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    Overview of Polyurea Technology

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    A Mahmood
    Developed for Automotive Fascia Parts 1986 - Polyurea Spray Systems Developed 1988 - First Commercial Use Basic Chemistry Advantages of the Technology 100% solids, 0-VOC's and low Odor Excellent Bond, Tear Strength, and Elongation Excellent Impact and Abrasion Resistance NSF Certified and USDA approved Limitations and Precautions: Color Stability of Aromatic Systems Aesthetics of Overlap and Overspray Chemical Resistance Should Always Be Verified

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    Overview of Polyurea Technology

    Uploaded by

    A Mahmood
    122 views42 pages
    Developed for Automotive Fascia Parts 1986 - Polyurea Spray Systems Developed 1988 - First Commercial Use Basic Chemistry Advantages of the Technology 100% solids, 0-VOC's and low Odor Excellent Bond, Tear Strength, and Elongation Excellent Impact and Abrasion Resistance NSF Certified and USDA approved Limitations and Precautions: Color Stability of Aromatic Systems Aesthetics of Overlap and Overspray Chemical Resistance Should Always Be Verified

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    Developed for Automotive Fascia Parts 1986 - Polyurea Spray Systems Developed 1988 - First Commercial Use Basic Chemistry Advantages of the Technology 100% solids, 0-VOC's and low Odor Excellent Bond, Tear Strength, and Elongation Excellent Impact and Abrasion Resistance NSF Certified and USDA approved Limitations and Precautions: Color Stability of Aromatic Systems Aesthetics of Overlap and Overspray Chemical Resistance Should Always Be Verified

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    122 views42 pages

    Overview of Polyurea Technology

    Uploaded by

    A Mahmood
    Developed for Automotive Fascia Parts 1986 - Polyurea Spray Systems Developed 1988 - First Commercial Use Basic Chemistry Advantages of the Technology 100% solids, 0-VOC's and low Odor Excellent Bond, Tear Strength, and Elongation Excellent Impact and Abrasion Resistance NSF Certified and USDA approved Limitations and Precautions: Color Stability of Aromatic Systems Aesthetics of Overlap and Overspray Chemical Resistance Should Always Be Verified

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    of 42

    Overview of Polyurea Technology

    Presented by Bob Johnson

    Polyurea History
    1981
    Developed for Automotive Fascia Parts

    1986
    Polyurea Spray Systems Developed

    1987
    Polyurea Spray Equipment Introduced to Industry

    1988
    First Commercial Use

    Basic Chemistry

    ISO + Amine polymer = Polyurea ISO + polyol (OH-) = Polyurethane

    ISO + (OH-) polymer = Hybrid Polyurea

    Advantages of the Technology


    Fast Cure: Rapid return to service Application at -20F to 120F Retain Physical Properties from -20F to 250F Waterproof and crack resistant to 15F Very Low Permeability

    Advantages of the Technology

    100% solids, 0-VOCs and Low Odor Excellent Bond, Tear Strength, and Elongation Excellent Impact and Abrasion Resistance NSF Certified and USDA approved

    Limitations & Precautions:


    Color Stability of Aromatic Systems Aesthetics of Overlap and Overspray Chemical Resistance Should Always Be Verified

    Systems Available
    Aromatic Aliphatic Joint

    Sealant Grade Repair

    Brush

    Equipment Requirements
    Material Air

    Temperature 150 to 170F

    & Surface Temperature -20 to 120F Pressure 2000 2500 PSI up to 2 gals per minute Proportioning of 1:1 ratio

    Line

    Output Critical Direct

    Impingement Mixing Guns

    Plural Component Equipment

    Direct Impingement Spray Guns

    All

    Polyurea Systems are not equal

    Physical Properties, Chemical Stability, and

    Performance Ratings are affected by formulation and application parameters

    Comparison of Properties
    Bis A Epoxy PU Elastomer Dry Time Full Cure 4-8 Hours 3-7 Days 4-6 Hours 3-7 Days Polyurea 12 seconds To 3 minutes 24 hours

    Comparison of Properties
    Bis A Epoxy Tensile Elongation ASTM D4541 Abrasion Resistance ASTM D 4060 Permeability ASTM E 96 Hardness ASTM D 2240 Application Temp. 7,000 psi 1% 100 mg Loss .16 perm-in. PU Elastomer 1,000 psi 500 % 42 mg Loss .080 perm-in. Polyurea 3,000 psi 425 % 6 mg Loss .02 perm-in.

    Shore D 85 50F - 90 F F160, R80 LBS

    Shore D 40-60 55 F - 90 F >160 Lbs. F and R

    Shore D 51 -20 F - 120 F >160 Lbs. F and R

    Impact Resistance ASTM D 2794

    Permeability Comparison
    Product Flake Filled Vinyl ester Flake Filled Polyester EnviroLastic AR200 HD and AR 425 (30 mil) Futura 5022 Hybrid Polyurea 4 Mil Polyethylene sheet General Purpose Bis A Epoxies (8 mil) Neogard Deck coating (36 mil) polyurethane elastomer 3M Topcoat (12 mil) polyurethane elastomer 3M Basecoat(25 mil) polyurethane elastomer Acrylic Permeability ASTM E96 .001 .005 .02 .06 .08 .16 1.06 2.4 2.7 3.5

    Polyurea Adhesion
    Adhesion

    to SSPC SP-10, 3 mil profile carbon steel = 1,750 to 2,000 psi. to primed concrete with ICRI CSP 3-5 is 8-10% of concrete compressive strength enhanced by adhesion promoter

    Adhesion

    Adhesion

    Crack Bridging @ -15 F @ 1/8


    (ASTM C 836)
    Mortar

    blocks coated with aromatic polyurea and crack bridging tested at -15 F

    Flexibility System

    showed no signs of cracking loss of adhesion or any other type of failure concluded by DL Laboratories

    Tests

    QUV Weatherometer ASTM G53


    250 Hours 500 Hours 1000 Hours Aromatic Polyurea Typical color changes Performance is Not Affected by Color Change 1500 Hours 2000 Hours 3000 Hours No chalking or cracking

    Radiation Exposure

    Gamma Radiation 1x107 yellowing, no change in adhesion. Decontamination (ASTM D 4256) - 99.26% Radiation shielding tests indicate 300 mils may shield 50% of low energy Gamma and up to 100% of Beta. Grant awarded to Hanford to complete testing.

    (Request Hanford/LATA test Report)

    Fire And Smoke Development


    Fire

    Test of Roof Covering Class A Class 1

    ASTM E 108

    Flammability

    ASTM E 84 Tunnel Test Flame Spread 10 Smoke Development 35

    Toxic Gases
    MIL-STD-2031

    Applications Inside Naval

    Submarines
    ASTM

    E 662 Test Method


    Results 100 ppm 1% 2 ppm <10 ppm Allowable 200 ppm 4% 30 ppm 100 ppm

    Carbon Monoxide Carbon Dioxide Hydrogen Cyanide Hydrogen Chloride -

    Polyurea vs. Polyurethanes and Hybrids


    Advantages of Polyurea Broader temperature use Faster return to service Higher abrasion resistance Lower permeation rating Tougher, high tensile & elongation Greater tear resistance Moisture tolerant-will not foam Disadvantages of Polyurea Higher cost

    Polyurea vs. Epoxy


    Advantages of Polyurea

    Disadvantages of Polyurea

    Broader temperature use Faster return to service Higher abrasion resistance Higher elongation Greater toughness Lower permeation rating

    Lower chemical resistance Lower hardness Critical mix ratio

    Surface Preparation

    Steel:

    SSPC-SP 10 /NACE 2 2 mil profile atmospheric 3 mil profile immersion ICRI CSP 3-5 profile minimum atmospheric or immersion

    Concrete:

    Steel Surface Preparation


    Clean

    surface of contaminants seams, rivets, welds anchor profile

    Inspect Provide

    Remember!
    Coatings

    & Linings Adhere to the Surface by Mechanical and/or Chemical Bond Cleaning Provides a Good Anchor

    Abrasive

    Acceptable Surface Preparation Standards


    SSPC-SP1 SSPC-SP10 NACE No. 2

    Solvent Cleaning Near-White Blast 2 mil profile for atmospheric 3 mil profile for immersion

    SSPC-SP12 NACE No. 5 Ultra High Water Jetting

    Recommended Primers
    Steel Direct to Metal, SSPC SP-10, 2-3 mil profile Epoxy Hold Primer Concrete, Masonry, & Wood High Solids Epoxy Low Temp 100% Solids Epoxy 100% Solids Conductive Epoxy

    MARINE APPLICATIONS

    Keys To Success
    State

    of the Art Polyurea Systems Reliable Spray Equipment Contractor Network

    Highly

    Certified

    Secondary Containment

    Pipelines

    Fuel Storage Areas

    Water & Wastewater

    Cooling Tower Liners

    Fish Hatcheries Aquariums Mining NSF 61 Approved

    Industrial Floor Coatings

    Roof Coatings

    Deck Coatings

    Wall & Ceiling Coatings

    Clean Rooms Rail Car Linings

    Industrial Waste Storage Tank

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