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Uint-Iv: Sbmcet/Mech/Pgk & Narayanan.S Asst - Prof/Mech/Dindigul

This document contains 6 questions related to thermodynamics and properties of gases. Question 1 involves calculating properties of gas mixtures using ideal gas law and compressibility factors. Question 2 involves calculating pressure of air using ideal gas and van der Waals equations. Question 3 involves determining properties like heat capacity and gas constant for a gas mixture. Question 4 involves calculating equilibrium properties when two vessels containing nitrogen are mixed. Question 5 involves generalized compressibility chart and properties of a gas mixture. Question 6 involves deriving van der Waals and Joule-Kelvin equations.

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Narayanan Srinivasan
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60 views4 pages

Uint-Iv: Sbmcet/Mech/Pgk & Narayanan.S Asst - Prof/Mech/Dindigul

This document contains 6 questions related to thermodynamics and properties of gases. Question 1 involves calculating properties of gas mixtures using ideal gas law and compressibility factors. Question 2 involves calculating pressure of air using ideal gas and van der Waals equations. Question 3 involves determining properties like heat capacity and gas constant for a gas mixture. Question 4 involves calculating equilibrium properties when two vessels containing nitrogen are mixed. Question 5 involves generalized compressibility chart and properties of a gas mixture. Question 6 involves deriving van der Waals and Joule-Kelvin equations.

Uploaded by

Narayanan Srinivasan
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOC, PDF, TXT or read online on Scribd
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UINT-IV

1. (i)A rigid tank contains 2 kmol of N2 and 6 kmol of CO2 gases at 300 K and 15 M a. !stimate t"e #ol$me of t"e tank on t"e %asis of t"e ideal&gas e'$ation of state( com)ressi%ilit* factors and Amagat+s la,( and com)ressi%ilit* factors and -alton+s la,. (.) (ii) An ins$lated rigid tank is di#ided into t,o com)artments %* a )artition. One com)artment contains / kg of o0*gen gas at 102C and 100 k a( and t"e ot"er com)artment contains 1 kg of nitrogen gas at 202C and 150 k a. No, t"e )artition is remo#ed( and t"e t,o gases are allo,ed to mi0. -etermine t"e mi0t$re tem)erat$re and t"e mi0t$re )ress$re after e'$ili%ri$m "as %een esta%lis"ed.(.) [NOV10] 2. (i) A #essel of #ol$me 0.3 m3 contains 15 kg of air at 303 K. -etermine t"e )ress$re e0erted %* t"e air $sing( (1) erfect gas e'$ation (2) #an der 3aals e'$ation. 4ake critical tem)erat$re of air as 132.. K. Critical )ress$re of air is 3/./ %ar. (6) (ii) A )erfect gas mi0t$re consists of 1 kg of N2 and 6 kg of CO2 at a )ress$re of 1 %ar and a tem)erat$re of 252C. 5or N26 C# 7 0./15 k89kgK and C) 7 1.011 k89kgK. 5or CO26 C# 7 0.653 k89kgK and C) 7 0..12 k89kgK. 5ind C) ( C# and : of t"e mi0t$re. ;f t"e mi0t$re is "eated at constant #ol$me to 502C( find t"e c"anges in internal energ*( ent"al)* and entro)* of t"e mi0t$re . (10) <NOV11] 3 ;n 5 kg mi0t$re of gases at 1.013 %ar and 300 K t"e #ario$s constit$ent gases are as follo,s( .0= N2( 1.= O2( 2= CO2. -etermine t"e s)ecific "eat at constant )ress$re( gas constant for t"e constit$ents and mi0t$re and also molar mass of mi0t$re taking > 7 for N2 and O2 and > 7 3.1 for CO2. ?ni#ersal gas constant 7.31189kg.K. (16) [APR11] 1 4,o #essel( A and @( %ot" containing nitrogen( are connected %* a #al#e ,"ic" is o)ened to allo, t"e contents to mi0 and ac"ie#e an e'$ili%ri$m( tem)erat$re of 2/2C. @efore mi0ing t"e follo,ing information is kno,n a%o$t t"e gases in t,o #essels. Aessel&A Aessel &@ ) 7 1.5 M a ) 7 0.6 M a t 7 502C t 7 202C Contents 7 0.5 kg mol Contents 7 2.5 kg mol Calc$late t"e final e'$ili%ri$m )rocess( and t"e amo$nt of "eat transferred to t"e s$rro$ndings. ;f t"e #essel "ad %een )erfectl* ins$lated( calc$late t"e final tem)erat$re and )ress$re ,"ic" ,o$ld "a#e %een reac"ed. 4ake > 7 1.1 [MAY 09] 5. (i) 3rite a s"ort note on BeneraliCed Com)ressi%ilit* c"art. (ii) A mi0t$re of ;deal gases consists of 2.5 kg of N 2 and 1.5 kg of CO2 at a )ress$re of 1 %ar and a tem)erat$re of 252C. -etermine 6 (i)Mole fraction of eac" constit$ent( (ii)!'$i#alent molec$lar ,eig"t of t"e mi0t$re( (iii)!'$i#alent gas constant of t"e mi0t$re( (i#)4"e )artial )ress$re and )artial #ol$mes(
SBMCET/MECH/PGK & NARAYANAN.S ASST.PROF/MECH/DINDIGUL Page 1

UINT-IV
(#) 4"e #ol$me and densit* of t"e mi0t$re. [ NOV 08]

6. (i) -eri#e #an der 3aal+s e'$ation in terms of red$ce )arameters. (ii) -eri#e 4dD e'$ations taking 4em)erat$re( #ol$me and tem)erat$re( )ress$re as de)endent )ro)erties. (ii) -escri%e 8o$le Kel#in effect ,it" t"e "el) of 4&) diagram. [ MAY /NOV08] /. .(i) ro#e t"at t"e total )ress$re is a s$m of )artial )ress$res. (ii) A closed #essel "as a ca)acit* of 0.5 m3. ;t contains 20= nitrogen and 20= o0*gen 60= car%on dio0ide %* #ol$me at 202C and 1 M a. Calc$late t"e molec$lar mass( gas constant( mass )ercentages and t"e mass of mi0t$re. [MAY 08]

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