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Name Chapter 1: Structure and Bonding Description Question pool for Chapter 1: Structure and Bonding Instructions

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Question 1

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Question Which is the most electronegative atom in the compound below?

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Carbon Nitrogen Oxygen Bromine Add Question Here

Question 2

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Question Which of the following correctly describes the electrons of a carbon atom in its ground state? Answer 3 s electrons; 3 p electrons 2 1s electrons; 4 2p electrons 2 1s electrons; 2 2s electrons; 2 2p electrons 2 1s electrons; 2 2s electrons; 4 2p electrons None of these choices is correct. Add Question Here

Question 3

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Question Which of the following statements correctly describes the typical bonding of carbon, nitrogen, and oxygen in organic molecules? Answer Carbon participates in 4 covalent bonds, oxygen participates in 2 covalent bonds and nitrogen participates in 5 covalent bonds. Carbon participates in 3 covalent bonds, oxygen participates in 2 covalent bonds and nitrogen participates in 5 covalent bonds. Carbon participates in 4 covalent bonds, oxygen participates in 3 covalent bonds and nitrogen participates in 3 covalent bonds. Carbon participates in 3 covalent bonds, oxygen participates in 3 covalent bonds and nitrogen participates in 5 covalent bonds. Carbon participates in 4 covalent bonds, oxygen participates in 2 covalent bonds and nitrogen participates in 3 covalent bonds. Add Question Here

Question 4

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Question Which is not an acceptable Lewis structure for the anion (CH2NCO)?

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a b c d Add Question Here

Question 5

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Question Which of the following is (are) valid Lewis structure(s) for the anion (HCONCH3) ?

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a b c d e

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Question 6

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Question Which of the following is (are) valid Lewis structure(s) for the anion (CH2NO2)? Assume the atoms are arranged as drawn.

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a b c d e Add Question Here

Question 7

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Question Which is the appropriate conversion of CH3CHClCH2CH(CH3)2 to a skeletal formula?

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a b c d e Add Question Here

Question 8

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Question Convert the following compound from a condensed formula to a skeletal formula: CH3CH2C(CH3)2CH2CH(CH2CH3)CH2CH(CH3)2.

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a b c d e Add Question Here

Question 9

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Question What is the condensed formula of the compound below?

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a b c Add Question Here

Question 10

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Question Convert the following skeletal formula to a condensed formula.

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a b c Add Question Here

Question 11

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Question Which of the following is not a valid Lewis structure of CH3NO2?

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a b c d Add Question Here

Question 12

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Question Which is not a valid resonance structure for the anion below?

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a b c d e Add Question Here

Question 13

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Question How are the molecules in the following pair related?

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They are constitutional isomers. They are resonance structures. They represent the same structure. Add Question Here

Question 14

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Question How are the molecules in the following pair related?

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They are constitutional isomers. They are resonance structures. Neither of the choices is correct. Add Question Here

Question 15

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Question How are the molecules in the following pair related?

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They are constitutional isomers. They are resonance structures. Neither of the choices is correct. Add Question Here

Question 16

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Question How are the molecules in the following pair related?

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Answer

They are constitutional isomers. They are resonance structures. They are unrelated molecules. Add Question Here

Question 17

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Question How are the molecules in the following pair related?

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They are constitutional isomers. They are resonance structures. Neither of the choices is correct. Add Question Here

Question 18

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Question How are the molecules in the following pair related?

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They are constitutional isomers. They are resonance structures. Neither of the choices is correct. Add Question Here

Question 19

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Question How are the molecules in the following pair related?

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They are constitutional isomers. They are resonance structures. Neither of the choices is correct. Add Question Here

Question 20

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Question How are the molecules in the following pair related?

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They are constitutional isomers. They are resonance structures. They are unrelated molecules. Add Question Here

Question 21

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Question How are the molecules in the following pair related?

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They are constitutional isomers. They are resonance structures. Neither of the choices is correct. Add Question Here

Question 22

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Question Which is the most accurate representation of the resonance hybrid for the resonance structures shown below?

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a b c

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d e Add Question Here

Question 23

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Question Which of the following pairs of compounds are resonance structures?

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a b c Add Question Here

Question 24

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Question Which of the following structures are resonance structures of each other?

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a and b b and c a and c All are resonance structures. None of these are resonance structures. Add Question Here

Question 25

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Question What is the hybridization for each of the indicated atoms in the following compound?

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a - sp2; b - sp2; c - sp2 a - sp2; b - sp3; c - sp3 a - sp; b - sp2; c - sp3 a - sp2; b - sp2; c - sp3 Add Question Here

Question 26

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Question Indicate the hybridization of the carbon ion in each compound below.

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a - sp2; b - sp2 a - sp2; b - sp3 a - sp3; b - sp3 a - sp3; b - sp2 Add Question Here

Question 27

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Question Consider the organic molecule drawn below. Describe which orbitals are used to form the C=O bond. Since there are two bonds, you must identify two different sets of orbitals.

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Csp2 Osp2 and Cs Op Csp Osp and Cp Op Csp2 Osp2 and Cs Os Csp3 Osp2 and Cp Op Csp2 Osp2 and C2p O2p

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Question 28

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Question Which of the following compounds has a labeled carbon atom that is sp2 hybridized?

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a b c d e Add Question Here

Question 29

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Question Which of the following compounds contains a labeled atom that is sp hybridized? (All nonbonded electron pairs have been drawn in.)

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a b c d e Add Question Here

Question 30

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Question Which of the compounds drawn below contains an sp2 hybridized carbon atom? Select any and all structures that apply.

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a only b only d only a and b b and c Add Question Here

Question 31

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Question Which of the labeled carbon atoms is (are) sp2 hybridized?

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a b c d e Add Question Here

Question 32

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Question Which statement best describes the orbital hybridization used to form bonds in the cation below?

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The bond between the two carbon atoms is formed between two sp2 hybridized atoms. The bond between the C and N is formed between an sp2 hybridized C and an sp hybridized N. The bond between the two carbons is formed between one sp3 hybridized C and one sp hybridized C. The lone pair of electrons on N is in an sp hybridized orbital. None of the statements is correct. Add Question Here

Question 33

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Question Indicate the formal charge on the B, O, and F atoms in the following compound.

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Answer

B: +1; O: +1; F: 0 B: 1; O: 1; F: 0 B: +1; O: 1; F: 0 B: 1; O: +1; F: 0 None of the choices is correct. Add Question Here

Question 34

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Question In the following compound, indicate the formal charge on all atoms except hydrogen.

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Carbon +1; Oxygen +1; Nitrogen 2 Carbon 1; Oxygen +1; Nitrogen 2 Carbon +1; Oxygen 1; Nitrogen 2 Carbon +1; Oxygen 1; Nitrogen 1 None of the choices is correct. Add Question Here

Question 35

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Question In the following compound, indicate the formal charge on all atoms except hydrogen, from left to right.

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Carbon 0; Nitrogen 1; Carbon +1; Oxygen 0 Carbon 0; Nitrogen 1; Carbon 0; Oxygen 1 Carbon 0; Nitrogen 1; Carbon 0; Oxygen 1 Carbon 0; Nitrogen +1; Carbon 0; Oxygen 1 None of the choices is correct. Add Question Here

Question 36

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Question Which of the following compounds has a labeled atom with a +1 formal charge? (All nonbonded electron pairs have been drawn in.)

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a b c d e Add Question Here

Question 37

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Question Which of the following species has a labeled atom with a +1 formal charge? (All nonbonded electron pairs have been drawn in.)

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a b c d e Add Question Here

Question 38

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Question Which of the following species contains a carbon atom with a +1 formal charge? (All nonbonded electron pairs have been drawn in.)

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a b c d

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e Add Question Here

Question 39

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Question Which of the following species contains a carbon atom with a 1 formal charge? (All nonbonded electron pairs have been drawn in.)

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a b c d e Add Question Here

Question 40

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Question Which of the following species contains an O atom with a +1 formal charge? (All nonbonded electron pairs have been drawn in.)

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a b c d e Add Question Here

Question 41

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Question Which of the following species contains a carbon atom with a +1 formal charge? (All nonbonded electrons and electron pairs have been drawn in.)

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a b c d e Add Question Here

Question 42

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Question Which of the following species has (have) a trigonal planar structure with 120 bond angles around the labeled carbon atom?

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a b c d e Add Question Here

Question 43

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Question Which of the following molecules has (have) a trigonal planar geometry?

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a b c d e Add Question Here

Question 44

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Question Which of the following compounds possess(es) a nitrogen with tetrahedral geometry? Answer CH C N:
3

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NH2 NH4+ CH3C N: and NH2 are both tetrahedral. NH2 and NH4+ are both tetrahedral. Add Question Here

Question 45

Multiple Choice Question Which of the following molecules is (are) polar?

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a b c a and b b and c Add Question Here

Question 46

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Question Which of the following statements is (are) correct? Answer Ethane has sp3 carbon atoms and the geometry around each carbon is trigonal planar. Ethane has sp3 carbon atoms and the geometry around each carbon is tetrahedral. Ethane has sp2 carbon atoms and the geometry around each carbon is tetrahedral. Ethane has sp2 carbon atoms and the geometry around each carbon is trigonal planar. None of the statements are correct. Add Question Here

Question 47

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Question Which of the following statements is (are) correct? Answer The carboncarbon distance in acetylene is longer than in ethylene. The carbonhydrogen bond in acetylene is weaker than the carbonhydrogen bond in ethane. The carboncarbon distance in acetylene is shorter than in ethane. The statements (The carboncarbon distance in acetylene is longer than in ethylene) and (The carbon hydrogen bond in acetylene is weaker than the carbon hydrogen bond in ethane) are correct. The statements (The carbon hydrogen bond in acetylene is weaker than the carbon hydrogen bond in ethane) and (The carboncarbon distance in acetylene is shorter than in ethane) are correct. Add Question Here

Question 48

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Question How many hydrogens are directly bonded to each of the indicated carbon atoms?

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Ca 1; Cb 3; Cc 2 Ca 2; Cb 3; Cc 2 Ca 1; Cb 2; Cc 2 Ca 1; Cb 3; Cc 3 None of the choices is correct. Add Question Here

Question 49

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Question Of the molecules listed, which does not have a dipole moment? Answer HCl NCl3 CO BF3 All molecules have a dipole moment. Add Question Here

Question 50

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Question For the elements Rb, F, and O, the order of increasing electronegativity is: Answer Rb < F < O Rb < O < F O < F < Rb F < Rb < O

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The order cannot be determined. Add Question Here

Question 51

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Question Which of the following Lewis dot structure(s) below bear(s) a positive charge?

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a b c c and d d and e Add Question Here

Question 52

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Question Which of the following species has (have) a trigonal planar structure?

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a, b, and c b and d d b, d, and e All of the choices are correct. Add Question Here

Question 53

Multiple Choice Question What is the molecular shape of methyl anion?

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Answer

Octahedral Tetrahedral Trigonal planar Trigonal pyramidal Linear Add Question Here

Question 54

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Question Enalapril is currently in clinical trials for congestive heart failure, and its structure is given below. What is the correct molecular formula for this interesting antihypertensive agent?

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a b c d e Add Question Here

Question 55

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Question The following compound is a synthetic intermediate in the production of lactacystin. Identify the orbital hybridization and geometry of the atoms next to the three arrows.

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Answer

a sp3; b sp2; c sp3 a sp2; b sp; c sp3 a sp2; b sp3; c sp2 a sp3; b sp2; c sp None of the choices is correct. Add Question Here

Question 56

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Question The following scheme represents an SN1 mechanism for the conversion of alkyl halide a to ether b. Determine the correct structure for intermediate X based on the curved arrow formulism shown.

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a b c d e Add Question Here

Question 57

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Question With reference to compound X drawn below, label each compound as an isomer, a resonance structure or neither.

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a. resonance structure; b. isomer; c. neither; d. isomer a. isomer; b. resonance structure; c. isomer; d. neither a. isomer; b. neither; c. isomer; d. resonance structure a. resonance structure; b. isomer; c. resonance structure; d. isomer None of the choices are correct. Add Question Here

Question 58

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Question Answer the following questions about lidocaine, a commonly used dental anesthetic.

Reference: Ref 1-1

What orbitals are used to form the bond indicated by a? Answer Csp2Csp2 Csp3Csp2 Csp2Csp CspCsp2 Csp3Csp Add Question Here

Question 59

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Question Answer the following questions about lidocaine, a commonly used dental anesthetic.

Reference: Ref 1-1

How many carbon atoms have sp2 hybridization?

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Answer

7 5 6 10 8 Add Question Here

Question 60

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Question Answer the following questions about lidocaine, a commonly used dental anesthetic.

Reference: Ref 1-1

Predict the geometry around the oxygen atom indicated by arrow c. Answer Linear Tetrahedral Trigonal bipyrimidal Trigonal planar Square planar Add Question Here