Scribd Logo
Upload

Welcome to Scribd!

  • 1K views

    Naming Amines and Amides Rules

    Uploaded by

    Anonymous Sfcml4GvZ
    This document provides rules for naming amines and amides. It defines amines and amides as derivatives of ammonia where hydrogen atoms are replaced. It describes how to classify and name simple amines based on the number of alkyl groups bonded to nitrogen, including common names that list the alkyl groups in alphabetical order before "amine" and IUPAC names that identify the parent alkane chain and substituents. The document also provides rules for naming amides, which are similar to amines but have a carbonyl group instead of nitrogen bonded to an alkyl or aryl group. Amides are named like carboxylic acids but with the acid ending replaced by "amide".

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd

    Naming Amines and Amides Rules

    Uploaded by

    Anonymous Sfcml4GvZ
    1K views3 pages
    This document provides rules for naming amines and amides. It defines amines and amides as derivatives of ammonia where hydrogen atoms are replaced. It describes how to classify and name simple amines based on the number of alkyl groups bonded to nitrogen, including common names that list the alkyl groups in alphabetical order before "amine" and IUPAC names that identify the parent alkane chain and substituents. The document also provides rules for naming amides, which are similar to amines but have a carbonyl group instead of nitrogen bonded to an alkyl or aryl group. Amides are named like carboxylic acids but with the acid ending replaced by "amide".

    Original Description:

    Amines and Amides

    Copyright

    © Attribution Non-Commercial (BY-NC)

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    This document provides rules for naming amines and amides. It defines amines and amides as derivatives of ammonia where hydrogen atoms are replaced. It describes how to classify and name simple amines based on the number of alkyl groups bonded to nitrogen, including common names that list the alkyl groups in alphabetical order before "amine" and IUPAC names that identify the parent alkane chain and substituents. The document also provides rules for naming amides, which are similar to amines but have a carbonyl group instead of nitrogen bonded to an alkyl or aryl group. Amides are named like carboxylic acids but with the acid ending replaced by "amide".

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    1K views3 pages

    Naming Amines and Amides Rules

    Uploaded by

    Anonymous Sfcml4GvZ
    This document provides rules for naming amines and amides. It defines amines and amides as derivatives of ammonia where hydrogen atoms are replaced. It describes how to classify and name simple amines based on the number of alkyl groups bonded to nitrogen, including common names that list the alkyl groups in alphabetical order before "amine" and IUPAC names that identify the parent alkane chain and substituents. The document also provides rules for naming amides, which are similar to amines but have a carbonyl group instead of nitrogen bonded to an alkyl or aryl group. Amides are named like carboxylic acids but with the acid ending replaced by "amide".

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 3

    Chem 30B - Naming Amines and Amides (Rules) Amines and amides come from ammonia (replacing the

    Hs).!
    H N H H R N R R R N R

    O C R

    Ammonia

    Amine

    Amide

    Classification of amines by the number of alkyl chains:

    N H

    N H

    N R

    N R

    Ammonia

    Naming Simple Amines (Common Names) Are named as alkylamines. List the names of the alkyl groups bonded to the N atom in alphabetical order in front of amine. CH3 CH3CH2NH2 CH3NHCH3 | ethylamine dimethylamine CH3NCH2CH3 ethyldimethylamine Name the following amines:
    CH 2 CH 3 CH2 NH CH2 CH2 CH 3 N CH 3 CH 3 CH NH 2

    Primary amine Secondary amine (one alkyl chain) (two alkyl chains)

    Tertiary amine (three alkyl chains)

    NH 2

    IUPAC Names of Amines Amines are named as alkanamines. The e in the alkane name of the longest chain is changed to amine. The chain is numbered to locate the amine group and substituents. CH3CH2NH2 ethanamine In a secondary or tertiary amine, The longest alkane chain is numbered. Each alkyl group bonded to the N atom is named as a N-alkyl group HNCH3 | CH3CH2CH2NHCH3 CH3CHCH2CH3 3 2 1 1 2 3 4 N-Methyl-1-propanamine N-Methyl-2-butanamine Name the following amines:
    CH 3 CH 3 CH2 NH CH2 CH2 CH 3 CH 3 N CH 2CH 2CH3

    NH2 | CH3CHCH3 2-propanamine

    NH 2

    NHCH3

    Amines as Branches When found in compounds with oxygen containing functional group:! -NH2 amino -NHR N-alkylamino -NR2 N,N-dialkylamino Name the following amine:
    Free to copy for educational purposes

    O H2N CH2CH2CH2C OH

    4-aminobutanoic acid ( !"aminobutyric acid) N(CH3) 2 CH3CH2CH2CHCH2CH2 OH 3-(N,N-dimethylamino)-1-hexanol 3-(N,N-dimethylamino)hexan-1-ol

    Ammonium Salts
    R

    R N R R

    Named by naming the positive ion first and then naming the negative ion.

    Pharmaceutical companies often name amine salts by naming the parent amine followed by the name of the acid used to synthesize the salt: HCl: amine hydrochlorides H2SO4: amine hydrogen sulfates
    O O N H H R C N R H R O C N R R

    Amides
    Classification of amides by the number of alkyl chains:
    R

    Primary amide

    Secondary amide

    Tertiary amide

    Amides are named as alkanamides. IUPAC replaces oic acid ending with amide. Common names replace -ic acid ending with amide. O O || Methanamide (IUPAC) || HCNH2 Formamide (common) CH3CH2CNH2

    Propanamide (IUPAC) Propionamide (common)

    An alkyl group bonded to the N atom is named as N-alkyl in front of the amide name. O H O H || ! || ! CH3 CNCH3 CH3CH2 CNCH2CH3 N-methylethanamide (IUPAC) N-ethylpropanamide (IUPAC) N-methylacetamide (common) N-ethylpropionamide (common) The amide of benzene is named benzamide.
    O C NH 2 O C NH CH 3

    Benzamide

    N-methylbenzamide

    Free to copy for educational purposes

    Naming Amines and Amides Key (Rules) Name the following amines (common names):

    Name the following amines (IUPAC names):

    Name the following amine:

    Free to copy for educational purposes

    You might also like