car)or(nd(*S cor(nd(* (")"or(nd(*S"ar)or(nd(*S oraKonS%ia*ond (%)none

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'3 The strongest Iewis acid is (A) <# ( ) "+#

(")

r#

(%) +#

'&.The acid (sed for etching the glass is G (A) /(lph(ric acid ( ) Ferchloric acid (") 9ydrofl(oric acid (%) AH(a-Degia '4.The co*po(nd (sed in lead acc(*(lator is G (A) F): (B) P92O3 (") P93O4 (%) F):2 %10.+n the red(ction of 97:# to 72:, the n(*)er of *oles of electrons involved per *ole of 97:# is Q (A) & ( )! (") # (%) $ %11.%initrogen tetrao5ide, 72:! is a *i5ed anhydride )eca(se it G (A) +s a *i5t(re of 72:# and 72:1 ( ) %eco*poses in to two o5ides of nitrogen (C) Deacts with water to for* two acids (%) Deacts with water to for* nitric acid %12 Colloidal particles of soap sol. in water are (A) negatively charged ( ) positively charged (") ne(tral (%) (npredicta)le %13 Tyndall effect in colloidal sol(tion is d(e toG (A) /cattering of light ( ) Deflection of light (") A)sorption of light (%) Fresence of electrically charged particles %14..hich of the following is a hydrophilic colloidal sol.L (A) ari(* s(lphate sol(tion ( ) Arsenio(s s(lphide sol(tion (") /tarch sol(tion (%) /ilver iodide sol(tion %15 A negatively charged s(spension of "lay in water will need for precipitation the *ini*(* a*o(nt ofG (A) Al(*ini(* chloride ()) Fotassi(* s(lphate (") /odi(* hydro5ide (%) 9ydrochloric acid '1$ +n colloidal state, particle siKe ranges fro* (A) 1 to 10A0 ()) 20 to 50A0 ( )10 !o 1000A0 (%)11 to 280A0 '13 Rold n(*)er is *ini*(* in case of (A) Relatin ()) Jgg al)(*in (c) R(* Ara)ic (d) /tarch '18 Mil2 is a colloid in whichG (a) A liH(id is dispersed in liH(id ()) A solid is dispersed in liH(id (c) A gas dispersed in liH(id (d) /o*e s(gar is dispersed in water '14 /*o2e is an e5a*ple 1-# (a) Ras dispersed in liH(id ()) Ras dispersed in solid (c) /olid dispersed in gas (d) /olid dispersed in solid %20 +ndigo )elongs to the class of (A) Mordant dyes ( ) Vat dyes (") %irect dyes (%) %isperse dyes '21 AliKarin a *odern dye is not (sed in (A) "otton dyeing ( ) Frinting (") Fainting (%) "hro*i(* la2es for wood dyeing. 22. :5ytone is (A) Anti)ody (") JnKy*e ( ) 9ar*one (%) 7one of these '2#. The following co*po(nd is (sed asG (a) An anti-infla**atory co*po(nd ( ) Analgesic (") 9ypnotic (%) Antiseptic %24 Faraceta*ol is-are (A) oth antipyretic and analgesic ( ) Analgesic (") Antipyretic (%) Anti*alarial '21 The val(e of n in the for*(la (C5H10 O5): for ins(lin is a)o(t. (a) #0 ()) #00 (c) #000 (d)#00000 %269igh density polyethylene (9%FJ) can )e prepared <ro* ethylene )y (A) @iegler-7atta process ()) 9eating with pero5ides (") "ondensing in sealed t()es (d) condensing with styrenes '23. The chloride which can )e e5tracted with ether is (a) 7a"l ()) C"l (c) Mg"l2 (d) 7a r '2&..hich of the following set contains species having sa*e angle aro(nd the central ato*L (A) /<! "9!, 79# ( )7<# ,7"+#,79# (") <# ,7<#, A+"+# (%) <#, "+#, r# '24./elect the co*po(nd fro* the following which dissolves in water

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(A) ""+! ( ) "/2 (") "9"+# (%) "291:9 '#0 e<2 has Kero dipole *o*ent while 92: has a net dipole *o*ent )eca(se (A) e<2 is linear ( ) 92: is )ent (") < is *ore electronegative than : (%) 9ydrogen )onding is present in 92: 8 '#1 +n an ionic co*po(nd A A the degree of covalent )onding is greatest when (A) A8 and A- ion are s*all ( ) A8 is s*all and A- is large (") A8 and A- ions are appro5i*ately of the sa*e siKe (%) A- is s*all and " is large '#2 Ieast *elting point is shown )y the co*po(nd (A) F)"+2 ( ) /n"+! (") 7a"l (%) A+"+# '## The order of )ond angles in 79#, F9# and As9#, is (A) 79# S F9# S As9# ( ) F9# S 79# S As9# (") As9# S F9# S 79# (%) F9# 6 79# T As9# '#! .hich is distilled firstL (A) liH(id 92 (") liH(id :2 ( ) liH(id ":2 (%) liH(id 72 '.#1 "hoose the co*po(nds of *a5i*(* and *ini*(* ionic character fro* Ii"+, D)"l, e"+2 and Mg"+2 (a) Ii"l and D)"l ()) D)"+ and e"l2 (c) D)"+ and Mg"+2 (d) Mg"+2 and e"l2 %36The decreasing order of sol()ility of silver halides is (A) Ag+ S Ag r S Ag"l S Ag< ( ) Ag< S Ag"+ S Ag r S Ag+ (") Ag"+ S Ag< S Ag r S Ag+ (%) Ag r S Ag< S Ag+ S Ag"+ Q37A 815;5 )154.(1: () 1:' .&;. 71:.;(:) 1:' 815' 1- )154.' (:(A)1000 of the solvent( ) one litre of the solvent(") one litre of the sol(tion(%) 22.! litres of the sol(tion '#&. The *olal elevation constant is the ratio of the elevation in .F. to (A) *olarity ( ) *olality (") *ole fraction (%) *ole fraction of solvent '#4. vant 9off factor for 0.1M ideal sol(tion is (A) 0.1 ( ) 1 (") 0.01 (%) none of these val(es '!0 .hich of the following 0.1 M aH(eo(s sol(tions will have the lowest freeKing pointL ; (A) potassi(* s(lphate ( ) sodi(* chloride (") (rea (%) Rl(cose '!1 The n(*)er of iodine *olec(les present in 1c*# of its 0.1 M sol(tion is , (A) $.0251023 ( ) $.0251022 (") $.02 A 1014 (%) $.02X1020 Q42 .hich of the following aH(eo(s sol(tions has the highest )oiling pointLRiven C6 0.12P /m. (A) 0.2 * C"+ ( ) 0.2 * 7a2/:! (") 0.2 * "a(7:#)2 (%) *ore than one Q43 The *olarity of the sol(tion containing 3.1g of 7a2/:! in 100*l of aH(eo(s sol(tion is . (A) 2M ( ) 0.1M (") 1M (%) 0.01M Q44. Vant 9off factor of "a(7:#)2 is (A) 1 ( ) 2 (") # (D) 4 Q.45The os*otic press(re of 0.2 *olar sol(tion of (rea at #00C (D 6 0.0&2 litre at* *ol-1C-1) is (A) !.42 at* ( ) 1 at* (") 0.21 at* (%) 23 at* Q46 +f 10" *l of 1.0 M 7a:9 sol(tion is dil(ted to 1.0I, the res(lting sol(tion contains (A) 1 *ole of 7a:9 ( ) 4.1 *ole of 7a:9 (") 10.0 *ole of 7a:9 (%) 0.01 *ole of 7a:9 Q!7 At constant te*perat(re the os*otic press(re of a sol(tion is (A) %irectly proportional to the concentration ( ) +nversely proportional to the concentration (") %irectly proportional to the sH(are of the concentration. (%) %irectly proportional to the sH(are root of the concentration . Q48 0.2 *oles of 9"+ and 0.1 *oles of calci(* chloride were dissolved in water to have 100*l of sol(tion, the

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*olarity of "+- ions is (A) 0.! M ( ) 0.& M (") 0.0! M (%) 0.0& M Q.49 .hich inorganic precipitate acts as se*i-per*ea)le *e*)rane (A) "alci(* s(lphate ( ) ari(* o5alate (") 7ic2el phosphate (%) "opper <errocyanide Q50 1.0 g of p(re calci(* car)onate was fo(nd to reH(ire 10*l of dil(te 9"+ for co*plete reaction. The strength of 9"+ sol(tion is given )y (A) !7 ( ) 27 (") 0.0!7 (%) 0.27 '11. %(ring deepening of color of dyeU, the a)sorption shift towards red shift. This shift is called (a) atho chro*ic shift ()) 9ypo chro*ic shift (c) 9yper chro*ic shift (d) A(5o chro*ic shift '12. Farathion is (a) an organic co*po(nd ()) chlorinated aro*atic co*po(nd hydrocar)on(c) chlorinated aliphatic 9-" (d) enKene derivatives '1#. Jster for*ed in *edicines is (a) Jthyl acetate ()) *ethyl acetate (c) *ethyl salicylate (d) Jthyl )enKoate '1! /tr(ct(ral )iodegrada)le detergents contains (a) nor*al al2yl chains ()) )ranched al2yl chains (c) Fhenyl side chains(d) cyclohe5yl sidechains '11. Anti)iotic effective in the treat*ent in pne(*onia, )ronchitis (a) Fencillin ()) ptalin (c) chlor*ycetin (d) tetracyclines '1$. chloroa*phenicol is (a) Analgesic ()) Anasthetic (c) Anti)iotic (d) /(lphadiaKine '13. *atch the following (1) +odofor* (a) Anaesthetic (a) 1), 2e, #c, !d (2) Methyl salicylate ()) Antiseptic ()) 1d, 2), #a, !c (#) %iethyl-ether (c) %etergent (c) 1), 2e, #a, !c (!) 9e5achloro cyclohe5ane (d) +nsectiside (d) 1c, 2a, #d, !) (e) Fain)al* '1&. "olidion is a colloidal sol of (a) /(crose in water ()) gl(cose in water (c) cell(lose in water (d) cellose nitrate in ethanol '14. "olloidal sol effective in c(ring eye disease is (a) colloidal / ()) "olloidal anti*ony (c) "olloidal gold (d) "olloidal silver '$0. .hich of the following has *a5. floc val(e (a) deco*position of nitroglycerin ()) )rea2down of "1! (c) ther*al reaction )etween C"l:! and Mn:2 (d) 9ydrogenation of oils )y 7i catalyst '$1. "olloidal gold is given )y inMection act as (a) disinfectant ()) anticancer agent (c) Rer* 2iller(d) to5ic to raise the vitality of h(*an )eing '$2. 92/ gas is passed thro(gh 97:# is (a) Dho*)ic / ()) Fris*atic / (c) A*orpho(s / (d) Monoclinic / '$#. calo*el electrode *ay( )e freed fro* traces of *etallic 9g )y war*ing with (a) %il 97:# ()) %il 92/:! (c) 92:(d) AH(a regia '$!. arytes is an ore of (a) e ()) a (c) "a (d) Mg '$1. +n serpec2Vs process, )y prod(ct o)tained )y p(rification of )a(5ite ore is (a) Al2:# ()) 72 (c) 79# (d) none '$$. <ire wor2s gives o(t the cri*son color. +t contains a salt of (a) Mg ()) "( (c) a (d) r '$3. @one refining is a *ethod to o)tain (a) very high T *etals ()) 0tra p(re *etals (c) 0ltra p(re Al (d) 0ltra p(re o5ides '$&. lasting of T7T is done )y *i5ing with (a) 79!"l ()) 79!7:# (c) 79!7:2 (d) (792)2/:! '$4..hich of the following can withstand high T of order 10000"L (a) '(artK ()) Fyre5 (c) Fotash (d) Fotash, lead '30. Oellow color shown )y 97:# can )e re*oved )y (a) adding Mg powder()) Fassing thro(gh(c) Fassing 79# thro(gh acid(d) Fassing air thro(gh war* acid

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'31. 9ypo (sed in the photography )eca(se of its (a) Ded(cing properties()) :5idising properties (c) co*ple5 for*ing tendency(d) reaction with light '32. %eep sea divers (sed to respirate a *i5t(re of (a) Ar and :2 ()) :2 and 9e (c) :2 and 72 (d) :2 and 92 '3#. .hich of the following is a colored gasL (a) r2: ()) "l:2 (c) "l2: (d) :<2 '3!. .hat is the vol(*e strength of 3.1E 92:2L (a) 21E ()) #0E (c) #1E (d) !0E '31. .hat is the vol(*e strength of 27 92:2 (a) 11.2 ()) 12.2 (c) 1#.2 (d) 1!.2 '3$. +n the reaction 292:2 292: 8 :2, :./ of o5ygen changes fro* (a) only -1 to -2 ()) only -1 to Kero (c) )oth (d) -1 to -# '33. .hich of the following acid is (na)le to prod(ce effervescence with sodi(* )icar)onateG (a) "$91:9 ()) "$91"::9 (c) 9"::9 (d) "$91/:#9

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