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    MSDS - Sulphur 90%: Section 1. Product Information

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    sahilchem
    The document is a material safety data sheet (MSDS) for a product called 90% Sulphur distributed by Pestell Minerals & Ingredients. It is a solid material made of 90% sulfur and 10% bentonite clay. The MSDS provides information on the product's physical properties, fire and explosion hazards, health effects, storage requirements, personal protective equipment needs, and transportation classifications.

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    Download as PDF, TXT or read online from Scribd

    MSDS - Sulphur 90%: Section 1. Product Information

    Uploaded by

    sahilchem
    124 views3 pages
    The document is a material safety data sheet (MSDS) for a product called 90% Sulphur distributed by Pestell Minerals & Ingredients. It is a solid material made of 90% sulfur and 10% bentonite clay. The MSDS provides information on the product's physical properties, fire and explosion hazards, health effects, storage requirements, personal protective equipment needs, and transportation classifications.

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    Sulphur

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    The document is a material safety data sheet (MSDS) for a product called 90% Sulphur distributed by Pestell Minerals & Ingredients. It is a solid material made of 90% sulfur and 10% bentonite clay. The MSDS provides information on the product's physical properties, fire and explosion hazards, health effects, storage requirements, personal protective equipment needs, and transportation classifications.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    124 views3 pages

    MSDS - Sulphur 90%: Section 1. Product Information

    Uploaded by

    sahilchem
    The document is a material safety data sheet (MSDS) for a product called 90% Sulphur distributed by Pestell Minerals & Ingredients. It is a solid material made of 90% sulfur and 10% bentonite clay. The MSDS provides information on the product's physical properties, fire and explosion hazards, health effects, storage requirements, personal protective equipment needs, and transportation classifications.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 3

    Pestell Minerals and Ingredients: 90% Sulphur

    Page 1 of 3

    MSDS - Sulphur 90%


    Revision January 2011

    Section 1. Product Information


    Family/Chemical Family: Sulfur Chemical Formula: S8 CAS No.: 7704-34-9

    Distributed by Pestell Minerals & Ingredients, New Hamburg, ON Canada 24 Hour Emergency Telephone (Canutec): 613-996-6666

    Section 2. Hazard Ingredients


    90% Sulphur (CAS.No. 7704-34-9) 10% Bentonite Clay

    Section 3. Physical Data


    Material is solid Appearance and Odour: Earth tone colours. May have slight sulphur odour. Pellet or pastille in shape Boiling Point: 444oC (832oF) Specific Gravity: Solid, 2.07/gm/ml Vapour Density: >1 Melting Point: 119oC (246oF) Solubility in Water: Insoluble pH: Neutral when dry Vapour Pressure (mm Hg at 20oC): Solid, less than 0.0001mm.Hg Evaporation Rate: N/A % Volatiles: N/A

    Section 4. Fire or Explosion Hazard


    Flash Point: Pure Liquid S - 188oC (370oF) Impure Liquid S - 168oC (335oF) Auto Ignition Temperature: Dust Clouds 190oC (374oF) Undispersed Dust 220oC (428oF)

    http://www.pestell.com/minerals/fert/msds/sulphur.html

    07/02/2008

    Pestell Minerals and Ingredients: 90% Sulphur

    Page 2 of 3

    Flammable Limits in Air: Minimum explosion concentration is approximately 35gm per cu. metre (0.035 oz per cu. ft.) Maximum explosive concentration lies between 1000 and 2000 gm/m3 probably about 1400 gm/m3, (1.4 oz per cu. ft.) Unusual Fire and Explosion Hazards: Dust suspended in air is readily ignited by flame, static electricity or friction spark. Every reasonable step must be taken to minimize dust formation. Handling equipment must be grounded or bonded to avoid static electricity. Keep away from sources of flame or sparks. Detailed recommendations in Manufacturing Chemists Association SD-74 and National Safety Council 612 Bulletins covering "Sulphur" should be followed when handling. Explosive Limits: LEL 35gm/m3 UEL: 1400 gm/m3

    Fire Extinguishing Agents Recommended A fine water spray or fog is recommended CO2 or dry chemical Small fires may be smothered with sand or solid sulfur

    Fire Extinguishing Agents to Avoid Hoses and extinguishers with pressure streams should be avoided where solid sulfur is dusty or where it may create a further hazard by raising more dust clouds.

    Special Fire Fighting Precautions Because burning sulfur evolves sulfur dioxide, breathing apparatus or gas masks approved for use in acid-gas atmosphere should be used. Fumes from unprotected sulfur fires shall be avoided if possible by approaching from the upwind side.

    Section 5. Reactivity Data


    Stability: Product is stable Conditions to Avoid: The main hazards are fire and dust explosions Hazardous Polymerization: Will not occur Materials to Avoid: Mixtures with chlorates, nitrates or other oxidizing agents may be explosive. Sulphur will react with alkalies or alkaline earths.

    Section 6. Toxicological Properties


    Inhalation: Sulfur dust may irritate the mucous membranes of the respiratory passages. Ingestion: Solid sulfur is virtually non-toxic. It can be taken internally in fairly large doses without injury. Skin: In some individuals, sulfur dust has an irritant action, which may be aggravated by perspiration or moisture. Eyes: Sulfur dust is capable of irritating the inner surfaces of the eyelids. Permissible Concentrations: None established Unusual Chronic Toxicity: N/A

    Section 7. Preventive Measures


    Personal Protective Equipment Respiratory Protection: Dust-type respirators shall be provided for dusty conditions. Breathing apparatus must be available for emergency use in case of fire. Eyes and Face: Dust tight goggles with plastic or rubber frames may be helpful in dusty conditions.

    http://www.pestell.com/minerals/fert/msds/sulphur.html

    07/02/2008

    Pestell Minerals and Ingredients: 90% Sulphur

    Page 3 of 3

    Hands, Arms and Body: Workers whose skin may be sensitive to sulphur dust should button collars, roll sleeves down, and gather trousers at the ankle. Gloves may be helpful. Other Clothing and Equipment: Hard hat and safety shoes. Fire retardant fabric is recommended. Sulphur impregnated clothing should not be worn. Ventilation: Local exhaust if dusty conditions prevail Normal Handling: Avoid breathing dust and keep clothing as free from dust as possible Storage: Solid becomes corrosive to metals when stored wet. Sulfur/bentonite fertilizer will physically break down when exposed to moisture or water Spill or Leak: Shovel into disposal containers or cover with tarp. For landfill disposal, mix with limestone 3 times the weight of sulphur. Special Precautions/Procedures/Label Instructions. Eye Wash Equipment Near The Work Area

    Section 8. First Aid Measures


    Skin: Wash with mild soap and water Eyes: Irrigate thoroughly with copious quantities of plain water for at least 15 minutes Inadequate irrigation may increase the irritation. Do Not Use Boric Acid.

    Section 9. Transportation
    Non regulated as per the following exemptions/provisions and observations: US and Canadian Shipments: Non regulated as per TDGAR's exemption part 2.3 (a) (xxxviii) and 49CFR (Canadian Shipments and Packaging 171.12 (a) and CFR49 (Special Provisions 172.102 pt 30.)

    Disclaimer: The information contained herein is accurate to the best of our knowledge. We do not suggest or guarantee that any hazards listed herein are the only ones which exist. Pestell Minerals & Ingredients makes no warranty of any kind, expressed or implied, concerning the safe use of this material in your process or combination with other substances. Effects can be aggravated by other materials and/or this material may aggravate or add to the effects of other materials. This material may be released from gas, liquid or solid materials made directly or indirectly from it. User has the sole responsibility to determine the suitability of the materials for any use and the manner of use contemplated. User must meet all applicable safety and health standards.

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    http://www.pestell.com/minerals/fert/msds/sulphur.html

    07/02/2008

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