IIT-JEE - 2010 Paper-2

Chemistry Section-1 Single Correct Choice Type This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct. 1. In the reaction T, the structure of the product T is

1)

2)

3)

4)

a a
1) SO3

2. Assuming that Hunds rule is violated, the bond order and magnetic nature of the diatomic molecule B2 is 1) 1 and diamagnetic 2) 0 and diamagnetic 3) 1 and paramagnetic 4) 0 and paramagnetic 3. The species having pyramidal shape is 2) BrF 3 3) SiO324) OSF 2 4. The complex showing a spin-only magnetic moment of 2.82 B.M. is

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1) Ni(CO)4 2) [NiCl4]2 3) Ni(PPh3)4 4) [Ni(CN)4]2 5. The compounds P, Q and S P.

Q.

S.

were separately subjected to nitration using HNO3/H2SO4 mixture. The major product formed in each case respectively, is 1)

2)

a a
4)

3)

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6. The packing efficiency of the two-dimensional square unit cell shown below is

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1) 39.27% 2) 68.02% 3) 74.05% 4) 78.54% Section-2

Integer Type This section contains a group of 5 questions. The answer to each of the questions is a Single-digit Integer, ranging from 0 to 9. The correct digit below the equation number in the ORS is to be bubbled. 7. Among the following, the number of elements showing only one non-zero oxidation state is O, Cl, F, N, P, Sn, Tl, Na, Ti 1) 0 2) 1 3) 2 4) 3 5) 4 6) 5 7) 6 8) 7 9) 8 10) 9

a a
1) 0 2) 1 3) 2 4) 3 5) 4 6) 5 7) 6 8) 7 9) 8 10) 9

8. The total number of diprotic acids among the following is H3PO4 H2SO4 H3PO3 H2CO3 H2S2O7 H3BO3 H3PO2 H2CrO4 H2SO3

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9. One mole of an ideal gas is taken from a to b along two paths denoted by the solid and the dashed lines as shown in the graph below. If the work done along the solid line path is Ws and that along the

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dotted line path is Wd, then the integer closest to the ratio Wd/Ws is

1) 0 2) 1 3) 2 4) 3 5) 4 6) 5 7) 6 8) 7 9) 8 10) 9

10. Total number of geometrical isomers for the complex [RhCl(CO)(PPh3)(NH3)] is 1) 0 2) 1 3) 2

a a
5) 4 6) 5 7) 6 8) 7 9) 8 10) 9 1) 0 2) 1 3) 2 4) 3 5) 4 6) 5 7) 6

4) 3

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11. Silver (atomic weight = 108 g mol1) has a density of 10.5 g cm 3. The number of silver atoms on a surface of area 1012 m 2 can be expressed in scientific notation as y 10x. The value of x is

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8) 7 9) 8 10) 9 Section-3 Paragraph Type This section contains 2 paragraphs. Based upon each of the paragraphs 3 multiple choice questions have to be answered. Each of these questions has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct. Directions for question 12 to 14 : The hydrogen-like species Li2+ is in a spherically symmetric state S1 with one radial node. Upon absorbing light the ion undergoes transition to a state S2. The state S2 has one radial node and its energy is equal to the ground state energy of the hydrogen atom. 12. The state S1 is 1) 1s 2) 2s 3) 2p 4) 3s

13. Energy of the state S1 in units of the hydrogen atom ground state energy is 1) 0.75 2) 1.50 3) 2.25

14. The orbital angular momentum quantum number of the state S2 is 1) 0 2) 1 3) 2

Directions for question 15 to 17 :

Two aliphatic aldehydes P and Q react in the presence of aqueous K2CO3 to give compound R, which upon treatment with HCN provides compound S. On acidification and heating, S gives the product shown below :

15. The compounds P and Q respectively are

a a
1) 2) 3)

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4) 4.50 4) 3

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4)

16. The compound R is 1)

2)

3)

4)

17. The compound S is

a a
2) 3)

1)

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4)

Section-4 Matrix Type This section contains 2 questions. Each question has four choices (A), (B), (C) and (D) given in Column I and five statements (p), (q), (r), (s) and (t) in Column II. Any given statement in Column I can have correct matching with one or more statement(s) given in Column II. For example, if for a given question, statement B matches with the statements given in (q) and (r), then for that particular question, against statement B, darken the bubbles corresponding to (q) and (r) in ORS. 18. All the compounds listed in Column I react with water. Match the result of the respective reactions with the appropriate options listed in Column II. Column I Column II A (CH3)2SiCl2 B XeF 4 C Cl2 D VCl5 p Hydrogen halide formation q Redox reaction r t 1) A-p 2) A-q 3) A-r 4) A-s 5) A-t 6) B-p 7) B-q 8) B-r 9) B-s Reacts with glass O2 formation s Polymerization

a a
10) B-t 11) C-p 12) C-q 13) C-r 15) C-t 16) D-p 17) D-q 18) D-r 19) D-s 20) D-t 14) C-s

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19. Match the reactions in Column I with appropriate option in Column II. Column I A p

Column II Racemic mixture

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Addition reaction

Substitution reaction Coupling reaction Carbocation intermediate

s t

1) A-p 2) A-q 3) A-r 4) A-s 5) A-t 6) B-p 7) B-q 8) B-r 9) B-s 10) B-t 11) C-p 12) C-q 13) C-r 14) C-s 15) C-t 16) D-p 17) D-q

a a
19) D-s 20) D-t all x 1) 1

18) D-r

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Mathematics Section-1

Single Correct Choice Type This section contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct. 20. Let f be a real-valued function defined on the interval (-1, 1) such that e-x f(x) = 2 + (1, 1), and let f1 be the inverse function of f. Then (f1) (2) is equal to 2) 1/3 3) 1/2 4) 1/e dt, for

21. A signal which can be green or red with probability (4/5) and (1/5) respectively, is received by station A and then transmitted to station B. The probability of each station receiving the signal correctly is (3/4). If the signal received at station B is green, then the probability that the original signal was green

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is 1) 3/5 2) 6/7 3) 20/23 4) 9/20

22. Let S = {1, 2, 3, 4}. The total number of unordered pairs of disjoint subsets of S is equal to 1) 25 2) 34 3) 42 4) 41

23. For r = 0, 1,....., 10, let Ar, Br and Cr denote, respectively, the coefficient of xr in the expansions of (1 + x)10, (1 + x)20 and (1 + x)30. Then 1) B10 C10 2) A10(B210 C10A10) 3) 0 4) C10 B10 (B10Br - C10Ar) is equal to

24. If the distance of the point P(1, 2, 1) from the plane x + 2y 2z = where > 0, is 5, then the foot , of the perpendicular from P to the plane is 1) (8/3, 4/3, -(7/3)) 2) (4/3, -(4/3), 1/3) 3) (1/3, 2/3, 10/3) 4) (2/3, -(1/3), 5/2)

25. Two adjacent sides of a parallelogram ABCD are given by AB = 2i + 10j + 11k and AD = -i + 2j + 2k. The side AD is rotated by an acute angle in the plane of the parallelogram so that AD becomes AD. If AD makes a right angle with the side AB, then the cosine of the angle is given by 1) 8/9 2) (17)/9 3) 1/9 4) 4(5)/9

Integer Type This Section contains 5 questions. The answer to each question is a single-digit integer, ranging from 0 to 9. The correct digit below the question no. in the ORS is to be bubbled. 26. Let f be a function defined on R (the set of all real numbers) such that f ' (x) = 2010 (x 2009) (x 2010)2 (x 2011)3 (x 2012)4, for all x R. If g is a function defined on R with values in the interval (0, ) such that f(x) = ln (g(x)), for all x then the number of points in R at which g has a local maximum is 1) 0 2) 1 3) 2 4) 3 5) 4 6) 5 7) 6 8) 7

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Section-2

R,

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9) 8 10) 9 27. Two parallel chords of a circle of radius 2 are at a distance (3) + 1 apart. If the chords subtend at the center, angles of (/k) and (2/k), where k > 0, then the value of [k] is [Note : [k] denotes the largest integer less than or equal to k] 1) 0 2) 1 3) 2 4) 3 5) 4 6) 5 7) 6 8) 7 9) 8 10) 9 28. Let k be a positive real number and let

If det (adj A) + det(adj B) = 106, then [k] is equal to [Note : adj M denotes the adjoint of a square matrix M and [k] denotes the largest integer less than or equal to k] 1) 0 2) 1 3) 2 4) 3 5) 4 6) 5 7) 6 8) 7 9) 8

29. Consider a triangle ABC and let a, b and c denote the lengths of the sides opposite to vertices A, B and C respectively. Suppose a = 6, b = 10 and the area of the triangle is 153. If ACB is obtuse and if r denotes the radius of the incircle of the triangle, then r2 is equal to 1) 0 2) 1 3) 2 4) 3 5) 4 6) 5 7) 6 8) 7 9) 8 10) 9

a a
10) 9

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10) 9 30. Let a1, a2, a3,......, a11 be real numbers satisfying a1 = 15, 27 2a2 > 0 and ak = 2ak 1 ak 2 for k = 3, 4,....., 11.

then the value of 1) 0 2) 1 3) 2 4) 3 5) 4 6) 5 7) 6 8) 7 9) 8 10) 9

is equal to

Section-3

Paragraph Type This section contains 2 paragraphs. Based upon each of the paragraphs 3 multiple choice questions have to be answered. Each of these question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct. Directions for question 31 to 33 : Tangents are drawn from the point P(3, 4) to the ellipse (x2/9) + (y2/4) = 1 touching the ellipse at points A and B. 31. The coordinates of A and B are 1) (3, 0) and (0, 2) 2)

a a
3) 4)

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32. The orthocentre of the triangle PAB is 1) (5, 8/7) 2) (7/5, 25/8) 3) (11/5, 8/5) 4) (8/25, 7/5) 33. The equation of the locus of the point whose distances from the point P and the line AB are equal, is 1) 9x2 + y2 6xy 54x 62y + 241 = 0 2) x2 + 9y2 + 6xy 54x + 62y 241 = 0 3) 9x2 + 9y2 6xy 54x 62y 241 = 0

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4) x2 + y2 2xy + 27x + 31y 120 = 0 Directions for question 34 to 36 : Consider the polynomial f(x) = 1 + 2x + 3x2 + 4x3. Let s be the sum of all distinct real roots of f(x) = 0 and let t = |s|. 34. The real number s lies in the interval 1) (-(1/4), 0) 2) (-11, -(3/4)) 3) (-(3/4), -(1/2)) 4) (0, 1/4) 35. The area bounded by the curve y = f(x) and the lines x = 0, y = 0 and x = t, lies in the interval 1) (3/4, 3) 2) (21/64, 11/16) 3) (9, 10) 4) (0, 21/64) 36. The function f(x) is 1) Increasing in (-t, -(1/4)) and decreasing in (-(1/4), t) 2) Decreasing in (-t, -(1/4)) and increasing in (-(1/4), t) 3) Increasing in (t, t) 4) Decreasing in (t, t)

Matrix Type This Section contains 2 questions. Each question has four statements (A, B, C and D) given in Column I and five statements (p, q, r, s and t) in Column II. Any given statement in Column I can have correct matching with one or more statement(s) given in Column II. For example, if for a given question, statement B matches with the statements given in q and r, then for that particular question, against statement B, darken the bubbles corresponding to q and r in the ORS. 37. Match the statements in Column-I with the values in Column-II. Column-I

a a
A B C

A line from the origin meets the lines and at P and Q respectively. If length PQ = d, then d2 is The values of x satisfying tan-1(x + 3) tan-1(x 3) = sin-1 (3/5) are Non-zero vectors a, b and c satisfy a . b = 0, (b a) . (b + c) = 0 and 2 |b + c| = |b a|. If a = b + 4c, then the possible values of are Let f be the function on [, ] given by f(0) = 9 and f(x) = sin (9x/2) / sin(x/2) for x 0. The value of dx is p -4

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Column-II

q r

0 4

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t 1) A-p 2) A-q 3) A-r 4) A-s 5) A-t 6) B-p 7) B-q 8) B-r 9) B-s 10) B-t 11) C-p 12) C-q 13) C-r 14) C-s 15) C-t 16) D-p 17) D-q 18) D-r 19) D-s 20) D-t

38. Match the statements in Column-I with those in Column-II. [Note: Here z takes values in the complex plane and lm z and Re z denote, respectively, the imaginary part and the real part of z.] Column-I Column-II The set of points z satisfying A p An ellipse with eccentricity (4/5) | z i | z || = | z + i | z || is contained in or equal to The set of points z satisfying B q The set of points z satisfying lm z = 0 | z + 4 | + | z 4 | = 10 is contained in or equal to If |w| = 2, then the set of points C r The set of points z satisfying |lm z| 1 z = w (1/w) is contained in or equal to If |w| = 1, then the set of points D s The set of points z satisfying |Re z| 2 z = w + (1/w) is contained in or equal to t The set of points z satisfying |z| 3

a a
1) A-p 2) A-q 3) A-r 4) A-s 5) A-t 6) B-p 7) B-q 8) B-r 9) B-s 10) B-t 11) C-p 12) C-q

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13) C-r 14) C-s 15) C-t 16) D-p 17) D-q 18) D-r 19) D-s 20) D-t Physics Section-1 Single Correct Choice Type This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct. 39. A biconvex lens of focal length 15 cm is in front of a plane mirror. The distance between the lens and the mirror is 10 cm. A small object is kept at a distance of 30 cm from the lens. The final image is 1) Virtual and at a distance of 16 cm from the mirror 2) Real and at a distance of 16 cm from the mirror 3) Virtual and at a distance of 20 cm from the mirror 4) Real and at a distance of 20 cm from the mirror

40. A uniformly charged thin spherical shell of radius R carries uniform surface charge density per of unit area. It is made of two hemispherical shells, held together by pressing them with force F (see figure). F is proportional to

1) (1/ 0) 2R2

a a

2) (1/ 0) 2R

3) (1/ 0) (2/R)

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4) (1/ 0) (2/R2)

41. A hollow pipe of length 0.8 m is closed at one end. At its open end a 0.5 m long uniform string is vibrating in its second harmonic and it resonates with the fundamental frequency of the pipe. If the tension in the wire is 50 N and the speed of sound is 320 ms1, the mass of the string is 1) 5 grams 2) 10 grams 3) 20 grams 4) 40 grams 42. A Vernier calipers has 1 mm marks on the main scale. It has 20 equal divisions on the Vernier scale which match with 16 main scale divisions. For this Vernier calipers, the least count is 1) 0.02 mm 2) 0.05 mm

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3) 0.1 mm 4) 0.2 mm 43. A block of mass 2 kg is free to move along the x-axis. It is at rest and from t = 0 onwards it is subjected to a time-dependent force F(t) in the x direction. The fore F(t) varies with t as shown in the figure. The kinetic energy of the block after 4.5 seconds is

1) 4.50 J 2) 7.50 J 3) 5.06 J 4) 14.06 J

44. A tiny spherical oil drop carrying a net charge q is balanced in still air with a vertical uniform electric field of strength (81 /7) 10 5 Vm -1. When the field is switched off, the drop is observed to fall with terminal velocity 2 103 ms1. Given g = 9.8 ms2, viscosity of the air = 1.8 105 Ns m 2 and the density of oil = 900 kg m 3, the magnitude of q is 1) 1.6 1019 C 2) 3.2 1019 C 3) 4.8 1019 C 4) 8.0 1019 C

Integer Type This section contains 5 questions. The answer to each of the questions is a single-digit integer, ranging from 0 to 9. The correct digit below the question number in the ORS is to be bubbled.

45. Image of an object approaching a convex mirror of radius of curvature 20 m along its optical axis is observed to move from (25/3) m to (50/7) m in 30 seconds. What is the speed of the object in km per hour ? 1) 0 2) 1 3) 2 4) 3 5) 4 6) 5 7) 6 8) 7 9) 8 10) 9 46. A diatomic ideal gas is compressed adiabatically to (1/32) of its initial volume. If the initial temperature

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of the gas is T i (in kelvin) and the final temperature is aT i, the value of a is 1) 0 2) 1 3) 2 4) 3 5) 4 6) 5 7) 6 8) 7 9) 8 10) 9 47. To determine the half life of a radioactive element, a student plots a graph of |dN(t)/dt| versus t. Here (dN(t)/dt) is the rate of radioactive decay at time t. If the number of radioactive nuclei of this element decreases by a factor of p after 4.16 years, the value of p is

1) 0 2) 1 3) 2 4) 3 5) 4 6) 5

a a
7) 6 8) 7 9) 8 10) 9

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48. At time t = 0, a battery of 10 V is connected across points A and B in the given circuit. If the capacitors have no charge initially, at what time (in seconds) does the voltage across them become 4 V? [Take : ln 5 = 1.6, ln 3 = 1.1]

1) 0 2) 1 3) 2

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4) 3 5) 4 6) 5 7) 6 8) 7 9) 8 10) 9 49. A large glass slab ( = 5/3) of thickness 8 cm is placed over a point source of light on a plane surface. It is seen that light emerges out of the top surface of the slab from a circular area of radius R cm. What is the value of R? 1) 0 2) 1 3) 2 4) 3 5) 4 6) 5 7) 6 8) 7 9) 8 10) 9

Section-3

Paragraph Type This section contains 2 paragraphs. Based upon each of the paragraphs 3 multiple choice questions have to be answered. Each of these questions has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct. Directions for question 50 to 52 : The key feature of Bohrs theory of spectrum of hydrogen atom is the quantization of angular momentum when an electron is revolving around a proton. We will extend this to a general rotational motion to find quantized rotational energy of a diatomic molecule assuming it to be rigid. The rule to be applied is Bohrs quantization condition. the nth level (n = 0 is not allowed) is 1) (1/n2) (h2/82l) 2) (1/n) (h2/82l) 3) n (h2/82l) 4) n2 (h2/82l) 51. It is found that the excitation frequency from ground to the first excited state of rotation for the CO molecule is close to (4/ ) 10 11 Hz. Then the moment of inertia of CO molecule about its centre of mass is close to (Take h = 2 1034 J s) 1) 2.76 1046 kg m 2 2) 1.87 1046 kg m 2 3) 4.67 1047 kg m 2 4) 1.17 1047 kg m 2

50. A diatomic molecule has moment of inertia l. By Bohrs quantization condition its rotational energy in

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52. In a CO molecule, the distance between C (mass = 12 a.m.u.) and O (mass = 16 a.m.u.), where 1 a.m.u. = (5/3) 10-27 kg, is close to 1) 2.4 1010 m 2) 1.9 1010 m 3) 1.3 1010 m 4) 4.4 1011 m Directions for question 53 to 55 : When liquid medicine of density is to be put in the eye, it is done with the help of a dropper. As the bulb on the top of the dropper is pressed, a drop forms at the opening of the dropper. We wish to estimate the size of the drop. We first assume that the drop formed at the opening is spherical because that requires a minimum increase in its surface energy. To determine the size, we calculate the net vertical force due to the surface tension T when the radius of the drop is R. When this force becomes smaller than the weight of the drop, the drop gets detached from the dropper. 53. If the radius of the opening of the dropper is r, the vertical force due to the surface tension on the drop of radius R(assuming r << R) is 1) 2rT 2) 2RT 3) 2r2T/R 4) 2r2T/r

54. If r = 5 104 m, = 103 kgm 3, g = 10 ms2, T = 0.11 Nm 1, the radius of the drop when it detaches from the dropper is approximately 1) 1.4 103 m 2) 3.3 103 m 3) 2.0 103 m 4) 4.1 103 m

55. After the drop detaches, its surface energy is

a a

1) 1.4 106 J 2) 2.7 106 J 3) 5.4 106 J 4) 8.1 106 J

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Section-4

Matrix Type This section contains 2 questions. Each Question has four statements (A, B, C and D) given in Column I and five statements (p, q, r, s and t) in Column II. Any given statement in Column I can have correct matching with one or more statement(s) given in Column II. For example, if for a given question, statement B matches with the statements given in q are r, then for that particular question, against statement B, darken the bubble corresponding to q and r in the ORS. 56. You are given many resistances, capacitors and inductors. These are connected to a variable DC voltage source (the first two circuits) or an AC voltage source of 50 Hz frequency (the next three circuits) in different ways as shown in Column II. When a current I (steady state for DC or rms for AC) flows through the circuit, the corresponding voltage V1 and V2. (indicated in circuits) are related as shown in Column I. Column I Column II

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A I 0, V1 is proportional to I

B I 0, V2 > V1

C V1 = 0, V2 = V

D I 0, V2 is proportional to I

1) A-p 2) A-q 3) A-r 4) A-s 5) A-t

a a
6) B-p 7) B-q 8) B-r 9) B-s 10) B-t 11) C-p 12) C-q 13) C-r 14) C-s 15) C-t 16) D-p 17) D-q 18) D-r 19) D-s 20) D-t

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57. Two transparent media of refractive indices 1 and 3 have a solid lens shaped transparent material of refractive index 2 between them as shown in figures in Column II. A ray traversing these media is also shown in figures. In Column I different relationships between them to the ray diagrams shown in Column II. Column I Column II A 1 < 2 p
1 , 2 and 3 are given. Match

1 > 2

2 = 3

2 > 3

1) A-p 2) A-q 3) A-r 4) A-s 5) A-t 6) B-p 7) B-q 8) B-r

a a
10) B-t 11) C-p 12) C-q 13) C-r 15) C-t 16) D-p 17) D-q 18) D-r 19) D-s 20) D-t 14) C-s

9) B-s

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Answer Key 1) 3 2) 1 3) 4 4) 2 5) 3 6) 4 11) 8 12) 2 13) 3 14) 2 15) 2 16) 1 21) 3 22) 4 23) 4 24) 1 25) 2 26) 2 31) 4 32) 3 33) 1 34) 3 35) 1 36) 2 41) 2 42) 4 43) 3 44) 4 45) 4 46) 5 7) 3 17) 4 27) 4 37) 5,6,8,12,18 47) 9 8) 7 18) 1,4,6,7,8,10,11,12,16 28) 5 48) 3 9) 3 29) 4 49) 3 10) 4 30) 1 40) 1 50) 4

19) 3,4,10,11,12,18 20) 2

38) 2,3,6,11,14,15,17,18,19,20 39) 2

51) 2 52) 3 53) 3 54) 1 55) 2 56) 3,4,5,7,8,9,10,11,12,17,18,19,20 57) 1,3,7,9,10,11,13,15,17,19

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