Polypropelen Glycol

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Development Associates, Inc

300 Old Baptist Rd. N Kingstown, RI 02852 Tel (401) 884-1350 FAX (401) 885-7888 www.developmentassociatesinc.com page 1 of 3

Material Safety Data Sheet


Product Name: Z-8200HG Part A Date: June 2, 2009 Supersedes: May 5, 2008

1. PRODUCT AND COMPANY IDENTIFICATION


Manufacturers Name: Development Associates, Inc. 300 Old Baptist Rd. North Kingstown, RI 02852 Chemtrec (800) 424-9300 24 Hour Z-8200HG Part A Polypropylene glycol, and additive mixture

Emergency Phone No: Product Name: Chemical Family/Name:

2. COMPOSITION / INGREDIENT INFORMATION


Component CAS # % Exposure limits(source) Polyether polyol Trade secret 90-99% none(5) Phenylmecuric Carboxylate 26545-49-3 <0.5 0.1mg/M3 CEL (1,2) Source of Exposure Limit Data: 1. ACGIH Threshold Limit Values 2. Federal OSHA Permissible exposure limit 3. DAI Exposure Guidelines 4. Chemical Manufacturer Recommended Guidelines 5. None Established Abbreviations: n/a-not applicable, n/d-not determined, n/e-not established

3. HAZARDS IDENTIFICATION
HMIS: Health 2, Fire 1, Reactivity 0 Threshold Limit Value: None established by ACGIH or OSHA Routes of Entry: At room temperature primary routes are skin absorption or ingestion. If heated or atomized by inhalation. If the material is heated or atomized the vapors or aerosol may cause exposure via inhalation. Signs and Symptoms of Exposure: Eyes: Redness and irritation Skin: Rash, redness Inhalation: Irritation of the respiratory system Ingestion: Nausea, irritation of digestive track. Acute Effects of Overexposure: Eye Contact: May cause severe eye irritation Ingestion: May cause irritation of gastrointestinal track and nausea. Skin Contact: May cause severe skin irritation. May cause an allergic skin reaction in some individuals. Skin Absorption: Slightly toxic by skin absorption Inhalation: Airborne aerosols or vapors from heated material may cause severe respiratory system irritation. Chronic Effects of Exposure: Chronic dermatitis, organo-mercury compounds can cause severe respiratory system irrritation. Conditions Aggravated by Exposure: Respiratory ailments, dermatitis, other conditions unknown. Carcinogenicity: This product and its constituents are not listed as carcinogens by IARC, NTP or regulated as carcinogens by OSHA at this time.

4. FIRST AID MEASURES


Emergency First Aid Procedures: Eyes: Irrigate with flowing water immediately and continuously for 15 minutes. Obtain medical attention. Swallowing: Give water or milk. Induce vomiting. Call a physician. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. Skin Contact: Remove contaminated clothing. Wash before reusing. Wash affected area well with soap and water. Consult physician. Inhalation: Remove to fresh air. Obtain medical attention.
Rev. Date: 6/2/2009 Rev. 2 Ref: Z8200HGAV2.doc

Development Associates, Inc

MSDS Z8200HG Part A

Page 2 of 3

5. FIRE AND EXPLOSION DATA

Flash Point: 3500F (1750C) TCC Flammable: Limits in Air % Volume: Upper: n/d Lower: n/d Extinguishing Media: Foam, CO+2+, or Dry Chemical Unusual Fire and Explosion Hazards: Do not breathe smoke when burning. Irritating and/or toxic vapors and gasses when burned. Special Fire Fighting Procedures: Fire fighters should wear full emergency equipment including selfcontained breathing apparatus. Do not direct solid stream of water or foam into hot, burning pools. This may cause frothing and increase fire intensity.

6. ACCIDENTAL RELEASE MEASURES


Steps to be Taken in Case Material is Released or Spilled: Contain spills with dams of absorbent material such as Zip Zorb. Absorb material and shovel into drums. Use appropriate safety equipment.

7. HANDLING AND STORAGE


Precautions to be Taken in Storage and Handling: Avoid skin and eye contact. Avoid breathing vapors if generated. Exercise reasonable care and cleanliness. Protect from moisture. Storage Temperatures: <1050F Condition material to 65-1000F before using. Mix well under dry atmosphere before using.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION


Eye Protection: Adequate eye protection as required to prevent contact during handling. i.e. Safety glasses, splash goggles, face shield. Skin Protection: Rubber Gloves, aprons and other protective clothing as required to prevent contact. Remove any contaminated clothing and wash before use. Routinely wash hands, arms and face with soap and water after handling. Do not smoke or eat until hands and face have been washed. Ventilation and Respiratory Protection: Good room ventilation is required. General mechanical ventilation is normally satisfactory. Use organic vapor respirator or supplied air respirator where supplemental protection is needed. Follow OSHA regulations when using personal protective equipment. Other: Eye wash, safety shower.

9. PHYSICAL AND CHEMICAL PROPERTIES


Appearance Color Odor Boiling Range Melting Point Evaporation Rate(BuAcet=1) Vapor Density (air=1) Weight per Gallon Specific Gravity Solubility in Water(%) Percent Volatile clear liquid slight yellow tint mild decomposes over 150oC. super cools, sets to glass <10oC. not volatile n/a 9.14 1.10 very slight negligible

10. STABILITY AND REACTIVITY


Stability Stable Conditions to Avoid High heat (over 225oF) Incompatibility (materials to avoid) Oxidizing materials. Hazardous Polymerization Will not occur. Hazardous Decomposition Products By fire: CO2, CO, mercury vaports, partially decomposed hydrocarbons, other undetermined irritating and or toxic fumes or vapors.

11. TOXICOLOGICAL INFORMATION


Polyether polyol:Skin rabbit LD50: >2000 mg/kg; dermal rat LD50: >2000 mg/kg; ingestion oral rat LD50: >2000 mg/kg. CAS# 26545-49-3 Phenylmecuric-carboxylate CAS# 26545-49-3: Oral rat values of 22-650mg/kg.
Rev. Date: 6/2/2009 Rev. 2 Ref: Z8200HGAV2.doc

Development Associates, Inc

MSDS Z8200HG Part A

Page 3 of 3

12. ECOLOGICAL INFORMATION


Mercury compounds are toxic to wildfile, fish and birds. Avoid contact with feed, food and drinking water. Do no allow into drains or otherwise introduce to soil or groundwater.

13. DISPOSAL CONSIDERATIONS


Waste Disposal Method: If discarded in its purchased form, this product is a toxicity characteristic waste(mercury, D009) according to 40CFR261.21. Under RCRA, it is the responsibility of the product user to determine, at the time of disposal, whether a material is hazardous waste. State and local disposal regulations may differ from federal disposal regulations. Dispose in accordance with all federal, state and local waste disposal laws and regulations.

14. TRANSPORT
D.O.T. Shipping Name Technical Shipping Name D.O.T. Hazard Class UN/NA Number NMFC Item None Z8200HG Part A Polyol, Plastic Related Material Not Regulated None Plastic Material Liquid, NMFC-156240 Class 60

15. REGULATORY
Chemical Inventories: All components of this mixture are listed in the TSCA inventory. TRI: Mercury Compounds N458 are reportable under the TRI program, there is no de minimis for mercury compounds. Reportable threshold for mercury compounds is 10 pounds, the maximum concentration is listed in section 2 of this MSDS. See http://epa.gov/tri/index.htm for more information on the TRI program.

16. OTHER
This data is offered in good faith as typical values and not as a product specification. The information in this data sheet was compiled from information supplied by the vendors of the components of this compound. No warranty, either expressed or implied is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate. The information on this data sheet is only to assist in the safe handling of this material, and may contain trade secrets which may not be divulged to anyone except the users of this material and health care and hygiene professionals as required for its safe use. No license or permission to infringe any patent or breach any trade secret is given.

Rev. Date: 6/2/2009

Rev. 2

Ref: Z8200HGAV2.doc

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