Lecture Tutorials on Qualitative Analysis

Group Zero (NH4+) Q.1 Fill in the blanks (i)

Water Soluble Compound (ii)

NH4 2 SO4

light blue powder

6 12 6 ____________ Gluconic acid (C6H12O7) + ___________ (glucose )

C H O

Red (iii) MgCl2 Na2 HPO4 NH 4OH

Black

(iv) Bi NO3 3 NH4OH Q.2 Q.3 Prepare Ammonia gas from lime stone economically? Given ,
NaOH (B) HCl White fumes (i) ( A) Gas

(ii) After (B) is expelled completely, resultant alkaline Solution again gives gas (B) on heating with Zinc dust.
(iii) (A)

N O H O 2 2

Identify (A) and (B)

Q.4

Identify (A) to (E). (A) + NaOH

(B) (g)
HCl

(C)(aq.) Zn

White fumes
H 2O D ( g )
Al, Heat

(E )

H O 2

(B) (g)

Q.5

Identify (A) to (G) in the following map

( E ) H 2O ( B ) ( F )
NaCl ( F ) (G) ( D)

Na CO H O ( B) (G) 2 3 2

Q.6 Colourless salt (A), on heating with NaOH gave gas (B) that can also be obtained by hydrolysis of Mg3N2. When reaction of (A) with NaOH was complete, solution obtained on reaction with FeSO4 and conc. H2SO4 gave a brown coloured ring (C) between two layers. (A) on heating (strongly) form (D) & (E). (E) is a neutral oxide of dibasic acid (F) that exists as cis & trans isomer . Identify (A) to (F).

Q.7 (i) An orange coloured Compound (A) on heating gives a gas (B) and green residue (C).

(ii) (A) On reaction with NaOH gives a gas (D) which on reaction with HCl gives dense white fumes. (iii) (B) on reaction with Mg powder gives a compound (E) which on reaction with water produces gas (D). Identify (A) to (D). (iv) Green residue on reaction with Conc. HCl gives compound (F) which on reaction with H2O2 in presence of alkali gives yellow Solution (G) (v) (G) on reaction with lead acetate /sugar of lead acidified with acetic acid produces a yellow ppt. (H) Identify (F), (G) and (H) also.

Q.8 (i) A colourless salt (A), soluble in water, gives a mixture of three gases (B), (C) and (D) along with water vapors on strong heating. (ii) (B) is blue, (C) is red and (D) is neutral toward litmus paper. (iii) Gas (B) is also obtained when (A) is heated with NaOH and gives brown ppt with K2HgI4. Residual solution after removal of gas gives white ppt (E) with CaCl2 Solution in presence of CH3COOH. (E) also decolourizes acidified KMNO4. (iv) Gas (C) turns lime water milky and gas (D) burns with blue flame and is fatal when inhaled. Identify (A) to (E).

Group- I (Ag+, Hg2+2, Pb+2) Q.1 Complete the following reactions. (i) AgNO3 + C2H2 + NH4OH (ii) Hg2Cl2 + NaOH __________________________

_________+ NaCl + H2O

_____________ (Black) (iii) Hg2Cl2 + HNO3 (iv) Pb3O4 + HNO3 _____________________ ______________________

_______________________ (v) (CH3COO)2Pb

Q.2 (i) Why Mercurous ion is Hg2+2 where as cuprous ion is Cu+ ? (ii) The Solubility of lead in soft water is known as plumbsolvancy. It doesnt occur in hard water, why? Q.3 One rupee coin contains some amount of silver, suggest a suitable method to get this silver from the coin? Q.4 (i) A black mineral (A) on treatment with dilute NaCN solution in presence of air gives clear solutions of (B) and (C) (ii) Solution of (B) on reaction with Zn gives a ppt of metal (D). (iii) (D) dissolve in dill HNO3 and resulting solution gives with ppt. (E) with dilute HCl (iv) (E) on fusion with Na2CO3 gives (D). (v) (E) dissolves aq. Solution of Ammonia giving a colourless solution of (F). Identify (A) to (F)?

Q.5 A colourless salt (X) is soluble in water and alcohol. On heating, (X) gives brown gas (Y) and grey solid. (X) dissolves in ammonia to give solution (Z). (Z) gives silver mirror with aldehydes. A solution of (X) is easily reducible by ferrous salts. The solution of (X) gives brick red ppt. with K2CrO4. Identify (X), (Y) and (Z)? Q.6
(A) (B) + (C) (A) is a metal carbonate which can form basic metal carbonate by suitable reactions. (B) is amphoteric oxide, often used for making glass paints and varnishes. (C) is a gas, changes colour of phenolphthalein from orange to colorless.

Identify (A), (B) and (C)? Q.7 (i) A colourless salt (A) on heating gives cracking noise and with conc. H2SO4 and freshly prepared FeSO4 solution , gives a brown ring. (ii) (A) on reaction with dilue HCl gives a white ppt. (B) which becomes soluble in hot water. (iii) (B) on reacton with KI gives a yellow ppt. of (C). Identify (A) to (C)?

Q.8 (i) A scarlet red compound (A) is treated with Conc. HNO3 and produces a chocolate brown ppt (B). (ii) Filtrate of (B) on warming with KI in presence of KOH gives yellow ppt. (C) and also, (B) on reaction with chromium hydroxide in alkaline medium produces a yellow ppt (D). (iii) The ppt (B) on reaction with Conc. HNO3 in presence of MnO2 produces a pink coloured solution due to formation of (E). Identify (A) to (E)? Q.9 Two salt (A) & (B) undergo following reactions

(i) Both (A) and (B) respond to ring test and when rubbed on copper coin, a white deposit is formed on coin surface. (ii) aq. solution of (B) reacts with NaCl Solution to give white ppt (C) which on reaction with aq. NH3 gives another ppt. (C1). (C) dissolves in aqua regia to give a solution of (C2) compound. (C2) gives white ppt. with AgNO3 solution. (C) also reacts with SnCl2 to give a grey ppt. which dissolves in dilute HNO3 to give (B).

(iii) Compound (A) doesnt react with NaCl solution but in presence of dil. HCl and on passing H2S gas gives a black ppt. (D) . Compound (D) dissolves in aqua regia to give (C2) which reacts with SnCl2 to give white ppt., which reacts with excess SnCl2 to give a grey ppt (E). (iv) Aq. solution of (B) reacts with NaOH to give a black ppt. (F) which on boiling charges to grey (G). (B) reacts with K2CrO4 to give red ppt. (H). Identify (A) to (H) and write all the reactions involved.

Group- II Q.1 Fill in the blanks (i) HgCl2 + Hg (ii) HgCl2 + KI

Excess KI _______________

(iii) Cu(NO3)2 + KI
(A)

(A) (B) + (C)

+ KNO3

Brown (B) + excess KI

Violet solid _______________ yellow Complex

(C) + KI

_________________(Orange) _______________ _______________

(iv) BiCl3 + excess Na2S2O3 (v) BiCl3 + cold H2O

_________(Brown) + H O (vi) Bi(OH)3 2

Q.2 (i) In qualitative analysis of II group, when H2S is passed with dil. HCl, We got yellowish turbidity? What can be concluded from this and what precautions we should take to avoid this? (ii) Why Pb+2 is included in both groups I & II of qualitative analysis? Q.3 A black coloured solid (A) doesnt dissolve In dilute HNO3 but dissolve in aqua regia to form (B). (B) gives orange ppt. (C) with KI. (C) dissolves in excess KI forming (D). (D) gives brawn ppt. (E) with ammonium salts in presence of NaOH. (A) is precipitated if H2S gas is passed into solution of (B) in dilute HCl. Identify (A) to (E). Q.4 (i) A blue coloured compound (A) on heating gives two products (B) and (C). (ii) A metal (D) is deposited on passing hydrogen through heated (B). (iii) The solution of (B) in HCl on treatment with K4[Fe(CN)6] gives a chocolate brown coloured ppt of compound (E). (iv) (C) turns are water milky which disappears on continuous passage of (C) forming a compound (F). Identify (A) to (F)?

Q.5 (i) An inorganic halide (A) on reaction with H2S in acidic medium gives a black ppt (B) (ii) (B) dissolves in hot dilute HNO3 to give a solution (C). (C) gives ring test. (iii) When NH4OH solution is added to ppt (C), ppt (D) is formed. (D) dissolves in minimum amount of dilute HCl and gives solution of (A) (iv) Aq. solution of (A) on addition of water gives white turbidity of (E). Identify (A) to (E). Q.6 (i) A metal (M) shows two types of oxidation states. (ii) Dry air have no effect on (M) but in presence of most air, it reacts slowly to form its basic metal carbonate (A). (iii) (M) reacts with oxygen to form a black oxide (B) and red oxide (C).

One chloride of (M), which has corresponding oxidation state of (M) as that of (B), gives chromyl chloride test. (iv) Metal sulphate (D) on reaction with NH4OH gives a blue colour compound (E). (v) Metal nitrate (F) on reaction with K4[Fe(CN)6] gives a chocolate brown ppt (G). (vi) Metal nitrate (F) on reaction with dilute HCl and H2S gas gives black ppt. (H). Identify (A) to (H) and Metal (M)?

Group III (Al+3, Fe+3, Cr+3) Q.1 Fill in the blanks (i) FeCl3. 6H2O

(ii) FeCl3. 6H2O + SOCl2

(vi) Al (OH)3 + NaOH (vii) Al (OH)3 + NH4OH (viii) Cr (OH)3 + NaOH

(ix) Cr (OH)3 +NaOH + Br2 water

Q.2 (i) Light green solution of (A) gives blue Colour Compound (B) on reacting with K3[Fe(CN)6]. (ii) (A) doesnt give any reaction with K4[Fe(CN)6] but on adding drops of HNO3, blue ppt.(C)is observed. (iii) (A) also gives a white ppt (D) with Ag NO3 solution which is completely soluble in aq.ammonia. Identify (A) to (D)?

Q.3 (i) A yellow colored solution (A) changes to light green coloured solution (B) on passing H2S gas into it. (ii) We can also get (B) from (A) by passing hypo to solution of (A) or by reacting with Zinc Powder. (iii) (A) gives blue coloured ppt. with K4[Fe(CN)6] but (B) doesnt. (iv) Both (A) & (B) gives chromyl chloride tests. Identify (A) & (B)? Q.4 (i) (A) on reacting with NaOH gives a compound (B) which is soluble in NaOH forming (C). (ii) (A) on reacting with NH4OH gives two white ppts (D) & (B). (D) gives white fumes but (B) is insoluble in NH4OH. (iii) (A) shows sublimation property and also exists as dimer. Identify (A) to (D)? Q.5 An inorganic Compound (A) in its aqueous solution produces white ppt with NaOH , which dissolves in excess of NaOH. The aqueous solution of (A) also produces white ppt. with NH4OH, which doesnt dissolved in excess of NH4OH. Also, its aqueous solution produces light yellow ppt. (B) with Ag NO3 Solution which is soluble in dilute HNO3 and partially soluble in aq. NH3. Identify (A) & (B)? Q.6 (i) A hydrated metallic salt (A), light green in colour, gives a white anhydrous residue (B) after being heated gradually. (ii) (B) reacts with NO to form a dark brown Compound (C). (iii) (B) on strong heating gives a brown residue (D) and mixture of two gases (E) and (F). (iv) (F) can decolourise acidified purple KMnO4 but (E) cannot. (v) (B) when passed through BaCl2 solution , gives a white ppt. (G). Identify (A) to (G)? Q.7 (i) A black mineral (A) on heating in presence of air gives a gas (B). (ii) (A) on reaction with dilute H2SO4 gives a gas (C) which changes the colour of lead acetate paper into black. (iii) Sodium carbonate extract of solution of (A) gives purple colouration to sodium nitro prusside solution give rise to a compound (D).

(iv) Gas (B) & gas (C) on reaction gives a yellowish turbidly of (E) . (v) Solution of mineral of (A) gives a blue colour compound (F) with potassium ferricyanide solution. Identify (A) and (F)? Group IV (Co+2, Ni+2, Mn+2, Zn+2) Q.1 Fill in the blanks (i) Zn + dilute H2SO4 __________________ (ii) Zn + Conc. H2SO4 __________________
__________________ (iii) Zn + Cold & Very dilute HNO3
__________________ (iv) Zn + hot & dilute HNO3 __________________ (v) Zn + Cold & Conc. HNO3 __________________ (vi) Zn + hot & Conc. HNO3 ________________( White ppt.) (vii) ZnCl2 + K4[Fe(CN)6]

+ KCl

Excess K4[Fe(CN)6] ___________________

+ NH4Cl

Excess NH4OH ___________________

Add excess NH4OH after removal of NH4Cl ___________________

 (ix) ZnCl2.2H2O __________________ _____________ + HCl (x) ZnSO4.7H2O _____________ ______________ _______________

______________ (Rinmanns green) (xi) CoO + ZnO ______________ (Cobalt pink) (xii) CoO + MgO ______________ (Cobalt green) (xiii) CoO + SnO ______________ (Thenard blue) (xiv) CoO + Al2O3

Q.2 Give Reason for (A) Why does zinc becomes dull in most air? (B) Zinc is used in galvanizing of iron, why? (C) ZnO is used as a white paint in spite of the fact it has less converging power than white lead, why? Q.3 (i) A white amorphous powder (A) when heated gives a colourless gas (B) which turns lime water milky and the residue (C) which is yellow when hot but white when cold. (ii) The residue (C) dissolves in dilute HCl give rise to compound (D). (D) gives white ppt. (E) with K4[Fe(CN)6] solution which on further reaction with K4[Fe(CN)6] gives a compound (F). (iii) The solution of (A) on addition of excess NH4OH and passing H2S gas gives white ppt. (G) (iv) Solution of (A), on addition of NaOH gives white ppt (H) which dissolves in excess of it. Identify (A) to (H)? Q.4 (i) A powdered substance (A) on treatment with fusion mixture gives a green coloured compound (B). (ii) The solution of (B) on acidification with hot dilute H2SO4 gives a pink/purple coloured Compound(C). (iii) The aqueous solution of (A) on treatment with excess of NaOH & bromine water gases a compound (D).

(iv) A solution (D) in conc. HNO3 with PbO2 produces a Compound (E) which is of the same colour of (C). (v) A solution of (A) on treatment with BaCl2 gave a white ppt of Compound (F). Identify (A) to (F)? Group V (Ca+2, Sr+2, Ba+2) Q.1 Fill in the blanks
__________________ (i) CaOCl2

(ii) CaOCl2 __________________

CoCl2

____________________ (iv) CaOCl2 + CO2

Q.2
(A)

(B) residue H2O

+ (C) gas

+ (D) gas

colourless

( D) (E)

milky

(A) gives brick red colour in flame and decolorizes acidified permanganate solution and gas (C) burns with blue flame. Identify (A) to (E)? Q.3 A certain Compound (A) gives brick red flame on performing the flame test and also : (i) when KI is added to an aq. solution of (A) containing acetic acid, iodine is liberated. (ii) when CO2 is passed through aq. solution of (A), turbidity transforms into a precipitate. (iii) when a paste of (A) with water is heated with ethyl alcohol, then a product of anesthetic use is obtained. Identify (A) and write all the reactions.

Group VI (Mg+2)

air (X) Q.1 Mg ribbon

+ (Y) H2O

Bleaching (Z) (gas) (W) (gas) powder

Identify (X), (Y), (Z) , and (W). Q.2

(C)

(i) (A) is metal carbonate , generally if we heat metal with Na2CO3 & water , we get basic metal carbonate of this metal (ii) (B) is metal oxide , basic in nature , has melting point around 28000C, it is used in basic lining in furnaces. (iii) (C) is a gas which turns lime water milky. Identify (A), (B) and (C). Additional questions on important reagents Q.1 Pyrolusite ore (MnO2) on heating with KOH in presence of air gives a dark green coloured compound (A). The solution of (A) on treatment with H2SO4 gives a purple coloured Compound (B), which can be decoloured by SO2 or H2S gas. Identify (A) and (B). Q.2 When a white crystalline Compound (A) is heated with K2Cr2O7 and conc. H2SO4, an

orange red gas (B) is evolved. On passing gas (B) into caustic soda solution, a yellow coloured solution of (C) is formed. Neutralizing the solution of (C) with acetic acid and on subsequent addition of lead acetate, a yellow ppt. of (D) is obtained. When (A) is treated with NaOH solution, a colourless gas (E) is evolved and on passing this gas into K2HgI4 solution, a reddish brown ppt. of (F) is formed . Identify (A) to (F).

Q.3

A peroxide (A) on reaction with an acid (B) gives a ppt. (C) and compound (D). (C) is

decomposed by dilute sulphuric acid to give a white ppt. (E) and tribasic acid (B) again. Solution of (A) in water on passing a current of CO2 produces white ppt (F) and Compound (D). (F) after dissolving in dilute acetic acid produces white ppt (E) on reaction with (NH4)2 SO4. (E) & (F) impart apple green colour to flame. Identify (A) to (F). Q.4 (i) Sodium salt of an acid (X) is formed on boiling white phosphorous with NaOH solution. (X) can be a reducing agent also. (ii) On passing chlorine through phosphorus kept under fused water, another acid (B) is formed, which on strong heating gives meta phosphorus acid (HPO2)n (iii) Phosphorus on treatment with conc. HNO3 gives an acid (Z), which is also formed by action of dilute H2SO4 on powered phosphorite rock Ca3(PO4)2. Identify (X), (Y) and (Z).