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Asphalt and Asphalt

Concrete
Introduction
Asphalt and Tar Material
Engineered Asphalt Cements
Hot-mixed asphalt
Cutbacks
Emulsions
Properties of Asphalt
History
One of the oldest engineering materials
asphaltos - sticky, firm - Greek
jatu-krit - pitch creating - Latin: pixtumen
Use:
Sumerians (3000 B.C.) - building purposes
Egyptians (2500 B.C.) - mumyia - mummy
Biblical times (2500 - 1500 B.C.)
Noahs ark - waterproofing
Tower of Babel - mortar
Paving
Sources:
Natural Asphalt
Crude Oil
Bitumen and Asphalt
Bitumen: non-volatile hydrocarbon, soluble
in carbon disulfide, very complex material
structure
Coal tar, asphalt (processed oil residue)
Asphalt (combination of asphaltine, resin, oil)
Asphaltine (C/H>0.8)
Resin (0.8>C/H>0.6)
Oil (C/H < 0.6)
Specific Gravity = 0.95 1.05
Composition of Asphalt Cement

Large organic molecules of varying size and polarity


Carbon 80-87% Nitrogen 0-1%
Hydrogen 9-11% Sulfur 0.5 -7%
Oxygen 2-8% Heavy metals 0-0.5%
Heavy metals play important role

Contribute to polarity

Molecular structure very complex

Asphaltenes - largest and most polar

Resins - intermediate, also polar

Oils - smallest, paraffin -like, non -polar

Colloidal model

Asphaltenes surrounded by resins

Oils continuous medium


Asphaltenes
Resins
Oils
Refinery Operation
FIELD STORAGE TANKS
PUMPING
STATION
LIGHT
DISTILLATE
HEAVY
DISTILLATE
ASPHALT
CEMENTS
STORAGE
TOWER
DISTILLATION
RESIDUAL
CONDENSERS
AND
COOLERS
TUBE
HEATER
MEDIUM
DISTILLATE
OIL WELL
SOLVENTS
GASOLENE
JET FUEL
LUBRICANTS
HEATING OIL
Lighter molecules vaporize
Asphalt cement remains
Residual varies in consistency
Asphalt Characterization
Flash Point: temperature at which a substance will ignite with a
open flame
Rolling Thin-Film Oven: indicator of the aging effect of
short term high temperatures when producing ACC.
Viscosity: rotational viscometer measures the viscosity at a
standard temperature (135C)
Complex Shear Modulus: dynamic shear rheometer
Flexural Creep: bending beam rheometer measure creep
stiffness
Tensile Strength
Engineered Asphalt Cement
Hot mixed asphalt (pavements)
Viscous semi-solid
Flows for heating into liquid range
Cutback asphalt
Viscous liquid
Cut with oil distillates
Emulsion asphalt
Viscous liquid
Cut with water
Emulsions Asphalt Binder Liquefied with Water
-

Water - reduces viscosity

Emulsifier gives surface charge to asphalt droplets suspended


in water medium

Anionic

Negative charge

Alkaline (Basic) aggregate

Good with limestones (positive charge)

Cationic

Positive charge

Acidic aggregate

Good with silica gravels (negative charge)

Consistency controlled by amount of water

Stability controlled by choicer of emulsifier

Environmentally correct
Water
Asphalt
Binder
Properties of Asphalt Cement
Adhesion: property to connect dissimilar materials
Cohesion: property to connect similar materials
3M scotch tape is adhesive, not cohesive
Silly putty is cohesive, not adhesive
Asphalt is adhesive and cohesive
Flow properties
Consistency: measure of fluidity at a given temperature
Absolute Viscosity, poises
Kinetic Viscosity, centistokes
Penetration: empirical measure of ease to penetration
Penetration of 1 mm diameter needle.
| | s Pa poises
rate shear
stress shear
- = = 1 . 0
_
_
u
( )
3
/
viscosity Absolute
cm g density
=
Performance-Graded Asphalt Binders
Maximum
Temperature
(C)
Minimum Temperature (C)
PG 46 -34 -40 -46
PG 52
-10 -16 -22 -28 -34 -40 -46
PG 58 -16 -22 -28 -34 -40
PG 64 -10 -16 -22 -28 -34 -40
PG 70 -10 -16 -22 -28 -34 -40
PG 76 -10 -16 -22 -28 -34
PG 82 -10 -16 -22 -28 -34
As an example, a PG 64-28 is acceptable for use in a
climatic region where the maximum temperature is
64C and the minimum temperature is -28C.
Selection of Grading Temperatures
Temperature
-28 -22 -16 64 70 76 82
Given that the minimum measured air temperature for a site is -21C and
the maximum 7-day average temperature is 73C, which PG grade should
be used for this site. Here, use PG 76-22.
Pavement
Temperature
Air Temperature
Maximum 7-day
(Running Average)
Alternative Grading System
Grade Viscosity
Abs., Poises Kinetic, cStokes
Penetration Flash Point
C
AC-2.5 250 125 220 163
AC-5 500 175 140 177
AC-10 1000 250 80 219
AC-20 2000 300 60 232
AC-30 3000 350 50 232
AC-40 4000 400 40 232
Asphalt and Asphalt Concrete
Asphalt Concrete
Aggregates
Properties
Pavements
Mixture Design
Asphalt Concrete
Aggregates
clean and dry aggregates are necessary for
adhesion (no dust, no water)
interlocking nature creates internal friction
which is important to the long-term
properties of the asphalt concrete.
angular shape aggregates 50-80% with 2
angular faces
ACC: Importance of Aggregate
Asphalt cement has
no strength at
temperatures > 60C
Stability of
pavements in hot
weather is due to
internal friction in
the aggregates -40 -20 0 20 40 60
Temperature, C
M
o
d
u
l
u
s
,

P
a
Asphalt Concrete Mixtures
Mixtures of aggregate
and asphalt cement
binder
about 95% aggregate
by weight
about 75% aggregate
by volume
ideally, 3-5% air voids
Asphalt Concrete
Flexibility
high binder content
low viscosity binder
Short-term Loadings
elastic properties of binder-aggregate
matrix
Asphalt Concrete
Long-term Durability
fluid properties of binder
dry clean aggregates
water causes stripping
strong porous angular stone
durable aggregates (LA abrasion)
Asphalt Concrete
Workability: Ease in which material is
handled and laid and compacted.
poor compaction leads to deformation and
the permeability of water and air.
temperature affects workability
Strength
high viscosity binder
crushed stone aggregates (interlock)
Pavement Section
ACC Surface
ACC Base
Granular Subbase
Subgrade
Asphalt Pavement Distress
-40 -20 0 20 40 60
Temperature, C
C
o
n
s
i
s
t
e
n
c
y
Cracking
Rutting
Traffic Associated Fatigue
Asphalt Concrete Applications
Roofing,
slurry
composition shingles
Sealants
waterproofing for foundations, etc
electrical insulation
Asphalt Concrete Applications
Pavements
Hot Mixed Asphalt Cement
(asphaltine, resin)
Emulsions (repairs, small jobs)
moist or dry aggregates
hot or cold applications
no fuel or solvents
anionic or cationic
Asphalt Concrete Applications
Cutbacks (on the way out)
RC - flash point in 27C
hard base (hot regions)
MC - safer
softer base (cold regions)
SC - Road Oils
rural roads, sealants
Primary Distress Modes HMA Pavements
Rutting Rutting
Fatigue Cracking Fatigue Cracking
5 - 15 m
Thermal Cracking
Moisture Damage?
Temperature is critical
Temperature Regimes where Distress Predominates
-25 75 50 25 0
Approximate Temperature,

C
C
o
n
s
i
s
t
e
n
c
y
Low-temperature thermal
Shrinkage cracking
Intermediate-temperature
traffic-associated fatigue
High-temperature
rutting
Plexiglas
Salt Water
Taffy
Molasses
THE END
By
Avneesh Koonjul
Avinash Nair
Gaurav Raj
Maya Mohan
Kovid Kalesh
Harsh Aggarwal
Prateek Draik
Joseph Sebastian

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