Radiation Health Series #5
Radiation Health Series #5
Radiation Health Series #5
H E A LT H NO. 5
SERIES
CODE OF PRACTICE FOR THE HANDLING, STORAGE, PACKAGING, TRANSPORTATION AND DISPOSAL OF RADIOACTIVE WASTE
Foreword The Radiation Health Series serves to provide some basic information on the safe use of ionizing radiation in medicine, industry and education in the Hong Kong SAR.
We have prepared these information brochures on the basis of the recommendations made by notable international authorities, such as the International Commission on Radiological Protection (ICRP), World Health Organisation (WHO), International Labour organization (ILO) and International Atomic Energy Agency (IAEA). We hope you find the information useful in safeguarding your own health, as well as the health of your neighbours, when you work with ionizing radiation.
If you have questions on the contents of these documents or have suggestions on improvements, please contact us at the
Radiation Health Unit Department of Health 3/F, Sai Wan Ho Health Centre, 28 Tai Hong Street, Sai Wan Ho, Hong Kong Tel: Fax: e-mail: Domain: 2886 1551 2834 1224 [email protected] http://www.info.gov.hk/dh-rhu
Contents Page Preface 1. General Principles 1.1 Description of radioactive waste 1.2 Physical form of radioactive wastes 1.3 Radioactive waste hazards Responsibilities of the User Handling of Radioactive Wastes Storage of Radioactive Wastes Packaging of Radioactive Wastes Transportation of Radioactive Wastes Disposal of Radioactive Wastes
1 1 1 2 3 5 5 7 7 10 12
2. 3. 4. 5. 6. 7.
Annex A Annex B
Preface This Code of Practice is concerned with the management of radioactive wastes of low levels of radioactivity, or radionuclides of relatively short half-life, such as those generated from medical, industrial and research uses of radioactivity in Hong Kong. The radioactive waste considered in this Code is that which is in the lowest category of activities and which presents such a low hazard to the human body that it is considered safe enough to be disposed of by the user. In Hong Kong, the management of radioactive wastes is controlled by the Radiation Ordinance Cap. 303, Laws of Hong Kong. Any activities involving handling, storage, transportation, packaging and disposal of radioactive wastes shall be approved by the Radiation Board and shall be carried out in such a way that the exposure to persons, besides being kept well within the prescribed limits, is reduced to as low as reasonably achievable. The purpose of this Code is to recommend standard practices, which have been found helpful in achieving the above objectives for small quantities of radioactive waste. Due to the complex nature of the subject it is impractical to include in this Code every detail which can apply to all situations. In such circumstances advice should be sought from the Radiation Board on interpretation and implementation wherever necessary to ensure compliance with the Regulations.
General Principles
1.1 Description of radioactive waste According to the local Radiation Ordinance, radioactive waste means waste radioactive substances or waste material contaminated by radioactive substances or which, having regard to its use, may have become so contaminated. One description as given by the IAEA for legal and regulatory purposes is that radioactive waste is waste that contains or is contaminated with, radionuclides at concentrations or activities greater than clearance levels as established by the regulatory body. 1.2 Physical form of radioactive wastes Airborne Wastes : may be radioactive gases or vapours, or particulate material to which radioactive atoms are attached as contaminants. Liquid Wastes : the usual forms of liquid radioactive wastes are aqueous solutions of radionuclides or suspensions of radioactive material in water or water-miscible liquid. Biological waste in the form of excreta or macerated material can also be regarded and treated as liquid waste. Another category of liquid wastes is that of organic solvents which, because they are flammable or toxic, usually require special methods of disposal. Solid Wastes : Solid wastes can take the forms of sealed sources, unsealed sources and trash. Sealed sources are generally in the form in which they were originally purchased, unsealed sources may include by-products of chemical analysis and residues of bulk supplies of radionuclides, whilst trash includes contaminated packing materials, laboratory glassware, pipette tips, plastic vials and trays, paper tissue, used syringes, tools, etc. 1.3 Radioactive waste hazards
Radioactive waste may present a range of external radiation hazards depending on their activities and emissions and may, if ingested or inhaled, present a variety of internal radiation hazards to the human body dependent upon the nuclide and its chemical and physical forms.
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The user is responsible for: 2.1 Complying with the conditions of his licence and the provisions of the Radiation Ordinance. 2.2 Obtaining the approval of the Radiation Board before disposing of any radioactive waste. When applying for the approval, the user should provide the Radiation Board with details of: - the design of its proposed discharge system - the activities, volumes and types of radionuclides likely to be discharged - the expected frequency of discharge - any other details that the Radiation Board may require 2.3 Seeking approval from the Radiation Board for any changes which might affect the safety of the method of disposal of radioactive waste, with special attention being paid to: - modifications to the plumbing system carrying liquid radioactive effluents - modification to the extraction system for radioactive gaseous products - installation of new inlets for air-conditioning systems or the construction of buildings or building extensions in the vicinity of the outlets of extraction systems for radioactive gases 2.4 Reporting to the Radiation Board of any accident or incident which might have resulted in a discharge of effluent in excess of the approved maximum activity, or in spillage of radioactive waste. 2.5 Informing the Radiation Board of any loss or suspected loss of a radioactive source. 2.6 Maintaining good management procedures and keeping accurate records of the purchase, use, storage and disposal of radioactive materials. 2.7 Providing all the necessary equipment for the safe handling and disposal of all radioactive waste.
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2.8 Providing detailed instructions for the handling of all radioactive waste and ensuring that employees receive, understand and comply with them. 2.9 Storing all radioactive waste in adequately shielded containers or in a secure shielded room as appropriate to the nature of the waste and so as to comply with the dose-rate limitations specified by the Radiation Board. 2.10 Ensuring that all radioactive waste leaving the working area, either as gaseous or liquid effluent released to the environment or sewerage system, does so within the activity limits specified by the Radiation Board. 2.11 Ensuring that all radioactive waste being transported from the premises to the place of disposal or storage is packed and transported so that in the event of an accident, there will be negligible risk to the public. All packaging and transportation should comply with the Regulations for the Safe Transport of Radioactive Material promulgated by the International Atomic Energy Agency.
3.1 Clearly defined working areas and adequate contamination and radiation control are essential components of radioactive waste management and are required to ensure that waste is produced and maintained under conditions appropriate to any subsequent transportation, storage and disposal operation. 3.2 Areas where radioactive materials are handled must be clearly labelled and demarcated in order to limit personal radiation exposures and the spread of contamination. A shoe/clothes change barrier may be required to limit the spread of contamination. Dedicated handwashing facilities should always be provided. 3.3 Suitable radiation/contamination monitoring equipment is also necessary in order to limit personal radiation exposure and the spread of contamination. 3.4 The need to segregate radioactive wastes at source is dictated by subsequent treatment, storage and disposal requirements. Segregation
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of wastes by their physical or chemical properties may be required if the waste is, for example, to be compacted. It may be necessary to segregate radioactive wastes by radionuclide half-life to avoid long term storage and special disposal of unnecessary large quantities of waste. If possible, short half-life (<120 days) waste should be decaystored and disposed of as normal refuse. This disposal option may not be applicable if long-lived radionuclides are present in the waste. Guidelines for segregating both solid and liquid wastes from nonactive wastes are given in Annex A. 3.5 A radiation protection supervisor (RPS) should be appointed to advise on the handling of radionuclides and to coordinate the acquisition and disposal of radioactive materials. The RPS shall be a person who is regularly working in the area and shall receive suitable training on radiation protection. The RPS shall also be familiar with the appropriate guidelines and regulations on radiotoxicity protection and on the safe handling of radionuclides. 3.6 It is essential that suitable radionuclide accountancy and assay systems are employed to determine the radionuclide activities present in the radioactive wastes. This is necessary in order to comply with subsequent transport, storage and disposal requirements. Radioactive wastes may be assayed at source by indirect measurements using, for example, hand held contamination or radiation monitors or by direct measurements using more sophisticated techniques such as alpha or gamma spectrometry or liquid scintillation counting. 3.7 When radioactive waste is moved from one defined radiation/contamination area to another, via an inactive area, it should be labelled and monitored for contamination and radiation levels. The waste package should be supervised at all times, and should not be left unattended in insecure areas unless it is suitable for dustbin disposal. Documentation may be required for complicated movements, and records of the movements may be required for future reference. 3.8 Radiological protection measures required by the Radiation Board include monitoring of handling areas and prohibition of certain activities such as eating, drinking, smoking and the application of cosmetics.
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A store designed to hold radioactive waste temporarily shall meet the following requirements: 4.1 It shall have signs and labels which clearly identify the purpose for which the store is used and shall be secured to avoid unauthorised entry. Appropriate advice to all persons who may enter it, including fire-fighting personnel, shall be clearly displayed at the entrance. The store should not be used for the storage of non-radioactive materials as these may become inadvertently contaminated. 4.2 The store should be dry to avoid deterioration of the waste packages and should be ventilated, if necessary, to remove toxic or radioactive emanation gases. Monitoring facilities should be provided in order to restrict exposure and the spread of radioactive contamination. 4.3 Internal and external dose rates should be in line with the limits specified in the Radiation (Control of Radioactive Substances) Regulations, and be at all times kept as low as reasonably achievable (ALARA), social and economic factors being taken into account. 4.4 Adequate records should be maintained in order to locate and fully identify the stored radioactive waste, and ascertain storage requirements. 4.5 It is important that the disposal of decay-stored solid or liquid waste is adequately controlled by management or assay procedures in order to prevent the occurrence of unauthorised disposals. 4.6 The inside of the store shall be of such material and so designed as to allow for easy decontamination.
5.1 Packaging of radioactive material for transport shall be secure and so designed that the package can be easily handled. The outer layer shall be of such material as to avoid, as far as practicable, the collection and retention of water and finished so that it may be easily decontaminated. When a package requires no visible labelling the outer layer of packaging should be opaque.
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5.2 Radioactive wastes to be disposed of shall be packaged in closed drums, opaque plastic bags or multi-layer bags on the premises of the user before transport. Suggested forms of packaging are: a) For soft materials such as paper, cardboard and textiles, and light solid objects including empty vials and disposable syringes (but not needles or other objects with sharp edges or points): (i) Material contained in a plastic garbage bag (which may have been the liner of a waste receptacle in the working area) and the whole placed in a plastic garbage bag in clean area of the users premises. Both bags are to be securely sealed or, (ii) Materials placed in a multilayer paper bag having a plastic inner liner and the bag securely sealed. b) Syringe needles, pipette tips and any other sharp objects: Be adequately protected by means of an impenetrable sleeve or container so that they will not puncture the outer package. Then depending on the size of the containment, it may be treated as in (a) or (c) below. c) For all materials regardless of size and weight: Material placed in a metal drum having a large plastic bag as a liner and a lid which can be sealed in position. 5.3 Detailed requirement for packaging are set out in the IAEA Regulations for the Safe Transport of Radioactive Material (1996 Edition) and the Supplementary Regulations. The Regulations specify five principal package types of generally increasing radioactivity contents: Excepted, Industrial (IP1, IP2, and IP3), Type A and lastly, Type B and Type C packagings which call for safety requirements outside the scope of this Code. It is necessary to ensure that packages are suitable for the applications involved and that certain minimum design requirements have been satisfied. It is also important to determine whether packages have been subjected to approved tests (such as those required for Type A, for example) and whether re-usable packages are regularly inspected and maintained.
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6.1 Any transportation of radioactive materials in Hong Kong shall be accompanied with a valid Removal Permit issued by the Radiation Board. 6.2 When packages are transported it is essential that they are labelled as specified in the Regulations, and that adequate documentation is supplied to the carriers describing the chemical and physical form of the radioactive material, its radionuclide activities etc. 6.3 Radiation warning label is not required for packages with a surface dose-rate of less than 5Sv/h or meeting the excepted package requirements. However, the inner layer of packaging should be labelled so that the word Radioactive, or the appropriate logo (as shown on the front page of this booklet), is visible when the outer packaging is opened. 6.4 In order to safely move and transport radioactive materials it is necessary to ensure, by direct monitoring techniques, that the surface contamination of the package is less than 0.4Bq/cm2 for beta and gamma emitters, and less than 0.04Bq/cm2 for alpha emitters. If any of these limits is exceeded, the Radiation Board shall be consulted for advice. One method of ensuring that contamination is eliminated is to enclose the package in a clean plastic garbage bag before it is being transported.
7.1 Authorisations for the disposal of solid and liquid radioactive waste are considered on an individual basis, each case being judged on its merits taking into account the needs of the disposer, type of waste, disposal route, destination of the wastes and protection of the environment and the public. Some disposal options are: 7.2 Dust Bin Disposal Small quantities of solid radioactive waste may be authorised for disposal with ordinary refuse provided the activity level is below
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400kBq in any 0.1m3 and less than 40kBq per article. Strontium-90 and alpha emitters are excluded. The limits may be relaxed by a factor of 10 for wastes contaminated solely with carbon-14 and/or tritium. 7.3 Direct to Landfill Within certain limits, and subject to the agreement and approval of the Radiation Board and the Environmental Protection Department (EPD), solid wastes that are too radioactive for dustbin disposal may be disposed of at an approved landfill site by special precautions disposal. In this case, conditions are placed on the containment of the waste, its carriage to the landfill site and its burial procedure. The usual limits placed on activity are that no sack should contain more than 4MBq of radionuclides with a half-life greater than 1 year, with the exception of waste contaminated solely by carbon-14 and/or tritium where the limit is raised to 200MBq per sack (0.1m3), and 40MBq of all other radionuclides. A permit to dispose of the waste is required and certain conditions regarding timing of delivery of the waste to the landfill site may be imposed by the EPD as the authority for the disposal of special wastes at landfills. 7.4 Regardless of the activities of the radionuclides contained in a package, the maximum dose-rate at the surface of the package shall be less than 5 Sv/h and this shall be checked with a survey meter before the package leaves the premises of the user. Disposal to Sewer 7.5 Disposal of organic radioactive wastes, such as liquid scintillation cocktails, to the sewerage reticulation system is not permitted on grounds of chemical and enhanced radiochemical hazards. Whenever possible and practicable liquid wastes should be immobilized and disposed of as solid wastes. This waste treatment system will be authorised on a case by case basis by the Radiation Board 7.6 Disposal to sewer may be considered by the Radiation Board. The waste producer is required to carry out a full safety assessment to establish radiation exposure pathways, identify critical groups (i.e.
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those most at risk form radiation exposure) and compare estimated predicted doses with appropriate safety limits. The safety assessment is necessary to prevent the accumulation of radioactive materials in sewers and drains. Delay storage tanks may be required prior to discharge. The requirements for a delay storage tank are given in Annex B. 7.7 Application for licenses to discharge radioactive waste to the sewer will only be considered after a full safety assessment is carried out and will be subject to periodic review.
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Annex A Segregation of Radioactive Waste by the User It is sensible that the volume of radioactive waste be kept to a minimum and that it be categorised according to its method of disposal at as early a stage as possible. It is therefore advisable that the user sets up the appropriate organisation and educates his staff to achieve this. The user of radioactive material should pay special attention to the management of working areas in which unsealed radioactive materials is used in view of the potential hazards of mishandling such material. A clean, well-ordered working environment, a well-instructed and disciplined staff and clear labels on cupboards, equipment and receptacles for radioactive waste are desirable elements in good management. In planning the working environment, the user should take into account the range of radioactive waste likely to be produced, including the radionuclides which will be disposed of and the physical form and volume of each type of waste. Liquid waste which must be stored should be specified and segregated from that which may be discharged directly to the sewerage system. Solid waste for disposal at the tip should be segregated from that which may require storage. Where liquid radioactive waste is being produced regularly at activities which may conceivably exceed the prescribed discharge limits, sinks connected to a delay tank system should be provided and labelled. These sinks should be restricted to uses involving radioactive waste products. Where the volume of liquid radioactive waste is small, a labelled screw top container in the working area may be adequate. Similarly, one or more fume cupboards should be reserved for work which might involve the release of radioactive gaseous products. Receptacles should be provided for the receipt of various types of radioactive solid waste and these should be clearly and appropriately
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labelled and placed near to where the materials are being handled. The contents of the solid waste receptacles should be packaged for storage or disposal as soon as practicable and the activity and nature of the radioactive materials should be recorded. The use of a plastic garbage bag as the inner liner of the solid waste receptacle is strongly recommended for waste destined for the municipal tip, as this can be sealed when nearly full and, when placed inside a second garbage bag, becomes a durable package suitable for transport and ultimate disposal. In the hospital environment, bed liner which may be contaminated with radioactive materials should remain segregated form other linen and laundered separately under instructions provided by the radiation safety officer in compliance with the requirements of the Radiation Ordinance. Linen and similar material contaminated with radionuclides shall be segregated from non-active waste and be appropriately disposed of as radioactive material. Toilets used by patients being treated with radioiodine should be clearly marked and only used by these patients. The effluent from these toilets should be connected to a holding tank system and be monitored before discharged to the sewerage system.
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Annex B Requirements for a Delay Storage Tank for Liquid Waste Holding tanks are usually constructed in sets of two or more so that one may be filling while the contents of a full one is being sampled, analysed and discharged. Before a tank designed to temporarily hold liquid radioactive waste is constructed, the Radiation Board shall be consulted. The tank shall meet the following general requirements: a) It shall be leak-free and so constructed that it can be expected to remain leak-free. b) It shall have visual indicators of the volume of the contents at any time and have warning devices which operate when the tank is almost full so that the effluent may manually or automatically be switched to fill a second tank. c) It shall be enclosed in a secondary enclosure of sufficient volume to hold the contents if at any time there should be a loss of tank contents. d) It shall have facilities which allow easy withdrawal of representative samples of the contents. e) It shall have a trapdoor to allow visual inspection for the build-up of any internal deposits on the base and sides and to allow access for clearing, should this become necessary. (The incorporation of mechanical agitators to keep the contents in motion during sampling and discharge will reduce the incidence of deposits) f) If the tank holds human or animal wastes, appropriate provision shall be made for sanitary control.
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Radiation Health Series No. 1 Guidance Notes on Diagnostic Radiology Radiation Protection for
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