Report Date : 27/10/2010 REVISION DATE: OCTOBER 2010

MATERIAL SAFETY DATA SHEET SILICONE MOULD RELEASE

SILICONE MOULD RELEASE DAS400 [EDAS400] Manufacture of electrical equipment HK WENTWORTH-AMERICA PO 279, Ramsey, NJ 07446 USA
MANUFACTURER

EMERGENCY TELEPHONE IDENTIFICATION No.

Call Infotrac-24 hr number 1-800-535-5053 in USA, Canada and Puerto Rico +1-352-323-3500 (Outside USA) 1950

ELECTROLUBE. A division of HK WENTWORTH LTD ASHBY PARK, COALFIELD WAY, ASHBY DE LA ZOUCH, LEICESTERSHIRE LE65 1JF UNITED KINGDOM +44 (0)844 375 9700 +44 (0)844 375 9799 [email protected]

2 HAZARDS IDENTIFICATION

EMERGENCY OVERVIEW
Aerosol Colorless liquid Stable under normal temperature conditions. Fire creates: Vapors/gases/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). HIGHLY FLAMMABLE! Irritating to skin. Vapours may cause drowsiness and dizziness. Keep away from sources of ignition - No smoking. Do not breathe vapour/spray. Avoid contact with skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves. Use only in well-ventilated areas. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Move the exposed person to fresh air at once. Keep the affected person warm and at rest. Get prompt medical attention. No hazard in normal industrial use.
ENVIRONMENT

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. Use appropriate containment to avoid environmental contamination. Avoid release to the environment. Refer to special instructions/safety data sheets. Dispose of waste and residues in accordance with local authority requirements.
PHYSICAL AND CHEMICAL HAZARDS

Aerosol containers can explode when heated, due to excessive pressure build-up. When sprayed on a naked flame or any incandescent material the aerosol vapors can be ignited.
INHALATION

POTENTIAL HEALTH EFFECTS

High concentrations of vapors may irritate respiratory system and lead to headache, fatigue, nausea and vomiting. Vapors may cause headache, fatigue, dizziness and nausea. Prolonged inhalation of high concentrations may damage respiratory system.
SKIN CONTACT

Irritating to skin. May cause allergic contact eczema. Product has a defatting effect on skin. Prolonged contact may cause dryness of the skin.
EYE CONTACT

Irritating to eyes. Inhalation:

ROUTE OF ENTRY CARCINOGENICITY

This substance has no evidence of carcinogenic properties. 3 COMPOSITION/INFORMATION ON INGREDIENTS

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Report Date : 27/10/2010 REVISION DATE: OCTOBER 2010

SILICONE MOULD RELEASE

BUTANE WHITE SPIRIT ISOBUTANE d-LIMONENE

203-448-7 265-151-9 200-857-2 227-813-5

106-97-8 64742-49-0 75-28-5 5989-27-5

30-60% 10-30% 10-30% < 1%

Ingredients not listed are classified as non-hazardous or at a concentration below reportable levels 4 FIRST-AID MEASURES
NOTES TO THE PHYSICIAN

Treat symptomatically
INHALATION INGESTION

Move the exposed person to fresh air at once. Keep the affected person warm and at rest. Get prompt medical attention. Rinse mouth thoroughly. Provide rest, warmth and fresh air.
SKIN CONTACT EYE CONTACT

Wash the skin immediately with soap and water. Get medical attention if any discomfort continues. Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues. 5 FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA

Use: Powder. Dry chemicals, sand, dolomite etc. Water spray, fog or mist.
SPECIAL FIRE FIGHTING PROCEDURES

Containers close to fire should be removed or cooled with water. Use water to keep fire exposed containers cool and disperse vapours.
UNUSUAL FIRE & EXPLOSION HAZARDS

LOWER(%) FLAMMABILITY LIMIT - UPPER(%) FLASH POINT (C)

Aerosol cans may explode in a fire. FLAMMABILITY LIMIT 1.9 9.5 <40 (104 F) CC (Closed cup).

6 ACCIDENTAL RELEASE MEASURES

Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Absorb in vermiculite, dry sand or earth and place into containers. 7 HANDLING AND STORAGE
HANDLING

Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact.
STORAGE

Aerosol cans: Must not be exposed to direct sunlight or temperatures above 50C. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
COMPONENT STD TWA (8-hrs) STEL (15 min) Notes

BUTANE ISOBUTANE

ACGIH ACGIH

1000 ppm 1000 ppm

ACGIH=American Conference of Governmental Industrial Hygienists. PROTECTIVE EQUIPMENT

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SILICONE MOULD RELEASE

ENGINEERING MEASURES

All handling to take place in well-ventilated area. Provide adequate ventilation. Observe Occupational Exposure Limits and minimize the risk of inhalation of vapors.
RESPIRATORY EQUIPMENT HAND PROTECTION

In case of inadequate ventilation and work of brief duration, use suitable respiratory equipment. Use suitable protective gloves if risk of skin contact. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material.
EYE PROTECTION

Wear approved, tight fitting safety glasses where splashing is probable.

Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapor contact.
HYGIENE MEASURES

DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. When using do not eat, drink or smoke. 9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE COLOR ODOR VOLATILITY DESCRIPTION SOLUBILITY BOILING POINT (C) FLASH POINT (C)

Aerosol Liquid Colorless Odorless Volatile. Insoluble in water 55 (131 F) <40 (104 F) CC (Closed cup).
RELATIVE DENSITY

0.750 @ 20 C (68 F)

10 STABILITY AND REACTIVITY

Stable under normal temperature conditions.

Avoid heat, flames and other sources of ignition. Avoid contact with: Strong oxidizing agents. Strong alkalis. Strong mineral acids.
HAZARDOUS DECOMPOSITION PRODUCTS

Fire creates: Vapors/gases/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). 11 TOXICOLOGICAL INFORMATION
Name Toxic Conc. - LC 50 Name Toxic Dose 1 - LD 50 Name Toxic Dose 1 - LD 50

BUTANE 658 mg/l/4h (inh-rat) d-LIMONENE >5000 mg/kg (oral rat) WHITE SPIRIT >5000 mg/kg (oral rat)

12 ECOLOGICAL INFORMATION
ECOTOXICITY

Dangerous for the environment if discharged into watercourses. Name d-LIMONENE

12.3

The product has poor water-solubility.

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Report Date : 27/10/2010 REVISION DATE: OCTOBER 2010

SILICONE MOULD RELEASE

Empty containers must not be burned because of explosion hazard. Dispose of waste and residues in accordance with local authority requirements. 14 TRANSPORT INFORMATION

DOT PROPER SHIPPING NAME TDG SHIPPING NAME IDENTIFICATION No. CEFIC TEC(R) NO. U.S DOT HAZARD LABEL IMDG CLASS EMS MARINE POLLUTANT AIR CLASS TDG CLASS

AEROSOLS, FLAMMABLE, (EACH NOT EXCEEDING 1 L CAPACITY) AEROSOLS, FLAMMABLE, (EACH NOT EXCEEDING 1 L CAPACITY) 1950 20G5F Flammable Gas 2.1 F-D, S-U No. 2.1 2.1
TUNNEL RESTRICTION CODE DOT HAZARD CLASS UN NO. SEA IMDG PACK GR. MFAG UN NO. AIR AIR PACK GR. TDG LABEL(S)

(D) 2.1 1950 # See Guide 1950 # 2.1

15 REGULATORY INFORMATION
INVENTORIES COMPONENT CAN US EU AUS JAP KOR CHN PHLP

BUTANE ISOBUTANE d-LIMONENE WHITE SPIRIT

DSL DSL DSL DSL

Yes. Yes. Yes. Yes.

EINECS Yes. EINECS Yes. EINECS Yes. EINECS Yes.

Yes. Yes. Yes. Yes.

TSCA 12(b) Export Notification

BUTANE ISOBUTANE d-LIMONENE WHITE SPIRIT

No. No. No. No.

SARA 302-TPQ

CERCLA-RQ

SARA 313

BUTANE ISOBUTANE d-LIMONENE WHITE SPIRIT

Not Listed Not Listed Not Listed Not Listed

No. No. No. No.

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Report Date : 27/10/2010 REVISION DATE: OCTOBER 2010

SILICONE MOULD RELEASE

BUTANE ISOBUTANE d-LIMONENE WHITE SPIRIT

10 000 lbs 10 000 lbs Not Listed Not Listed

CA

FL

MA

MN

NJ

PA

RI

BUTANE

106-97-8

ISOBUTANE

75-28-5

d-LIMONENE

5989-27-5

WHITE SPIRIT

64742-49-0

Not Liste d Not Liste d Not Liste d Not Liste d

Not Liste d Not Liste d Not Liste d Not Liste d

Yes.

Yes. Yes.

Yes.

Yes.

Yes.

Not Liste d Not Liste d

Not Liste d Not Liste d Not Liste d

Yes.

Yes.

Not Liste d Not Liste d

Not Liste d Not Liste d

Not Liste d Not Liste d Not Liste d

REGULATORY STATUS (US)

SECTION 313: This product does not contain toxic chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR Part 372. TSCA: The ingredients of this product are on the TSCA Inventory.

WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM -WHMIS

Compressed Gas. 16 OTHER INFORMATION

Flammable Aerosol.

HAZARDOUS MATERIAL INFORMATION SYSTEM (HMIS) HEALTH FLAMMABILITY PHYSICAL PERSONAL PROTECTION NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) FIRE (2) HEALTH (1) (1) INSTABILITY SPECIAL ISSUED BY 1 2 1 B

Pawel Zmarzly
VERSION No.

REVISION DATE

OCTOBER 2010 1
5

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Report Date : 27/10/2010 REVISION DATE: OCTOBER 2010

SDS NO.

10994

SILICONE MOULD RELEASE

DISCLAIMER This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 6 /6