KSP MCQ

Chapter 17
Name___________________________________
MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question.
1) The pH of a solution that contains 0.818 M acetic acid (Ka = 1.76 10-5) and 0.172 M sodium
1)
acetate is __________.
A) 4.08
B) 8.37
C) 5.43
D) 9.92
E) 8.57
2) Consider a solution containing 0.100 M fluoride ions and 0.126 M hydrogen fluoride. The
concentration of fluoride ions after the addition of 5.00 mL of 0.0100 M HCl to 25.0 mL of this
solution is __________ M.
A) 0.0817
B) 0.0850
C) 0.00253
D) 0.00167
E) 0.0980
3) Consider a solution containing 0.100 M fluoride ions and 0.126 M hydrogen fluoride. The
concentration of hydrogen fluoride after addition of 5.00 mL of 0.0100 M HCl to 25.0 mL of this
solution is __________ M.
A) 0.126
B) 0.107
C) 0.00193
D) 0.100
2)
3)
E) 0.00976
4) The Ka of acetic acid is 1.76 10-5 . The pH of a buffer prepared by combining 50.0 mL of 1.00 M
4)
potassium acetate and 50.0 mL of 1.00 M acetic acid is __________.

A) 4.77
B) 1.70
C) 2.38
D) 0.85
E) 3.40
5) The Kb of ammonia is 1.77 10-5 . The pH of a buffer prepared by combining 50.0 mL of 1.00 M
5)
ammonia and 50.0 mL of 1.00 M ammonium nitrate is __________.

A) 9.37
B) 9.25
C) 7.00
D) 4.63
E) 4.74
6) Calculate the pH of a solution prepared by dissolving 0.370 mol of formic acid (HCO2 H) and 0.230
6)
mol of sodium formate (NaCO2 H) in water sufficient to yield 1.00 L of solution. The Ka of formic
acid is 1.77 10-4 .
A) 3.54
B) 3.95
C) 10.46
D) 2.09
E) 2.30
7) Calculate the pH of a solution prepared by dissolving 0.750 mol of NH3 and 0.250 mol of NH4Cl in
water sufficient to yield 1.00 L of solution. The Kb of ammonia is 1.77 10-4 .
A) 4.27
B) 8.78
C) 0.89
D) 5.22
E) 9.73
7)
8) Calculate the pH of a solution prepared by dissolving 0.250 mol of benzoic acid (C7H5 O2 H) and
8)
0.150 mol of sodium benzoate (NaC7 H5O2 ) in water sufficient to yield 1.00 L of solution. The Ka of
benzoic acid is 6.50 10-5.
A) 4.41
B) 2.39
C) 10.0
D) 4.19
E) 3.97
9) Calculate the pH of a solution prepared by dissolving 0.150 mol of benzoic acid (HBz) and
0.300 mol of sodium benzoate in water sufficient to yield 1.00 L of solution. The Ka of benzoic acid
9)
is 6.50 10-5 .
A) 4.49
B) 4.19
C) 3.89
D) 10.1
E) 2.51
10) The pH of a solution prepared by dissolving 0.350 mol of solid methylamine hydrochloride
(CH3 NH3 Cl) in 1.00 L of 1.10 M methylamine (CH3 NH2 ) is __________. The Kb for methylamine
10)
is 4.40 10-4 .
A) 2.86
B) 1.66
C) 10.2
D) 11.1
E) 10.6
11) A 25.0 mL sample of 0.723 M HClO4 is titrated with a 0.273 M KOH solution. What is the [H+ ]
11)
(molarity) before any base is added?

A) 1.00 10-7
B) 0.439
C) 0.273
D) 2.81 10-13
E) 0.723
12) A 25.0 mL sample of 0.723 M HClO4 is titrated with a 0.273 M KOH solution. The H3 O+
12)
concentration after the addition of 10.0 mL of KOH is __________ M.

A) 0.440
B) 0.723
C) 1.00 10-7
D) 0.273
E) 2.81 10-13
A) 0.439
B) 2.81 10-13
C) 1.00 10-7
D) 0.273
E) 0.723
13)
14)
A) 0.72
B) 2.8 10-13
C) 3.6 10-2
D) 0.44
E) 1.0 10-7
15) The pH of a solution prepared by mixing 50.0 mL of 0.125 M KOH and 50.0 mL of 0.125 M HCl is
__________.
A) 0.00
B) 6.29
C) 8.11
D) 5.78
15)
E) 7.00
16) A 25.0 mL sample of an acetic acid solution is titrated with a 0.175 M NaOH solution. The
equivalence point is reached when 37.5 mL of the base is added. The concentration of acetic acid is
__________ M.
16)
A) 1.83 10-4
B) 0.119
C) 0.263
D) 0.365
E) 0.175
17) A 50.0 mL sample of an aqueous H2 SO4 solution is titrated with a 0.375 M NaOH solution. The
17)
equivalence point is reached with 62.5 mL of the base. The concentration of H2 SO4 is __________
M.
A) 0.938
B) 0.469
C) 0.150
D) 0.300
E) 0.234
18) The concentration of iodide ions in a saturated solution of lead (II) iodide is __________ M. The
solubility product constant of PbI2 is 1.4 10-8 .
A) 1.4 10-8
B) 3.8 10-4
C) 3.5 10-9
D) 1.5 10-3
E) 3.0 10-3
19) The solubility of lead (II) chloride (PbCl2 ) is 1.6 10-2 M. What is the Ksp of PbCl2 ?
A) 3.1 10-7
B) 4.1 10-6
C) 5.0 10-4
D) 1.6 10-2
18)
19)
E) 1.6 10-5
20) The solubility of manganese (II) hydroxide (Mn(OH)2 ) is 2.2 10-5 M. What is the Ksp of Mn
20)
(OH)2 ?
A) 4.8 10-10
B) 1.1 10-14
C) 4.3 10-14
D) 2.1 10-14
E) 2.2 10-5
21) Determine the Ksp for magnesium hydroxide (Mg(OH)2 ) where the solubility of Mg(OH)2 is 1.4
21)
10-4 M.
A) 3.9 10-8
B) 1.1 10-11
C) 2.7 10-12
D) 2.0 10-8
E) 1.4 10-4
22) Calculate the maximum concentration (in M) of silver ions (Ag+) in a solution that contains 0.025 M
of CO3 2- . The Ksp of Ag2CO3 is 8.1 10-12.
22)
A) 8.1 10-12
B) 1.8 10-5
C) 3.2 10-10
D) 1.4 10-6
E) 2.8 10-6
23) What is the solubility (in M) of PbCl2 in a 0.15 M solution of HCl? The Ksp of PbCl2 is 1.6 10-5 .
A) 1.6 10-5
B) 2.0 10-3
C) 1.8 10-4
D) 1.1 10-4
E) 7.1 10-4
24) The Ksp for Zn(OH)2 is 5.0 10-17. Determine the molar solubility of Zn(OH) 2 in a buffer solution
with a pH of 11.5.
A) 1.6 10-14
B) 5.0 106
C) 5.0 10-12
D) 5.0 10-17
E) 1.2 10-12
23)
24)
Answer Key
Testname: CHAPTER 17 PRACTICE
1) A
2) A
3) B
4) A
5) B
6) A
7) E
8) E
9) A
10) D
11) E
12) A
13) C
14) C
15) E
16) C
17) E
18) E
19) E
20) C
21) B
22) B
23) E
24) C

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Chapter 17

potassium acetate and 50.0 mL of 1.00 M acetic acid is __________.

ammonia and 50.0 mL of 1.00 M ammonium nitrate is __________.

(molarity) before any base is added?

concentration after the addition of 10.0 mL of KOH is __________ M.

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