MATERIAL SAFETY DATA SHEET

PRODUCT AND COMPANY IDENTIFICATION

Sai Sulphonates Pvt. Ltd. 21, Princep Street, 2nd Floor Kolkata-700072, India Ph: +91 33 2236-3055 / 3849 Fax: +91 33 2221-9145 Mr.Sandeep Fogla [email protected] A R Sulphonates Pvt. Ltd. 9 Hemant Basu Sarani, 2nd Floor Cooke & Kelvey Building, Kolkata700001 Ph:: +91 33 2248-7239/1866 Fax: +91 33 2213-8732 Mr. Sanjeev Fogla Mr. Rishi Fogla [email protected] [email protected] [email protected] A R Stanchem Pvt Ltd 9 Hemant Basu Sarani, 2nd Floor Cooke & Kelvey Building, Kolkata700001 Ph: +91 33 2248-7239 /1866 Fax: +91 33 2213-8732 Mr. Udhav Modi Mr. Ramesh Modi [email protected] [email protected]

SUBSTANCE: TRADE NAME COMMODITY CODE APPLICATION : LABSA : HSN 2904-10-90 / 3402-11-90 : Intermediary for the production of Detergent.

COMPOSITION / INFORMATION ON INGREDIENTS CHEMICAL NATURE CHEMICAL NAME CHEMICAL FORMULA CAS NUMBER EINECS NUMBER EC NUMBER : : : : : : Substance Linear Alkyl Benzene Sulfonic Acid C6H4(SO3H)(CS2)10CS3 42615-29-2 248-289-4 Not Classified.

HAZARDOUS IMPURITIES
NAME Sulfuric Acid Concentr. 4-7% max CAS N. 7664-93-9 EC N. 016-020-00-8 SYMBOL C-Corrosive R Phrases R 35

R 35: Causes severe burns. HAZARDS IDENTIFICATION ADVERSE HUMAN HEALTH EFFECTS : The product is a corrosive substance. Contact with the eyes may cause ocular lesions. ontact with the skin may cause burns. It is seriously irritating to the mucous if swallowed. The product is harmful if ingested. ENVIRONMENTAL EFFECTS : The product is not classified as dangerous to environment. The user is advised to use anyway good work practice and to avoid contamination of environment. : The product is a strong acid which reacts exothermally with bases. Dilution with water produces heat.

OTHER EFFECTS

FIRST AID MEASURES INGESTION : The product may cause severe irritation of the mouth and esophagus. If accidentally ingested, administer water. Do not induce vomiting. Call a physician immediately. The product is not volatile. If under particular conditions, such as in the case of fire, fumes or aerosols are inhaled, remove the patient to a well ventilated location and call a physician. Flush eyes immediately with running water for a long time. Seek medical assistance immediately. The product may cause burns. Remove the contaminated clothing and wash with plenty of water and call a physician immediately. The product is a high foaming anionic surfactant. If gastric lavage is Necessary, then use a silicone antifoam (dimethicone).

INHALATION

EYE CONTACT SKIN CONTACT

: :

ANNOTATIONS TO A PHYSICIAN

FIRE FIGHTING MEASURES GENERAL INFORMATION : The product poses little risk of ignition. If it happens to be involved in a Fire, keep the tank cooled by means of water spray in order to avoid the Decomposition of the product. : Water spray, foam, carbon dioxide. : Combustion produces carbon dioxide, carbon monoxide and oxides of Sulphur. When heated to decomposition, toxic fumes of SO2 and SO3 are Emitted. : For large fires, wear self-contained breathing apparatus.

SUITABLE EXTINGUISHING MEDIA SPECIFIC HAZARDS

NOT SUITABLE EXTINGUISHING MEDIA : None in particular.

SPECIAL EQUIPMENTS

ACCIDENTAL SPILL MEASURES PERSONAL PRECAUTIONS : Avoid direct contact with the product. Wear rubber gloves and rubber Boots, face shield and keep close by a gas mask provided with filter For acid vapors. : Surround the spill with earth or sand. Collect the spilled material in suitable Containers, if necessary absorb the spill onto inert materials. Dispose of material according to the uirements of local law. In case of Leaking into sewer inform the local authorities. : Neutralize the residue of the product with NaOH or with caustic lime. Wash the contaminated area with plenty of water. If excessive foam is produced, use a silicone based antifoam to bring it down.

ENVIRONMENTAL PRECAUTIONS

METHODS FOR CLEANING UP

HANDLING AND STORAGE HANDLING : Avoid contact with the product. While handling the product, wear a protective apron, rubber or PVC gloves and a face shield.Handle the product in well ventilated areas.Neutralize with base under controlled conditions.Do not heat above 50 degrees C.Compatible materials: stainless steel, mild steel, plastic materials.incompatible with galvanized steel, aluminium, copper alloys

EXPOSURE CONTROLS / PERSONAL PROTECTION PRECAUTIONARY MEASURES : Installation of an eyewash fountain is recommended. Do not eat or drink onto the work place, When handling the product use approved protective clothing, rubber or PVC gloves, and a face shield. : Wear safety goggles or a face shield and approved protective clothing. : Not established. : Specific measures are not foreseen.

PERSONAL PROTECTIVE EQUIPMENT THRESHOLD LIMIT VALUE

REQUIREMENTS FOR PERIODIC HEALTH CHECK UP PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE AT 20 DEGREES C ODOR NOMINAL ACTIVE MATTER CONCENTR AVERAGE MOLECULAR MASS SOLUBILITY AT 20 DEGREES C - water - ethanol - acetone - aliphatic hydrocarbons MASS DENSITY AT 20 DEGREES C VISCOSITY AT 20 DEGREES C MELTING RANGE BOILING POINT VAPOUR PRESSURE at 20 DEGREES c VAPOUR DENSITY (air = 1) FLASH POINT (PMcc) AUTOIGNITION TEMPERATURE DECOMPOSITION TEMPERATURE Ph EXPLOSION PROPERTIES OXIDIZING PROPERTIES : : : :

: Brown viscous liquid. : Of sulfur. : ~ 90% m/m. : ~ 326 Soluble. Soluble. Not compatible. Insoluble. : ~ 1.070 g/cm3 : ~ 1500 2000 mPa.s. : ~ - 10 DEGREES C. : ~ 315 DEGREES C. : Below 0.15 (0.001 mm Hg). : Not applicable to this product. : >200 DEGREES C. : Not applicable to this product. : > 100 DEGREES C. : ~ 2. : Not pertinent to this product. : Not pertinent to this product.

STABILITY AND REACTIVITY HAZARDOUS DECOMPOSITION PRODUCTS : In case of overheating, sulfur oxides can be emitted. CONDITIONS TO AVOID MATERIALS TO AVOID INTENDED USE AND TRANSFORMATION : Do not heat above 80 90 DEGREES C. : Neutralization with bases under uncontrolled conditions. : The product maybe neutralized under controlled conditions with the appropriate base to produce the corresponding salt.

TOXICOLOGY INFORMATION POSSIBLE ROUTES OF PENETRATION : Ingestion and contact. INGESTION EYE CONTACT SKIN CONTACT SENSITIZATION INHALATION : Corrosive substance, harmful for ingestion. Oral acute LD50 : > 500 2,000 mg/Kg. : Severe eye irritant (rabbit). It may cause irreversible damage to the eyes. : Contact may cause ulcerations. : Not sensitizing. : Inhalation is possible only as an aerosol. Strong irritant to respiratory passages.

ECOLOGICAL INFORMATION ENVIRONMENTAL DISTRIBUTION : Water is likely to be the main transport medium for the chemical, to extimate its possible environmental distribution. : > 90% (OECD screening test (sodium salt)) The surfactant fulfils the requisite minimum requirements of primary Biodegradability. : Not available. : 2.49 mg O2/mg. : Not available. : Not applicable, surface active substance. : Insufficient available information.

PRIMARY BIODEGRADABLITY

ABIOTIC DEGRADABILITY ECOTOXITY CHEMICAL OXYGEN DEMAND(COD) LOG P o/w BCF DISPOSAL CONSIDERATIONS

Dispose of product in authorized places / methods in observance with current laws. It may be treated in a biological waste water treatment plant. TRANSPORT INFORMATION UN CLASSIFICATION NUMBER NAME OF THE DELIVERING PRODUCT : 2586 : Linear Alkyl Benzene Sulphonate (HLAS / LABS)

BY SEA (IMO / IMDG): Class : 8 Page 8105 MARPOL Annex II: Cat. C EmS: F-A, S-B Packing Group: III Label: of class 8 - model H - Alkylbenzenesulphonic acid MARPOL Annex III: --------MFAG: Table no. 007]

BY ROAD (ADR) : Class 8; 34 DEGREES C Identification number on the plate: 80 / 2586 Packing group III Label 8 BY RAIL (RID) : Class 8; 34 DEGREES C Identification number on the plate: 80 / 2586 Packing group III Label 8

BY AIR (ICAO / IATA) Class 8 REGULATORY INFORMATION CLASSIFICATION AND LABELLING PROVISIONAL SYMBOLS OF HAZARD: RISK PHRASES: R 22 Harmful if swallowed. R 34 Causes burns. SAFETY ADVICES: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical help. S 28 After contact with skin, wash immediately with plenty of water. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection.

The information contained in this MSDS sheet is based on the available knowledge at the time of compilation. This information was obtained from tests conducted by or for A.R.Sulphonates or extracted from the literature and is relative to the safety prescriptions and correct use of the product. A.R. Sulphonates assumes no responsibility for applications that are incorrect or improper or not in accordance with the information reported above. For any application outside normal foreseen it is advisable to ask information from A.R. Sulphonates. The data provided herein do not constitute specifications of quality. This MSDS cancels and replaces any preceding release.