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Boilers & Cooling Towers: Application Bulletin

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Application Bulletin

BOILERS & COOLING TOWERS


Boilers and cooling towers share two major waterrelated problems: deposits and corrosion. As steam is generated by a boiler or water evaporating from a cooling tower, dissolved minerals are left behind, increasing the concentration of these minerals. Additional minerals are introduced via the water added to makeup the water lost to steam/evaporation. Eventually, the minerals reach a level (or cycle) of concentration that will cause either loss of efficiency due to scale or damage from corrosion. This level can be determined by the Ryznar or Langelier indices and correlated to a conductivity or TDS range. Most people recognize problems associated with corrosion. Effects from scale deposits, however, are equally important. For example, as little as 1/8" of scale can reduce the efficiency of a boiler by 18% or a cooling tower heat exchanger by 40%! A variety of water treatment methods are employed in an effort to control these problems. Even with water treatment, it is still necessary to regularly blowdown or bleedoff part of the concentrated water and make up with lower salinity water to reduce the overall mineral concentration. To conserve water and treatment chemicals, it is desirable to allow the dissolved minerals to reach a maximum cycle of concentration while still avoiding problems. Because feedwater/make-up waters vary in the types and amounts of minerals present, the allowable cycles of concentration will vary. As a result, regular testing of boiler and cooling waters is essential to optimize water treatment programs and blowdown schedules. Tests commonly performed include conductivity or TDS, pH and ORP. MyronL Company instrumentation provides you with a simple, fast, and accurate means of testing these parameters. Many cooling towers and boilers have in-line controllers used to release water from the tower or boiler and feed chemical(s) into the system. The controllers must be calibrated regularly to ensure fouling or drift of the sensor has not occurred. Our portable instruments in conjunction with NIST traceable standard solutions provide rapid verification of the accuracy of in-line controllers. This method reduces manpower and the likelihood of disturbing or damaging sensors.

conductivity
Conductivity is the measurement of a solution's ability to transmit an electrical current. It is usually expressed in microsiemens/cm (micromhos/cm). Pure water is actually a poor electrical conductor (18,200,000 ohms/cm of resistance). It is the amount of ionized substances (or salts) dissolved in water which determines the conductivity. Because the vast majority of the dissolved minerals in water are these conductive inorganic impurities, conductivity measurement is an excellent indicator of mineral concentration. The MyronL Instruments were developed for just this purpose. Models are available which display conductivity and/or ppm of TDS. For detailed information regarding the relationship between conductivity and TDS, please see the MyronL Application Bulletin: Standard Solutions and Buffers.

pH
pH, the measurement of acidity or basicity, is one of the most important factors affecting scale formation or corrosion in a boiler or cooling system. The types of impurities comprising the mineral concentration behave differently at various pHs. Low pH waters have a tendency to cause corrosion, while high pH waters may cause scale formation.

Boiler water
Boiler water requirements can range from very pure to more than 6500 microsiemens, depending on size, pressure, application, and feedwater. Once the maximum cycles of concentration has been established, a conductivity instrument can conveniently help you to determine if the blowdown schedule is adequate. Samples should be cooled to at least 160F/71C to ensure accurate temperature compensated readings.

Water Quality Instrumentation


Accuracy Reliability Simplicity

Boiler condensate
Boiler condensate samples are often tested to determine if there are any carryover of boiler water solids or contaminants entering from outside the system. Condensate is relatively pure water, and values of 2-100 microsiemens are common. Because of these low values, a multiple-range instrument is recommended to increase the resolution and accuracy of the reading. Monitoring the pH of condensate is also important since condensate is very corrosive at low pHs. Treatment additives are often added to elevate the pH to minimize corrosion in condensate lines.

can cause rapid scaling of heat exchangers.

Biological growth
Biological growth is another extremely important facet to proper cooling water management. Microbes can cause corrosion, fouling, and disease. Oxidizing biocides (chlorine, chlorine dioxide, ozone and bromine) have been employed to keep bacteria under control. Monitoring of the ORP (Oxidation Reduction Potential)/REDOX is very useful in its ability to correlate millivolt readings to sanitization strength of the water. The Ultrameter 6PIIFCE and the 9PTK include this parameter for quick on-site determinations. The following tables list recommended MyronL instruments for boilers and cooling towers. For additional information, please refer to MyronL data sheets, visit our website at www.myronl.com, or contact us by phone, fax, or email ([email protected]).

Cooling tower water


Cooling tower water has become more challenging since the reduced use of acid and the elimination of chromate. Monitoring conductivity and pH has become imperative to maintain a proper treatment program. Although many systems have controls on these parameters, the possibility of a system upset is always present. Even slight upsets APPLICATION BOILERS Make-up/Feedwater Blowdown Condensate COOLING TOWERS PRETREATMENT Reverse Osmosis Deionization Biological Growth

ULTRAPEN Ultrameter DS Meter pDS Meter TechPro II PT1 PT2 9PTK 4PII 6PIIFCE TH1 TP1 TPH1 M6/PH EP11/PH 512M5 EP-10 EP

X X X X X

X X X X X X

X X X X X X X

X X X X X X

X X X X X X X
726II Analog Monitor

X X X X X

X X X X X X

X X X X X X

X X X

X X X X X

X X X

X X X X X

X X X X X X

APPLICATION
BOILERS
Make-up/Feedwater Condensate Blowdown

721II Analog Monitor

723II 722II Digital Analog Controller Controller

pH

724II Digital Monitor

727II 728II Analog Digital Controller Controller

ORP

729II Digital Monitor

756II Analog Monitor

757II 758II Analog Digital Controller Controller

Conductivity/TDS

759II Digital Monitor

X X X X X X X X X X X

X X X X X

X X X X X X X X X X X

X X X X X

PRETREATMENT Deionization

Reverse Osmosis

X X

COOLING TOWERS
Biological Control

MyronL Company pH/ORP and Conductivity/TDS in-line Monitor/controllers are available for continuous in-line water quality control. Contact us or your local Distributor with your requirements.

2450 Impala Drive Carlsbad, CA 92010-7226 USA Tel: +1-760-438-2021 Fax: +1-800-869-7668 / +1-760-931-9189 www.myronl.com
Printed in U.S.A.

Built On Trust. Founded in 1957, the MyronL Company is one of the worlds leading manufacturers of water quality instruments. Because of our commitment to product improvement, changes in design and specifications are possible. You have our assurance any changes will be guided by our product philosophy: accuracy, reliability, and simplicity.
MyronL Company 2012 BCTAB 05-12

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