MATERIAL SAFETY DATA SHEET 3M Bondo Fiberglass Resin Liquid Hardener, 20126 11/09/12

Material Safety Data Sheet

Copyright, 2012, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: 3M Bondo Fiberglass Resin Liquid Hardener, 20126 MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000

EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 11/09/12 Supercedes Date: 06/26/12 Document Group: 24-8528-2 Product Use: Intended Use: Specific Use:

Automotive Curing Agent

SECTION 2: INGREDIENTS
Ingredient
DIMETHYL PHTHALATE METHYL ETHYL KETONE PEROXIDE 2,2,4-TRIMETHYL-1,3-PENTANEDIOL DIISOBUTYRATE METHYL ETHYL KETONE HYDROGEN PEROXIDE WATER

C.A.S. No.
131-11-3 1338-23-4 6846-50-0 78-93-3 7722-84-1 7732-18-5

% by Wt
30 - 60 15 - 40 10 - 30 1- 5 0.5 - 1.5 0.5 - 1.5

SECTION 3: HAZARDS IDENTIFICATION

3.1 EMERGENCY OVERVIEW
Odor, Color, Grade: Slight odor. Clear. General Physical Form: Liquid Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. May cause chemical eye burns. May cause severe skin irritation. May cause chemical gastrointestinal burns. May cause target organ effects.

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MATERIAL SAFETY DATA SHEET 3M Bondo Fiberglass Resin Liquid Hardener, 20126 11/09/12

3.2 POTENTIAL HEALTH EFFECTS

Eye Contact: Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Skin Contact: Severe Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Prolonged or repeated exposure may cause: Dermal Effects: Signs/symptoms may include changes in skin pigmentation and/or coloration. Inhalation: May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Ingestion: May be harmful if swallowed. Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain; nausea; vomiting; and diarrhea; blood in the feces and/or vomitus may also be seen. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness.

SECTION 4: FIRST AID MEASURES

4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention.

SECTION 5: FIRE FIGHTING MEASURES

5.1 FLAMMABLE PROPERTIES
Autoignition temperature Flash Point Flammable Limits(LEL) No Data Available > 200 F [Test Method: Closed Cup] [Details: No flash to boiling point.] No Data Available

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MATERIAL SAFETY DATA SHEET 3M Bondo Fiberglass Resin Liquid Hardener, 20126 11/09/12

Flammable Limits(UEL)

No Data Available

5.2 EXTINGUISHING MEDIA

Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).

5.3 PROTECTION OF FIRE FIGHTERS

Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Water may be used to blanket the fire. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Avoid contact with incompatible materials listed in the Reactivity Data Section. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Place in a metal container approved for use in transportation by appropriate authorities. The container must be lined with polyethylene plastic or contain a plastic drum liner made of polyethylene. Dispose of collected material as soon as possible. Clean-up methods Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Cover spill area with a fire-extinguishing foam. An aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible using non-sparking tools. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Seal the container. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations.

SECTION 7: HANDLING AND STORAGE

7.1 HANDLING
Avoid eye contact. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid breathing of vapors, mists or spray. Avoid skin contact. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Avoid breathing of dust created by cutting, sanding, grinding or machining. Avoid contact with oxidizing agents.

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MATERIAL SAFETY DATA SHEET 3M Bondo Fiberglass Resin Liquid Hardener, 20126 11/09/12

7.2 STORAGE
Store away from acids. Store away from heat. Store out of direct sunlight. Keep container tightly closed. Store away from oxidizing agents. Store in a cool, dry place.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 ENGINEERING CONTROLS
Provide appropriate local exhaust for cutting, grinding, sanding or machining. Use in a well-ventilated area. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment.

8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)

8.2.1 Eye/Face Protection Avoid eye contact. Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Indirect Vented Goggles . 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Nitrile Rubber Polymer laminate . 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Full facepiece supplied-air respirator Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.

8.3 EXPOSURE GUIDELINES

Ingredient
DIMETHYL PHTHALATE DIMETHYL PHTHALATE HYDROGEN PEROXIDE HYDROGEN PEROXIDE METHYL ETHYL KETONE METHYL ETHYL KETONE METHYL ETHYL KETONE METHYL ETHYL KETONE PEROXIDE

Authority
ACGIH OSHA ACGIH OSHA ACGIH ACGIH OSHA ACGIH

Type
TWA TWA TWA TWA TWA STEL TWA CEIL

Limit
5 mg/m3 5 mg/m3 1 ppm 1.4 mg/m3 200 ppm 300 ppm 590 mg/m3 0.2 ppm

Additional Information

SOURCE OF EXPOSURE LIMIT DATA:

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MATERIAL SAFETY DATA SHEET 3M Bondo Fiberglass Resin Liquid Hardener, 20126 11/09/12

ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Odor, Color, Grade: General Physical Form: Autoignition temperature Flash Point Flammable Limits(LEL) Flammable Limits(UEL) Boiling Point Density Vapor Density Vapor Pressure Specific Gravity pH Melting point Solubility In Water Solubility in Water Evaporation rate Hazardous Air Pollutants Volatile Organic Compounds Volatile Organic Compounds Kow - Oct/Water partition coef Percent volatile VOC Less H2O & Exempt Solvents Viscosity Slight odor. Clear. Liquid No Data Available > 200 F [Test Method: Closed Cup] [Details: No flash to boiling point.] No Data Available No Data Available 244 F 1.128 g/ml No Data Available No Data Available 1.128 [Ref Std: WATER=1] No Data Available No Data Available No Data Available Negligible No Data Available 43.0 % weight [Test Method: Calculated] 903 g/l [Test Method: calculated SCAQMD rule 443.1] 80.0 % weight [Test Method: calculated per CARB title 2] No Data Available 9.7 % weight 913 g/l [Test Method: calculated SCAQMD rule 443.1] No Data Available

SECTION 10: STABILITY AND REACTIVITY

Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid Light Sparks and/or flames Temperatures above the boiling point 10.2 Materials to avoid Strong oxidizing agents Alkali and alkaline earth metals Strong acids Hazardous Polymerization: Hazardous polymerization will not occur.

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MATERIAL SAFETY DATA SHEET 3M Bondo Fiberglass Resin Liquid Hardener, 20126 11/09/12

Hazardous Decomposition or By-Products

Substance
Carbon monoxide Carbon dioxide

Condition
During Combustion During Combustion

SECTION 11: TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components.

SECTION 12: ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION CHEMICAL FATE INFORMATION

SECTION 13: DISPOSAL CONSIDERATIONS

Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. EPA Hazardous Waste Number (RCRA): D001 (Ignitable), D003 (Reactive), D035 (Methyl ethyl ketone) Since regulations vary, consult applicable regulations or authorities before disposal.

SECTION 14:TRANSPORT INFORMATION

ID Number(s): 60-4550-6834-0, 70-0080-0319-9 For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501.

SECTION 15: REGULATORY INFORMATION

US FEDERAL REGULATIONS
Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No

Reactivity Hazard - No

Immediate Hazard - Yes

Delayed Hazard - Yes

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient
DIMETHYL PHTHALATE

C.A.S. No
131-11-3

% by Wt
30 - 60

STATE REGULATIONS
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MATERIAL SAFETY DATA SHEET 3M Bondo Fiberglass Resin Liquid Hardener, 20126 11/09/12

Contact 3M for more information.

CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA. The components of this product are listed on the Canadian Domestic Substances List. Contact 3M for more information.

INTERNATIONAL REGULATIONS
Contact 3M for more information. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: OTHER INFORMATION

NFPA Hazard Classification
Health: 3 Flammability: 1 Reactivity: 1 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

HMIS Hazard Classification

Health: 3 Flammability: 1 Reactivity: 1 Protection: X - See PPE section. Hazardous Material Identification System (HMIS) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS ratings are to be used with a fully implemented HMIS program. HMIS is a registered mark of the National Paint and Coatings Association (NPCA).

Reason for Reissue: The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format. The potential hazards of the product have not changed. We encourage you to reread the MSDS and review the information. Revision Changes: Section 13: Waste disposal method information was modified. Section 13: EPA hazardous waste number (RCRA) information was modified. Section 8: Respiratory protection - recommended respirators was modified. Section 8: Respiratory protection - recommended respirators guide was modified. Section 6: Personal precautions information was modified. Section 6: Environmental procedures information was modified. Section 6: Methods for cleaning up information was modified. Section 8: Respiratory protection - recommended respirators punctuation was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. _________________________________________________________________________________________________ Page 7 of 8

MATERIAL SAFETY DATA SHEET 3M Bondo Fiberglass Resin Liquid Hardener, 20126 11/09/12

In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M

3M USA MSDSs are available at www.3M.com

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