MOC Approach For Open Cooling Water System
MOC Approach For Open Cooling Water System
2011]
SM
Agenda Mechanical
Cooling tower Heat exchanger Metallurgy
Operation
pH Cycle
Chemical
Makeup water chemistry
SM
SM
Cooling Tower
Essential Expertise for Water, Energy and Air SM
SM
Why cooling is important? Cooling tower performance provide significant contribution to the plant performance and efficiency Poor cooling tower performance could limit the plant production
SM
A 3 C (5.4 F) increase in approach temperature (on all stages) is equivalent to a 1% increase in energy consumption
SM
SM
SM
SM
SM
10
SM
11
Tower Fill
SM
12 12
Fill Characteristics
SPLASH
EFFICIENCY Medium
FILM
High
DURABILITY FOULING
Medium Low
Low/Medium High
SM
13
Problems with Film Fill Easily fouled with microbio and solids Hard to clean once fouled Quick loss of efficiency
Tower Fill
SM
14
Factors Affecting Cooling Tower Performance Wet bulb temperature Dry bulb temperature Plant (heat) load
Cooling water T
Air flow
Fan (tip, angle, motor; etc)
SM
15
A measurement of the lowest temperature that can be achieved by evaporative cooling of a water wetted ventilated surface.
Sling Psychrometer
SM
16
37 35 33 31
TYPICAL L/G
L/G = 2.0 L/G = 1.5
L/G < 1, TOWER OVERSIZED
PERFORMANCE CURVES
L/G = 1.0
29 27 25 12 14 16 18 20 22 24 26 WET BULB TEMPERATURE, OC
- TURN OFF FANS OR DOWNSIZE L/G > 2.5, TOWER UNDERSIZED AND WILL NOT PROVIDE LOW APPROACH TEMPERATURES
SM
17
Air flow is a critical component to ensuring the proper heat rejection from a cooling system Many cooling tower performance issues may well be airflow problems
ROTATION
Air In-leakage From Fan Shaft Fan Stall (Incorrect Pitch)
SM
18 18
What is the Correct Way to Evaluate Cooling Tower Performance ? 1) CW temperature range (T) 2) Cooling tower heat load
M x Cp x T
19
Heat Exchanger
Essential Expertise for Water, Energy and Air SM
SM
21
22 22
Heat Exchanger What We Need to Know ? Type of heat exchangers Hydraulic, mechanical and metallurgical Mechanical stress to cooling water treatment Performance monitoring
SM
23
Type of Heat Exchangers There are several general types of heat exchangers: Shell-and-tube
Plate-and-frame
Spiral flow
SM
24 24
Shell and Tube Heat Exchanger (Water in Tube) Most common heat exchanger type found in cooling water systems Typically has adequate velocity
Throttle and spatial relationship could create problem
SM
25
A shell side heat exchanger offers challenges Low velocity High skin temperatures
SM
26
Mechanical Stresses Three main mechanical stress factors that impact the efficiency of heat transfer in heat exchanger are: 1)Cooling Water Velocity 2)Skin Temperature 3)Heat Flux
SM
27 27
Scale and fouling deposition is more prone to occur at low velocity Lower flow rate, lower turbulence that can lead to static thicker film of water at metal surfaces reduces heat transfer Lower velocity = higher skin temperature
SM
28 28
High heat flux will lead to high skin temperature Typically v 3.15 15.8 kW/ M2 v 15.8 31.5 kW/ M2 v 31.5 63.1 kW/M2
SM
29 29
Reasons:
Corrosion rates ~double for each 10C increase in metal temperature Scaling tendencies become much more pronounced at high temperature Film boiling may occur as skin temperature Some treatment chemicals break down at high temperature
SM
30 30
SM
31 31
108C
146C
115C
128C 116C
124C
101JC 127C
2002JC
SM
32
Metallurgy
Copper alloys
High thermal conductivity Sensitive to ammonia and oxidant Need film forming inhibitor
Titanium
Self passivating metal Extremely brittle with very thin walls Leaks common (especially during initial commissioning and startup) ANY mechanical impingement can cause leaks
Ammonia Grooving
Stainless Steel
Self passivating metal Subject to chloride stress corrosion Must ensure cooling water chloride level remains within limits Under-deposit corrosion, MIC issues
Pitting / MIC
Essential Expertise for Water, Energy and Air
SM
33
PLANT DATA Duty Area U Heat Flux Velocity T CW in T CW Out Process In Process Out CALCULATIO N T Skin Max T Skin 3,286,000 Btu/hr 424 ft2 Btu/hr.ft2 91.2 .C 7750 Btu/hr.ft2 6.111 ft/s 91 F 100 F 637 F 300 F
SM
34
SM
35 35
SM
36
SM
37
Cooling Water Operation What We Need to Know ? Basic mass balance calculation Cycle management Operational stress factor
SM
38
Windage
Windage
Makeup
Blowdown Loss
39 39
SM
SM
40
SM
41
SM
42 42
Holding Time Index (HTI) HTI is indicate the time required to reduce the chemical added to the system to 50% of its original concentration HTI = 0.693 x Holding Volume Blowdown Rate It is important to select the right chemical program
SM
43
Operational Stresses Variation of operational and control parameters cause stress in cooling water systems. The key examples of operational stresses as follows 1)Variation of cycle 2)Variation of pH 3)Variation of HTI
SM
44 44
Variation of Cycle
Mild Stress Moderate Stress High Stress Severe Stress Minimal effect of reliability Needs to be considered Will typically be a problem Typically a problem <20% 20-50% 50-80% > 80%
SM
45
Variation of pH
Mild Stress Moderate Stress High Stress Severe Stress Minimal effect of reliability Needs to be considered Will typically be a problem Typically a problem + 0.1 + 0.2 + 0.4 + 0.6
Control Parameter pH
STD 0.19
SM
46
Variation of HTI
Mild Stress Moderate Stress High Stress Severe Stress Minimal effect of reliability Needs to be considered Will typically be a problem Typically a problem < 40 hrs 40 - 100 hrs 100 - 200 hrs > 200 hrs
SM
47
SM
48
Cycle Management
SM
49
SM
50
SM
51
Corrosion
A natural process converting processed metals to their native states Factors affecting:
- Water chemistry - Physical environment (temperature, velocity, hydrodynamic) - Dissolved gases - Halogen or other oxidizers - Deposit
SM
52
Scale
A dense, adherent layer of minerals tightly bound to itself and to metal surface Factors influences
- pH - Minerals concentration (Ca, Mg, SiO2, Alkalinity;etc) - Temperature
SM
53
Fouling
Deposits that formed from material suspended in water (clay, silt, iron, manganese, microbiological) Factors affecting
Suspended solids concentration Hydraulic and flow velocity Spatial relationship Scale, corrosion and microbiological
SM
54
Microbio Fouling
The most prevalent problems in industrial cooling water systems A good control of microbial growth is essential if we are to control the other water chemistry problems Factors affecting:
Suspended solids Contaminants (organics, ammonia, phosphate; etc) Physical factor (velocity and hydrodynamic) pH
SM
55
General Methods for Corrosion Inhibition Use Corrosion Resistant Materials Apply Inert Barrier or Coating Use Cathodic Protection Adjustments to Water Chemistry Application of Corrosion Inhibitors
SM
56
Anodic inhibition
prevents the dissolution of the base metal, iron.
Combinations of both anodic and cathodic inhibitors generally provide the best protection. These combinations are called synergistic because the combination provides lower corrosion rates than either inhibitor could alone,
SM
57
WATER CHEMISTRY
pH
TEMPERATURE
SATURATION INDEX
PROGRAM DESIGN
VARY CYCLE
VARY pH
VARY TEMPERATURE
VARY CHEMISTRY
SM
58
SM
59
SM
60
Alkaline Zinc
Under-saturated (corrosive)
Over-saturated (Scale)
SM
61
Function of Dispersant
Prevent deposition commonly found minerals & inorganic particulates such as
Calcium phosphate Iron, Silt Zinc
SM
62
SM
63
SM
64
SM
65
Microbiological Control
The goal is not to STERILIZE the system, but to MANAGE microbial fouling to a level that minimizes mechanical, operational, and chemical problems at an acceptable cost.
SM
66 66
SM
67 67
Non-Oxidizing biocides
Organic compounds, react with cell components
enyzm enyzm
amino
Biofouling control
Quat Glut
SM
68 68
SM
69 69
Operational factor
Cycle management pH control
SM
70
Understanding the MOC enables a complete understanding of the system stresses that need to be addressed
SM
71
O Operational variables
Control is very important for getting performance. Automation is best.
C Chemical variables
Scale and corrosion modeling with programs available. Determine control limits.
SM
72
Thank You!
SM
73